FI68601C - Foerfarande foer framstaellning av klordioxid med laog klorhalt - Google Patents

Foerfarande foer framstaellning av klordioxid med laog klorhalt Download PDF

Info

Publication number: FI68601C
Authority: FI; Finland
Prior art keywords: chlorine; sodium; chlorate; chlorine dioxide; reaction
Prior art date: 1978-05-19

Application number

FI791552A

Other languages

English (en)

Finnish (fi)

Other versions

FI68601B (fi

FI791552A7 (fi

Inventor

Daniel J Jaszka

Harold Devere Partridge

Original Assignee

Kema Nord Ab

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-05-19

Filing date

1979-05-15

Publication date

1985-10-10

1979-05-15 Application filed by Kema Nord Ab filed Critical Kema Nord Ab

1979-11-19 Publication of FI791552A7 publication Critical patent/FI791552A7/fi

1985-06-28 Application granted granted Critical

1985-06-28 Publication of FI68601B publication Critical patent/FI68601B/fi

1985-10-10 Publication of FI68601C publication Critical patent/FI68601C/fi

Links

239000000460 chlorine Substances 0.000 title claims description 40
229910052801 chlorine Inorganic materials 0.000 title claims description 23
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 title description 8
239000002699 waste material Substances 0.000 title 1
OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 80
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 41
239000004155 Chlorine dioxide Substances 0.000 claims description 40
235000019398 chlorine dioxide Nutrition 0.000 claims description 40
XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 33
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 33
238000006243 chemical reaction Methods 0.000 claims description 25
238000000034 method Methods 0.000 claims description 25
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 23
239000011780 sodium chloride Substances 0.000 claims description 21
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 12
BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims description 10
238000004519 manufacturing process Methods 0.000 claims description 9
239000007864 aqueous solution Substances 0.000 claims description 4
239000000243 solution Substances 0.000 description 30
239000000203 mixture Substances 0.000 description 21
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 16
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 12
239000007789 gas Substances 0.000 description 12
229910052938 sodium sulfate Inorganic materials 0.000 description 12
235000011152 sodium sulphate Nutrition 0.000 description 12
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 11
239000002253 acid Substances 0.000 description 11
239000000047 product Substances 0.000 description 9
238000005406 washing Methods 0.000 description 9
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 7
238000004061 bleaching Methods 0.000 description 5
239000013078 crystal Substances 0.000 description 5
229910052500 inorganic mineral Inorganic materials 0.000 description 5
239000011707 mineral Substances 0.000 description 5
239000000376 reactant Substances 0.000 description 5
238000011282 treatment Methods 0.000 description 5
239000006096 absorbing agent Substances 0.000 description 4
239000012527 feed solution Substances 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
238000004537 pulping Methods 0.000 description 4
UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 description 4
239000000126 substance Substances 0.000 description 4
229910001514 alkali metal chloride Inorganic materials 0.000 description 3
229910052936 alkali metal sulfate Inorganic materials 0.000 description 3
239000003054 catalyst Substances 0.000 description 3
239000003638 chemical reducing agent Substances 0.000 description 3
229910001902 chlorine oxide Inorganic materials 0.000 description 3
239000011521 glass Substances 0.000 description 3
230000007935 neutral effect Effects 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
238000000926 separation method Methods 0.000 description 3
239000002002 slurry Substances 0.000 description 3
239000011734 sodium Substances 0.000 description 3
239000007787 solid Substances 0.000 description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
230000002378 acidificating effect Effects 0.000 description 2
239000003513 alkali Substances 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
239000000835 fiber Substances 0.000 description 2
239000000706 filtrate Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000004033 plastic Substances 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
238000004076 pulp bleaching Methods 0.000 description 2
238000005201 scrubbing Methods 0.000 description 2
239000000741 silica gel Substances 0.000 description 2
229910002027 silica gel Inorganic materials 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
229920003043 Cellulose fiber Polymers 0.000 description 1
108700024827 HOC1 Proteins 0.000 description 1
239000007832 Na2SO4 Substances 0.000 description 1
229910019093 NaOCl Inorganic materials 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
101100178273 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) HOC1 gene Proteins 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
YUHVVTLNLCJEOB-UHFFFAOYSA-N [Cl].O=Cl=O Chemical compound [Cl].O=Cl=O YUHVVTLNLCJEOB-UHFFFAOYSA-N 0.000 description 1
230000002411 adverse Effects 0.000 description 1
-1 alkali metal salt Chemical class 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
235000014121 butter Nutrition 0.000 description 1
YALMXYPQBUJUME-UHFFFAOYSA-L calcium chlorate Chemical compound [Ca+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O YALMXYPQBUJUME-UHFFFAOYSA-L 0.000 description 1
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
239000000292 calcium oxide Substances 0.000 description 1
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
229940005989 chlorate ion Drugs 0.000 description 1
238000005660 chlorination reaction Methods 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
238000011067 equilibration Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000008246 gaseous mixture Substances 0.000 description 1
239000004519 grease Substances 0.000 description 1
IXCSERBJSXMMFS-UHFFFAOYSA-N hcl hcl Chemical compound Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
239000002440 industrial waste Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
229910001510 metal chloride Inorganic materials 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
238000011084 recovery Methods 0.000 description 1
239000011833 salt mixture Substances 0.000 description 1
WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
229910000342 sodium bisulfate Inorganic materials 0.000 description 1
BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 description 1
229910001488 sodium perchlorate Inorganic materials 0.000 description 1
238000003860 storage Methods 0.000 description 1
235000011149 sulphuric acid Nutrition 0.000 description 1
239000004753 textile Substances 0.000 description 1
238000007738 vacuum evaporation Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
- C01B11/025—Preparation from chlorites or chlorates from chlorates without any other reaction reducing agent than chloride ions

