FR2387949A1 - Procede de preparation de mercaptans - Google Patents
Procede de preparation de mercaptansInfo
- Publication number
- FR2387949A1 FR2387949A1 FR7712002A FR7712002A FR2387949A1 FR 2387949 A1 FR2387949 A1 FR 2387949A1 FR 7712002 A FR7712002 A FR 7712002A FR 7712002 A FR7712002 A FR 7712002A FR 2387949 A1 FR2387949 A1 FR 2387949A1
- Authority
- FR
- France
- Prior art keywords
- mercaptans
- preparation process
- mercaptan
- thiocarbonyl
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title 1
- 238000000034 method Methods 0.000 abstract 3
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical group SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 abstract 2
- SKOLWUPSYHWYAM-UHFFFAOYSA-N carbonodithioic O,S-acid Chemical compound SC(S)=O SKOLWUPSYHWYAM-UHFFFAOYSA-N 0.000 abstract 1
- 150000001728 carbonyl compounds Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 150000003564 thiocarbonyl compounds Chemical class 0.000 abstract 1
- 125000002813 thiocarbonyl group Chemical group *C(*)=S 0.000 abstract 1
- 150000003573 thiols Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
- C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Procédé pour la production de mercaptan primaire ou secondaire, par chauffage de dérivé thiocarbonylé (thioaldéhyde, thiocétone) correspondant, en présence d'un autre mercaptan << partenaire >> et d'un catalyseur. Le composé thiocarbonylé peut être formé in situ à partir du composé carbonylé et d'hydrogène sulfuré. Ce procédé est particulièrement intéressant pour l'obtention de thiols secondaires difficiles à obtenir par les méthodes déjà connues.
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7712002A FR2387949A1 (fr) | 1977-04-21 | 1977-04-21 | Procede de preparation de mercaptans |
| DE19782816826 DE2816826A1 (de) | 1977-04-21 | 1978-04-18 | Verfahren zur herstellung von mercaptanen |
| US05/897,387 US4161493A (en) | 1977-04-21 | 1978-04-18 | Process for the production of mercaptans |
| IT22500/78A IT1094079B (it) | 1977-04-21 | 1978-04-20 | Procedimento per la preparazione di mercaptani |
| CA301,516A CA1108189A (fr) | 1977-04-21 | 1978-04-20 | Procede de preparation de mercaptans |
| JP4599478A JPS53132513A (en) | 1977-04-21 | 1978-04-20 | Process for preparing mercaptan |
| BE186947A BE866179A (fr) | 1977-04-21 | 1978-04-20 | Procede de preparation de mercaptans |
| NL7804301A NL7804301A (nl) | 1977-04-21 | 1978-04-21 | Werkwijze voor de bereiding van mercaptanen. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7712002A FR2387949A1 (fr) | 1977-04-21 | 1977-04-21 | Procede de preparation de mercaptans |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2387949A1 true FR2387949A1 (fr) | 1978-11-17 |
| FR2387949B1 FR2387949B1 (fr) | 1980-01-18 |
Family
ID=9189719
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7712002A Granted FR2387949A1 (fr) | 1977-04-21 | 1977-04-21 | Procede de preparation de mercaptans |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4161493A (fr) |
| JP (1) | JPS53132513A (fr) |
| BE (1) | BE866179A (fr) |
| CA (1) | CA1108189A (fr) |
| DE (1) | DE2816826A1 (fr) |
| FR (1) | FR2387949A1 (fr) |
| IT (1) | IT1094079B (fr) |
| NL (1) | NL7804301A (fr) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7217843B2 (en) * | 2005-04-27 | 2007-05-15 | Chevron Phillips Chemical Company Lp | Method of making 2-thiols |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2051806A (en) * | 1935-03-18 | 1936-08-25 | Shell Dev | Production of mercaptans |
| US2402613A (en) * | 1939-08-11 | 1946-06-25 | Du Pont | Method of producing thiols |
| US2402694A (en) * | 1940-09-19 | 1946-06-25 | Du Pont | Chemical processes |
| US2402615A (en) * | 1940-09-19 | 1946-06-25 | Du Pont | Catalytic process and products thereof |
| US2437985A (en) * | 1944-06-16 | 1948-03-16 | Shell Dev | Production of thioketones |
| US3994980A (en) * | 1975-10-15 | 1976-11-30 | Phillips Petroleum Company | Cobalt molybdate as catalyst for preparation of mercaptans from carbonyl compounds hydrogen sulfide and hydrogen |
-
1977
- 1977-04-21 FR FR7712002A patent/FR2387949A1/fr active Granted
-
1978
- 1978-04-18 DE DE19782816826 patent/DE2816826A1/de not_active Withdrawn
- 1978-04-18 US US05/897,387 patent/US4161493A/en not_active Expired - Lifetime
- 1978-04-20 IT IT22500/78A patent/IT1094079B/it active
- 1978-04-20 CA CA301,516A patent/CA1108189A/fr not_active Expired
- 1978-04-20 JP JP4599478A patent/JPS53132513A/ja active Pending
- 1978-04-20 BE BE186947A patent/BE866179A/fr unknown
- 1978-04-21 NL NL7804301A patent/NL7804301A/xx not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| US4161493A (en) | 1979-07-17 |
| CA1108189A (fr) | 1981-09-01 |
| IT7822500A0 (it) | 1978-04-20 |
| BE866179A (fr) | 1978-08-14 |
| JPS53132513A (en) | 1978-11-18 |
| IT1094079B (it) | 1985-07-26 |
| NL7804301A (nl) | 1978-10-24 |
| FR2387949B1 (fr) | 1980-01-18 |
| DE2816826A1 (de) | 1978-10-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |