FI68341C - Vattenhaltig dispersion-mikrobicid-komposition som innehaollermetylenbis(tiocyanat) och dess anvaendning - Google Patents
Vattenhaltig dispersion-mikrobicid-komposition som innehaollermetylenbis(tiocyanat) och dess anvaendning Download PDFInfo
- Publication number
- FI68341C FI68341C FI822294A FI822294A FI68341C FI 68341 C FI68341 C FI 68341C FI 822294 A FI822294 A FI 822294A FI 822294 A FI822294 A FI 822294A FI 68341 C FI68341 C FI 68341C
- Authority
- FI
- Finland
- Prior art keywords
- weight
- thiocyanate
- aqueous dispersion
- composition
- methylene bis
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 21
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 title description 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 title description 2
- 239000006185 dispersion Substances 0.000 claims abstract description 49
- JWZXKXIUSSIAMR-UHFFFAOYSA-N methylene bis(thiocyanate) Chemical compound N#CSCSC#N JWZXKXIUSSIAMR-UHFFFAOYSA-N 0.000 claims abstract description 41
- 230000003641 microbiacidal effect Effects 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 241000894006 Bacteria Species 0.000 claims abstract description 11
- 241000233866 Fungi Species 0.000 claims abstract description 10
- 239000000839 emulsion Substances 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 10
- 229920000642 polymer Polymers 0.000 claims abstract description 6
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical compound C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000010419 fine particle Substances 0.000 claims abstract 4
- 229940124561 microbicide Drugs 0.000 claims description 30
- 239000002855 microbicide agent Substances 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 9
- 239000000725 suspension Substances 0.000 claims description 8
- 239000000080 wetting agent Substances 0.000 claims description 8
- 239000000178 monomer Substances 0.000 claims description 7
- 150000001450 anions Chemical class 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 239000011591 potassium Substances 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 238000007710 freezing Methods 0.000 claims description 3
- 230000008014 freezing Effects 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 230000002401 inhibitory effect Effects 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- 241000195493 Cryptophyta Species 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 2
- 230000000844 anti-bacterial effect Effects 0.000 claims 1
- 230000001580 bacterial effect Effects 0.000 claims 1
- 230000002708 enhancing effect Effects 0.000 claims 1
- 239000004088 foaming agent Substances 0.000 claims 1
- 230000002538 fungal effect Effects 0.000 claims 1
- 230000000855 fungicidal effect Effects 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 230000000813 microbial effect Effects 0.000 claims 1
- 239000003595 mist Substances 0.000 claims 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 abstract description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 239000002245 particle Substances 0.000 description 11
- 239000000084 colloidal system Substances 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 239000004927 clay Substances 0.000 description 8
- IOMDIVZAGXCCAC-UHFFFAOYSA-M diethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](CC)(CC)CC=C IOMDIVZAGXCCAC-UHFFFAOYSA-M 0.000 description 8
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 8
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
- 239000002518 antifoaming agent Substances 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 239000004599 antimicrobial Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 238000005086 pumping Methods 0.000 description 4
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 3
- 239000013504 Triton X-100 Substances 0.000 description 3
- 229920004890 Triton X-100 Polymers 0.000 description 3
- 235000019253 formic acid Nutrition 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- -1 MBT Chemical compound 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 239000000546 pharmaceutical excipient Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- AEMRFAOFKBGASW-UHFFFAOYSA-M Glycolate Chemical compound OCC([O-])=O AEMRFAOFKBGASW-UHFFFAOYSA-M 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000013011 aqueous formulation Substances 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 210000003097 mucus Anatomy 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/008—Prevention of corrosion or formation of deposits on pulp-treating equipment
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/48—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —S—C≡N groups
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/02—Non-contaminated water, e.g. for industrial water supply
- C02F2103/023—Water in cooling circuits
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Zoology (AREA)
- Chemical & Material Sciences (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Environmental Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Dispersion Chemistry (AREA)
- Toxicology (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Paper (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
Claims (10)
1. Vattenhaltig dispersion-mikrobicid-komposition, kännetecknad därav, att den innehäller (a) 5 metylen-bis(tiocyanat); (b) 0,75-3,0 vikt-% av en sjMlv- inverterande emulsion av en kopolyamfolyt med formeln I --DMDAAiP -DEDAA}^ —|--CH_-CH — — CH„-CH--- j Z I Z j
10. C=0 C=0 (I) j ^! jt — — k —'1 — —1 m ^ n väri DMDAA)^ är en polymerenhet resulterande frän monomeren 15 dimetyldiallylammonium 5^; DEDAA)^ Mr en polymerenhet re sulterande fran monomeren dietyldiallylammonium 3p; Mr en anjon; ivf^ Mr vMte; ammonium; natrium eller kalium; k och 1 utgör tillsammans 50 vikt-%, varvid k Mr 45-48 vikt-% och 1 Mr 2-5 vikt-%; ooh m och n utgör tillsammans 50 vikt-%, 20 varvid m Mr 45-50 vikt-% och n Mr 0-5 vikt-%, varvid kopo-lyamfolyten har en molekylvikt större Μη 1 x 10°; och (c) 5.0- 15,0 vikt-% av en suspension och viskositet-för-bMttrande oorganisk substans i form av kolloidiska fina partiklar.
