HU197774B - Organic solvent process for the hydrolytic saccharification of vegetable materials of starch type - Google Patents

Organic solvent process for the hydrolytic saccharification of vegetable materials of starch type Download PDF

Info

Publication number: HU197774B
Authority: HU; Hungary
Prior art keywords: sugars; hydrolysis; acetone; solution; acid
Prior art date: 1983-02-16

Application number

HU83545A

Other languages

English (en)

Hungarian (hu)

Other versions

HUT34777A (en

Inventor

Laszlo Paszner

Original Assignee

Laszlo Paszner

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-02-16

Filing date

1983-02-16

Publication date

1989-05-29

1983-02-16 Application filed by Laszlo Paszner filed Critical Laszlo Paszner

1983-02-16 Priority to HU83545A priority Critical patent/HU197774B/hu

1984-02-16 Priority to PCT/US1984/000213 priority patent/WO1984003304A1/fr

1984-02-16 Priority to AU25779/84A priority patent/AU579094B2/en

1984-02-16 Priority to EP84901147A priority patent/EP0138882A1/fr

1984-03-28 Priority to CA000449637A priority patent/CA1230592A/fr

1985-04-28 Publication of HUT34777A publication Critical patent/HUT34777A/hu

1985-07-27 Priority to CN85105752A priority patent/CN85105752A/zh

1989-05-29 Publication of HU197774B publication Critical patent/HU197774B/hu

1992-07-30 Priority to CN92108976A priority patent/CN1082115A/zh

Links

229920002472 Starch Polymers 0.000 title claims abstract description 38
235000019698 starch Nutrition 0.000 title claims abstract description 36
238000000034 method Methods 0.000 title claims abstract description 31
239000008107 starch Substances 0.000 title claims abstract description 27
239000003960 organic solvent Substances 0.000 title claims description 9
230000003301 hydrolyzing effect Effects 0.000 title claims description 6
239000005418 vegetable material Substances 0.000 title 1
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 81
235000000346 sugar Nutrition 0.000 claims abstract description 77
150000008163 sugars Chemical class 0.000 claims abstract description 36
150000001720 carbohydrates Chemical class 0.000 claims abstract description 27
235000014633 carbohydrates Nutrition 0.000 claims abstract description 27
239000000463 material Substances 0.000 claims abstract description 20
238000006243 chemical reaction Methods 0.000 claims abstract description 10
239000000243 solution Substances 0.000 claims description 47
239000002253 acid Substances 0.000 claims description 30
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 19
239000007864 aqueous solution Substances 0.000 claims description 10
239000000203 mixture Substances 0.000 claims description 10
229910052500 inorganic mineral Inorganic materials 0.000 claims description 6
239000011707 mineral Substances 0.000 claims description 6
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 5
238000001914 filtration Methods 0.000 claims description 5
238000010438 heat treatment Methods 0.000 claims description 3
OVARTBFNCCXQKS-UHFFFAOYSA-N propan-2-one;hydrate Chemical compound O.CC(C)=O OVARTBFNCCXQKS-UHFFFAOYSA-N 0.000 claims description 3
238000009833 condensation Methods 0.000 claims description 2
230000005494 condensation Effects 0.000 claims description 2
238000002156 mixing Methods 0.000 claims description 2
230000003247 decreasing effect Effects 0.000 claims 1
239000007857 degradation product Substances 0.000 claims 1
239000002198 insoluble material Substances 0.000 claims 1
230000001502 supplementing effect Effects 0.000 claims 1
230000007062 hydrolysis Effects 0.000 abstract description 57
238000006460 hydrolysis reaction Methods 0.000 abstract description 57
102000004169 proteins and genes Human genes 0.000 abstract description 9
108090000623 proteins and genes Proteins 0.000 abstract description 9
230000015556 catabolic process Effects 0.000 abstract description 8
238000006731 degradation reaction Methods 0.000 abstract description 8
229920005610 lignin Polymers 0.000 abstract description 4
150000001875 compounds Chemical class 0.000 abstract description 3
238000000926 separation method Methods 0.000 abstract description 3
150000007513 acids Chemical class 0.000 abstract description 2
238000001816 cooling Methods 0.000 abstract description 2
239000011877 solvent mixture Substances 0.000 abstract description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 18
