FI70611C - Foerfarande foer utfaellning av ligninsulfonater ur en sulfitavlut - Google Patents

Foerfarande foer utfaellning av ligninsulfonater ur en sulfitavlut Download PDF

Info

Publication number: FI70611C
Authority: FI; Finland
Prior art keywords: polyimine; process according; precipitation; dissolved; precipitate
Prior art date: 1980-10-10

Application number

FI812932A

Other languages

English (en)

Finnish (fi)

Swedish (sv)

Other versions

FI812932L (fi

FI70611B (fi

Inventor

Annegret Haars

Aloys Huettermann

Original Assignee

Biotechnolog Forschung Gmbh

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-10-10

Filing date

1981-09-21

Publication date

1986-09-24

1981-09-21 Application filed by Biotechnolog Forschung Gmbh filed Critical Biotechnolog Forschung Gmbh

1982-04-11 Publication of FI812932L publication Critical patent/FI812932L/fi

1986-06-06 Application granted granted Critical

1986-06-06 Publication of FI70611B publication Critical patent/FI70611B/fi

1986-09-24 Publication of FI70611C publication Critical patent/FI70611C/fi

Links

NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title description 3
239000011593 sulfur Substances 0.000 title description 3
229910052717 sulfur Inorganic materials 0.000 title description 3
239000000446 fuel Substances 0.000 title 1
238000000034 method Methods 0.000 claims abstract description 30
238000001556 precipitation Methods 0.000 claims abstract description 25
239000002699 waste material Substances 0.000 claims abstract description 21
230000001376 precipitating effect Effects 0.000 claims abstract 2
239000002244 precipitate Substances 0.000 claims description 24
229920001732 Lignosulfonate Polymers 0.000 claims description 21
239000000243 solution Substances 0.000 claims description 20
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 18
230000008569 process Effects 0.000 claims description 17
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
229920000333 poly(propyleneimine) Polymers 0.000 claims description 15
239000003960 organic solvent Substances 0.000 claims description 10
239000007864 aqueous solution Substances 0.000 claims description 8
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 6
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
238000001704 evaporation Methods 0.000 claims description 5
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 4
239000003513 alkali Substances 0.000 claims description 4
238000000605 extraction Methods 0.000 claims description 4
238000000622 liquid--liquid extraction Methods 0.000 claims description 4
238000004519 manufacturing process Methods 0.000 claims description 4
238000000638 solvent extraction Methods 0.000 claims description 4
229920002873 Polyethylenimine Polymers 0.000 claims description 3
240000004808 Saccharomyces cerevisiae Species 0.000 claims description 3
230000008020 evaporation Effects 0.000 claims description 3
OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 claims description 2
230000002378 acidificating effect Effects 0.000 claims description 2
239000012670 alkaline solution Substances 0.000 claims description 2
239000008346 aqueous phase Substances 0.000 claims description 2
229940117389 dichlorobenzene Drugs 0.000 claims description 2
238000000855 fermentation Methods 0.000 claims description 2
230000004151 fermentation Effects 0.000 claims description 2
239000012074 organic phase Substances 0.000 claims description 2
239000002904 solvent Substances 0.000 claims description 2
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims 1
239000000920 calcium hydroxide Substances 0.000 claims 1
229910001861 calcium hydroxide Inorganic materials 0.000 claims 1
102000004169 proteins and genes Human genes 0.000 claims 1
108090000623 proteins and genes Proteins 0.000 claims 1
229920005610 lignin Polymers 0.000 abstract description 11
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 abstract description 3
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
238000010411 cooking Methods 0.000 description 6
229920002678 cellulose Polymers 0.000 description 4