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
General Life Sciences & Earth Sciences (AREA)
Geology (AREA)
Paper (AREA)
Treating Waste Gases (AREA)

FI791552A 1978-05-19 1979-05-15 Foerfarande foer framstaellning av klordioxid med laog klorhalt FI68601C (fi)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US90743278		1978-05-19
US05/907,432 US4216195A (en)	1978-05-19	1978-05-19	Production of chlorine dioxide having low chlorine content

Publications (3)

Publication Number	Publication Date
FI791552A7 FI791552A7 (fi)	1979-11-19
FI68601B FI68601B (fi)	1985-06-28
FI68601C true FI68601C (fi)	1985-10-10

Family

ID=25424090

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FI791552A FI68601C (fi)	1978-05-19	1979-05-15	Foerfarande foer framstaellning av klordioxid med laog klorhalt

Country Status (8)

Country	Link
US (1)	US4216195A (fr)
BR (1)	BR7903118A (fr)
CA (1)	CA1118580A (fr)
FI (1)	FI68601C (fr)
FR (1)	FR2426017A1 (fr)
NZ (1)	NZ190345A (fr)
PT (1)	PT69625A (fr)
SE (1)	SE448864B (fr)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
SE9002262D0 (sv) *	1990-06-27	1990-06-27	Eka Nobel Ab	Foerfarande foer framstaellning av klorioxid
US5205995A (en) *	1991-04-22	1993-04-27	Sterling Canada Inc.	Metathesis of acidic by-product of chlorine dioxide generating apparatus
US5324497A (en) *	1992-02-26	1994-06-28	Westerlund G Oscar	Integrated procedure for high yield production of chlorine dioxide and apparatus used therefor
CA2079633C (fr) *	1992-07-31	1998-04-28	John Robert Jackson	Methode de preparation des chlorates provenant des ecoulements de gaz de combustion obtenus lors de la production de dioxyde de chlore
US5294307A (en) *	1992-07-31	1994-03-15	Huron Tech Corp	Integrated process for the production of alkali and alkaline earth metal chlorates and chlorine dioxide
US5433938A (en) *	1992-10-23	1995-07-18	Vulcan Chemicals	Chlorine-destruct method
US6322768B1 (en)	1998-09-29	2001-11-27	International Paper Company	Recovery of chlorine dioxide from gas streams
KR100521652B1 (ko) *	2002-04-29	2005-10-14	(주)데오테크	기체상 이산화염소의 고순도 제조장치, 그의 제조 방법 및장기 보존 방법
TWI447065B (zh) *	2007-07-13	2014-08-01	Akzo Nobel Nv	二氧化氯之製造方法
UY32927A (es) *	2009-10-12	2011-03-31	Akzo Nobel Chemicals Int Bv	Proceso para la producción de dióxido de cloro
CA3025918A1 (fr) *	2018-08-30	2020-02-29	Guangxi Bossco Environmental Protection Technology Co., Ltd.	Une methode de preparation de dioxyde de chlore a haute purete au moyen de methanol et de peroxyde d'hydrogene comme agent de reduction
BR112021019660A2 (pt)	2019-04-02	2021-12-07	Ecolab Usa Inc	Métodos para produzir dióxido de cloro e para tratar água de processo
TW202348787A (zh)	2022-04-01	2023-12-16	美商藝康美國公司	用於乙烯系單體流之高苛刻度加工的防汙劑組成物
TW202404930A (zh)	2022-04-01	2024-02-01	美商藝康美國公司	在共軛二烯單體之萃取蒸餾期間減少非所要之乳化聚合
TW202348786A (zh)	2022-04-01	2023-12-16	美商藝康美國公司	用於蒸氣空間應用之防汙劑組成物