239000007787 solid Substances 0.000 description 16
240000008042 Zea mays Species 0.000 description 11
235000002017 Zea mays subsp mays Nutrition 0.000 description 11
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235000010980 cellulose Nutrition 0.000 description 10
239000002904 solvent Substances 0.000 description 9
235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 8
239000001913 cellulose Substances 0.000 description 8
235000005822 corn Nutrition 0.000 description 8
230000000694 effects Effects 0.000 description 8
235000018102 proteins Nutrition 0.000 description 8
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
240000008892 Helianthus tuberosus Species 0.000 description 7
235000003230 Helianthus tuberosus Nutrition 0.000 description 7
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 7
238000000855 fermentation Methods 0.000 description 7
230000004151 fermentation Effects 0.000 description 7
235000013312 flour Nutrition 0.000 description 7
230000035484 reaction time Effects 0.000 description 7
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108010065511 Amylases Proteins 0.000 description 6
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238000001704 evaporation Methods 0.000 description 6
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WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 5
238000005903 acid hydrolysis reaction Methods 0.000 description 5
235000019418 amylase Nutrition 0.000 description 5
230000002255 enzymatic effect Effects 0.000 description 5
239000004382 Amylase Substances 0.000 description 4
241000196324 Embryophyta Species 0.000 description 4
240000003183 Manihot esculenta Species 0.000 description 4
230000002378 acidificating effect Effects 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
238000005755 formation reaction Methods 0.000 description 4
239000002244 precipitate Substances 0.000 description 4
238000012545 processing Methods 0.000 description 4
238000011084 recovery Methods 0.000 description 4
238000009923 sugaring Methods 0.000 description 4
NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 3
229920000945 Amylopectin Polymers 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 3
235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 3
238000010306 acid treatment Methods 0.000 description 3
108090000637 alpha-Amylases Proteins 0.000 description 3
108010019077 beta-Amylase Proteins 0.000 description 3
238000009835 boiling Methods 0.000 description 3
239000006227 byproduct Substances 0.000 description 3
238000004090 dissolution Methods 0.000 description 3
239000008103 glucose Substances 0.000 description 3
239000003456 ion exchange resin Substances 0.000 description 3
229920003303 ion-exchange polymer Polymers 0.000 description 3
235000009973 maize Nutrition 0.000 description 3
239000002245 particle Substances 0.000 description 3
229910001220 stainless steel Inorganic materials 0.000 description 3
239000010935 stainless steel Substances 0.000 description 3
239000003039 volatile agent Substances 0.000 description 3
OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
239000002028 Biomass Substances 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
229920002261 Corn starch Polymers 0.000 description 2
SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 2
102000004139 alpha-Amylases Human genes 0.000 description 2
229940024171 alpha-amylase Drugs 0.000 description 2
239000008346 aqueous phase Substances 0.000 description 2
230000008901 benefit Effects 0.000 description 2
238000005119 centrifugation Methods 0.000 description 2
238000010924 continuous production Methods 0.000 description 2
238000010411 cooking Methods 0.000 description 2
239000008120 corn starch Substances 0.000 description 2
238000004821 distillation Methods 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
230000007071 enzymatic hydrolysis Effects 0.000 description 2
238000006047 enzymatic hydrolysis reaction Methods 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 2
239000011521 glass Substances 0.000 description 2
238000000227 grinding Methods 0.000 description 2
239000007788 liquid Substances 0.000 description 2
235000012054 meals Nutrition 0.000 description 2
238000006386 neutralization reaction Methods 0.000 description 2
239000000047 product Substances 0.000 description 2
239000002994 raw material Substances 0.000 description 2
