HUE032607T2 - Eljárás kemény poliuretánhabok elõállítására - Google Patents
Eljárás kemény poliuretánhabok elõállítására Download PDFInfo
- Publication number
- HUE032607T2 HUE032607T2 HUE12712682A HUE12712682A HUE032607T2 HU E032607 T2 HUE032607 T2 HU E032607T2 HU E12712682 A HUE12712682 A HU E12712682A HU E12712682 A HUE12712682 A HU E12712682A HU E032607 T2 HUE032607 T2 HU E032607T2
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- HU
- Hungary
- Prior art keywords
- weight
- parts
- koh
- compounds
- polyol
- Prior art date
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- 238000000034 method Methods 0.000 title claims description 28
- 229920005830 Polyurethane Foam Polymers 0.000 title claims description 15
- 239000011496 polyurethane foam Substances 0.000 title claims description 8
- 229920005862 polyol Polymers 0.000 claims description 45
- 150000003077 polyols Chemical class 0.000 claims description 44
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 30
- 239000000203 mixture Substances 0.000 claims description 29
- 239000006260 foam Substances 0.000 claims description 26
- -1 polypropylene Polymers 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 20
- 229920000570 polyether Polymers 0.000 claims description 20
- 150000001298 alcohols Chemical class 0.000 claims description 19
- 239000012948 isocyanate Substances 0.000 claims description 16
- 150000002513 isocyanates Chemical class 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 8
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 5
- 239000005056 polyisocyanate Substances 0.000 claims description 5
- 229920001228 polyisocyanate Polymers 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- 230000001605 fetal effect Effects 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 150000004676 glycans Chemical class 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 239000008188 pellet Substances 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 229920001282 polysaccharide Polymers 0.000 claims 1
- 239000005017 polysaccharide Substances 0.000 claims 1
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 40
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 39
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 22
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- 239000003054 catalyst Substances 0.000 description 13
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- 229910019142 PO4 Inorganic materials 0.000 description 10
- 235000021317 phosphate Nutrition 0.000 description 10
- 239000004604 Blowing Agent Substances 0.000 description 9
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 9
- 229930006000 Sucrose Natural products 0.000 description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 9
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- 239000005720 sucrose Substances 0.000 description 9
- 125000003118 aryl group Chemical group 0.000 description 8
- 150000002148 esters Chemical class 0.000 description 8
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 8
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 7
- 239000004359 castor oil Substances 0.000 description 7
- 235000019438 castor oil Nutrition 0.000 description 7
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 7
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical class C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 229920005906 polyester polyol Polymers 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 5
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 125000005442 diisocyanate group Chemical group 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 239000000600 sorbitol Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 125000002947 alkylene group Chemical group 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 4
- 150000002334 glycols Chemical class 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
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- 235000011056 potassium acetate Nutrition 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 3
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 3
- 238000007664 blowing Methods 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 229920005903 polyol mixture Polymers 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 238000005057 refrigeration Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
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- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
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- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 1
- PCHXZXKMYCGVFA-UHFFFAOYSA-N 1,3-diazetidine-2,4-dione Chemical compound O=C1NC(=O)N1 PCHXZXKMYCGVFA-UHFFFAOYSA-N 0.000 description 1
