FR3131310B1 - Procédé de production d’une solution aqueuse de 5-hydroxyméthylfurfural (5-HMF) de pureté élevée - Google Patents

Procédé de production d’une solution aqueuse de 5-hydroxyméthylfurfural (5-HMF) de pureté élevée Download PDF

Info

Publication number
FR3131310B1
FR3131310B1 FR2114337A FR2114337A FR3131310B1 FR 3131310 B1 FR3131310 B1 FR 3131310B1 FR 2114337 A FR2114337 A FR 2114337A FR 2114337 A FR2114337 A FR 2114337A FR 3131310 B1 FR3131310 B1 FR 3131310B1
Authority
FR
France
Prior art keywords
aqueous
hmf
counter
extract
hydroxymethylfurfural
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2114337A
Other languages
English (en)
Other versions
FR3131310A1 (fr
Inventor
Marc Jacquin
Espada Pastor Maria Fernandez
Kim Larmier
Hélène Lorcet
Thi Bich Ngoc Dang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR2114337A priority Critical patent/FR3131310B1/fr
Priority to US18/723,000 priority patent/US20250051297A1/en
Priority to EP22830746.8A priority patent/EP4452960A1/fr
Priority to JP2024537842A priority patent/JP2024547102A/ja
Priority to PCT/EP2022/084588 priority patent/WO2023117407A1/fr
Priority to CN202280085330.8A priority patent/CN118475564A/zh
Publication of FR3131310A1 publication Critical patent/FR3131310A1/fr
Application granted granted Critical
Publication of FR3131310B1 publication Critical patent/FR3131310B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Furan Compounds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L’invention concerne un procédé de production d’une solution aqueuse de 5-hydroxyméthylfurfural (5-HMF), comprenant :- une étape a) de mise en contact d’une charge comprenant du 5-HMF et du diméthoxysulfoxyde (DMSO), avec un contre-extrait aqueux intermédiaire issu de l’étape c), pour obtenir un mélange aqueux,- une étape b) d’extraction liquide-liquide du mélange aqueux par un flux de solvant d’extraction, pour produire un raffinat aqueux et un extrait organique intermédiaire,- une étape c) de contre-lavage de l’extrait organique intermédiaire par un solvant aqueux, pour produire le contre-extrait aqueux intermédiaire et un raffinat organique,- une étape d) de contre-extraction liquide-liquide du raffinat organique obtenu à l’issue de l’étape c) par un flux aqueux, pour produire un effluent organique et un contre-extrait aqueux de 5-HMF. Figure 1 à publier
FR2114337A 2021-12-23 2021-12-23 Procédé de production d’une solution aqueuse de 5-hydroxyméthylfurfural (5-HMF) de pureté élevée Active FR3131310B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR2114337A FR3131310B1 (fr) 2021-12-23 2021-12-23 Procédé de production d’une solution aqueuse de 5-hydroxyméthylfurfural (5-HMF) de pureté élevée
US18/723,000 US20250051297A1 (en) 2021-12-23 2022-12-06 Method for producing a high-purity aqueous 5-hydroxymethylfurfural (5-hmf) solution
EP22830746.8A EP4452960A1 (fr) 2021-12-23 2022-12-06 Procédé de production d'une solution aqueuse de 5-hydroxyméthylfurfural (5-hmf) de pureté élevée
JP2024537842A JP2024547102A (ja) 2021-12-23 2022-12-06 高純度の５－ヒドロキシメチルフルフラール（５－ｈｍｆ）水溶液の製造方法
PCT/EP2022/084588 WO2023117407A1 (fr) 2021-12-23 2022-12-06 Procédé de production d'une solution aqueuse de 5-hydroxyméthylfurfural (5-hmf) de pureté élevée
CN202280085330.8A CN118475564A (zh) 2021-12-23 2022-12-06 生产高纯度5-羟甲基糠醛（5-hmf）水溶液的方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2114337 2021-12-23
FR2114337A FR3131310B1 (fr) 2021-12-23 2021-12-23 Procédé de production d’une solution aqueuse de 5-hydroxyméthylfurfural (5-HMF) de pureté élevée

Publications (2)

Publication Number Publication Date
FR3131310A1 FR3131310A1 (fr) 2023-06-30
FR3131310B1 true FR3131310B1 (fr) 2023-12-01

Family

ID=80786623

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2114337A Active FR3131310B1 (fr) 2021-12-23 2021-12-23 Procédé de production d’une solution aqueuse de 5-hydroxyméthylfurfural (5-HMF) de pureté élevée

Country Status (6)

