FR3150521B1 - Polymère à étapes multiples, son procédé de préparation, composition le comprenant et son utilisation - Google Patents

Polymère à étapes multiples, son procédé de préparation, composition le comprenant et son utilisation

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Publication number
FR3150521B1
FR3150521B1 FR2306769A FR2306769A FR3150521B1 FR 3150521 B1 FR3150521 B1 FR 3150521B1 FR 2306769 A FR2306769 A FR 2306769A FR 2306769 A FR2306769 A FR 2306769A FR 3150521 B1 FR3150521 B1 FR 3150521B1
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France
Prior art keywords
composition
preparation process
polymer
relates
stage polymer
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2306769A
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English (en)
Other versions
FR3150521A1 (fr
Inventor
Aline Couffin
Rabi Inoubli
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
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Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to FR2306769A priority Critical patent/FR3150521B1/fr
Priority to EP24736789.9A priority patent/EP4735493A1/fr
Priority to CN202480052257.3A priority patent/CN121693524A/zh
Priority to KR1020257042985A priority patent/KR20260026501A/ko
Priority to PCT/EP2024/067806 priority patent/WO2025003134A1/fr
Priority to TW113123996A priority patent/TW202515950A/zh
Publication of FR3150521A1 publication Critical patent/FR3150521A1/fr
Application granted granted Critical
Publication of FR3150521B1 publication Critical patent/FR3150521B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/22Emulsion polymerisation
    • C08F2/24Emulsion polymerisation with the aid of emulsifying agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/14Methyl esters, e.g. methyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1811C10or C11-(Meth)acrylate, e.g. isodecyl (meth)acrylate, isobornyl (meth)acrylate or 2-naphthyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00Post-polymerisation treatments
    • C08F6/14Treatment of polymer emulsions
    • C08F6/22Coagulation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/09Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
    • C08J3/091Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids characterised by the chemical constitution of the organic liquid
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/12Powdering or granulating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12Homopolymers or copolymers of methyl methacrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/10Homopolymers or copolymers of methacrylic acid esters
    • C08J2333/12Homopolymers or copolymers of methyl methacrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2351/00Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2351/00Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2351/04Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

POLYMÈRE À ÉTAPES MULTIPLES, SON PROCÉDÉ DE PRÉPARATION, COMPOSITION LE COMPRENANT ET SON UTILISATION La présente invention concerne une composition comprenant un polymère à étapes multiples, son procédé de préparation, une composition le comprenant et son utilisation. En particulier, la présente invention concerne une composition sous forme d’une poudre de polymère comprenant un simple polymère à étapes multiples sous forme de particules polymériques préparé par un procédé à étapes multiples. Plus particulièrement, la présente invention concerne une composition de polymère sous forme d’une poudre de polymère poreuse comprenant des particules polymériques préparée par un procédé à étapes multiples comprenant deux étapes et comprenant, comme enveloppe externe, un copolymère (méth)acrylique comprenant des groupes hydrocarbonés alicycliques, son procédé de préparation, son utilisation et des compositions et des articles la comprenant.
FR2306769A 2023-06-28 2023-06-28 Polymère à étapes multiples, son procédé de préparation, composition le comprenant et son utilisation Active FR3150521B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR2306769A FR3150521B1 (fr) 2023-06-28 2023-06-28 Polymère à étapes multiples, son procédé de préparation, composition le comprenant et son utilisation
EP24736789.9A EP4735493A1 (fr) 2023-06-28 2024-06-25 Polymère à phases multiples, son procédé de préparation, composition le comprenant et son utilisation
CN202480052257.3A CN121693524A (zh) 2023-06-28 2024-06-25 多级聚合物、其制备方法、包含其的组合物及其用途
KR1020257042985A KR20260026501A (ko) 2023-06-28 2024-06-25 다단 중합체, 이의 제조 방법, 이를 포함하는 조성물 및 이의 용도
PCT/EP2024/067806 WO2025003134A1 (fr) 2023-06-28 2024-06-25 Polymère à phases multiples, son procédé de préparation, composition le comprenant et son utilisation
TW113123996A TW202515950A (zh) 2023-06-28 2024-06-27 多階段聚合物,其製備方法,包含其之組成物及該組成物之用途

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2306769 2023-06-28
FR2306769A FR3150521B1 (fr) 2023-06-28 2023-06-28 Polymère à étapes multiples, son procédé de préparation, composition le comprenant et son utilisation

Publications (2)

Publication Number Publication Date
FR3150521A1 FR3150521A1 (fr) 2025-01-03
FR3150521B1 true FR3150521B1 (fr) 2026-03-13

Family

ID=88965161

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2306769A Active FR3150521B1 (fr) 2023-06-28 2023-06-28 Polymère à étapes multiples, son procédé de préparation, composition le comprenant et son utilisation

Country Status (6)

Country Link
EP (1) EP4735493A1 (fr)
KR (1) KR20260026501A (fr)
CN (1) CN121693524A (fr)
FR (1) FR3150521B1 (fr)
TW (1) TW202515950A (fr)
WO (1) WO2025003134A1 (fr)

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2007040041A1 (ja) * 2005-10-03 2009-04-16 株式会社カネカ 熱可塑性ポリエステル樹脂用増粘剤、これを配合してなる熱可塑性ポリエステル樹脂組成物、および当該組成物からなる成形体
FR3031108B1 (fr) 2014-12-24 2018-08-17 Arkema France Composition comprenant un polymere a phases multiples, son procede de preparation et son utlisation
FR3031106B1 (fr) 2014-12-24 2017-02-03 Arkema France Composition de polymeres a phases multiples, son procede de preparation, son utilisation et composition la comprenant
FR3068977B1 (fr) 2017-07-12 2020-09-04 Arkema France Composition comprenant un polymere a phases multiples et un polymere (meth)acrylique, son procede de preparation et son utilisation
JP7592404B2 (ja) * 2019-05-24 2024-12-02 キヤノン株式会社 硬化性樹脂組成物およびその硬化物、ならびに立体造形物の製造方法
FR3097866B1 (fr) 2019-06-26 2022-01-21 Arkema France Composition comprenant un composé renfermant deux groupes polymérisables, un polymère à étages multiples et un polymère thermoplastique, son procédé de préparation, son utilisation et article la comprenant

Also Published As

Publication number Publication date
CN121693524A (zh) 2026-03-17
FR3150521A1 (fr) 2025-01-03
KR20260026501A (ko) 2026-02-26
TW202515950A (zh) 2025-04-16
EP4735493A1 (fr) 2026-05-06
WO2025003134A1 (fr) 2025-01-02

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