FR2405914A1 - Procede de preparation de p-alkyl-phenols - Google Patents

Procede de preparation de p-alkyl-phenols

Info

Publication number
FR2405914A1
FR2405914A1 FR7828849A FR7828849A FR2405914A1 FR 2405914 A1 FR2405914 A1 FR 2405914A1 FR 7828849 A FR7828849 A FR 7828849A FR 7828849 A FR7828849 A FR 7828849A FR 2405914 A1 FR2405914 A1 FR 2405914A1
Authority
FR
France
Prior art keywords
alkyl
phenols
catalyst
reaction
degrees
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7828849A
Other languages
English (en)
Other versions
FR2405914B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huels AG
Original Assignee
Chemische Werke Huels AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemische Werke Huels AG filed Critical Chemische Werke Huels AG
Publication of FR2405914A1 publication Critical patent/FR2405914A1/fr
Application granted granted Critical
Publication of FR2405914B1 publication Critical patent/FR2405914B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon unsaturated bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention est relative à un procédé de préparation de p-alkyl-phénols. Selon l'invention, dans un premier stade de réaction on conduit l'alkylation à une température de 80 à 140 degrés C en présence d'un catalyseur en suspension, en introduisant par le bas dans le mélange réactionnel les oléfines à l'état gazeux avec une vitesse de 3 à 20 cm/s rapportée à la section libre du réacteur vide, sur la base d'un volume molaire de 25 litres par mole d'oléfine, tandis que dans un deuxième stade de réaction, on fait passer sur un catalyseur disposé de façon fixe le produit de réaction liquide obtenu, à une température de 80 à 140 degrés C et que l'on utilise aux deux stades de réaction un catalyseur dont la capacité d'échange est de 70 à 120 millivalences/100 ml. Le procédé permet d'obtenir de p-alkyl-phénols de haute qualité avec une grande sélectivité et un grand rendement.
FR7828849A 1977-10-11 1978-10-10 Procede de preparation de p-alkyl-phenols Granted FR2405914A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2745589A DE2745589C3 (de) 1977-10-11 1977-10-11 Verfahren zur Herstellung von p-Alkylphenolen

Publications (2)

Publication Number Publication Date
FR2405914A1 true FR2405914A1 (fr) 1979-05-11
FR2405914B1 FR2405914B1 (fr) 1983-11-25

Family

ID=6021128

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7828849A Granted FR2405914A1 (fr) 1977-10-11 1978-10-10 Procede de preparation de p-alkyl-phenols

Country Status (10)

Country Link
US (1) US4236033A (fr)
JP (1) JPS5461130A (fr)
BE (1) BE871105A (fr)
BR (1) BR7806690A (fr)
DE (1) DE2745589C3 (fr)
FR (1) FR2405914A1 (fr)
GB (1) GB2007224B (fr)
IT (1) IT1157363B (fr)
NL (1) NL7810189A (fr)
SU (1) SU1178321A3 (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4380677A (en) * 1981-05-11 1983-04-19 Uop Inc. Preparation of 2,6-di-tert-butyl-4-alkylphenols
US4418222A (en) * 1981-05-26 1983-11-29 Chevron Research Company Continuous phenol alkylation process
US4391998A (en) * 1981-10-21 1983-07-05 Mobil Oil Corporation Production of para-isopropylphenol
DE3151693A1 (de) * 1981-12-29 1983-07-07 Chemische Werke Hüls AG, 4370 Marl Verfahren zur herstellung von p-tert.-octylphenol durch katalytische alkylierung von phenol
DE3443736A1 (de) * 1984-11-30 1986-06-05 Hüls AG, 4370 Marl Verfahren zur gleichzeitigen herstellung von ortho-, para- und 2.4-di-tert.-butylphenol
CN1056597C (zh) * 1996-01-25 2000-09-20 中国石油化工总公司 烷基酚制备工艺
GB9722719D0 (en) 1997-10-29 1997-12-24 Fmc Corp Uk Ltd Production of phosphate esters
US6124512A (en) * 1998-09-18 2000-09-26 Occidental Chemical Corporation Ring halogenation of aromatic compounds
US6339177B1 (en) 2000-05-24 2002-01-15 Sea Lion Technology, Inc. Dinitroalkyl aromatics polymerization retarders or inhibitors and methods for making and for using same
JP2003040822A (ja) * 2001-07-30 2003-02-13 Dainippon Ink & Chem Inc ４−ターシャリーブチルフェノールの製造方法
TWI624450B (zh) * 2009-12-04 2018-05-21 Ｓｉ集團股份有限公司 從ｃ萃餘物之物流製造三級丁基酚之方法
JP6885487B1 (ja) 2020-03-30 2021-06-16 住友大阪セメント株式会社 リチウムイオン二次電池用正極材料、リチウムイオン二次電池用正極及びリチウムイオン二次電池

