FR2575484A1 - Complexes silicate feuillete-amas d'alcoxysilanes et leur procede de preparation - Google Patents

Complexes silicate feuillete-amas d'alcoxysilanes et leur procede de preparation Download PDF

Info

Publication number: FR2575484A1
Authority: FR; France
Prior art keywords: silicate; cations; alcoxysilanes; interstitial; cluster
Prior art date: 1984-12-31
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

FR8519134A

Other languages

English (en)

French (fr)

Inventor

Thomas Michael Tymon

Franklin Lee Fox

Burt Frederick Hofferth

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Armstrong World Industries Inc

Original Assignee

Armstrong World Industries Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-12-31

Filing date

1985-12-24

Publication date

1986-07-04

1985-12-24 Application filed by Armstrong World Industries Inc filed Critical Armstrong World Industries Inc

1986-07-04 Publication of FR2575484A1 publication Critical patent/FR2575484A1/fr

Status Withdrawn legal-status Critical Current

Links

VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title abstract description 14
238000002360 preparation method Methods 0.000 title description 4
150000001768 cations Chemical class 0.000 abstract description 19
150000001875 compounds Chemical class 0.000 abstract description 11
239000000463 material Substances 0.000 abstract description 11
239000002808 molecular sieve Substances 0.000 abstract description 9
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract description 9
238000006243 chemical reaction Methods 0.000 abstract description 8
238000005342 ion exchange Methods 0.000 abstract description 8
150000002500 ions Chemical class 0.000 abstract description 6
229910052500 inorganic mineral Inorganic materials 0.000 abstract description 5
239000011707 mineral Substances 0.000 abstract description 5
229910052710 silicon Inorganic materials 0.000 abstract 2
239000010703 silicon Substances 0.000 abstract 2
-1 cracking Chemical class 0.000 description 15
238000000034 method Methods 0.000 description 15
150000004760 silicates Chemical class 0.000 description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 14
239000004927 clay Substances 0.000 description 12
125000004432 carbon atom Chemical group C* 0.000 description 10
125000000217 alkyl group Chemical group 0.000 description 9
239000010410 layer Substances 0.000 description 9
125000002091 cationic group Chemical group 0.000 description 8
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
230000008961 swelling Effects 0.000 description 7
239000013078 crystal Substances 0.000 description 6
239000007788 liquid Substances 0.000 description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 5
229910052744 lithium Inorganic materials 0.000 description 5
239000010445 mica Substances 0.000 description 5
229910052618 mica group Inorganic materials 0.000 description 5
229910052628 phlogopite Inorganic materials 0.000 description 5
239000011734 sodium Substances 0.000 description 5
125000003342 alkenyl group Chemical group 0.000 description 4
125000003710 aryl alkyl group Chemical group 0.000 description 4
125000003118 aryl group Chemical group 0.000 description 4
244000144992 flock Species 0.000 description 4
239000011148 porous material Substances 0.000 description 4
239000000377 silicon dioxide Substances 0.000 description 4
229910052708 sodium Inorganic materials 0.000 description 4
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
238000002441 X-ray diffraction Methods 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
229910052796 boron Inorganic materials 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000000203 mixture Substances 0.000 description 3
239000007858 starting material Substances 0.000 description 3
239000010455 vermiculite Substances 0.000 description 3
229910052902 vermiculite Inorganic materials 0.000 description 3
235000019354 vermiculite Nutrition 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
238000005336 cracking Methods 0.000 description 2
239000008367 deionised water Substances 0.000 description 2
229910021641 deionized water Inorganic materials 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
239000011229 interlayer Substances 0.000 description 2
238000011017 operating method Methods 0.000 description 2
239000002245 particle Substances 0.000 description 2
239000006104 solid solution Substances 0.000 description 2
239000000243 solution Substances 0.000 description 2
241000894007 species Species 0.000 description 2
239000000758 substrate Substances 0.000 description 2
239000000725 suspension Substances 0.000 description 2
239000000454 talc Substances 0.000 description 2
229910052623 talc Inorganic materials 0.000 description 2
239000010457 zeolite Substances 0.000 description 2
125000006176 2-ethylbutyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])*)C([H])([H])C([H])([H])[H] 0.000 description 1
125000004337 3-ethylpentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
235000017399 Caesalpinia tinctoria Nutrition 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
241000388430 Tara Species 0.000 description 1
OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
238000013019 agitation Methods 0.000 description 1
125000005024 alkenyl aryl group Chemical group 0.000 description 1
125000003545 alkoxy group Chemical class 0.000 description 1
230000029936 alkylation Effects 0.000 description 1
238000005804 alkylation reaction Methods 0.000 description 1
150000001413 amino acids Chemical class 0.000 description 1
239000003125 aqueous solvent Substances 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
GRHHVGHRQARKAM-UHFFFAOYSA-N benzyl-dimethyl-propylazanium Chemical compound CCC[N+](C)(C)CC1=CC=CC=C1 GRHHVGHRQARKAM-UHFFFAOYSA-N 0.000 description 1
150000001638 boron Chemical class 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
238000004517 catalytic hydrocracking Methods 0.000 description 1
238000012512 characterization method Methods 0.000 description 1
239000002734 clay mineral Substances 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
230000020335 dealkylation Effects 0.000 description 1
238000006900 dealkylation reaction Methods 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000010586 diagram Methods 0.000 description 1
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
238000005189 flocculation Methods 0.000 description 1
230000016615 flocculation Effects 0.000 description 1
239000011521 glass Substances 0.000 description 1
KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
229910000271 hectorite Inorganic materials 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
238000003780 insertion Methods 0.000 description 1
230000037431 insertion Effects 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
238000006317 isomerization reaction Methods 0.000 description 1
239000002648 laminated material Substances 0.000 description 1
229910001416 lithium ion Inorganic materials 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
238000006053 organic reaction Methods 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000002798 polar solvent Substances 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
125000001453 quaternary ammonium group Chemical class 0.000 description 1
230000005855 radiation Effects 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
238000007665 sagging Methods 0.000 description 1
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
150000004819 silanols Chemical class 0.000 description 1
125000004469 siloxy group Chemical group [SiH3]O* 0.000 description 1
229910001415 sodium ion Inorganic materials 0.000 description 1
239000002904 solvent Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/06—Boron halogen compounds
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
- C01B33/38—Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
- C01B33/44—Products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds, e.g. organoclay material
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
- C01B35/10—Compounds containing boron and oxygen
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/20—Mica; Vermiculite
- C04B14/206—Mica or vermiculite modified by cation-exchange; chemically exfoliated vermiculate

