GR3036654T3 - Water-dispersible polymer and coating composition containing the same - Google Patents
Water-dispersible polymer and coating composition containing the sameInfo
- Publication number
- GR3036654T3 GR3036654T3 GR20010401512T GR20010401512T GR3036654T3 GR 3036654 T3 GR3036654 T3 GR 3036654T3 GR 20010401512 T GR20010401512 T GR 20010401512T GR 20010401512 T GR20010401512 T GR 20010401512T GR 3036654 T3 GR3036654 T3 GR 3036654T3
- Authority
- GR
- Greece
- Prior art keywords
- water
- polymer
- dispersible polymer
- coating composition
- epoxy
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title abstract 8
- 239000008199 coating composition Substances 0.000 title abstract 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- 239000004593 Epoxy Substances 0.000 abstract 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 abstract 2
- 125000003700 epoxy group Chemical group 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 238000009877 rendering Methods 0.000 abstract 1
- 229940075582 sorbic acid Drugs 0.000 abstract 1
- 235000010199 sorbic acid Nutrition 0.000 abstract 1
- 239000004334 sorbic acid Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/08—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated side groups
- C08F290/14—Polymers provided for in subclass C08G
- C08F290/144—Polymers containing more than one epoxy group per molecule
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31529—Next to metal
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Epoxy Resins (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/603,885 US5830952A (en) | 1996-02-22 | 1996-02-22 | Water-dispersible polymer and coating composition containing the same |
| PCT/US1997/000728 WO1997031044A1 (en) | 1996-02-22 | 1997-01-14 | Water-dispersible polymer and coating composition containing the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GR3036654T3 true GR3036654T3 (en) | 2001-12-31 |
Family
ID=24417327
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GR20010401512T GR3036654T3 (en) | 1996-02-22 | 2001-09-18 | Water-dispersible polymer and coating composition containing the same |
Country Status (13)
| Country | Link |
|---|---|
| US (3) | US5830952A (el) |
| EP (1) | EP0882080B1 (el) |
| JP (1) | JP3957228B2 (el) |
| KR (1) | KR100483263B1 (el) |
| CN (1) | CN1118495C (el) |
| AT (1) | ATE203030T1 (el) |
| AU (1) | AU715870B2 (el) |
| BR (1) | BR9707641A (el) |
| DE (1) | DE69705606T2 (el) |
| GR (1) | GR3036654T3 (el) |
| RU (1) | RU2171264C2 (el) |
| WO (1) | WO1997031044A1 (el) |
| ZA (1) | ZA9610680B (el) |
Families Citing this family (57)
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|---|---|---|---|---|
| US6359062B1 (en) | 1999-03-02 | 2002-03-19 | The Valspar Corporation | Coating compositions |
| US6350843B1 (en) * | 1999-06-02 | 2002-02-26 | Hsu San Fa | Epoxy resin low electronic impedance high molecular polymer |
| AU2002239438A1 (en) * | 2000-10-27 | 2002-06-03 | Ingenuity And Ideas, Llc | 2,4-hexadienoic acid and derivatives as corrosion inhibitors |
| CN100379831C (zh) * | 2002-03-08 | 2008-04-09 | 瓦尔斯帕供应公司 | 在胺固化环氧材料存在下反应性稀释剂的聚合及由此制备的涂料组合物 |
