FR3122183B1 - Composition de copolymère à blocs polyamides et à blocs polyéthers et de polyuréthane thermoplastique - Google Patents

Composition de copolymère à blocs polyamides et à blocs polyéthers et de polyuréthane thermoplastique Download PDF

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Publication number
FR3122183B1
FR3122183B1 FR2104202A FR2104202A FR3122183B1 FR 3122183 B1 FR3122183 B1 FR 3122183B1 FR 2104202 A FR2104202 A FR 2104202A FR 2104202 A FR2104202 A FR 2104202A FR 3122183 B1 FR3122183 B1 FR 3122183B1
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France
Prior art keywords
composition
thermoplastic polyurethane
polyamide
polyether
copolymer
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Active
Application number
FR2104202A
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English (en)
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FR3122183A1 (fr
Inventor
Frédérique Pery
Florent Abgrall
Thomas Prenveille
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Arkema France SA
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Arkema France SA
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Filing date
Publication date
Priority to FR2104202A priority Critical patent/FR3122183B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to JP2023564154A priority patent/JP2024517422A/ja
Priority to EP22735516.1A priority patent/EP4326818A1/fr
Priority to US18/555,991 priority patent/US20240218177A1/en
Priority to PCT/FR2022/050770 priority patent/WO2022223935A1/fr
Priority to CN202280040073.6A priority patent/CN117425698A/zh
Priority to KR1020237040091A priority patent/KR20230173182A/ko
Publication of FR3122183A1 publication Critical patent/FR3122183A1/fr
Application granted granted Critical
Publication of FR3122183B1 publication Critical patent/FR3122183B1/fr
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C08L75/08—Polyurethanes from polyethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/12—Powdering or granulating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C08L75/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L87/00—Compositions of unspecified macromolecular compounds, obtained otherwise than by polymerisation reactions only involving unsaturated carbon-to-carbon bonds
    • C08L87/005—Block or graft polymers not provided for in groups C08L1/00 - C08L85/04
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/40—Polyamides containing oxygen in the form of ether groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C08J2375/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2377/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2475/04—Polyurethanes
    • C08J2475/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2477/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/04—Thermoplastic elastomer

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyamides (AREA)

Abstract

L’invention concerne une composition comprenant, par rapport au poids total de la composition, de 40 à 95 en poids d’au moins un copolymère à blocs polyamides et à blocs polyéthers et de 5 à 60 %, en poids, d’au moins un polyuréthane thermoplastique, ladite composition ayant un module de traction à 23°C inférieur ou égal à 150 MPa. L’invention concerne également une composition par la réaction d’au moins un copolymère à blocs polyamides et à blocs polyéthers et d’au moins un polyuréthane thermoplastique ou de précurseurs de polyuréthane thermoplastique, des procédés de préparation de telles compositions et des articles fabriqués à partie de celles-ci. Pas de figure
FR2104202A 2021-04-22 2021-04-22 Composition de copolymère à blocs polyamides et à blocs polyéthers et de polyuréthane thermoplastique Active FR3122183B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR2104202A FR3122183B1 (fr) 2021-04-22 2021-04-22 Composition de copolymère à blocs polyamides et à blocs polyéthers et de polyuréthane thermoplastique
EP22735516.1A EP4326818A1 (fr) 2021-04-22 2022-04-22 Composition de copolymère à blocs polyamides et à blocs polyéthers et de polyuréthane thermoplastique
US18/555,991 US20240218177A1 (en) 2021-04-22 2022-04-22 Copolymer composition containing polyamide blocks, polyether blocks and thermoplastic polyurethane
PCT/FR2022/050770 WO2022223935A1 (fr) 2021-04-22 2022-04-22 Composition de copolymère à blocs polyamides et à blocs polyéthers et de polyuréthane thermoplastique
JP2023564154A JP2024517422A (ja) 2021-04-22 2022-04-22 ポリアミドブロック、ポリエーテルブロックおよび熱可塑性ポリウレタンを含有する共重合体組成物
CN202280040073.6A CN117425698A (zh) 2021-04-22 2022-04-22 含有聚酰胺嵌段、聚醚嵌段和热塑性聚氨酯的共聚物组合物
KR1020237040091A KR20230173182A (ko) 2021-04-22 2022-04-22 폴리아미드 블록, 폴리에테르 블록 및 열가소성 폴리우레탄을 포함하는 공중합체 조성물

