HUE028508T2 - A method for purifying isocyanate-containing residuals - Google Patents

A method for purifying isocyanate-containing residuals Download PDF

Info

Publication number: HUE028508T2
Authority: HU; Hungary
Prior art keywords: residue; monomer; forced; less; residues
Prior art date: 2005-09-29

Application number

HUE06793700A

Other languages

English (en)

Hungarian (hu)

Inventor

Andreas Woelfert

Carsten Knoesche

Matthias Kloetzer

Hermann Ascherl

Eckhard Stroefer

Heinrich-Josef Blankertz

Michael Schoenherr

Martin Karches

Christian Benz

Original Assignee

Basf Se

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2005-09-29

Filing date

2006-09-21

Publication date

2017-02-28

2005-09-29 Priority claimed from DE200510046816 external-priority patent/DE102005046816A1/de

2005-10-25 Priority claimed from DE200510051399 external-priority patent/DE102005051399A1/de

2006-09-21 Application filed by Basf Se filed Critical Basf Se

2017-02-28 Publication of HUE028508T2 publication Critical patent/HUE028508T2/en

Links

238000000034 method Methods 0.000 title claims description 68
239000012948 isocyanate Substances 0.000 title description 9
150000002513 isocyanates Chemical class 0.000 title description 7
239000000178 monomer Substances 0.000 claims description 42
239000007787 solid Substances 0.000 claims description 13
229910000831 Steel Inorganic materials 0.000 claims description 12
239000010959 steel Substances 0.000 claims description 12
238000001816 cooling Methods 0.000 claims description 11
125000005442 diisocyanate group Chemical group 0.000 claims description 11
239000007788 liquid Substances 0.000 claims description 11
239000011651 chromium Substances 0.000 claims description 5
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
239000000460 chlorine Substances 0.000 claims description 4
229910052801 chlorine Inorganic materials 0.000 claims description 4
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
229910052804 chromium Inorganic materials 0.000 claims description 3
150000004985 diamines Chemical class 0.000 claims description 3
239000000843 powder Substances 0.000 claims description 2
239000010409 thin film Substances 0.000 claims description 2
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims 3
125000001931 aliphatic group Chemical group 0.000 claims 2
210000004556 brain Anatomy 0.000 claims 2
238000001125 extrusion Methods 0.000 claims 2
238000004965 Hartree-Fock calculation Methods 0.000 claims 1
UHWVSEOVJBQKBE-UHFFFAOYSA-N Trimetazidine Chemical compound COC1=C(OC)C(OC)=CC=C1CN1CCNCC1 UHWVSEOVJBQKBE-UHFFFAOYSA-N 0.000 claims 1
208000037386 Typhoid Diseases 0.000 claims 1
230000036528 appetite Effects 0.000 claims 1
235000019789 appetite Nutrition 0.000 claims 1
210000000481 breast Anatomy 0.000 claims 1
238000003776 cleavage reaction Methods 0.000 claims 1
229920005989 resin Polymers 0.000 claims 1
239000011347 resin Substances 0.000 claims 1
230000007017 scission Effects 0.000 claims 1
201000008297 typhoid fever Diseases 0.000 claims 1
239000000463 material Substances 0.000 description 15
239000000047 product Substances 0.000 description 14
238000004821 distillation Methods 0.000 description 12
238000010494 dissociation reaction Methods 0.000 description 10
230000005593 dissociations Effects 0.000 description 10
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
239000000203 mixture Substances 0.000 description 9
238000010438 heat treatment Methods 0.000 description 8
238000004519 manufacturing process Methods 0.000 description 7
JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 6
238000009835 boiling Methods 0.000 description 6
238000004898 kneading Methods 0.000 description 6
238000000926 separation method Methods 0.000 description 6
YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 5
230000015572 biosynthetic process Effects 0.000 description 5
UDHXJZHVNHGCEC-UHFFFAOYSA-N Chlorophacinone Chemical compound C1=CC(Cl)=CC=C1C(C=1C=CC=CC=1)C(=O)C1C(=O)C2=CC=CC=C2C1=O UDHXJZHVNHGCEC-UHFFFAOYSA-N 0.000 description 4
239000006227 byproduct Substances 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
238000004140 cleaning Methods 0.000 description 4
238000001228 spectrum Methods 0.000 description 4
239000000126 substance Substances 0.000 description 4
238000013022 venting Methods 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