Country Link
US (1) US20250051297A1 (fr)
EP (1) EP4452960A1 (fr)
JP (1) JP2024547102A (fr)
CN (1) CN118475564A (fr)
FR (1) FR3131310B1 (fr)
WO (1) WO2023117407A1 (fr)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2669635B1 (fr) 1990-11-22 1994-06-10 Furchim Procede de fabrication d'hydroxymethylfurfural (hmf) du purete elevee.
EP1834950A1 (fr) 2006-03-10 2007-09-19 Avantium International B.V. Procédé de fabrication d'alkoxyméthylfurfurales et leur utilisation
FR3071172B1 (fr) * 2017-09-18 2019-10-04 IFP Energies Nouvelles Procede de separation des composes furaniques, en particulier le 5- hydroxymethylfurfural, du dimethoxysulfoxyde par des extractions liquide-liquide

Also Published As

Publication number Publication date
FR3131310A1 (fr) 2023-06-30
JP2024547102A (ja) 2024-12-26
WO2023117407A1 (fr) 2023-06-29
US20250051297A1 (en) 2025-02-13
EP4452960A1 (fr) 2024-10-30
CN118475564A (zh) 2024-08-09

Similar Documents

Publication Publication Date Title
Frankowski et al. Inverting the reactivity of troponoid systems in enantioselective higher-order cycloaddition
Peng et al. Direct transition-metal-free intramolecular C–O bond formation: Synthesis of benzoxazole derivatives
Borrel et al. Azido-alkynylation of alkenes through radical-polar crossover
Majumder et al. Stereoselective synthesis of novel annulated thiopyrano indole derivatives from simple oxindole via intramolecular 1, 3-dipolar cycloaddition reactions of nitrone and nitrile oxide
JOP20190264A1 (ar) طريقة لتحضير مركب وسيط من مشتق 4 - ميثوكسي بيرول
JP2017534586A (ja) キラルγ−第二級アミンアルコールの製造方法
CA3156015A1 (fr) Procede d'obtention d'une composition d'huile de lignine a l'aide d'un gaz comprime et procede assiste par acide
Darcsi et al. Structure elucidation of a process-related impurity of dapoxetine
MX2022001602A (es) Recuperacion de acido metansulfonico libre de agua del flujo de fondo de una columna de destilacion.
Wu et al. A versatile and practical method for regioselective synthesis of polysubstituted furanonaphthoquinones
AR098053A1 (es) Proceso para la síntesis industrial de lurasidona
Rodrigues Jr et al. 1, 1′-Carbonyldiimidazole mediates the synthesis of N-substituted imidazole derivatives from Morita–Baylis–Hillman adducts
Liu et al. 2-Chlorotetrafluoroethanesulfinamide induced asymmetric vinylogous Mannich reaction
Ghorai et al. Intramolecular 1, 3-dipolar nitrone and nitrile oxide cycloaddition of 2-and 4-O-allyl and propargyl glucose derivatives: a versatile approach to chiral cyclic ether fused isoxazolidines, isoxazolines and isoxazoles
FR3086548B1 (fr) Procede de purification d'une charge hydroalcoolique comprenant de l'ethanol, de l'acetaldehyde et des impuretes
Wang et al. Diastereoselectivity in the triethylamine-catalyzed sulfa-Michael addition of thiols to nitroalkenes: kinetic and thermodynamic control
Zhou et al. Catalyst-and additive-free Baeyer–Villiger-type oxidation of α-iodocyclopentenones to α-pyrones: using air as the oxidant
FR3143379B1 (fr) Procédé de production d’une solution aqueuse de 5-hydroxyméthylfurfural comportant une extraction liquide-liquide intégrant ou suivie d’une filtration
Duran-Lara et al. Studies towards the construction of quaternary indolizidines by [2, 3]-sigmatropic rearrangement cocatalyzed by ionic liquid
Dolna et al. Remotely controlled flow photo-Fries-type rearrangement of N-vinylazetidinones: an efficient route to structurally diverse 2, 3-dihydro-4-pyridones
WO2022088306A1 (fr) Procédé pour la préparation d'intermédiaire 4,4-diméthylisoxazol-3-one
Sharma et al. Asymmetric desymmetrization of 2, 5-cyclohexadienones initiated by organocatalytic conjugate addition to 4-nitro-5-styrylisoxazoles
SA520412074B1 (ar) طريقة ونظام لإنتاج إيبوكسي ألكان
US8558010B2 (en) Aziridination of olefins
Deng et al. Synthesis of 2-(α-Substituted N-Tosylaminomethyl)-2, 5-Dihydrofurans by Reaction of N-Sulfonylimines with Arsonium or Sulfonium 4-Hydroxyl-cis-2-butenylides

Legal Events

Date Code Title Description
PLFP Fee payment

Year of fee payment: 2

PLSC Publication of the preliminary search report

Effective date: 20230630

PLFP Fee payment

Year of fee payment: 3

PLFP Fee payment

Year of fee payment: 4

PLFP Fee payment

Year of fee payment: 5