238000011160 research Methods 0.000 description 2
239000000758 substrate Substances 0.000 description 2
239000006188 syrup Substances 0.000 description 2
235000020357 syrup Nutrition 0.000 description 2
238000005406 washing Methods 0.000 description 2
NOEGNKMFWQHSLB-UHFFFAOYSA-N 5-hydroxymethylfurfural Chemical compound OCC1=CC=C(C=O)O1 NOEGNKMFWQHSLB-UHFFFAOYSA-N 0.000 description 1
229920000856 Amylose Polymers 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
244000019459 Cynara cardunculus Species 0.000 description 1
235000019106 Cynara scolymus Nutrition 0.000 description 1
108090000790 Enzymes Proteins 0.000 description 1
102000004190 Enzymes Human genes 0.000 description 1
241000233866 Fungi Species 0.000 description 1
229920001503 Glucan Polymers 0.000 description 1
108010068370 Glutens Proteins 0.000 description 1
229920002488 Hemicellulose Polymers 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
244000061456 Solanum tuberosum Species 0.000 description 1
235000002595 Solanum tuberosum Nutrition 0.000 description 1
240000006394 Sorghum bicolor Species 0.000 description 1
235000021307 Triticum Nutrition 0.000 description 1
244000098338 Triticum aestivum Species 0.000 description 1
238000002835 absorbance Methods 0.000 description 1
239000003513 alkali Substances 0.000 description 1
WQZGKKKJIJFFOK-DVKNGEFBSA-N alpha-D-glucose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-DVKNGEFBSA-N 0.000 description 1
229940025131 amylases Drugs 0.000 description 1
PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 1
235000016520 artichoke thistle Nutrition 0.000 description 1
SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 1
238000011088 calibration curve Methods 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
239000004464 cereal grain Substances 0.000 description 1
239000003610 charcoal Substances 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
238000007906 compression Methods 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
230000006378 damage Effects 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
238000006297 dehydration reaction Methods 0.000 description 1
230000029087 digestion Effects 0.000 description 1
238000007865 diluting Methods 0.000 description 1
150000002016 disaccharides Chemical class 0.000 description 1
235000013399 edible fruits Nutrition 0.000 description 1
229940088598 enzyme Drugs 0.000 description 1
239000000446 fuel Substances 0.000 description 1
125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
235000021312 gluten Nutrition 0.000 description 1
239000010931 gold Substances 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
-1 hexose sugars Chemical class 0.000 description 1
150000002402 hexoses Chemical class 0.000 description 1
239000010903 husk Substances 0.000 description 1
RJGBSYZFOCAGQY-UHFFFAOYSA-N hydroxymethylfurfural Natural products COC1=CC=C(C=O)O1 RJGBSYZFOCAGQY-UHFFFAOYSA-N 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
108010090785 inulinase Proteins 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
238000000622 liquid--liquid extraction Methods 0.000 description 1
235000005739 manihot Nutrition 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
230000000813 microbial effect Effects 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000001814 pectin Substances 0.000 description 1
229920001277 pectin Polymers 0.000 description 1
235000010987 pectin Nutrition 0.000 description 1
239000008188 pellet Substances 0.000 description 1
150000002972 pentoses Chemical class 0.000 description 1
238000005325 percolation Methods 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
238000003825 pressing Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
238000007789 sealing Methods 0.000 description 1
239000013049 sediment Substances 0.000 description 1
239000002002 slurry Substances 0.000 description 1
238000005063 solubilization Methods 0.000 description 1
230000007928 solubilization Effects 0.000 description 1
238000000638 solvent extraction Methods 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
230000001954 sterilising effect Effects 0.000 description 1
238000004659 sterilization and disinfection Methods 0.000 description 1
230000008961 swelling Effects 0.000 description 1
210000005239 tubule Anatomy 0.000 description 1
239000002699 waste material Substances 0.000 description 1
230000004580 weight loss Effects 0.000 description 1