239000001913 cellulose Substances 0.000 description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
239000011575 calcium Substances 0.000 description 3
239000011777 magnesium Substances 0.000 description 3
238000011084 recovery Methods 0.000 description 3
239000000126 substance Substances 0.000 description 3
239000002023 wood Substances 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
241000196324 Embryophyta Species 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
230000002745 absorbent Effects 0.000 description 2
239000002250 absorbent Substances 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
238000005119 centrifugation Methods 0.000 description 2
235000019441 ethanol Nutrition 0.000 description 2
150000002402 hexoses Chemical class 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
239000002245 particle Substances 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
239000000047 product Substances 0.000 description 2
238000000746 purification Methods 0.000 description 2
150000003242 quaternary ammonium salts Chemical class 0.000 description 2
230000008929 regeneration Effects 0.000 description 2
238000011069 regeneration method Methods 0.000 description 2
229910021653 sulphate ion Inorganic materials 0.000 description 2
239000002351 wastewater Substances 0.000 description 2
241000894006 Bacteria Species 0.000 description 1
229920002101 Chitin Polymers 0.000 description 1
240000000731 Fagus sylvatica Species 0.000 description 1
235000010099 Fagus sylvatica Nutrition 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
241000218657 Picea Species 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
238000004026 adhesive bonding Methods 0.000 description 1
230000002411 adverse Effects 0.000 description 1
235000019270 ammonium chloride Nutrition 0.000 description 1
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
239000010796 biological waste Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000001175 calcium sulphate Substances 0.000 description 1
235000011132 calcium sulphate Nutrition 0.000 description 1
RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000002894 chemical waste Substances 0.000 description 1
239000011093 chipboard Substances 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
238000007906 compression Methods 0.000 description 1
230000006835 compression Effects 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
239000003599 detergent Substances 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000002255 enzymatic effect Effects 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
235000013305 food Nutrition 0.000 description 1
XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 1
229910052602 gypsum Inorganic materials 0.000 description 1
239000010440 gypsum Substances 0.000 description 1
230000008676 import Effects 0.000 description 1
239000003295 industrial effluent Substances 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
230000009972 noncorrosive effect Effects 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
230000036284 oxygen consumption Effects 0.000 description 1
239000008188 pellet Substances 0.000 description 1
150000002972 pentoses Chemical class 0.000 description 1
229920000447 polyanionic polymer Polymers 0.000 description 1
-1 polyimine Chemical class 0.000 description 1
238000000926 separation method Methods 0.000 description 1
108010027322 single cell proteins Proteins 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
150000008054 sulfonate salts Chemical class 0.000 description 1
230000008719 thickening Effects 0.000 description 1
MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
235000012141 vanillin Nutrition 0.000 description 1
238000004065 wastewater treatment Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H6/00—Macromolecular compounds derived from lignin, e.g. tannins, humic acids
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C11/00—Regeneration of pulp liquors or effluent waste waters
- D21C11/0007—Recovery of by-products, i.e. compounds other than those necessary for pulping, for multiple uses or not otherwise provided for