2. Komposition enligt patentkravet 1, kMnne- t e c k n a d dMrav, att den ytterligare innehäller föl-jande tillsatsämnen; ett vätningsmedel, ett skumhindrande medel, ett frysning/smMltning stabiliserande medel och en syra, som Mr förenligmed den vattenhaltiga dispersion-30 mikrobicid-kompositionen samt med slutförhandlingsomgiv- ningen och som används i en mängd som ger den vattenhaltiga dispersion-mikrobicid-kompositionen ett slut-pH-vMrde av 2.0- 3,0.
3. Komposition enligt patentkravet 1, kMnne -35 tecknad därav, att mMngden av metylen-bis(tiocyanat) Mr 10,0 vikt-%. 16 68341
4. Komposition enligt patentkravet 1, känne- t e c k n a d därav, att är klor, k är 47,5 vikt-%, 1 är 2,5 vikt-%, m är 47,64 vikt-% och n är 2,36 vikt-%.
5. Komposition enligt patentkravet 1, kanne- 5 tecknad därav, att är klor, k är 47,5 vikt-%, 1 är 2,5 vikt-%, m är 50 vikt-% och n är 0 vikt-%.
6. Förfarande för behandling av mikrob-, dvs. bakte-rie-, svamp- och/eller algförorenat vatten, känne- t e c k n a t därav, att vattnet tillsätts minst en mikro-10 bicid mängd av en vattenhaltig dispersion-raikrobicid-kom-position som innehäller (a) metylen-bis(tiocyanat); (b) 0,75-3,0 vikt-% av en själv-inverterande emulsion av en kopolyamfolyt med formeln (I) “l-DMDAA^-l [- DEDAA^---i—j-Cd^-CH-- • | ¢=0 I i C=0 (I) ! ! 1 nh2 I I cP ~ — k !— —1 — —m :— j^±) _J n 2 0 väri DMDAA}^ är en polymerenhet resulterande frän monomeren dimetyldiallylammoniuiTi DEDAA}^ är en polymerenhet re sulterande frän monomeren dietyldiallylammonium #>, är en anjon; P0 är väte; ammonium; natrium;eller kalium; k och 25 1 utgör tillsammans 50 vikt-%, varvid k är 45-48 vikt-% och 1 är 2-5 vikt-%; och m och n utgör tillsammans 50 vikt-%, varvid m är 45-50 vikt-% och n är 0-5 vikt-%; varvid kopoly-amfolyten har en molekylvikt större än 1 x 10^; och (c) 5,0-15,0-vikt-% av en suspension och viskositet-förbätt-30 rande oorganisk substans i form av kolloidiska fina partiklar.
7. Förfarande enligt patentkravet 6, k ä n n e - t e c k n a t därav, att kompositionen ytterligare innehäller följande tillsatsämnen: ett vätningsmedel, ett skum-hindrande medel, ett frvsning/smältning stabillserande me-35 del och en syra, som är förenlig med den vattenhaltiga dis-persion-mikrobicid-kompositionen sarat med slutförhandlings- 17 68341 omgivningen och sora används i en mängd som ger den vatten-haltiga dispersion-mikrobicid-korapositionen ett slut-pH-värde av 2,0-3,0.