| CN101851441A (zh) * | 2002-03-08 | 2010-10-06 | 瓦尔斯帕供应公司 | 具有低挥发性有机化合物含量的涂料 |
| US7341762B2 (en) * | 2003-01-08 | 2008-03-11 | The Glidden Company | Coating composition having improved release properties and the process for making the same |
| US20040234701A1 (en) * | 2003-02-19 | 2004-11-25 | Caton Gregory James | Lower alkyl carboxylic acid moieties as organoleptic stabilizers and preservatives of food and beverages and for preventing oxidative corrosion of metals |
| MXPA05010454A (es) | 2003-04-02 | 2005-11-04 | Valspar Sourcing Inc | Dispersiones y recubrimientos acuosos. |
| EP3037488B1 (en) | 2004-10-20 | 2022-10-05 | Swimc Llc | Coating compositions for cans and methods of coating |
| WO2007048094A2 (en) | 2005-10-18 | 2007-04-26 | Valspar Sourcing, Inc. | Coating compositions for containers and methods of coating |
| WO2008036628A2 (en) * | 2006-09-19 | 2008-03-27 | Valspar Sourcing, Inc. | Food and beverage coated containers, method of coating and coating composition |
| EP3489015A1 (en) * | 2006-09-19 | 2019-05-29 | Swimc Llc | Food and beverage containers and methods of coating |
| US20090061219A1 (en) * | 2007-08-28 | 2009-03-05 | Valspar Sourcing, Inc. | Composition for Coating Glass |
| WO2009073791A1 (en) | 2007-12-07 | 2009-06-11 | Valspar Sourcing, Inc. | Coating suitable for medicament contact |
| US8227027B2 (en) * | 2007-12-07 | 2012-07-24 | Presspart Gmbh & Co. Kg | Method for applying a polymer coating to an internal surface of a container |
| MX338773B (es) | 2009-04-09 | 2016-05-02 | Valspar Sourcing Inc | Polimero que tiene funcionalidad cicloalifatica insaturada y composiciones de recubrimiento formadas de este. |
| US8486574B2 (en) * | 2009-07-14 | 2013-07-16 | Ford Global Technologies, Llc | Method and system for power control in an automotive vehicle |
| US8754614B2 (en) * | 2009-07-17 | 2014-06-17 | Tesla Motors, Inc. | Fast charging of battery using adjustable voltage control |
| KR101854476B1 (ko) | 2009-07-17 | 2018-06-14 | 발스파 소싱 인코포레이티드 | 코팅 조성물 및 그것으로 코팅된 용품 |
| US9296870B2 (en) * | 2009-07-27 | 2016-03-29 | The Trustees Of Columbia University In The City Of New York | Modification of surfaces with nanoparticles |
| EP3498751A1 (en) | 2009-09-18 | 2019-06-19 | Swimc Llc | Coating composition including an unsaturated polymer |
| KR102032749B1 (ko) | 2010-04-16 | 2019-10-16 | 에스더블유아이엠씨 엘엘씨 | 패키징 용품을 위한 코팅 조성물 및 코팅 방법 |
| WO2012161758A2 (en) | 2011-02-07 | 2012-11-29 | Valspar Sourcing, Inc. | Coating compositions for containers and other articles and methods of coating |
| BR112013031811B1 (pt) * | 2011-06-23 | 2020-05-19 | Dow Global Technologies Llc | pó de polímero de epóxi redispersável em água, método para preparar o pó de polímero de epóxi dispersável em água, e, dispersão do pó de polímero de epóxi redispersável em água |
| MX373246B (es) * | 2012-02-07 | 2020-05-11 | Swimc Llc | Composiciones para contenedores y otros articulos y metodos para usarlos. |
| BR112014020209B1 (pt) | 2012-02-17 | 2020-12-01 | Swimc Llc | artigo |
| WO2014011730A1 (en) * | 2012-07-12 | 2014-01-16 | Dow Global Technologies Llc | Alkali-soluble resin (asr) shell epoxy rdp with divalent metal ions exhibiting improved powder redispersibility |