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Biochemistry (AREA)
Materials Engineering (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Paper (AREA)
Compounds Of Unknown Constitution (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Medicines Containing Plant Substances (AREA)
Treating Waste Gases (AREA)
Preparation Of Compounds By Using Micro-Organisms (AREA)
Extraction Or Liquid Replacement (AREA)
Processing Of Solid Wastes (AREA)
Separation Of Suspended Particles By Flocculating Agents (AREA)

FI812932A 1980-10-10 1981-09-21 Foerfarande foer utfaellning av ligninsulfonater ur en sulfitavlut FI70611C (fi)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE3038241A DE3038241C2 (de)	1980-10-10	1980-10-10	Verfahren zur Ausfällung von Ligninsulfonaten aus Sulfitablaugen
DE3038241		1980-10-10

Publications (3)

Publication Number	Publication Date
FI812932L FI812932L (fi)	1982-04-11
FI70611B FI70611B (fi)	1986-06-06
FI70611C true FI70611C (fi)	1986-09-24

Family

ID=6114037

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FI812932A FI70611C (fi)	1980-10-10	1981-09-21	Foerfarande foer utfaellning av ligninsulfonater ur en sulfitavlut

Country Status (7)

Country	Link
US (1)	US4459228A (fr)
EP (1)	EP0049831B1 (fr)
AT (1)	ATE9481T1 (fr)
CA (1)	CA1187487A (fr)
DE (1)	DE3038241C2 (fr)
FI (1)	FI70611C (fr)
NO (1)	NO153178C (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3611676A1 (de) *	1986-04-08	1987-10-15	Pfleiderer Fa G A	Verfahren und vorrichtung zum ausfaellen von negativ geladenen lignin-derivaten
DE3621217C1 (en) *	1986-06-25	1987-08-06	Pfleiderer Fa G A	Method for cultivating heterotrophic microorganisms
FR2612916B1 (fr) *	1987-03-27	1991-02-15	Elf Aquitaine	Traitement des rejets d'eaux de bourbiers contenant des lignosulfonates
US4992417A (en) *	1987-07-17	1991-02-12	Mount Sinai School Of Medicine	Superactive human insulin analogues
SE459925B (sv) *	1987-12-23	1989-08-21	Boliden Ab	Avskiljning av harts ur massaavlutar
US20040158033A1 (en) *	2003-02-06	2004-08-12	Benson Robert A.C.	Treated lignosulfonates as additives for cementitous systems

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
USRE24213E (en) *	1952-06-07	1956-09-11		Ammonia recovery
US2842534A (en) *	1956-02-20	1958-07-08	West Virginia Pulp & Paper Co	Nitrogen containing lignins and method of making same
US2839417A (en) *	1956-05-07	1958-06-17	Dow Chemical Co	Stabilized soil compositions containing reaction products of lignin with polyalkylene polyamines
US3271382A (en) *	1963-09-26	1966-09-06	Rayonier Inc	Recovery of lignosulfonates from spent sulfite liquors
DE1570363A1 (de) *	1964-06-24	1970-02-05	Chemirad Corp	Verfahren zur Herstellung von vorzugsweise gelartigen Produkten Reaktionsprodukten von Polyaethylenimin und Lignin und solche enthaltende Faserprodukte
US3697497A (en) *	1970-09-17	1972-10-10	Bayer Ag	Hexamethylene tetramine derivatives of alkali lignins
FI60873C (fi) *	1979-05-28	1982-04-13	Tampella Oy Ab	Foerfarande foer avskiljning av lignosulfonsyror och lignosulfonater genom extraktion ur avlut fraon kok av cellulosahaltigt material

1980
- 1980-10-10 DE DE3038241A patent/DE3038241C2/de not_active Expired
1981
- 1981-09-21 FI FI812932A patent/FI70611C/fi not_active IP Right Cessation
- 1981-10-02 EP EP81107849A patent/EP0049831B1/fr not_active Expired
- 1981-10-02 AT AT81107849T patent/ATE9481T1/de not_active IP Right Cessation
- 1981-10-07 US US06/309,175 patent/US4459228A/en not_active Expired - Fee Related
- 1981-10-09 CA CA000387701A patent/CA1187487A/fr not_active Expired
- 1981-10-09 NO NO813422A patent/NO153178C/no unknown

Also Published As

Publication number	Publication date
EP0049831B1 (fr)	1984-09-19
NO813422L (no)	1982-04-13
EP0049831A3 (en)	1982-05-05
ATE9481T1 (de)	1984-10-15
CA1187487A (fr)	1985-05-21
FI812932L (fi)	1982-04-11
EP0049831A2 (fr)	1982-04-21
NO153178B (no)	1985-10-21
US4459228A (en)	1984-07-10
DE3038241C2 (de)	1983-01-05
DE3038241A1 (de)	1982-09-16
NO153178C (no)	1986-01-29
FI70611B (fi)	1986-06-06

Legal Events

Date	Code	Title	Description
2004-08-31	MM	Patent lapsed	Owner name: G.A. PFLEIDERER UNTERNEHMENSVERWALTUNG

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