FR2964102B1 - Utilisation de sels de diazonium pour la formation de couches epaisses sur au moins une surface d'un substrat - Google Patents

Utilisation de sels de diazonium pour la formation de couches epaisses sur au moins une surface d'un substrat

Info

Publication number
FR2964102B1
FR2964102B1 FR1003498A FR1003498A FR2964102B1 FR 2964102 B1 FR2964102 B1 FR 2964102B1 FR 1003498 A FR1003498 A FR 1003498A FR 1003498 A FR1003498 A FR 1003498A FR 2964102 B1 FR2964102 B1 FR 2964102B1
Authority
FR
France
Prior art keywords
formation
diazonium salts
substrate
thick layers
integer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1003498A
Other languages
English (en)
Other versions
FR2964102A1 (fr
Inventor
Fabien Lefloch
Muriel Matheron
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat a lEnergie Atomique CEA, Commissariat a lEnergie Atomique et aux Energies Alternatives CEA filed Critical Commissariat a lEnergie Atomique CEA
Priority to FR1003498A priority Critical patent/FR2964102B1/fr
Priority to EP11760863.8A priority patent/EP2611773A1/fr
Priority to PCT/IB2011/053815 priority patent/WO2012029035A1/fr
Priority to US13/820,325 priority patent/US8926821B2/en
Priority to CN201180041868.0A priority patent/CN103097347B/zh
Publication of FR2964102A1 publication Critical patent/FR2964102A1/fr
Application granted granted Critical
Publication of FR2964102B1 publication Critical patent/FR2964102B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/28—Electrolytic cell components
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/32—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
    • C07C255/34—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring with cyano groups linked to the six-membered aromatic ring, or to the condensed ring system containing that ring, by unsaturated carbon chains
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4476—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications comprising polymerisation in situ
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D9/00—Electrolytic coating other than with metals
    • C25D9/02—Electrolytic coating other than with metals with organic materials
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004—Gaseous mixtures, e.g. polluted air
    • G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
    • G01N33/0036—General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component
    • G01N33/0047—Organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/007—Processes for applying liquids or other fluent materials using an electrostatic field
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/02—Ortho- or ortho- and peri-condensed systems
    • C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
    • C07C2603/06—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members
    • C07C2603/10—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings
    • C07C2603/12—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings only one five-membered ring
    • C07C2603/18—Fluorenes; Hydrogenated fluorenes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Physics & Mathematics (AREA)
  • Molecular Biology (AREA)
  • Pathology (AREA)
  • Immunology (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Analytical Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Food Science & Technology (AREA)
  • Combustion & Propulsion (AREA)
  • Wood Science & Technology (AREA)
  • Metallurgy (AREA)
  • Investigating Or Analyzing Materials By The Use Of Fluid Adsorption Or Reactions (AREA)
  • Hybrid Cells (AREA)
  • Heat Sensitive Colour Forming Recording (AREA)