239000004202 carbamide Substances 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
229930195733 hydrocarbon Natural products 0.000 description 3
150000002430 hydrocarbons Chemical class 0.000 description 3
238000002156 mixing Methods 0.000 description 3
239000012071 phase Substances 0.000 description 3
238000011084 recovery Methods 0.000 description 3
229910001220 stainless steel Inorganic materials 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
150000001805 chlorine compounds Chemical class 0.000 description 2
238000010276 construction Methods 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
230000007797 corrosion Effects 0.000 description 2
230000007423 decrease Effects 0.000 description 2
ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
238000007599 discharging Methods 0.000 description 2
238000005265 energy consumption Methods 0.000 description 2
239000010408 film Substances 0.000 description 2
239000006260 foam Substances 0.000 description 2
239000007789 gas Substances 0.000 description 2
230000005484 gravity Effects 0.000 description 2
238000003801 milling Methods 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
238000000746 purification Methods 0.000 description 2
239000002904 solvent Substances 0.000 description 2
DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
229910000859 α-Fe Inorganic materials 0.000 description 2
MHCVCKDNQYMGEX-UHFFFAOYSA-N 1,1'-biphenyl;phenoxybenzene Chemical group C1=CC=CC=C1C1=CC=CC=C1.C=1C=CC=CC=1OC1=CC=CC=C1 MHCVCKDNQYMGEX-UHFFFAOYSA-N 0.000 description 1
NNOZGCICXAYKLW-UHFFFAOYSA-N 1,2-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=CC=C1C(C)(C)N=C=O NNOZGCICXAYKLW-UHFFFAOYSA-N 0.000 description 1
TXHLIIZKFKXDKR-UHFFFAOYSA-N 1-(2-chloro-6-methylphenyl)-3-(pyridin-4-ylmethyl)urea Chemical compound CC1=CC=CC(Cl)=C1NC(=O)NCC1=CC=NC=C1 TXHLIIZKFKXDKR-UHFFFAOYSA-N 0.000 description 1
229920004435 Aclon® Polymers 0.000 description 1
241000555825 Clupeidae Species 0.000 description 1
241001245789 Goodea atripinnis Species 0.000 description 1
241000282414 Homo sapiens Species 0.000 description 1
230000005483 Hooke's law Effects 0.000 description 1
241000283986 Lepus Species 0.000 description 1
235000009421 Myristica fragrans Nutrition 0.000 description 1
241001246312 Otis Species 0.000 description 1
241000282320 Panthera leo Species 0.000 description 1
241000270295 Serpentes Species 0.000 description 1
-1 aliphatic isocyanates Chemical class 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
239000000956 alloy Substances 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
239000010426 asphalt Substances 0.000 description 1
235000010290 biphenyl Nutrition 0.000 description 1
239000004305 biphenyl Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
230000009194 climbing Effects 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000000470 constituent Substances 0.000 description 1
239000013078 crystal Substances 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
238000007872 degassing Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
239000000428 dust Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
239000011552 falling film Substances 0.000 description 1
238000005187 foaming Methods 0.000 description 1
229910000856 hastalloy Inorganic materials 0.000 description 1
231100001261 hazardous Toxicity 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
238000002955 isolation Methods 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000001115 mace Substances 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000002245 particle Substances 0.000 description 1
101150091331 plp gene Proteins 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
238000010186 staining Methods 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
150000003673 urethanes Chemical class 0.000 description 1
239000002699 waste material Substances 0.000 description 1
238000010626 work up procedure Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C263/00—Preparation of derivatives of isocyanic acid
- C07C263/18—Separation; Purification; Stabilisation; Use of additives
- C07C263/20—Separation; Purification
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C265/00—Derivatives of isocyanic acid
- C07C265/14—Derivatives of isocyanic acid containing at least two isocyanate groups bound to the same carbon skeleton
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

