FI64751C - Foerfarande foer katalytisk oxidering av en aromatisk karboxylsyra till motsvarande fenol - Google Patents

Foerfarande foer katalytisk oxidering av en aromatisk karboxylsyra till motsvarande fenol Download PDF

Info

Publication number: FI64751C
Authority: FI; Finland
Prior art keywords: catalyst; process according; carboxylic acid; zirconium; catalytic
Prior art date: 1977-11-21

Application number

FI783262A

Other languages

English (en)

Finnish (fi)

Other versions

FI783262A7 (fi

FI64751B (fi

Inventor

Abraham Perry Gelbein

Ali Mohammad Khonsari

Original Assignee

Lummus Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-11-21

Filing date

1978-10-26

Publication date

1984-01-10

1978-10-26 Application filed by Lummus Co filed Critical Lummus Co

1979-05-22 Publication of FI783262A7 publication Critical patent/FI783262A7/fi

1983-09-30 Application granted granted Critical

1983-09-30 Publication of FI64751B publication Critical patent/FI64751B/fi

1984-01-10 Publication of FI64751C publication Critical patent/FI64751C/fi

Links

ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title claims description 9
230000003197 catalytic effect Effects 0.000 title claims description 5
239000003054 catalyst Substances 0.000 claims description 23
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 17
238000000034 method Methods 0.000 claims description 15
239000010949 copper Substances 0.000 claims description 12
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 10
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 10
229910052802 copper Inorganic materials 0.000 claims description 10
229910052726 zirconium Inorganic materials 0.000 claims description 10
229910052783 alkali metal Inorganic materials 0.000 claims description 9
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 9
150000001340 alkali metals Chemical class 0.000 claims description 8
230000003647 oxidation Effects 0.000 claims description 7
238000007254 oxidation reaction Methods 0.000 claims description 7
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
239000001301 oxygen Substances 0.000 claims description 6
229910052760 oxygen Inorganic materials 0.000 claims description 6
PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical group [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
239000005711 Benzoic acid Substances 0.000 claims description 5
125000003118 aryl group Chemical group 0.000 claims description 5
235000010233 benzoic acid Nutrition 0.000 claims description 5
QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 claims 1
150000001559 benzoic acids Chemical class 0.000 claims 1
229930003836 cresol Natural products 0.000 claims 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 7
-1 aromatic carboxylic acids Chemical class 0.000 description 6
239000007791 liquid phase Substances 0.000 description 4
150000002989 phenols Chemical class 0.000 description 4
230000000694 effects Effects 0.000 description 3
239000000243 solution Substances 0.000 description 3
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
239000008187 granular material Substances 0.000 description 2
238000005470 impregnation Methods 0.000 description 2
239000000463 material Substances 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
239000000203 mixture Substances 0.000 description 2
150000002823 nitrates Chemical class 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
239000007787 solid Substances 0.000 description 2
239000007858 starting material Substances 0.000 description 2
125000001424 substituent group Chemical group 0.000 description 2
239000012808 vapor phase Substances 0.000 description 2
MHCVCKDNQYMGEX-UHFFFAOYSA-N 1,1'-biphenyl;phenoxybenzene Chemical compound C1=CC=CC=C1C1=CC=CC=C1.C=1C=CC=CC=1OC1=CC=CC=C1 MHCVCKDNQYMGEX-UHFFFAOYSA-N 0.000 description 1
229910000619 316 stainless steel Inorganic materials 0.000 description 1
239000005751 Copper oxide Substances 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
239000000956 alloy Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
238000001354 calcination Methods 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
229910000431 copper oxide Inorganic materials 0.000 description 1
150000001896 cresols Chemical class 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
229910001882 dioxygen Inorganic materials 0.000 description 1
238000004821 distillation Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
239000007789 gas Substances 0.000 description 1
125000001475 halogen functional group Chemical group 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
238000002156 mixing Methods 0.000 description 1
125000001624 naphthyl group Chemical group 0.000 description 1
239000005416 organic matter Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000012071 phase Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
238000011084 recovery Methods 0.000 description 1
229910010271 silicon carbide Inorganic materials 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
239000002918 waste heat Substances 0.000 description 1
239000002699 waste material Substances 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions decreasing the number of carbon atoms
- C07C37/56—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions decreasing the number of carbon atoms by replacing a carboxyl or aldehyde group by a hydroxy group
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Catalysts (AREA)

FI783262A 1977-11-21 1978-10-26 Foerfarande foer katalytisk oxidering av en aromatisk karboxylsyra till motsvarande fenol FI64751C (fi)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US85304077A	1977-11-21	1977-11-21
US85304077		1977-11-21

Publications (3)

Publication Number	Publication Date
FI783262A7 FI783262A7 (fi)	1979-05-22
FI64751B FI64751B (fi)	1983-09-30
FI64751C true FI64751C (fi)	1984-01-10

Family

ID=25314866

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FI783262A FI64751C (fi)	1977-11-21	1978-10-26	Foerfarande foer katalytisk oxidering av en aromatisk karboxylsyra till motsvarande fenol

Country Status (9)