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3257467A (en) * 1960-07-21 1966-06-21 Monsanto Co Continuous methods for effecting ring substitution of phenols
DE1443346A1 (de) * 1960-10-12 1968-10-31 Union Carbide Corp Verfahren zur Alkylierung von Arylhydroxyden
US3422157A (en) * 1966-04-18 1969-01-14 Union Carbide Corp Process for continuous alkylation of arylhydroxides using ion exchange resins
FR2228749A1 (en) * 1973-05-08 1974-12-06 Sidobre Sinnova Produit Chimiq Para-(octyl or tert-butyl) phenol prodn. - from phenol and diisobutylene over cation exchanger pref. with anhydrous catalyst
DE2346273B1 (de) * 1973-09-14 1975-01-23 Huels Chemische Werke Ag Verfahren zur Herstellung von Alkylphenolen
DE2526644A1 (de) * 1975-06-14 1976-12-30 Basf Ag Verfahren zur herstellung von p-alkylphenolen

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL263528A (fr) * 1960-04-13
US3308168A (en) * 1961-03-02 1967-03-07 Monsanto Co Method for effecting alkyl ring substitution of phenols employing a sulfonated polyvinyl aryl resin derivative as a catalyst

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3257467A (en) * 1960-07-21 1966-06-21 Monsanto Co Continuous methods for effecting ring substitution of phenols
DE1443346A1 (de) * 1960-10-12 1968-10-31 Union Carbide Corp Verfahren zur Alkylierung von Arylhydroxyden
US3422157A (en) * 1966-04-18 1969-01-14 Union Carbide Corp Process for continuous alkylation of arylhydroxides using ion exchange resins
FR2228749A1 (en) * 1973-05-08 1974-12-06 Sidobre Sinnova Produit Chimiq Para-(octyl or tert-butyl) phenol prodn. - from phenol and diisobutylene over cation exchanger pref. with anhydrous catalyst
DE2346273B1 (de) * 1973-09-14 1975-01-23 Huels Chemische Werke Ag Verfahren zur Herstellung von Alkylphenolen
DE2526644A1 (de) * 1975-06-14 1976-12-30 Basf Ag Verfahren zur herstellung von p-alkylphenolen
FR2314167A1 (fr) * 1975-06-14 1977-01-07 Basf Ag Procede de preparation de para-alkylphenols

Also Published As

Publication number Publication date
DE2745589B2 (de) 1979-07-12
FR2405914B1 (fr) 1983-11-25
SU1178321A3 (ru) 1985-09-07
IT1157363B (it) 1987-02-11
JPS5461130A (en) 1979-05-17
BE871105A (fr) 1979-04-09
US4236033A (en) 1980-11-25
DE2745589A1 (de) 1979-04-12
NL7810189A (nl) 1979-04-17
BR7806690A (pt) 1979-05-02
GB2007224B (en) 1982-05-06
JPS6237617B2 (fr) 1987-08-13
IT7851414A0 (it) 1978-10-09
GB2007224A (en) 1979-05-16
DE2745589C3 (de) 1980-03-27

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Legal Events

Date Code Title Description
ST Notification of lapse