HUE06793700A 2005-09-29 2006-09-21 A method for purifying isocyanate-containing residuals HUE028508T2 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE200510046816 DE102005046816A1 (de)	2005-09-29	2005-09-29	Verfahren zur Aufreinigung von isocyanathaltigen Rückständen
DE200510051399 DE102005051399A1 (de)	2005-10-25	2005-10-25	Verfahren zur Aufreinigung von isocyanathaltigen Rückständen

Publications (1)

Publication Number	Publication Date
HUE028508T2 true HUE028508T2 (en)	2017-02-28

Family

ID=37635743

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
HUE06793700A HUE028508T2 (en)	2005-09-29	2006-09-21	A method for purifying isocyanate-containing residuals

Country Status (6)

Country	Link
US (1)	US9061971B2 (de)
EP (1)	EP1931625B1 (de)
JP (1)	JP5254020B2 (de)
KR (1)	KR101287282B1 (de)
HU (1)	HUE028508T2 (de)
WO (1)	WO2007036479A1 (de)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2010507614A (ja)	2006-10-26	2010-03-11	ビーエーエスエフソシエタス・ヨーロピア	イソシアネートの製造方法
WO2009127591A2 (de) *	2008-04-14	2009-10-22	Basf Se	Verfahren zur aufarbeitung von rückständen aus der produktion von isocyanaten
US8492580B2 (en)	2009-08-04	2013-07-23	Basf Se	Process for preparing isocyanates
JP2013505280A (ja)	2009-09-22	2013-02-14	ビーエーエスエフソシエタス・ヨーロピア	イソシアナートの製造方法
TWI552982B (zh)	2013-03-29	2016-10-11	旭化成化學股份有限公司	異氰酸酯的製造方法
EP3571185A1 (de)	2017-01-18	2019-11-27	Covestro Deutschland AG	Verfahren zur rückgewinnung von diisocyanaten aus destillationsrückständen
US11578030B2 (en)	2017-12-27	2023-02-14	Asahi Kasei Kabushiki Kaisha	Organic amine collection method
EP3549931A1 (de)	2018-04-06	2019-10-09	Covestro Deutschland AG	Verfahren zur rückgewinnung von diisocyanaten aus destillationsrückständen
EP3597632A1 (de) *	2018-07-18	2020-01-22	Covestro Deutschland AG	Verfahren zur rückgewinnung von diisocyanaten aus destillationsrückständen
US20240425448A1 (en)	2021-11-08	2024-12-26	Asahi Kasei Kabushiki Kaisha	Method for producing isocyanate compound, method for producing carbamate compound, method for recovering amine compound, and isocyanate composition

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3405040A (en) *	1965-08-31	1968-10-08	Mobay Chemical Corp	Method for recovering tolylene diisocyanate
US3694323A (en) *	1968-08-05	1972-09-26	Du Pont	Separation of distillable isocyanates from their phosgenation masses
JPS5354168A (en) *	1976-10-28	1978-05-17	Artisan Ind	Improvement of evapolation apparatus
FR2397396A1 (fr) *	1977-07-12	1979-02-09	Ugine Kuhlmann	Procede de recuperation du toluene diisocyanate a partir des residus de fabrication
DE2915830A1 (de) *	1979-04-19	1980-10-23	Basf Ag	Gewinnung von toluylendiisocyanat und/oder hoehersiedenden loesungsmitteln im wirbelbett aus destillationsrueckstaenden der toluylendiisocanat-herstellung
CA1250572A (en) *	1982-09-30	1989-02-28	Kenneth L. Dunlap	Reduction of free monomer in isocyanate adducts
US4672094A (en) *	1986-01-21	1987-06-09	The Dow Chemical Company	Method for increasing the molecular weight of polyamides and polyesteramides
JPS62197101A (ja) *	1986-02-26	1987-08-31	Mitsui Toatsu Chem Inc	蒸発機
DE4317669A1 (de) *	1993-05-27	1994-12-01	Bayer Ag	Verfahren zur Herstellung von Isocyanaten und kontinuierlichen Aufarbeitung des Rückstandes
US5962728A (en) *	1997-10-31	1999-10-05	Arco Chemical Technology, L.P.	Isocyanate residue purification
DE19827086A1 (de) *	1998-06-18	1999-12-23	Basf Ag	Verfahren zur Aufarbeitung von Destillationsrückständen aus der Synthese von Toluylendiisocyanat
DE10260092A1 (de) *	2002-12-19	2004-07-01	Basf Ag	Verfahren zur Reinigung von Isocyanaten
US20050159495A1 (en) *	2004-01-20	2005-07-21	Jennings William J.	Toluene diisocyanate tar fluidizer and method of use

