FR2362916A1 - Catalyseur et procede perfectionnes de reformage catalytique des hy drocarbures - Google Patents

Catalyseur et procede perfectionnes de reformage catalytique des hy drocarbures

Info

Publication number
FR2362916A1
FR2362916A1 FR7725185A FR7725185A FR2362916A1 FR 2362916 A1 FR2362916 A1 FR 2362916A1 FR 7725185 A FR7725185 A FR 7725185A FR 7725185 A FR7725185 A FR 7725185A FR 2362916 A1 FR2362916 A1 FR 2362916A1
Authority
FR
France
Prior art keywords
catalyst
pore volume
hydrocarbons
angstroms
catalytic reforming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7725185A
Other languages
English (en)
Other versions
FR2362916B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chevron USA Inc
Original Assignee
Chevron Research and Technology Co
Chevron Research Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/716,924 external-priority patent/US4082697A/en
Application filed by Chevron Research and Technology Co, Chevron Research Co filed Critical Chevron Research and Technology Co
Publication of FR2362916A1 publication Critical patent/FR2362916A1/fr
Application granted granted Critical
Publication of FR2362916B1 publication Critical patent/FR2362916B1/fr
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/6350.5-1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66Pore distribution
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00Reforming naphtha
    • C10G35/04Catalytic reforming
    • C10G35/06Catalytic reforming characterised by the catalyst used
    • C10G35/085Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
    • C10G35/09Bimetallic catalysts in which at least one of the metals is a platinum group metal
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1064Platinum group metal catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1064Platinum group metal catalysts
    • C01B2203/107Platinum catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1082Composition of support materials
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1094Promotors or activators
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

L'invention décrit un catalyseur perfectionné et son application dans un procédé de reformage des hydrocarbures. Le catalyseur nouveau et perfectionné de reformage des hydrocarbures comprend : 1. Un support, formé surtout d'alumine comportant au moins 0,65 cm**3 de volume de pore par gramme, dont les micropores situées entre 80 et 150 Angstrom de diamètre représentent au moins 70 % du volume des pores et dont les pores ayant plus de 1000 Angstrom constituent environ 0,1 à 3 % de ce volume des pores; et 2. Un constituant catalytique classique pour le reformage des hydrocarbures (métal noble avec promoteur et/ou stabilisant). Le catalyseur a une bonne durée de vie et il peut donner des essences à indice élevé d'octane.
FR7725185A 1976-08-23 1977-08-17 Catalyseur et procede perfectionnes de reformage catalytique des hy drocarbures Granted FR2362916A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/716,924 US4082697A (en) 1974-08-12 1976-08-23 Catalyst carrier, its method of preparation and a reforming catalyst supported on the carrier

Publications (2)

Publication Number Publication Date
FR2362916A1 true FR2362916A1 (fr) 1978-03-24
FR2362916B1 FR2362916B1 (fr) 1982-01-08

Family

ID=24880011

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7725185A Granted FR2362916A1 (fr) 1976-08-23 1977-08-17 Catalyseur et procede perfectionnes de reformage catalytique des hy drocarbures

Country Status (10)

Country Link
US (1) US4129497A (fr)
JP (1) JPS585702B2 (fr)
AU (1) AU511968B2 (fr)
BE (1) BE858011A (fr)
CA (1) CA1094533A (fr)
DE (1) DE2736996C2 (fr)
ES (1) ES461834A1 (fr)
FR (1) FR2362916A1 (fr)
GB (1) GB1570427A (fr)
NL (1) NL179347C (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8334155D0 (en) * 1983-12-22 1984-02-01 Ici Plc Catalytic composition
US5134109A (en) * 1989-07-07 1992-07-28 Idemitsu Kosan Company Limited Catalyst for reforming hydrocarbon with steam
EP0950638B1 (fr) * 1997-07-15 2012-10-17 Japan Energy Corporation Poudre de pseudo-boehmite pour support catalytique et son procede de fabrication
WO2011068665A1 (fr) * 2009-12-04 2011-06-09 Exxonmobil Research And Engineering Company Procédé de reformage à cycle rapide
CA2871356C (fr) * 2012-04-26 2020-06-30 Opinder Kishan Bhan Catalyseur d'hydrotraitement et procede de traitement de charges d'alimentation a base d'hydrocarbures lourds