Abstract

L'invention concerne l'utilisation de sels de diazonium pour la formation de couches épaisses sur au moins une surface d'un substrat. Les sels de diazonium utilisés dans l'invention ont la formule I suivante : dans laquelle : - R est un groupement susceptible d'être réduit électrochimiquement de façon réversible à un potentiel cathodique compris entre 0 et -1,5 V, - E est une chaîne espaceur constituée d'au moins un groupe cyclique aromatique de 5 à 6 chaînons, contenant optionnellement un ou plusieurs hétéroatomes de préférence choisis parmi N, S, O ou P et éventuellement substitué par un ou plusieurs groupements choisis parmi les alkyles en C -C , les halogènes, - r vaut 1 ou 2 - m est un entier compris entre 1 et 5 inclus, - p est un entier compris entre 1 et 5, et - B est un contre-ion, pour la formation, par électrogreffage, d'une couche, d'une épaisseur supérieure à 10 nm, sur une surface d'un substrat en un matériau conducteur ou semi-conducteur. L'invention trouve application, en particulier, dans le domaine des capteurs de gaz.
FR1003498A 2010-09-01 2010-09-01 Utilisation de sels de diazonium pour la formation de couches epaisses sur au moins une surface d'un substrat Expired - Fee Related FR2964102B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1003498A FR2964102B1 (fr) 2010-09-01 2010-09-01 Utilisation de sels de diazonium pour la formation de couches epaisses sur au moins une surface d'un substrat
EP11760863.8A EP2611773A1 (fr) 2010-09-01 2011-08-31 Utilisation de sels de diazonium pour la formation de couches epaisses sur au moins une surface d'un substrat
PCT/IB2011/053815 WO2012029035A1 (fr) 2010-09-01 2011-08-31 Utilisation de sels de diazonium pour la formation de couches epaisses sur au moins une surface d'un substrat
US13/820,325 US8926821B2 (en) 2010-09-01 2011-08-31 Use of diazonium salts for the formation of thick layers on at least one surface of a substrate
CN201180041868.0A CN103097347B (zh) 2010-09-01 2011-08-31 重氮盐在基材的至少一个表面上形成厚层的应用

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1003498A FR2964102B1 (fr) 2010-09-01 2010-09-01 Utilisation de sels de diazonium pour la formation de couches epaisses sur au moins une surface d'un substrat

Publications (2)

Publication Number Publication Date
FR2964102A1 FR2964102A1 (fr) 2012-03-02
FR2964102B1 true FR2964102B1 (fr) 2013-03-29

Family

ID=43708899

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1003498A Expired - Fee Related FR2964102B1 (fr) 2010-09-01 2010-09-01 Utilisation de sels de diazonium pour la formation de couches epaisses sur au moins une surface d'un substrat

Country Status (5)

Country Link
US (1) US8926821B2 (fr)
EP (1) EP2611773A1 (fr)
CN (1) CN103097347B (fr)
FR (1) FR2964102B1 (fr)
WO (1) WO2012029035A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2998585B1 (fr) * 2012-11-26 2014-12-19 Univ Rennes Procede de revetement d'un materiau organique ou metallique par des composes organiques par reduction electrochimique des ions diazonium desdits composes organiques, en courant pulse
JP7043205B2 (ja) * 2017-09-19 2022-03-29 株式会社東芝 分子検出装置及び分子検出方法
TWI716869B (zh) * 2018-12-26 2021-01-21 財團法人工業技術研究院 芳香族重氮鹽、表面改質的載體、複合材料與其形成方法
CN113325041B (zh) * 2021-05-31 2022-10-04 吉林大学 基于金修饰富含氧空位二氧化锡的dmmp传感器及其制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07456A (ja) * 1991-08-19 1995-01-06 Ichiro Sasaki 車椅子用斜行昇降装置
FR2829046B1 (fr) * 2001-08-28 2005-01-14 Commissariat Energie Atomique Procede de greffage et de croissance d'un film organique conducteur sur une surface
DE10153450A1 (de) * 2001-10-30 2003-05-22 Covion Organic Semiconductors Verfahren zur Herstellung von Arylaminen
CN1280676C (zh) * 2003-07-21 2006-10-18 财团法人工业技术研究院 正型光阻剂组合物及形成光阻图样的方法
US7560161B2 (en) * 2004-08-09 2009-07-14 Xerox Corporation Inorganic material surface grafted with charge transport moiety
FR2904319B1 (fr) 2006-07-27 2009-10-30 Commissariat Energie Atomique Sels de diazonium polymerisables, procede de fabrication et utilisations de ceux-ci

Also Published As

Publication number Publication date
WO2012029035A1 (fr) 2012-03-08
CN103097347A (zh) 2013-05-08
CN103097347B (zh) 2014-11-05
US8926821B2 (en) 2015-01-06
US20130239661A1 (en) 2013-09-19
EP2611773A1 (fr) 2013-07-10
FR2964102A1 (fr) 2012-03-02

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Effective date: 20170531