8. Förfarande enligt patenrkravet 6, kanne- 5 tecknat därav, att mängden av metylen-bis(tiocyanat) är 10,0 vikt-%.
9. Förfarande för hämmande av växten av slem-bildan·-de bakterier och svampar som vanligt förekommer i massa-och pappersbrukssystem, kännetecknat därav, att 10 fibermassan och vattnet i ett sädant massa- och papperbruks-system tillsätts minst en bactericidt och fungisidt effektiv mängd av en vattenhaltig dispersion-mikrobicid-komposition, för att bringa den i kontakt med bakterierna och svarapar, varvid kompositionen innehäller (a) metylen-bis(tiocyanat); 15 (b) 0,75-3-0 vikt-% av en själv-inverterande emulsion av en kopolyamfolyt. med formeln (I): ---DMDAAp---DEDAAjP---CH2-CH------(I) 20 c=o Co ' i© I NH0 οχ I_ ,_k I__ _j1 !— ^ Jm - jP -1n väri DMDAA)^ är en polymerenhet resuiterande fran monomeren G © 25 dimetyldially Laramonium X ; DEDAA.X ^ är en polymerenhet resui- terande frän monomeren dietyldiallylammonium 3^; är en © anjon; M är väte; ammonium; natrium; eller kalium; k och 1 utgör tillsammans 59 vikt-%, varvid k är 45-48 vikt-% och 1 är 2-5 vikt-%; och m är n utgör tillsammans 50 vikt-%, 30 varvid m är 45-50 vikt-% och n är 0-5 vikt-%; varvid kopoly-amfolyten har en molekylvikt större än 1 x 10°; och (c) 5,0-15,0 vikt-% av en suspension och viskositet förbätt-rande oorganisk substans i form av kolloidiska fina partik-lar. 35
10. Förfarande enligt patentkravet 9, känne tecknat därav, att kompositionen ytterligare inne-
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US28056781A | 1981-07-06 | 1981-07-06 | |
| US28056781 | 1981-07-06 |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| FI822294A0 FI822294A0 (fi) | 1982-06-28 |
| FI822294L FI822294L (fi) | 1983-01-07 |
| FI68341B FI68341B (fi) | 1985-05-31 |
| FI68341C true FI68341C (fi) | 1985-09-10 |
Family
ID=23073643
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI822294A FI68341C (fi) | 1981-07-06 | 1982-06-28 | Vattenhaltig dispersion-mikrobicid-komposition som innehaollermetylenbis(tiocyanat) och dess anvaendning |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP0069573B1 (sv) |
| JP (1) | JPS5823603A (sv) |
| AT (1) | ATE12873T1 (sv) |
| AU (1) | AU552946B2 (sv) |
| CA (1) | CA1201640A (sv) |
| DE (1) | DE3263253D1 (sv) |
| DK (1) | DK300382A (sv) |
| ES (1) | ES8402266A1 (sv) |
| FI (1) | FI68341C (sv) |
| GR (1) | GR76551B (sv) |
| IE (1) | IE53397B1 (sv) |
| NO (1) | NO158983C (sv) |
| NZ (1) | NZ201065A (sv) |
| PT (1) | PT75137B (sv) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3324499A1 (de) * | 1983-07-07 | 1985-01-17 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von quellmittel enthaltenden pflanzenschutzmitteldispersionen |
| US5626720A (en) * | 1986-01-09 | 1997-05-06 | W.R. Grace & Co.-Conn. | Method for controlling pitch on a papermaking machine |
| US5223097A (en) * | 1986-01-09 | 1993-06-29 | W. R. Grace Ab | Method for controlling pitch on a paper-making machine |
| GB2202872A (en) * | 1987-02-13 | 1988-10-05 | Grace W R & Co | Pitch control aid and dye assistant |
| US4995944A (en) * | 1988-09-16 | 1991-02-26 | Dearborn Chemical Company Ltd. | Controlling deposits on paper machine felts using cationic polymer and cationic surfactant mixture |
| AR019119A1 (es) * | 1998-04-29 | 2001-12-26 | Nz Forest Research Inst Ltd | Un metodo para inhibir el ataque fungico y composiciones para utilizar con dicho metodo |
| US20040101539A1 (en) * | 2002-11-22 | 2004-05-27 | Ernst Engler | Aqueous dispersion of low-melting organic solids |
| EP2713720B1 (en) | 2011-05-27 | 2016-01-06 | Basf Se | Copolymers of n-vinylcarboxamide and diallyldialkylammonium salt as dispersant for agrochemical formulations |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4823897B1 (sv) * | 1965-07-13 | 1973-07-17 | ||