Country	Link
JP (1)	JPS5920384B2 (fr)
AU (1)	AU520114B2 (fr)
CA (1)	CA1098888A (fr)
DE (1)	DE2844195C2 (fr)
FI (1)	FI64751C (fr)
FR (1)	FR2409086A1 (fr)
GB (1)	GB1602669A (fr)
IT (1)	IT1106056B (fr)
NL (1)	NL7810528A (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
ES502219A0 (es) *	1980-05-16	1982-10-01	Stamicarbon	Metodo para la preparacion de fenol sustituido o no susti- tuido
US4390736A (en) *	1980-11-26	1983-06-28	Sumitomo Chemical Company, Limited	Process for producing phenols

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
BE637598A (fr) *	1962-09-21	1964-03-19	Shell Int Research	Procédé pour la transformation d'acides carboxyliques aromatiques en composés phénoliques, préparation d'un catalyseur approprié et nouveaux produits ainsi obtenus

1978
- 1978-05-30 GB GB24190/78A patent/GB1602669A/en not_active Expired
- 1978-09-13 CA CA311,277A patent/CA1098888A/fr not_active Expired
- 1978-09-18 AU AU39929/78A patent/AU520114B2/en not_active Expired
- 1978-10-11 JP JP53125016A patent/JPS5920384B2/ja not_active Expired
- 1978-10-11 DE DE2844195A patent/DE2844195C2/de not_active Expired
- 1978-10-20 NL NL7810528A patent/NL7810528A/xx not_active Application Discontinuation
- 1978-10-26 FI FI783262A patent/FI64751C/fi not_active IP Right Cessation
- 1978-11-03 IT IT51770/78A patent/IT1106056B/it active
- 1978-11-15 FR FR7832229A patent/FR2409086A1/fr active Granted

Also Published As

Publication number	Publication date
DE2844195A1 (de)	1979-05-23
JPS5920384B2 (ja)	1984-05-12
FR2409086A1 (fr)	1979-06-15
CA1098888A (fr)	1981-04-07
NL7810528A (nl)	1979-05-23
JPS5472789A (en)	1979-06-11
AU520114B2 (en)	1982-01-14
AU3992978A (en)	1980-03-27
FR2409086B3 (fr)	1981-09-04
FI783262A7 (fi)	1979-05-22
DE2844195C2 (de)	1985-02-14
IT1106056B (it)	1985-11-11
FI64751B (fi)	1983-09-30
GB1602669A (en)	1981-11-11
IT7851770A0 (it)	1978-11-03

Legal Events

Date	Code	Title	Description
2004-08-31	MM	Patent lapsed	Owner name: THE LUMMUS CO

Publication	Publication Date	Title
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Fu et al.	1997	Two-step synthesis of diphenyl carbonate from dimethyl carbonate and phenol using MoO3SiO2 catalysts
EP0043100B1 (fr)	1984-09-12	Catalyseur d'oxydation et son procédé de préparation
US4329517A (en)	1982-05-11	Process for production of mono- or di-ortho-methyl-substituted phenols by catalytic methylation and catalyst therefor
Bernhardt et al.	2010	Solvent-free and time-efficient Suzuki–Miyaura reaction in a ball mill: the solid reagent system KF–Al2O3 under inspection
SU436486A3 (ru)	1974-07-15	Способ получения ненасыщенной карбоновой кислоты
CN102625793A (zh)	2012-08-01	用于部分氧化烃的催化剂和方法
US4201880A (en)	1980-05-06	Preparation of ortho-alkylated phenols
US3893951A (en)	1975-07-08	Catalysts for oxidation reactions
PL83243B1 (fr)	1975-12-31
FI64751C (fi)	1984-01-10	Foerfarande foer katalytisk oxidering av en aromatisk karboxylsyra till motsvarande fenol
JPS60172352A (ja)	1985-09-05	炭酸マンガンから調製された触媒前駆体および活性触媒とオルトアルキル化フエノ−ルの製法
RU2186055C2 (ru)	2002-07-27	Способ получения производных 3-карбокси-4-гидроксибензальдегида, способ получения 4-гидроксибензальдегида, способы получения ванилина и этилванилина
US4415752A (en)	1983-11-15	Process for preparing unsaturated acids with Mo, V, Nb, Fe-containing catalysts
US4333858A (en)	1982-06-08	Catalyst with Mo, V, Ti and process
US4048239A (en)	1977-09-13	Process for the ortho alkylation of phenols using aldehydes and hydrogen in the presence of a copper-chromium catalyst
CA1045106A (fr)	1978-12-26	Catalyseur au mo, v et ti, et procede pour la preparation d'acides insatures
EP0146099A2 (fr)	1985-06-26	Procédé de préparation d'acide acrylique par oxidation de l'acroléine ainsi qu'un nouveau catalyseur pour ledit procédé
EP0100057B1 (fr)	1986-02-26	Procédé de production d'acide méthacrylique et/ou d'ester d'acide méthacrylique
KR20030036171A (ko)	2003-05-09	저 올레핀을 불포화 알데히드로 산화하기 위한 촉매, 그제조방법 및 그 이용
JPH07324080A (ja)	1995-12-12	エチレンオキシドの製造方法
NL194001C (nl)	2001-04-03	Werkwijze voor bereiden van gesubstitueerd benzaldehyde.
EP0228275B1 (fr)	1991-03-13	Procédé pour la préparation de p-méthoxybenzaldéhyde
BE1005723A5 (fr)	1993-12-28	Systeme catalytique pour l'oxydation selective de compose organique et procede de preparation d'un tel systeme.
US4165439A (en)	1979-08-21	Process for the selective ortho-alkylation of a phenol in the presence of a copper-chromium catalyst