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Engineering & Computer Science (AREA)
Ceramic Engineering (AREA)
Health & Medical Sciences (AREA)
General Health & Medical Sciences (AREA)
Civil Engineering (AREA)
Materials Engineering (AREA)
Structural Engineering (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)
Catalysts (AREA)

FR8519134A 1984-12-31 1985-12-24 Complexes silicate feuillete-amas d'alcoxysilanes et leur procede de preparation Withdrawn FR2575484A1 (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US68785284A	1984-12-31	1984-12-31

Publications (1)

Publication Number	Publication Date
FR2575484A1 true FR2575484A1 (fr)	1986-07-04

Family

ID=24762135

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FR8519134A Withdrawn FR2575484A1 (fr)	1984-12-31	1985-12-24	Complexes silicate feuillete-amas d'alcoxysilanes et leur procede de preparation

Country Status (12)

Country	Link
JP (1)	JPS61163113A (it)
CN (1)	CN85109768A (it)
AU (1)	AU4931085A (it)
BE (1)	BE903974A (it)
DE (1)	DE3540102A1 (it)
ES (1)	ES8700962A1 (it)
FR (1)	FR2575484A1 (it)
GB (1)	GB2169274A (it)
IT (1)	IT1201509B (it)
LU (1)	LU86236A1 (it)
NL (1)	NL8503565A (it)
SE (1)	SE8506154L (it)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5462905A (en) *	1992-08-21	1995-10-31	Toyota Jidosha Kabushiki Kaisha	Exhaust gas purifying catalyst

Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1571983A (en) *	1977-05-16	1980-07-23	Imai M	Sol of ultra-fine particles of layered structure material
US4367163A (en) *	1981-04-15	1983-01-04	Research Corporation	Silica-clay complexes

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4239519A (en) *	1979-03-26	1980-12-16	Corning Glass Works	Inorganic gels and ceramic papers, films, fibers, boards, and coatings made therefrom
US4510257A (en) *	1983-12-08	1985-04-09	Shell Oil Company	Silica-clay complexes

1985
- 1985-10-30 ES ES548368A patent/ES8700962A1/es not_active Expired
- 1985-11-04 AU AU49310/85A patent/AU4931085A/en not_active Abandoned
- 1985-11-12 DE DE19853540102 patent/DE3540102A1/de not_active Withdrawn
- 1985-12-12 JP JP60278122A patent/JPS61163113A/ja active Pending
- 1985-12-20 IT IT23350/85A patent/IT1201509B/it active
- 1985-12-24 FR FR8519134A patent/FR2575484A1/fr not_active Withdrawn
- 1985-12-24 NL NL8503565A patent/NL8503565A/nl not_active Application Discontinuation
- 1985-12-30 GB GB08531865A patent/GB2169274A/en not_active Withdrawn
- 1985-12-30 CN CN198585109768A patent/CN85109768A/zh not_active Withdrawn
- 1985-12-30 LU LU86236A patent/LU86236A1/de unknown
- 1985-12-30 SE SE8506154A patent/SE8506154L/ not_active Application Discontinuation
- 1985-12-31 BE BE0/216090A patent/BE903974A/fr unknown