| NL1039737C2 (en) | 2012-07-17 | 2014-01-20 | Hovis Internat B V | Mehod for the manufacture of a sorbic acid-based polymer network. |
| RU2618704C2 (ru) | 2012-08-09 | 2017-05-11 | Вэлспар Сорсинг, Инк. | Композиции для контейнеров и других изделий и способы их применения |
| AU2013300118B2 (en) | 2012-08-09 | 2017-07-13 | Swimc Llc | Container coating system |
| CN105121569B (zh) | 2013-03-01 | 2018-07-06 | 威士伯采购公司 | 包含酚醛树脂旳水性涂料组合物 |
| JP2014234560A (ja) * | 2013-05-31 | 2014-12-15 | ヘンケルジャパン株式会社 | 水分散型樹脂組成物 |
| CN103436062B (zh) * | 2013-08-30 | 2015-09-16 | 湖州大名湖针织服装有限公司 | 一种改进的纺织机器养护剂 |
| EP2989016B1 (en) | 2013-10-02 | 2021-08-04 | Swimc Llc | Removable closure and coating system |
| BR112016007093A2 (pt) | 2013-10-02 | 2017-08-01 | Valspar Sourcing Inc | fechamento removível para um artigo de embalagem, embalagem, método para fabricação de um fechamento removível para um artigo de embalagem, e, sistema de revestimento |
| JP6538036B2 (ja) | 2013-10-17 | 2019-07-03 | ヴァルスパー・ソーシング・インコーポレーテッド | ジ(アミド(アルキル)フェノール)化合物、及びその化合物から形成されるポリマー |
| EP3131965B1 (en) | 2014-04-14 | 2024-06-12 | Swimc Llc | Methods of preparing compositions for containers and other articles and methods of using same |
| MX2016015219A (es) | 2014-05-19 | 2017-03-23 | Valspar Sourcing Inc | Polieteres que contienen grupos ciclicos no bisfenolicos. |
| GB2529723B (en) | 2014-09-01 | 2017-04-05 | Schlumberger Holdings | A method of corrosion inhibition of metal |
| US11981822B2 (en) | 2014-12-24 | 2024-05-14 | Swimc Llc | Crosslinked coating compositions for packaging articles such as food and beverage containers |
| EP4155356B1 (en) | 2014-12-24 | 2024-09-11 | Swimc Llc | Coating compositions for packaging articles such as food and beverage containers |
| US11059989B2 (en) | 2017-06-30 | 2021-07-13 | Valspar Sourcing, Inc. | Crosslinked coating compositions for packaging articles such as food and beverage containers |
| JP6829686B2 (ja) | 2014-12-24 | 2021-02-10 | ヴァルスパー・ソーシング・インコーポレーテッド | 食品及び飲料用容器等の包装物品のためのスチレンを含まないコーティング組成物 |
| TWI614275B (zh) | 2015-11-03 | 2018-02-11 | Valspar Sourcing Inc | 用於製備聚合物的液體環氧樹脂組合物 |
| AR108133A1 (es) | 2016-04-15 | 2018-07-18 | Valspar Sourcing Inc | Composiciones de revestimiento que contienen copolímeros libres de estireno |
| US11117164B2 (en) | 2016-08-10 | 2021-09-14 | Swimc Llc | Edge build and edge blister performance of coil coatings |
| EP4053225A1 (en) | 2016-10-19 | 2022-09-07 | Swimc Llc | Acylic polymers and compositions containing such polymers |
| EP3673019B1 (en) | 2017-08-25 | 2025-12-03 | Swimc Llc | Adhesion promoters and compositions for containers and other articles |
| EP3676342A4 (en) | 2017-09-01 | 2021-07-07 | Swimc LLC | MULTI-STAGE POLYMERIC LATEX, COATING COMPOSITIONS CONTAINING SUCH LATEX, AND ARTICLES WHICH ARE COATED |
| DE112018004899T5 (de) | 2017-09-01 | 2020-06-04 | Swimc Llc | Mehrstufige, polymere latizes, diese latizes enthaltende beschichtungszusammensetzungen und damit beschichtete artikel |
| MY201814A (en) | 2017-12-11 | 2024-03-19 | Sherwin Williams Co | Method for making water-dispersible and water-dispersed polymers |