| CA970684A (en) * | 1971-01-13 | 1975-07-08 | Salem Shair | Liquid, water-dispersible microbicide compositions and methods for using |
| US3996378A (en) * | 1974-10-24 | 1976-12-07 | Nalco Chemical Company | Water-based microbicide formulation |
| US4147681A (en) * | 1976-02-24 | 1979-04-03 | Calgon Corporation | Stable, self-inverting water-in-oil emulsions |
-
1982
- 1982-06-24 NZ NZ201065A patent/NZ201065A/en unknown
- 1982-06-25 AU AU85340/82A patent/AU552946B2/en not_active Ceased
- 1982-06-28 FI FI822294A patent/FI68341C/fi not_active IP Right Cessation
- 1982-06-28 PT PT75137A patent/PT75137B/pt not_active IP Right Cessation
- 1982-06-29 IE IE1571/82A patent/IE53397B1/en not_active IP Right Cessation
- 1982-06-30 NO NO822290A patent/NO158983C/no unknown
- 1982-07-01 GR GR68621A patent/GR76551B/el unknown
- 1982-07-05 DE DE8282303516T patent/DE3263253D1/de not_active Expired
- 1982-07-05 DK DK300382A patent/DK300382A/da not_active Application Discontinuation
- 1982-07-05 CA CA000406609A patent/CA1201640A/en not_active Expired
- 1982-07-05 ES ES513732A patent/ES8402266A1/es not_active Expired
- 1982-07-05 AT AT82303516T patent/ATE12873T1/de not_active IP Right Cessation
- 1982-07-05 EP EP82303516A patent/EP0069573B1/en not_active Expired
- 1982-07-06 JP JP57116318A patent/JPS5823603A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5823603A (ja) | 1983-02-12 |
| EP0069573B1 (en) | 1985-04-24 |
| DE3263253D1 (en) | 1985-05-30 |
| IE53397B1 (en) | 1988-11-09 |
| NZ201065A (en) | 1984-09-28 |
| CA1201640A (en) | 1986-03-11 |
| ES513732A0 (es) | 1984-01-16 |
| NO158983C (no) | 1988-11-23 |
| NO158983B (no) | 1988-08-15 |
| DK300382A (da) | 1983-01-07 |
| EP0069573A1 (en) | 1983-01-12 |
| ATE12873T1 (de) | 1985-05-15 |
| IE821571L (en) | 1983-01-06 |
| FI822294A0 (fi) | 1982-06-28 |
| FI822294L (fi) | 1983-01-07 |
| PT75137A (en) | 1982-07-01 |
| AU8534082A (en) | 1983-01-13 |
| FI68341B (fi) | 1985-05-31 |
| NO822290L (no) | 1983-01-07 |
| JPH0229646B2 (sv) | 1990-07-02 |
| AU552946B2 (en) | 1986-06-26 |
| ES8402266A1 (es) | 1984-01-16 |
| PT75137B (en) | 1985-06-28 |
| GR76551B (sv) | 1984-08-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69032819T2 (de) | Mikrobizide Zusammensetzungen von Dimethylamin-Epichlorhydrin-Amin-Polymeren | |
| US6288010B1 (en) | Compositions comprising anti-drift agents and processes and methods for their use | |
| US5441981A (en) | Synergistic antimicrobial compositions containing a halogenated acetophenone and an organic acid | |
| FI68341C (fi) | Vattenhaltig dispersion-mikrobicid-komposition som innehaollermetylenbis(tiocyanat) och dess anvaendning | |
| JP2018535959A (ja) | モノクロラミンと過酸とを含む殺微生物水性溶液、及びそれを使用する方法 | |
| FI61606C (fi) | Mikrobicida kompositioner foer industriella vattensystem | |
| JP2001509474A (ja) | ２−（チオシアノメチルチオ）ベンゾチアゾールとメチレン−ビス（チオシアネート）との混合物をカルボン酸ジメチルアミドとともに含有する相乗的抗微生物組成物 | |
| EP0910952A1 (en) | Stable microbicide formulation | |
| CA2532536C (en) | Aqueous suspension formulation for foliar application fungicide | |
| CN101669911B (zh) | 一种地克珠利可溶性粉及其制备方法 | |
| JPH0737362B2 (ja) | 工業用殺菌組成物 | |
| ZA200200708B (en) | Aqueous suspensions of low solubility and low stability water additives. | |
| JP6320390B2 (ja) | 助剤添加剤及びそれを含む農薬組成物 | |
| US5017592A (en) | Stable biocide composition for industrial use | |
| EP0983723A1 (en) | Stable microbicide formulation | |
| JP2773165B2 (ja) | 殺菌剤組成物 | |
| JPH0611813B2 (ja) | 抗菌性ラテツクス組成物 | |
| JPS6248603A (ja) | 工業用殺菌組成物 | |
| JPH0853314A (ja) | 工業用殺菌剤及び工業用殺菌方法 | |
| JP2664480B2 (ja) | 工業用殺菌／静菌剤及び殺菌／静菌方法 | |
| JP3396721B2 (ja) | 工業用殺菌方法 | |
| JP3009273B2 (ja) | 工業用殺菌剤 | |
| JP2851347B2 (ja) | 工業用殺菌・静菌剤 | |
| GB2250737A (en) | Biocide | |
| JPS62286963A (ja) | 安定化されたアルキレンビスジチオカルバミン酸塩水溶液 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM | Patent lapsed | ||
| MM | Patent lapsed |
Owner name: MERCK & CO., INC. |