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7204709A (fr) * 1971-04-09 1972-10-11
US3790503A (en) * 1972-03-27 1974-02-05 Universal Oil Prod Co Method of manufacturing a germanium catalyst
FR2229758A1 (fr) * 1973-05-14 1974-12-13 Continental Oil Co
US3884799A (en) * 1972-12-11 1975-05-20 Standard Oil Co Reforming with platinum-rhenium-selenium catalysts
NL7415191A (nl) * 1973-11-23 1975-05-27 Raffinage Cie Francaise Reformkatalysator.
FR2268558A1 (en) * 1974-04-23 1975-11-21 Catalyse Soc Prod Francais Catalysts for hydrocarbon conversion - contg. gp. VIII metal, manganese and germanium, tin or rhenium, on alumina carrier
GB1438010A (fr) * 1972-09-07 1976-06-03
US3972990A (en) * 1975-05-30 1976-08-03 Universal Oil Products Company Method of preparing low density-high micropore volume refractory inorganic oxide particles
US4008182A (en) * 1973-12-28 1977-02-15 Uop Inc. Low density refractory inorganic oxide particles having high micropore volume

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2973330A (en) * 1957-12-23 1961-02-28 Exxon Research Engineering Co Hydroforming catalyst
US3193348A (en) * 1962-02-19 1965-07-06 Sinclair Research Inc Method of producing boehmite having crystal size in excess of 100 a
US3415737A (en) * 1966-06-24 1968-12-10 Chevron Res Reforming a sulfur-free naphtha with a platinum-rhenium catalyst
FR2076937A5 (fr) * 1970-01-30 1971-10-15 Chevron Res
US3846343A (en) * 1970-02-13 1974-11-05 H Erickson Process for preparing a platinum-rhenium catalyst on an alumina support
US3743709A (en) * 1971-07-12 1973-07-03 Canadian Patents Dev Preparation of highly porous alumina
BE787953A (fr) * 1971-08-26 1973-02-26 Franc De Comp Procede de regulation de la teneur en halogene des catalyseurs de conversion des hydrocarbures
US3804781A (en) * 1972-07-28 1974-04-16 American Cyanamid Co Extruded alumina catalyst supports
US4006074A (en) * 1972-09-07 1977-02-01 Atlantic Richfield Company Reforming with a platinum-alumina catalyst
US3948804A (en) * 1973-12-10 1976-04-06 Universal Oil Products Company Superactive acidic bimetallic catalytic composite and use thereof in conversion of hydrocarbons
BE832072A (fr) * 1974-08-12 1975-12-01 Compositions ameliorees pour catalyse et leur procede de preparation

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7204709A (fr) * 1971-04-09 1972-10-11
FR2132676A1 (fr) * 1971-04-09 1972-11-24 Chevron Res
US3790503A (en) * 1972-03-27 1974-02-05 Universal Oil Prod Co Method of manufacturing a germanium catalyst
GB1438010A (fr) * 1972-09-07 1976-06-03
US3884799A (en) * 1972-12-11 1975-05-20 Standard Oil Co Reforming with platinum-rhenium-selenium catalysts
FR2229758A1 (fr) * 1973-05-14 1974-12-13 Continental Oil Co
NL7415191A (nl) * 1973-11-23 1975-05-27 Raffinage Cie Francaise Reformkatalysator.
FR2252394A1 (fr) * 1973-11-23 1975-06-20 Raffinage Cie Francaise
US4008182A (en) * 1973-12-28 1977-02-15 Uop Inc. Low density refractory inorganic oxide particles having high micropore volume
FR2268558A1 (en) * 1974-04-23 1975-11-21 Catalyse Soc Prod Francais Catalysts for hydrocarbon conversion - contg. gp. VIII metal, manganese and germanium, tin or rhenium, on alumina carrier
US3972990A (en) * 1975-05-30 1976-08-03 Universal Oil Products Company Method of preparing low density-high micropore volume refractory inorganic oxide particles

Also Published As

Publication number Publication date
BE858011A (fr) 1977-12-16
DE2736996A1 (de) 1978-03-09
JPS5326789A (en) 1978-03-13
NL179347B (nl) 1986-04-01
JPS585702B2 (ja) 1983-02-01
GB1570427A (en) 1980-07-02
NL7709251A (nl) 1978-02-27
AU2815477A (en) 1979-03-01
CA1094533A (fr) 1981-01-27
NL179347C (nl) 1986-09-01
DE2736996C2 (de) 1986-03-06
ES461834A1 (es) 1978-12-16
FR2362916B1 (fr) 1982-01-08
US4129497A (en) 1978-12-12
AU511968B2 (en) 1980-09-18

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