| KR101966645B1 (ko) * | 2018-07-03 | 2019-04-09 | (주)에스씨글로벌 | 발포폴리스티렌(eps) 코팅 조성물 및 이를 이용한 경량골재의 제조방법 |
| FI131178B1 (en) | 2018-07-13 | 2024-11-22 | Paptic Oy | Water-dispersed composite structure and method of production thereof |
| CN109236662B (zh) * | 2018-08-13 | 2020-12-29 | 安徽卧龙泵阀股份有限公司 | 一种故障率低的离心泵 |
| CN109236661B (zh) * | 2018-08-13 | 2020-12-29 | 安徽卧龙泵阀股份有限公司 | 一种耐磨耐腐的离心泵 |
| CN115895395B (zh) * | 2022-07-05 | 2023-07-25 | 衡水新光新材料科技有限公司 | 一种耐候性单组分环氧乳液及其制备方法 |
| TW202511239A (zh) * | 2023-08-23 | 2025-03-16 | 美商布魯爾科技公司 | 丙炔酸酯官能化分子及聚合物之無催化劑交聯 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1720922A1 (de) * | 1968-01-31 | 1971-08-05 | Herbig Haarhaus Herbol Werke | Modifizierte hitzehaertbare Acrylmischpolymerisate |
| US4021395A (en) * | 1973-06-29 | 1977-05-03 | E. I. Du Pont De Nemours And Company | Aqueous dispersion of an aryloxysulfone copolymer |
| US4247439A (en) * | 1973-11-06 | 1981-01-27 | E. I. Du Pont De Nemours And Company | Water-borne coating composition made from epoxy resin, polymeric acid and tertiary amine |
| US3943187A (en) * | 1973-12-12 | 1976-03-09 | E. I. Du Pont De Nemours And Company | Ductile coating composition of an acrylic polymer having reactive sites and an epoxy resin |
| US3997694A (en) * | 1973-12-12 | 1976-12-14 | E. I. Du Pont De Nemours And Company | Container coated with a ductile coating of an acrylic polymer having reactive sites and an epoxy resin |
| US4021396A (en) * | 1973-12-12 | 1977-05-03 | E. I. Du Pont De Nemours And Company | Aqueous coating composition of an acrylic polymer having reactive sites and an epoxy resin |
| US4212781A (en) * | 1977-04-18 | 1980-07-15 | Scm Corporation | Modified epoxy resins, processes for making and using same and substrates coated therewith |
| US4308185A (en) * | 1976-05-11 | 1981-12-29 | Scm Corporation | Graft polymer compositions of terminated epoxy resin, processes for making and using same, and substrates coated therewith |
| US4585813A (en) * | 1978-06-12 | 1986-04-29 | Scm Corporation | Aqueous coating composition comprising self-emulsifiable ester of epoxy and acid containing addition polymer and method of its preparation |
| US4183869A (en) * | 1978-08-04 | 1980-01-15 | Hughes Aircraft Company | Ethynyl-terminated epoxy resin derivatives and process for making the same |
| US4212776A (en) * | 1978-10-16 | 1980-07-15 | Mobil Oil Corporation | Self crosslinking water dispersible epoxy ester-acrylate polymers |
| US4302373A (en) * | 1980-08-05 | 1981-11-24 | E. I. Du Pont De Nemours And Company | Water-borne coating composition made from modified epoxy resin, polymeric acid and tertiary amine |
| US4480058A (en) * | 1980-12-04 | 1984-10-30 | Scm Corporation | Aqueous epoxy ester emulsions |
| US4374875A (en) * | 1980-12-15 | 1983-02-22 | Union Carbide Corporation | Water-borne thermoplastic polyhydroxyether compositions |
| US4355122A (en) * | 1980-12-15 | 1982-10-19 | Union Carbide Corporation | Water-borne thermoplastic polyhydroxyether compositions |
| US4446258A (en) * | 1982-12-30 | 1984-05-01 | Mobil Oil Corporation | Aqueous coating comprising dispersible epoxy resin-acid polymer ester and diluent polymer, and method of preparation |
