FR2072367A5 - Vinylidene chloride copolymers of improved - solubility - Google Patents

Vinylidene chloride copolymers of improved - solubility

Info

Publication number
FR2072367A5
FR2072367A5 FR7042291A FR7042291A FR2072367A5 FR 2072367 A5 FR2072367 A5 FR 2072367A5 FR 7042291 A FR7042291 A FR 7042291A FR 7042291 A FR7042291 A FR 7042291A FR 2072367 A5 FR2072367 A5 FR 2072367A5
Authority
FR
France
Prior art keywords
monomers
monomer
vinylidene chloride
charge
solubility
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
FR7042291A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of FR2072367A5 publication Critical patent/FR2072367A5/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/02Monomers containing chlorine
    • C08F214/04Monomers containing two carbon atoms
    • C08F214/08Vinylidene chloride
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/08Homopolymers or copolymers of vinylidene chloride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paints Or Removers (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

The copolymers are prepd by:- dissolving the reacting monomers in a monomer free aqs. emulsion, where the monomers are soluble in aqs. and oily phases; maintaining reaction temp at 50-60% C; adding a second charge of monomers at 3-20 wt.% of the total monomers, where monomer proportions are 88-93 mol % vinylidene chloride and 12-7 mol % of (I) (unsatd monomer). Maintaining reaction temp. at 50-65 degrees C under autogenous pressure, introducing a continuous charge of residual monomers (III) at the end of polymerisation of the second charge before a pressure drop of more than 0.14 kg/cm2 is produced. (II) are added in the same proportions as before and at a rate of 4.5-11.5% of total monomers/hr. continuing reaction until a 50% pressure drop is produced, cooling and purifying the product.
FR7042291A 1969-11-26 1970-11-25 Vinylidene chloride copolymers of improved - solubility Expired FR2072367A5 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US88038969A 1969-11-26 1969-11-26
US8579870A 1970-10-30 1970-10-30

Publications (1)

Publication Number Publication Date
FR2072367A5 true FR2072367A5 (en) 1971-09-24

Family

ID=26773092

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7042291A Expired FR2072367A5 (en) 1969-11-26 1970-11-25 Vinylidene chloride copolymers of improved - solubility

Country Status (8)

Country Link
AT (1) AT309817B (en)
BE (1) BE759418A (en)
CA (1) CA946542A (en)
DE (1) DE2057932A1 (en)
ES (1) ES385900A1 (en)
FR (1) FR2072367A5 (en)
LU (1) LU62130A1 (en)
NL (1) NL7017258A (en)

Also Published As

Publication number Publication date
CA946542A (en) 1974-04-30
ES385900A1 (en) 1973-11-16
DE2057932A1 (en) 1971-06-03
AT309817B (en) 1973-07-15
LU62130A1 (en) 1972-08-03
BE759418A (en) 1971-05-25
NL7017258A (en) 1971-05-28

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Legal Events

Date Code Title Description
ST Notification of lapse