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2104202 2021-04-22
FR2104202A FR3122183B1 (fr) 2021-04-22 2021-04-22 Composition de copolymère à blocs polyamides et à blocs polyéthers et de polyuréthane thermoplastique

Publications (2)

Publication Number Publication Date
FR3122183A1 FR3122183A1 (fr) 2022-10-28
FR3122183B1 true FR3122183B1 (fr) 2024-05-03

Family

ID=75954122

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2104202A Active FR3122183B1 (fr) 2021-04-22 2021-04-22 Composition de copolymère à blocs polyamides et à blocs polyéthers et de polyuréthane thermoplastique

Country Status (7)

Country Link
US (1) US20240218177A1 (fr)
EP (1) EP4326818A1 (fr)
JP (1) JP2024517422A (fr)
KR (1) KR20230173182A (fr)
CN (1) CN117425698A (fr)
FR (1) FR3122183B1 (fr)
WO (1) WO2022223935A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3165593A1 (fr) * 2024-08-13 2026-02-20 Arkema France Composition souple avec une résistance au glissement améliorée
CN120134772B (zh) * 2025-04-08 2025-09-23 清远市缀妃化妆品有限公司 一种隔水防菌软质型气垫粉扑及其制备方法
CN120209254B (zh) * 2025-05-28 2025-09-05 陕西振铭时代科技有限公司 一种高耐磨的聚氨酯材料及其制备方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5652326A (en) 1993-03-03 1997-07-29 Sanyo Chemical Industries, Ltd. Polyetheresteramide and antistatic resin composition
FR2831175B1 (fr) 2001-10-22 2004-02-13 Salomon Sa Agent de compatibilisation de polyurethannes, materiau thermoplastique contenant un tel agent et utilisation de ce materiau pour la confection d'articles de sport
FR2846332B1 (fr) 2002-10-23 2004-12-03 Atofina Copolymeres transparents a blocs polyamides et blocs polyethers
US7056975B2 (en) 2003-05-27 2006-06-06 Ube Industries, Ltd. Thermoplastic resin composition having improved resistance to hydrolysis
US7151134B2 (en) * 2003-06-17 2006-12-19 Freudenberg-Nok General Partnership Dynamic vulcanization of polyurethane elastomeric material in the presence of thermoplastics
US7383647B2 (en) 2005-03-10 2008-06-10 New Balance Athletic Shoe, Inc Mechanical cushioning system for footwear
JP2008532618A (ja) 2005-03-10 2008-08-21 ニュー バランス アスレティック シュー，インコーポレーテッド 履物用の機械的緩衝システム
JP5393036B2 (ja) 2008-02-14 2014-01-22 花王株式会社 熱可塑性樹脂組成物
FR2963624B1 (fr) * 2010-08-04 2014-02-21 Hutchinson Procede de preparation d'une composition thermoplastique renforcee et reactive, cette composition et son utilisation
KR102492865B1 (ko) * 2017-01-31 2023-01-31 뮐티바스 에스아 열가소성 조성물

Also Published As

Publication number Publication date
US20240218177A1 (en) 2024-07-04
JP2024517422A (ja) 2024-04-22
WO2022223935A1 (fr) 2022-10-27
EP4326818A1 (fr) 2024-02-28
KR20230173182A (ko) 2023-12-26
CN117425698A (zh) 2024-01-19
FR3122183A1 (fr) 2022-10-28

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