FR2444657A1 - Procede de preparation du methyl-nonyl-acetaldehyde - Google Patents
Procede de preparation du methyl-nonyl-acetaldehydeInfo
- Publication number
- FR2444657A1 FR2444657A1 FR7930767A FR7930767A FR2444657A1 FR 2444657 A1 FR2444657 A1 FR 2444657A1 FR 7930767 A FR7930767 A FR 7930767A FR 7930767 A FR7930767 A FR 7930767A FR 2444657 A1 FR2444657 A1 FR 2444657A1
- Authority
- FR
- France
- Prior art keywords
- methyl
- undecanal
- acetaldehyde
- nonyl
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- NFAVNWJJYQAGNB-UHFFFAOYSA-N 2-methylundecanal Chemical compound CCCCCCCCCC(C)C=O NFAVNWJJYQAGNB-UHFFFAOYSA-N 0.000 title abstract 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 6
- KMPQYAYAQWNLME-UHFFFAOYSA-N Undecanal Natural products CCCCCCCCCCC=O KMPQYAYAQWNLME-UHFFFAOYSA-N 0.000 abstract 5
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical group CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000007037 hydroformylation reaction Methods 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 150000003335 secondary amines Chemical class 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- FBJOZYRPJMTSNP-UHFFFAOYSA-N undecanal Chemical compound CCCCCCCCCCC=O.CCCCCCCCCCC=O FBJOZYRPJMTSNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/62—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by hydrogenation of carbon-to-carbon double or triple bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
- C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
- C07C45/75—Reactions with formaldehyde
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Procédé pour préparer le méthyl-nonyl-acétaldéhyde à partir de l'undécanal et du formaldéhyde ou d'une substance libérant du formaldéhyde en présence de quantités catalytiques d'une amine secondaire On utilise l'undécanal sous la forme du mélange de réaction obtenu à l'hydroformylation du 1-décène, le catalyseur est la di-n-butylamine, le rapport molaire catalyseur/undécanal va de 0,025 à 0,050: 1, la réaction est effectuée à une température de 90 à 100 degrés C, et le 2-méthyl-undécanal obtenu est ensuite converti par hydrogénation partielle en méthyl-nonyl-acétaldéhyde.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2855506A DE2855506C3 (de) | 1978-12-22 | 1978-12-22 | Verfahren zur Herstellung von Methyl-nonyl-acetaldehyd |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2444657A1 true FR2444657A1 (fr) | 1980-07-18 |
| FR2444657B1 FR2444657B1 (fr) | 1983-08-19 |
Family
ID=6058010
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7930767A Granted FR2444657A1 (fr) | 1978-12-22 | 1979-12-14 | Procede de preparation du methyl-nonyl-acetaldehyde |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4263460A (fr) |
| JP (1) | JPS5826890B2 (fr) |
| CA (1) | CA1105056A (fr) |
| CH (1) | CH641433A5 (fr) |
| DE (1) | DE2855506C3 (fr) |
| FR (1) | FR2444657A1 (fr) |
| GB (1) | GB2037769B (fr) |
| IT (1) | IT1207017B (fr) |
| NL (1) | NL178414C (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0487035A3 (en) * | 1990-11-20 | 1992-11-25 | Himont Incorporated | Process for the preparation of diethers |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4740639A (en) * | 1987-06-12 | 1988-04-26 | Eastman Kodak Company | Process for preparation of 2,4-disubstituted-1,5-pentanediols |
| DE3744212A1 (de) * | 1987-12-24 | 1989-07-06 | Ruhrchemie Ag | Verfahren zur herstellung von 2-methylbutanal |
| DE3842186A1 (de) * | 1988-12-15 | 1990-06-21 | Basf Ag | Verfahren zur gewinnung von 2-alkylverzweigten alkanalen aus alkanalgemischen |
| KR101529828B1 (ko) * | 2013-07-26 | 2015-06-17 | 주식회사 엘지화학 | 메틸올알칸알의 제조방법 |
| ES2714899T3 (es) | 2016-09-30 | 2019-05-30 | Oxea Gmbh | Método de producción continuo para 2-metilenos-alcanales |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2639295A (en) * | 1948-07-16 | 1953-05-19 | Eastman Kodak Co | Manufacture of unsaturated aldehydes |
| FR1508854A (fr) * | 1966-01-25 | 1968-01-05 | Int Flavors & Fragrances Inc | Procédé pour la préparation d'alpha-méthylène- et alpha-méthylaldéhydes et -alcools et de leurs dérivés, et produits ainsi obtenus |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3448158A (en) * | 1966-01-28 | 1969-06-03 | Shell Oil Co | Hydroformylation of olefins |
| US3981925A (en) * | 1972-05-08 | 1976-09-21 | Texaco Inc. | Selective hydroformylation process using homogeneous catalysts |
| US3959386A (en) * | 1974-05-13 | 1976-05-25 | Universal Oil Products Company | Production of primary compounds |
-
1978
- 1978-12-22 DE DE2855506A patent/DE2855506C3/de not_active Expired
-
1979
- 1979-12-12 NL NLAANVRAGE7908947,A patent/NL178414C/xx not_active IP Right Cessation
- 1979-12-14 FR FR7930767A patent/FR2444657A1/fr active Granted
- 1979-12-14 CH CH1112379A patent/CH641433A5/de not_active IP Right Cessation
- 1979-12-15 JP JP54162204A patent/JPS5826890B2/ja not_active Expired
- 1979-12-18 GB GB7943591A patent/GB2037769B/en not_active Expired
- 1979-12-18 IT IT7951127A patent/IT1207017B/it active
- 1979-12-20 CA CA342,425A patent/CA1105056A/fr not_active Expired
- 1979-12-21 US US06/106,299 patent/US4263460A/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2639295A (en) * | 1948-07-16 | 1953-05-19 | Eastman Kodak Co | Manufacture of unsaturated aldehydes |
| FR1508854A (fr) * | 1966-01-25 | 1968-01-05 | Int Flavors & Fragrances Inc | Procédé pour la préparation d'alpha-méthylène- et alpha-méthylaldéhydes et -alcools et de leurs dérivés, et produits ainsi obtenus |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0487035A3 (en) * | 1990-11-20 | 1992-11-25 | Himont Incorporated | Process for the preparation of diethers |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1105056A (fr) | 1981-07-14 |
| CH641433A5 (de) | 1984-02-29 |
| GB2037769A (en) | 1980-07-16 |
| GB2037769B (en) | 1983-05-05 |
| FR2444657B1 (fr) | 1983-08-19 |
| IT7951127A0 (it) | 1979-12-18 |
| DE2855506B2 (de) | 1980-09-11 |
| IT1207017B (it) | 1989-05-17 |
| US4263460A (en) | 1981-04-21 |
| JPS5592334A (en) | 1980-07-12 |
| NL178414C (nl) | 1986-03-17 |
| DE2855506A1 (de) | 1980-06-26 |
| NL178414B (nl) | 1985-10-16 |
| NL7908947A (nl) | 1980-06-24 |
| DE2855506C3 (de) | 1981-04-30 |
| JPS5826890B2 (ja) | 1983-06-06 |
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