FR3131310B1 - Procédé de production d’une solution aqueuse de 5-hydroxyméthylfurfural (5-HMF) de pureté élevée - Google Patents

Procédé de production d’une solution aqueuse de 5-hydroxyméthylfurfural (5-HMF) de pureté élevée Download PDF

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Publication number
FR3131310B1
FR3131310B1 FR2114337A FR2114337A FR3131310B1 FR 3131310 B1 FR3131310 B1 FR 3131310B1 FR 2114337 A FR2114337 A FR 2114337A FR 2114337 A FR2114337 A FR 2114337A FR 3131310 B1 FR3131310 B1 FR 3131310B1
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FR
France
Prior art keywords
aqueous
hmf
counter
extract
hydroxymethylfurfural
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
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FR2114337A
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English (en)
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FR3131310A1 (fr
Inventor
Marc Jacquin
Espada Pastor Maria Fernandez
Kim Larmier
Hélène Lorcet
Thi Bich Ngoc Dang
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR2114337A priority Critical patent/FR3131310B1/fr
Priority to EP22830746.8A priority patent/EP4452960A1/fr
Priority to PCT/EP2022/084588 priority patent/WO2023117407A1/fr
Priority to CN202280085330.8A priority patent/CN118475564A/zh
Priority to US18/723,000 priority patent/US20250051297A1/en
Priority to JP2024537842A priority patent/JP2024547102A/ja
Publication of FR3131310A1 publication Critical patent/FR3131310A1/fr
Application granted granted Critical
Publication of FR3131310B1 publication Critical patent/FR3131310B1/fr
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Furan Compounds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L’invention concerne un procédé de production d’une solution aqueuse de 5-hydroxyméthylfurfural (5-HMF), comprenant :- une étape a) de mise en contact d’une charge comprenant du 5-HMF et du diméthoxysulfoxyde (DMSO), avec un contre-extrait aqueux intermédiaire issu de l’étape c), pour obtenir un mélange aqueux,- une étape b) d’extraction liquide-liquide du mélange aqueux par un flux de solvant d’extraction, pour produire un raffinat aqueux et un extrait organique intermédiaire,- une étape c) de contre-lavage de l’extrait organique intermédiaire par un solvant aqueux, pour produire le contre-extrait aqueux intermédiaire et un raffinat organique,- une étape d) de contre-extraction liquide-liquide du raffinat organique obtenu à l’issue de l’étape c) par un flux aqueux, pour produire un effluent organique et un contre-extrait aqueux de 5-HMF. Figure 1 à publier
FR2114337A 2021-12-23 2021-12-23 Procédé de production d’une solution aqueuse de 5-hydroxyméthylfurfural (5-HMF) de pureté élevée Active FR3131310B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR2114337A FR3131310B1 (fr) 2021-12-23 2021-12-23 Procédé de production d’une solution aqueuse de 5-hydroxyméthylfurfural (5-HMF) de pureté élevée
EP22830746.8A EP4452960A1 (fr) 2021-12-23 2022-12-06 Procédé de production d'une solution aqueuse de 5-hydroxyméthylfurfural (5-hmf) de pureté élevée
PCT/EP2022/084588 WO2023117407A1 (fr) 2021-12-23 2022-12-06 Procédé de production d'une solution aqueuse de 5-hydroxyméthylfurfural (5-hmf) de pureté élevée
CN202280085330.8A CN118475564A (zh) 2021-12-23 2022-12-06 生产高纯度5-羟甲基糠醛（5-hmf）水溶液的方法
US18/723,000 US20250051297A1 (en) 2021-12-23 2022-12-06 Method for producing a high-purity aqueous 5-hydroxymethylfurfural (5-hmf) solution
JP2024537842A JP2024547102A (ja) 2021-12-23 2022-12-06 高純度の５－ヒドロキシメチルフルフラール（５－ｈｍｆ）水溶液の製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2114337 2021-12-23
FR2114337A FR3131310B1 (fr) 2021-12-23 2021-12-23 Procédé de production d’une solution aqueuse de 5-hydroxyméthylfurfural (5-HMF) de pureté élevée

Publications (2)

Publication Number Publication Date
FR3131310A1 FR3131310A1 (fr) 2023-06-30
FR3131310B1 true FR3131310B1 (fr) 2023-12-01

Family

ID=80786623

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2114337A Active FR3131310B1 (fr) 2021-12-23 2021-12-23 Procédé de production d’une solution aqueuse de 5-hydroxyméthylfurfural (5-HMF) de pureté élevée

Country Status (6)

Country Link
US (1) US20250051297A1 (fr)
EP (1) EP4452960A1 (fr)
JP (1) JP2024547102A (fr)
CN (1) CN118475564A (fr)
FR (1) FR3131310B1 (fr)
WO (1) WO2023117407A1 (fr)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2669635B1 (fr) 1990-11-22 1994-06-10 Furchim Procede de fabrication d'hydroxymethylfurfural (hmf) du purete elevee.
EP1834950A1 (fr) 2006-03-10 2007-09-19 Avantium International B.V. Procédé de fabrication d'alkoxyméthylfurfurales et leur utilisation
FR3071172B1 (fr) * 2017-09-18 2019-10-04 IFP Energies Nouvelles Procede de separation des composes furaniques, en particulier le 5- hydroxymethylfurfural, du dimethoxysulfoxyde par des extractions liquide-liquide

Also Published As

Publication number Publication date
CN118475564A (zh) 2024-08-09
EP4452960A1 (fr) 2024-10-30
US20250051297A1 (en) 2025-02-13
JP2024547102A (ja) 2024-12-26
FR3131310A1 (fr) 2023-06-30
WO2023117407A1 (fr) 2023-06-29

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