FR2429802A1 - Procede perfectionne pour preparer des copolyether glycols a groupes terminaux ester - Google Patents

Procede perfectionne pour preparer des copolyether glycols a groupes terminaux ester

Info

Publication number
FR2429802A1
FR2429802A1 FR7819654A FR7819654A FR2429802A1 FR 2429802 A1 FR2429802 A1 FR 2429802A1 FR 7819654 A FR7819654 A FR 7819654A FR 7819654 A FR7819654 A FR 7819654A FR 2429802 A1 FR2429802 A1 FR 2429802A1
Authority
FR
France
Prior art keywords
polymer
gps
catalyst
monomer
terminal ester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7819654A
Other languages
English (en)
Other versions
FR2429802B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority to FR7819654A priority Critical patent/FR2429802A1/fr
Priority to BE189066A priority patent/BE868726A/fr
Publication of FR2429802A1 publication Critical patent/FR2429802A1/fr
Application granted granted Critical
Publication of FR2429802B1 publication Critical patent/FR2429802B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2654—Aluminium or boron; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/16—Cyclic ethers having four or more ring atoms
    • C08G65/20—Tetrahydrofuran
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2669—Non-metals or compounds thereof
    • C08G65/2684—Halogens or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyethers (AREA)

Abstract

Procédé perfectionné pour copolymériser du tétrahydrofuranne et un oxyde d'alcoylène ou un acétal cyclique. On prépare un copolyéther glycol à groupes terminaux ester en copolymérisant du tétrahydrofuranne et un oxyde d'alcoylène ou un acétal Cyclique dans un milieu de réaction qui contient, en plus du tétrahydrofuranne et de l'oxyde d'alcoylène ou de l'acétal cyclique : un catalyseur polymère contenant des groupes acide alpha -fluoro sulfonique, et un progéniteur d'ion acylium tel que l'anhydride acétique. Application à la préparation de polyuréthanes.
FR7819654A 1978-06-30 1978-06-30 Procede perfectionne pour preparer des copolyether glycols a groupes terminaux ester Granted FR2429802A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR7819654A FR2429802A1 (fr) 1978-06-30 1978-06-30 Procede perfectionne pour preparer des copolyether glycols a groupes terminaux ester
BE189066A BE868726A (fr) 1978-06-30 1978-07-04 Procede perfectionne pour preparer des copolyether-glycols a groupes terminaux ester

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR7819654A FR2429802A1 (fr) 1978-06-30 1978-06-30 Procede perfectionne pour preparer des copolyether glycols a groupes terminaux ester
BE189066A BE868726A (fr) 1978-06-30 1978-07-04 Procede perfectionne pour preparer des copolyether-glycols a groupes terminaux ester

Publications (2)

Publication Number Publication Date
FR2429802A1 true FR2429802A1 (fr) 1980-01-25
FR2429802B1 FR2429802B1 (fr) 1984-12-14

Family

ID=25650880

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7819654A Granted FR2429802A1 (fr) 1978-06-30 1978-06-30 Procede perfectionne pour preparer des copolyether glycols a groupes terminaux ester

Country Status (2)

Country Link
BE (1) BE868726A (fr)
FR (1) FR2429802A1 (fr)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2357591A1 (fr) * 1976-03-31 1978-02-03 Du Pont Preparation de poly(tetramethylene ether glycol et d'esters de celui-ci

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2357591A1 (fr) * 1976-03-31 1978-02-03 Du Pont Preparation de poly(tetramethylene ether glycol et d'esters de celui-ci

Also Published As

Publication number Publication date
BE868726A (fr) 1979-01-04
FR2429802B1 (fr) 1984-12-14

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Legal Events

Date Code Title Description
ST Notification of lapse