| US4444923A (en) * | 1982-12-30 | 1984-04-24 | Mobil Oil Corporation | Process for preparing aqueous coatings comprising dispersible epoxy resin-acid polymer ester |
| US4638038A (en) * | 1985-04-22 | 1987-01-20 | Union Carbide Corporation | Carboxylic acid-grafted phenoxy resins |
| MX169357B (es) * | 1987-08-13 | 1993-09-30 | Valspar Corp | Composicion de revestimiento en composicion acuosa |
| US4954553A (en) * | 1988-09-30 | 1990-09-04 | Union Carbide Chemicals And Plastics Company Inc. | Modified waterborne phenoxy resins |
| US4963602A (en) * | 1989-11-13 | 1990-10-16 | Hi-Tek Polymers, Inc. | Aqueous epoxy resin-acrylic resin coating compositions containing also phenoxy, novolac and resole resin combination |
| DE69117581T2 (de) * | 1990-05-24 | 1996-10-31 | Nippon Paint Co Ltd | Modifizierte Epoxydharze, die acetylenisch ungesättigte Endgruppen enthalten |
| JPH04233926A (ja) * | 1990-08-02 | 1992-08-21 | Akzo Nv | ハイブリッドポリマ−、それより得られる水性分散物及びコ−ティング組成物 |
| EP0469646A1 (en) * | 1990-08-02 | 1992-02-05 | Akzo Nobel N.V. | Hybrid polymer, aqueous dispersions and coating composition therefrom |
| DE4105134C1 (el) * | 1991-02-15 | 1992-10-08 | Lankwitzer Lackfabrik Gmbh & Co.Kg, 1000 Berlin, De |
-
1996
- 1996-02-22 US US08/603,885 patent/US5830952A/en not_active Expired - Lifetime
- 1996-12-19 ZA ZA9610680A patent/ZA9610680B/xx unknown
-
1997
- 1997-01-14 KR KR10-1998-0706512A patent/KR100483263B1/ko not_active Expired - Lifetime
- 1997-01-14 AU AU17019/97A patent/AU715870B2/en not_active Expired
- 1997-01-14 JP JP53014997A patent/JP3957228B2/ja not_active Expired - Lifetime
- 1997-01-14 RU RU98117382/04A patent/RU2171264C2/ru active
- 1997-01-14 EP EP97902973A patent/EP0882080B1/en not_active Expired - Lifetime
- 1997-01-14 CN CN97192327A patent/CN1118495C/zh not_active Expired - Lifetime
- 1997-01-14 WO PCT/US1997/000728 patent/WO1997031044A1/en not_active Ceased
- 1997-01-14 DE DE69705606T patent/DE69705606T2/de not_active Expired - Lifetime
- 1997-01-14 AT AT97902973T patent/ATE203030T1/de not_active IP Right Cessation
- 1997-01-14 BR BR9707641A patent/BR9707641A/pt not_active IP Right Cessation
- 1997-07-25 US US08/900,816 patent/US5869552A/en not_active Expired - Lifetime
-
1998
- 1998-05-11 US US09/075,796 patent/US5922817A/en not_active Expired - Lifetime
-
2001
- 2001-09-18 GR GR20010401512T patent/GR3036654T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR100483263B1 (ko) | 2005-09-12 |
| CN1211261A (zh) | 1999-03-17 |
| AU715870B2 (en) | 2000-02-10 |
| RU2171264C2 (ru) | 2001-07-27 |
| CN1118495C (zh) | 2003-08-20 |
| EP0882080B1 (en) | 2001-07-11 |
| EP0882080A1 (en) | 1998-12-09 |
| BR9707641A (pt) | 1999-07-27 |
| WO1997031044A1 (en) | 1997-08-28 |
| KR19990087121A (ko) | 1999-12-15 |
| ATE203030T1 (de) | 2001-07-15 |
| US5869552A (en) | 1999-02-09 |
| AU1701997A (en) | 1997-09-10 |
| JP2000505129A (ja) | 2000-04-25 |
| JP3957228B2 (ja) | 2007-08-15 |
| US5830952A (en) | 1998-11-03 |
| ZA9610680B (en) | 1997-06-24 |
| DE69705606D1 (de) | 2001-08-16 |
| DE69705606T2 (de) | 2002-10-02 |
| US5922817A (en) | 1999-07-13 |
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