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2036375A (en) *	1934-08-15	1936-04-07	Mathieson Alkali Works Inc	Production of chlorine dioxide
US2036311A (en) *	1934-08-15	1936-04-07	Mathieson Alkali Works Inc	Production of chlorine dioxide
US2731329A (en) *	1952-09-20	1956-01-17	Kamlet Lab	Process for oxidizing nitrosyl chloride
US2863722A (en) *	1955-03-08	1958-12-09	Hooker Chemical Corp	Chlorine dioxide production
US2871097A (en) *	1956-02-06	1959-01-27	Hooker Chemical Corp	Production of chlorine dioxide
NL113586C (fr) *	1956-04-26	1900-01-01
US3056656A (en) *	1958-05-20	1962-10-02	Olin Mathieson	Production of aqueous perchloric acid
US3816077A (en) *	1971-05-21	1974-06-11	Hooker Chemical Corp	Chlorine dioxide generating system
US3823225A (en) *	1972-10-19	1974-07-09	Olin Corp	Removal of available chlorine from alkali metal chlorate-chloride solution and production of chlorine dioxide from said solution
US3920801A (en) *	1974-04-05	1975-11-18	Hooker Chemicals Plastics Corp	Method of producing chlorine dioxide from hydrogen chloride

1978
- 1978-05-19 US US05/907,432 patent/US4216195A/en not_active Expired - Lifetime
1979
- 1979-05-02 NZ NZ190345A patent/NZ190345A/xx unknown
- 1979-05-15 FI FI791552A patent/FI68601C/fi not_active IP Right Cessation
- 1979-05-16 FR FR7912408A patent/FR2426017A1/fr active Granted
- 1979-05-17 PT PT69625A patent/PT69625A/pt unknown
- 1979-05-17 CA CA000327966A patent/CA1118580A/fr not_active Expired
- 1979-05-18 BR BR7903118A patent/BR7903118A/pt unknown
- 1979-05-18 SE SE7904377A patent/SE448864B/sv not_active IP Right Cessation

Also Published As

Publication number	Publication date
FR2426017A1 (fr)	1979-12-14
BR7903118A (pt)	1979-12-11
US4216195A (en)	1980-08-05
NZ190345A (en)	1981-02-11
PT69625A (en)	1979-06-01
SE7904377L (sv)	1979-11-20
CA1118580A (fr)	1982-02-23
SE448864B (sv)	1987-03-23
FI68601B (fi)	1985-06-28
FI791552A7 (fi)	1979-11-19
FR2426017B1 (fr)	1984-12-21

Legal Events

Date	Code	Title	Description
1994-12-13	MM	Patent lapsed
2004-08-31	MM	Patent lapsed	Owner name: KEMANORD AB

Publication	Publication Date	Title
FI68601B (fi)	1985-06-28	Foerfarande foer framstaellning av klordioxid med laog klorhalt
AU603252B2 (en)	1990-11-08	Process for production of chlorine dioxide
JPH0742090B2 (ja)	1995-05-10	二酸化塩素の製造方法
US5124135A (en)	1992-06-23	Process for the selective absorption of chlorine and/or bromine from CO.sub. -containing off-gases with the aid of steam
CA1333519C (fr)	1994-12-20	Procede pour la production de dioxyde de chlore
US3966889A (en)	1976-06-29	Process for the recovery of selenium from waste gas
TWI447065B (zh)	2014-08-01	二氧化氯之製造方法
US4634582A (en)	1987-01-06	Sulfur dioxide removal process
US4203959A (en)	1980-05-20	Process for the preparation of nitrous oxide
US4454102A (en)	1984-06-12	Method of purifying flue gases from sulphur dioxide
US4355015A (en)	1982-10-19	Process for the production of finely divided oxides of metals
JPH0776081B2 (ja)	1995-08-16	二酸化塩素の製造方法
US3709978A (en)	1973-01-09	Process for purifying industrial waste gases containing hydrogen fluoride
CA1129628A (fr)	1982-08-17	Separation et recuperation des oxydes d'azote et du dioxyde de soufre contenus dans des melanges gazeux
US4162299A (en)	1979-07-24	Process for the removal of sulfur oxides
FI107252B (fi)	2001-06-29	Menetelmä klooridioksidin valmistamiseksi
US7052669B2 (en)	2006-05-30	Process for production of ammonium thiosulphate
US4086324A (en)	1978-04-25	Removal of sulfur and nitrogen oxides with aqueous absorbent
FI69292C (fi)	1986-01-10	Foerfarande foer framstaellning av klordioxid
CA2433291C (fr)	2011-08-16	Methode de production de thiosulfate d'ammonium
FI73603C (fi)	1987-11-09	Foerfarande foer tillvaratagande och tillgodogoerande av svaveldioxiden i svavelhaltiga gaser saosom roekgaser.
SU1139700A1 (ru)	1985-02-15	Способ получени брома
CA1079030A (fr)	1980-06-10	Systeme de filtration du dioxyde de soufre
CA2061645A1 (fr)	1993-08-22	Dioxyde de chlore exempt de chlore
SU320447A1 (ru)		СПОСОБ ПОЛУЧЕНИЯ СОЛЯНОЙ кислоты НЗ АБГАЗОВ