FR3110570B1 - PROCEDE DE PREPARATION D’ACIDE ACRYLIQUE A PARTIR DE β-PROPIOLACTONE - Google Patents
PROCEDE DE PREPARATION D’ACIDE ACRYLIQUE A PARTIR DE β-PROPIOLACTONE Download PDFInfo
- Publication number
- FR3110570B1 FR3110570B1 FR2005098A FR2005098A FR3110570B1 FR 3110570 B1 FR3110570 B1 FR 3110570B1 FR 2005098 A FR2005098 A FR 2005098A FR 2005098 A FR2005098 A FR 2005098A FR 3110570 B1 FR3110570 B1 FR 3110570B1
- Authority
- FR
- France
- Prior art keywords
- propiolactone
- acrylic acid
- preparation
- abstract
- none
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
- B01J20/264—Synthetic macromolecular compounds derived from different types of monomers, e.g. linear or branched copolymers, block copolymers, graft copolymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
- B01J20/28038—Membranes or mats made from fibers or filaments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
- B01J20/3206—Organic carriers, supports or substrates
- B01J20/3208—Polymeric carriers, supports or substrates
- B01J20/321—Polymeric carriers, supports or substrates consisting of a polymer obtained by reactions involving only carbon to carbon unsaturated bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3214—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the method for obtaining this coating or impregnating
- B01J20/3217—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
- B01J20/3268—Macromolecular compounds
- B01J20/3278—Polymers being grafted on the carrier
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3291—Characterised by the shape of the carrier, the coating or the obtained coated product
- B01J20/3293—Coatings on a core, the core being particle or fiber shaped, e.g. encapsulated particles, coated fibers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/32—Materials not provided for elsewhere for absorbing liquids to remove pollution, e.g. oil, gasoline, fat
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Textile Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Public Health (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La présente invention concerne un procédé de préparation d’acide acrylique à partir de β-propiolactone et ses utilisations. Le procédé de l’invention repose sur une réactivité spécifique de la β-propiolactone qui, dans des conditions opératoires douces notamment en termes de température, conduit sélectivement à la formation de l’acide acrylique. Figure pour l'abrégé : Néant
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR2005098A FR3110570B1 (fr) | 2020-05-19 | 2020-05-19 | PROCEDE DE PREPARATION D’ACIDE ACRYLIQUE A PARTIR DE β-PROPIOLACTONE |
| US17/926,107 US12428362B2 (en) | 2020-05-19 | 2021-05-17 | Method for preparing acrylic acid from beta- propiolactone |
| PCT/EP2021/063014 WO2021233839A1 (fr) | 2020-05-19 | 2021-05-17 | PROCEDE DE PREPARATION D'ACIDE ACRYLIQUE A PARTIR DE β-PROPIOLACTONE |
| JP2022569522A JP7716429B2 (ja) | 2020-05-19 | 2021-05-17 | β-プロピオラクトンからアクリル酸を製造する方法 |
| EP21725208.9A EP4153556A1 (fr) | 2020-05-19 | 2021-05-17 | Procede de preparation d'acide acrylique a partir de beta-propiolactone |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR2005098A FR3110570B1 (fr) | 2020-05-19 | 2020-05-19 | PROCEDE DE PREPARATION D’ACIDE ACRYLIQUE A PARTIR DE β-PROPIOLACTONE |
| FR2005098 | 2020-05-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR3110570A1 FR3110570A1 (fr) | 2021-11-26 |
| FR3110570B1 true FR3110570B1 (fr) | 2022-05-20 |
Family
ID=72178727
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR2005098A Active FR3110570B1 (fr) | 2020-05-19 | 2020-05-19 | PROCEDE DE PREPARATION D’ACIDE ACRYLIQUE A PARTIR DE β-PROPIOLACTONE |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US12428362B2 (fr) |
| EP (1) | EP4153556A1 (fr) |
| JP (1) | JP7716429B2 (fr) |
| FR (1) | FR3110570B1 (fr) |
| WO (1) | WO2021233839A1 (fr) |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2449987A (en) * | 1945-10-05 | 1948-09-28 | Goodrich Co B F | Preparation of substituted acids from lactones |
| US3176042A (en) | 1959-10-20 | 1965-03-30 | Celanese Corp | Treating propiolactone with heated phosphoric acid to produce acrylic acid |
| WO2011107559A2 (fr) | 2010-03-03 | 2011-09-09 | Basf Se | Préparation de sels d'acides carboxyliques éthyléniquement insaturés par carboxylation d'alcènes |
| EP2709979B1 (fr) | 2011-05-16 | 2018-08-22 | Council of Scientific & Industrial Research | Procédé amélioré pour la déshydratation catalytique d'acide lactique en acide acrylique |
| CN103987682B (zh) * | 2011-10-26 | 2017-06-16 | 诺沃梅尔公司 | 用于由环氧化物制备丙烯酸酯的工艺 |
| RS58521B1 (sr) | 2012-02-22 | 2019-04-30 | Novomer Inc | Postupci dobijanja akrilne kiseline |
| JP5818716B2 (ja) | 2012-02-24 | 2015-11-18 | 株式会社日本触媒 | 不飽和カルボン酸類製造用触媒及びその触媒を用いた不飽和カルボン酸製造方法 |
| US10106484B2 (en) | 2012-04-11 | 2018-10-23 | The Procter & Gamble Company | Catalysts for the conversion of hydroxypropionic acid or its derivatives to acrylic acid or its derivatives |
| DE102013210840A1 (de) | 2013-06-11 | 2014-12-11 | Evonik Industries Ag | Synthese von a,ß-ungesättigten Carbonsäuren (Meth)acrylaten aus Olefinen und CO2 |
| JP6997459B2 (ja) | 2016-03-21 | 2022-02-04 | ノボマー, インコーポレイテッド | 改良されたアクリル酸製造プロセス |
| US10307744B2 (en) | 2016-07-29 | 2019-06-04 | The Procter & Gamble Company | Catalysts for making acrylic acid from lactic acid or its derivatives in liquid phase |
-
2020
- 2020-05-19 FR FR2005098A patent/FR3110570B1/fr active Active
-
2021
- 2021-05-17 JP JP2022569522A patent/JP7716429B2/ja active Active
- 2021-05-17 WO PCT/EP2021/063014 patent/WO2021233839A1/fr not_active Ceased
- 2021-05-17 EP EP21725208.9A patent/EP4153556A1/fr active Pending
- 2021-05-17 US US17/926,107 patent/US12428362B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2023526331A (ja) | 2023-06-21 |
| JP7716429B2 (ja) | 2025-07-31 |
| WO2021233839A1 (fr) | 2021-11-25 |
| FR3110570A1 (fr) | 2021-11-26 |
| US12428362B2 (en) | 2025-09-30 |
| US20230192585A1 (en) | 2023-06-22 |
| EP4153556A1 (fr) | 2023-03-29 |
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