2006
- 2006-09-21 KR KR1020087009100A patent/KR101287282B1/ko active Active
- 2006-09-21 US US12/067,104 patent/US9061971B2/en active Active
- 2006-09-21 HU HUE06793700A patent/HUE028508T2/en unknown
- 2006-09-21 WO PCT/EP2006/066577 patent/WO2007036479A1/de not_active Ceased
- 2006-09-21 JP JP2008532737A patent/JP5254020B2/ja active Active
- 2006-09-21 EP EP06793700.3A patent/EP1931625B1/de active Active

Also Published As

Publication number	Publication date
EP1931625B1 (de)	2015-11-11
EP1931625A1 (de)	2008-06-18
JP2009510015A (ja)	2009-03-12
WO2007036479A1 (de)	2007-04-05
KR101287282B1 (ko)	2013-07-23
US9061971B2 (en)	2015-06-23
US20080262263A1 (en)	2008-10-23
KR20080050615A (ko)	2008-06-09
JP5254020B2 (ja)	2013-08-07

Publication	Publication Date	Title
TWI281912B (en)	2007-06-01	Process for the purification of mixtures of toluenediisocyanate incorporating a dividing-wall distillation column
HUE028508T2 (en)	2017-02-28	A method for purifying isocyanate-containing residuals
KR101073965B1 (ko)	2011-10-17	이소시아네이트의 정제 방법
US9029595B1 (en)	2015-05-12	Method for working up distillation residues from isocyanate production
EP0626368B1 (de)	1998-04-15	Verfahren zur Herstellung von Isocyanaten und kontinuierlicher Aufarbeitung des Rückstandes
WO2008086922A1 (de)	2008-07-24	Verfahren zur herstellung von isocyanaten
EP3558940B1 (de)	2021-01-20	Verfahren zur herstellung eines isocyanats
EP2373616A1 (de)	2011-10-12	Verfahren zur herstellung von isocyanaten
US5962728A (en)	1999-10-05	Isocyanate residue purification
JP6581581B2 (ja)	2019-09-25	イソシアネート製造において生じる蒸留残渣から有機イソシアネートを取得する方法
WO2009027418A1 (de)	2009-03-05	Verfahren zur herstellung von isocyanaten
DE10260093A1 (de)	2004-07-01	Verfahren zur Abtrennung von Isocyanaten aus einem Reaktionsgemisch
CN1186317C (zh)	2005-01-26	制备有机多异氰酸酯的方法
DE4142769A1 (de)	1993-06-24	Verfahren zur herstellung von isocyanaten und aufarbeitung des rueckstandes
JP2022540452A (ja)	2022-09-15	ポリイソシアネートの蒸留
EP2540702A2 (de)	2013-01-02	Verfahren zur Gewinnung von Toluylendiisocyanat aus flüssigen Rückständen der Toluylendiisocyanatherstellung
CN101273010B (zh)	2012-04-18	纯化含有异氰酸酯的残余物的方法
JPH08501106A (ja)	1996-02-06	残渣のない２，４／２，６−ジアミノトルエン混合物
KR100369455B1 (ko)	2003-01-24	증류찌꺼기의 처리방법
DE102005051399A1 (de)	2007-04-26	Verfahren zur Aufreinigung von isocyanathaltigen Rückständen
US3379749A (en)	1968-04-23	Preparation of monoisocyanates from isocyanate distillation residues
WO2021052894A1 (de)	2021-03-25	Verfahren zur herstellung von isocyanaten
US20260062379A1 (en)	2026-03-05	Method for treating residue from the production of organic isocyanates