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1571983A (en) *	1977-05-16	1980-07-23	Imai M	Sol of ultra-fine particles of layered structure material
US4367163A (en) *	1981-04-15	1983-01-04	Research Corporation	Silica-clay complexes

Also Published As

Publication number	Publication date
JPS61163113A (ja)	1986-07-23
DE3540102A1 (de)	1986-07-10
SE8506154L (sv)	1986-07-01
AU4931085A (en)	1986-07-10
ES548368A0 (es)	1986-11-16
LU86236A1 (de)	1986-06-11
IT1201509B (it)	1989-02-02
GB8531865D0 (en)	1986-02-05
BE903974A (fr)	1986-06-30
SE8506154D0 (sv)	1985-12-30
ES8700962A1 (es)	1986-11-16
GB2169274A (en)	1986-07-09
IT8523350A0 (it)	1985-12-20
CN85109768A (zh)	1986-09-24
NL8503565A (nl)	1986-07-16

Legal Events

Date	Code	Title	Description
1987-10-23	ST	Notification of lapse

Publication	Publication Date	Title
DE69404876T2 (de)	1998-02-26	Verfahren zur Herstellung von, im wesentlichen Silanol-freien Silikonharzpulvern
CA1212658A (fr)	1986-10-14	Procede de preparation de zeolites synthetiques et zeolites obtenues par ce procede
FR2547826A1 (fr)	1984-12-28	Argiles organophiles modifiees
EP0118030A1 (de)	1984-09-12	Unter Ausschluss von Wasser lagerfähige, bei Zutritt von Wasser bei Raumtemperatur zu Elastomeren vernetzende Massen
DE2433697A1 (de)	1976-01-29	Verfahren zum herstellen von zu elastomeren vernetzbaren massen
EP0544318B1 (de)	1995-02-08	Einkomponenten-RTV-Massen
DE2839830A1 (de)	1979-03-22	Hydrophile, silanbehandelte zeolithmaterialien
FR2589459A1 (fr)	1987-05-07	Procede de preparation de suspensions de matieres a base de silicates en feuilles, les suspensions ainsi preparees et les produits realises a partir de ces dernieres
DE3546376A1 (de)	1986-07-17	Bis(aminoalkyl)-disiloxane und verfahren zu ihrer herstellung
EP0707028B1 (de)	1997-08-27	Organopolysiloxanharzlösungen, Verfahren zu deren Herstellung sowie deren Verwendung in Beschichtungsmassen
KR920004196B1 (ko)	1992-05-30	표면처리된 폴리오르가노시르세스키옥산 미분말
WO1989012603A2 (fr)	1989-12-28	Granule de zeolites a liant zeolitique
JPS6243468A (ja)	1987-02-25	水性有機珪素樹脂被覆組成物
FR2575484A1 (fr)	1986-07-04	Complexes silicate feuillete-amas d'alcoxysilanes et leur procede de preparation
DE3606262A1 (de)	1986-09-04	Silylcarbamate und verfahren zu ihrer herstellung
DE3642058C2 (de)	1999-02-25	Hydrosilylierungskatalysator und dessen Verwendung
WO2006062531A1 (en)	2006-06-15	An organoclay composition containing quat mixtures
EP0123321B1 (de)	1987-03-25	Verfahren zum Vernetzen von Organopolysiloxanmassen
DE3650660T2 (de)	1998-05-07	Mit Silikonpolymer überzogenes Pulver oder teilchenförmiges Material
DE60006111T2 (de)	2004-07-22	Aluminosiloxanverbindungen und verfahren zu ihrer herstellung
DE1444923A1 (de)	1969-01-23	Verfahren zur Herstellung von Dispersionen der Erdalkalimetallverbindungen
DE3929866A1 (de)	1991-03-21	Spaltbare tenside, verfahren zu ihrer herstellung und ihre verwendung
DE2325852A1 (de)	1973-12-06	Als hydraulische fluessigkeiten brauchbare hydrocarbonoxy-haltige silicone
DE1668637A1 (de)	1971-07-29	Neue Organosiliciumverbindungen mit Esterfunktionen
Rojo et al.	1986	29Si MAS‐NMR spectra of lamellar silicic acid H‐magadiite and its trimethylsilyl derivative