Classifications

- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/20—Pulping cellulose-containing materials with organic solvents or in solvent environment
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K20/00—Accessory food factors for animal feeding-stuffs
- A23K20/10—Organic substances
- A23K20/142—Amino acids; Derivatives thereof
- A23K20/147—Polymeric derivatives, e.g. peptides or proteins
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K1/00—Glucose; Glucose-containing syrups
- C13K1/02—Glucose; Glucose-containing syrups obtained by saccharification of cellulosic materials
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K1/00—Glucose; Glucose-containing syrups
- C13K1/06—Glucose; Glucose-containing syrups obtained by saccharification of starch or raw materials containing starch
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C11/00—Regeneration of pulp liquors or effluent waste waters
- D21C11/0007—Recovery of by-products, i.e. compounds other than those necessary for pulping, for multiple uses or not otherwise provided for

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Polymers & Plastics (AREA)
Proteomics, Peptides & Aminoacids (AREA)
General Health & Medical Sciences (AREA)
Biochemistry (AREA)
Organic Chemistry (AREA)
Emergency Medicine (AREA)
Health & Medical Sciences (AREA)
Zoology (AREA)
Animal Husbandry (AREA)
Engineering & Computer Science (AREA)
Food Science & Technology (AREA)
Saccharide Compounds (AREA)
Polysaccharides And Polysaccharide Derivatives (AREA)
Preparation Of Compounds By Using Micro-Organisms (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

HU83545A 1983-02-16 1983-02-16 Organic solvent process for the hydrolytic saccharification of vegetable materials of starch type HU197774B (en)

Priority Applications (7)

Application Number	Priority Date	Filing Date	Title
HU83545A HU197774B (en)	1983-02-16	1983-02-16	Organic solvent process for the hydrolytic saccharification of vegetable materials of starch type
PCT/US1984/000213 WO1984003304A1 (fr)	1983-02-16	1984-02-16	Procede d'organosolv ameliore pour la decomposition hydrolytique de materiau lignocellulosique et a base d'amidon
AU25779/84A AU579094B2 (en)	1983-02-16	1984-02-16	Improved organosolv process for hydrolytic decomposition of lignocellulosic and starch materials
EP84901147A EP0138882A1 (fr)	1983-02-16	1984-02-16	Procede d'organosolv ameliore pour la decomposition hydrolytique de materiau lignocellulosique et a base d'amidon
CA000449637A CA1230592A (fr)	1983-02-16	1984-03-28	Decomposition hydrolytique, a l'aide d'n solvant organique, de matieres a base de lignocellulose et d'amidon
CN85105752A CN85105752A (zh)	1983-02-16	1985-07-27	水解分解木质纤维素和淀粉物质的有机溶胶化方法
CN92108976A CN1082115A (zh)	1983-02-16	1992-07-30	水解分解木质纤维素和淀粉物质的有机溶胶化方法

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
HU83545A HU197774B (en)	1983-02-16	1983-02-16	Organic solvent process for the hydrolytic saccharification of vegetable materials of starch type
CN92108976A CN1082115A (zh)	1983-02-16	1992-07-30	水解分解木质纤维素和淀粉物质的有机溶胶化方法

Publications (2)

Publication Number	Publication Date
HUT34777A HUT34777A (en)	1985-04-28
HU197774B true HU197774B (en)	1989-05-29

Family

ID=36782303

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
HU83545A HU197774B (en)	1983-02-16	1983-02-16	Organic solvent process for the hydrolytic saccharification of vegetable materials of starch type

Country Status (6)

Country	Link
EP (1)	EP0138882A1 (fr)
CN (2)	CN85105752A (fr)
AU (1)	AU579094B2 (fr)
CA (1)	CA1230592A (fr)
HU (1)	HU197774B (fr)
WO (1)	WO1984003304A1 (fr)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5756533A (en) *	1995-03-10	1998-05-26	G.D. Searle & Co.	Amino acid hydroxyethylamino sulfonamide retroviral protease inhibitors
EP2479341A1 (fr)	2006-05-08	2012-07-25	Vertichem Corporation	Procédé de production de biocarburant à partir de matières végétales
US8193324B2 (en)	2007-05-31	2012-06-05	Lignol Innovations Ltd.	Continuous counter-current organosolv processing of lignocellulosic feedstocks
US20080295980A1 (en)	2007-05-31	2008-12-04	Lignol Innovations Ltd.	Continuous counter-current organosolv processing of lignocellulosic feedstocks
NZ580751A (en) *	2007-05-31	2012-08-31	Lignol Innovations Ltd	Continuous counter-current organosolv processing of lignocellulosic feedstocks
CN101121735B (zh) *	2007-07-06	2011-04-06	陈培豪	植物纤维原料水解液及利用该水解液预处理植物纤维原料的方法
AU2008293139A1 (en)	2007-08-31	2009-03-05	Vertichem Corporation	Lignin and other products isolated from plant material, and methods and compositions therefor
CN101199944B (zh) *	2007-11-23	2013-01-30	淮北中润生物能源技术开发有限公司	纤维素仿生催化水解系统及其在纤维素生物质生产液体燃料中的应用
US20110223643A1 (en) *	2007-11-23	2011-09-15	China Fuel (Huaibei) Bioenergy Technology Developm	System for bionic catalytic hydrolyzing cellulose and its use in producing liquid fuel from cellulose biomass
JP4524351B2 (ja)	2008-02-01	2010-08-18	三菱重工業株式会社	バイオマス原料を用いた有機原料の製造システム及び方法
JP4427584B2 (ja)	2008-02-01	2010-03-10	三菱重工業株式会社	バイオマスの水熱分解装置及び方法、バイオマス原料を用いた有機原料の製造システム
JP4427583B2 (ja)	2008-02-01	2010-03-10	三菱重工業株式会社	バイオマスの水熱分解装置及び方法、バイオマス原料を用いた有機原料の製造システム
EP2265625B1 (fr) *	2008-03-17	2014-11-12	Bio Tech Ltd	Procédé d'hydrolyse acide en continu de substances contenant de la cellulose
BRPI1012286A2 (pt)	2009-05-28	2015-09-22	Lignol Innovations Ltd	derivados de lignina nativa de matérias-primas de fibras de plantas anuais
CA2824446C (fr)	2010-02-15	2018-09-18	Suzano Canada Inc.	Compositions de liant comprenant des derives de lignine
WO2011097721A1 (fr)	2010-02-15	2011-08-18	Lignol Innovations Ltd.	Compositions en fibres de carbone contenant des dérivés de lignine
CA2741602C (fr)	2010-03-10	2013-04-30	Mitsubishi Heavy Industries, Ltd.	Appareil de decomposition hydrothermale de biomasse, methode de regulation de la temperature connexe et systeme de production de materiau organique brut utilisant le materiau de biomasse
BRPI1006883B1 (pt)	2010-03-10	2021-06-29	Mitsubishi Power Environmental Solutions, Ltd.	Equipamento de decomposição hidrotérmica de biomassa, método de controle de temperatura da mesma, e sistema de produção de matéria-prima orgânica usando material de biomassa
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1983
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1984
- 1984-02-16 WO PCT/US1984/000213 patent/WO1984003304A1/fr not_active Ceased
- 1984-02-16 EP EP84901147A patent/EP0138882A1/fr not_active Withdrawn
- 1984-02-16 AU AU25779/84A patent/AU579094B2/en not_active Ceased
- 1984-03-28 CA CA000449637A patent/CA1230592A/fr not_active Expired
1985
- 1985-07-27 CN CN85105752A patent/CN85105752A/zh active Pending
1992
- 1992-07-30 CN CN92108976A patent/CN1082115A/zh active Pending

Also Published As

Publication number	Publication date
CN85105752A (zh)	1987-01-28
CA1230592A (fr)	1987-12-22
HUT34777A (en)	1985-04-28
EP0138882A1 (fr)	1985-05-02
WO1984003304A1 (fr)	1984-08-30
AU579094B2 (en)	1988-11-17
AU2577984A (en)	1984-09-10
CN1082115A (zh)	1994-02-16

Legal Events

Date	Code	Title
1990-06-28	HU90	Patent valid on 900628
1997-11-28	HMM4	Cancellation of final prot. due to non-payment of fee
1998-01-28	DNF4	Restoration of lapsed final protection
1999-11-29	HMM4	Cancellation of final prot. due to non-payment of fee

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