- AKSLIQRKLWDOPD-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethanol;2-(2-hydroxypropoxy)propan-1-ol Chemical compound OCCOCCO.CC(O)COC(C)CO AKSLIQRKLWDOPD-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- XHCNINMOALIGKM-UHFFFAOYSA-N 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetrazacyclotetradecane Chemical compound CC1CC(C)(C)NCCNC(C)CC(C)(C)NCCN1 XHCNINMOALIGKM-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
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- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
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- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
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- 101100353161 Drosophila melanogaster prel gene Proteins 0.000 description 1
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- 239000002841 Lewis acid Substances 0.000 description 1
- 101100238304 Mus musculus Morc1 gene Proteins 0.000 description 1
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 1
- JNJZLAHUXHBYIS-UHFFFAOYSA-N OP(O)(=O)OP1(=O)OCCO1 Chemical compound OP(O)(=O)OP1(=O)OCCO1 JNJZLAHUXHBYIS-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
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- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 101100023111 Schizosaccharomyces pombe (strain 972 / ATCC 24843) mfc1 gene Proteins 0.000 description 1
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- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
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- 150000001412 amines Chemical class 0.000 description 1
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- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
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- WMWXXXSCZVGQAR-UHFFFAOYSA-N dialuminum;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3] WMWXXXSCZVGQAR-UHFFFAOYSA-N 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
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Claims (4)
- iy#Ä Mrpiny polipréfitiiiabok atSÉftitâeâri SEÄBafMYMl IGÉNYPONTOK1, Eljárás kemény poíiuretánhabok előállítására a) szerves poliizocianátoknak b) legalább két, izocianât-csoportokkai reaktiv hidrogénatommal rendelkező vegyülő-tekkél való reakciójával, o) gázképző anyagok. d| katallzátemk valamint adott esetben éj seildanyagók^is adailkanyagpk jiíeníiiiöeo, œaipiiemeavej Èc^iy b} komponinspnt egy olyan keveréket alkalmazunk, amely ált 11} IfMG tömegrész egy vagy több olyan nagyfunkdonalltású políéter-alkohöiökbáf, ámeneknek funkcionalitása 3,5-5,5 és hidroxí-száma 400-550 mg KöH/g, és stador-vegyüíetekként bidrozil-tartalmu nagyfunkcionalitású vegyOtetekkal rendelkeznek, b2) 5 -15 fömegtész egy vagy több olyan políéter-aíkoholökboí, amelyek; 4^s funkcionalitású és 470-800 mg KOH/g hidfoxi-számú alifás aminokon alapulnak, b3) 10-30 tőmeg% egy vagy több olyan poliéter-alkohoíokből, amelyek 2-3 funkcionalitással és 220-430 mg KOH/g Niroxi-számmal rendelkeznek, és 04} adott eset bén 1-5 iömegrész vízből, ahol a b) pokol-komponensek b1)-b4) tömegrészef nem haladják meg a 100 tömeg-részt,
- 2, Az 1, Igénypont szerinti eprié, azzal Jellemezve, hegy a b2) poliéter-alko-holdk itnkcionailtáaa 4 és hidroxi-széma 730-800 mg KQH/g. I, Az 1. vagy I, igénypont szerinti eljárás, azzal jellemezve, bogy a b3) poli-éter-alkoholok funkploniíitlsa 3 és hídroxí-száma 380-420 mg KOH/g.
- 4. Az 1-3. igénypontok egyike szerinti eljárás., azzal Jellemezve, bogy a reakciót egy 100 és 150 közötti izocianát-indexen valósítjuk meg. I* Az 1-4. Igénypontok egyike szerinti eljárás, azzal jellemezve, hogy a gáz-képző anyagként n-pentáni és/vagy ízopentánt alkalmazunk.
- 8, Poliyrelln keményhabok., amelyeket az 1, igénypont szerinti eljárással állítottunk elő. t* Egy p) poliol-komponens, amely áll fel ) 20-60 timegreaz egy vagy több olyan hág yfynkeiebalííásy patétef-aíköfebifekbéj,: imalyaknek ftinkcbyalltiss 3,5-5,5 és Hürösfetáma 400-550 mg KOH/g, és Sfáífir-yegyületekként hioroxl-tartalmú nagyfunkoionaistásu vegyületekkel: tfendeíkeinek,, b2) 5-15 fömegrész egy vagy több olyan poliéter-alkohölökbóí, amelyek 4~es funkcionál itású és 470-800 rng KOH/g ivdröxészámú alifás amínokon alapulnak, 13) 10-30 tömeg% egy vagy több olyan poíéter-aíkahöjekfeli, amelyek 2-3 funkele-naíifássai és 220-430 mg KOH/g hidroxí-számmaí rendeilézpék, éf b4) adott esetben 1 -5 tömeg rész vízből, ahol a b) pellol h1)-b4| tomegrészei aem haladják meg a 100 tömeg részt.
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| HUE12712682A HUE032607T2 (hu) | 2011-04-15 | 2012-04-11 | Eljárás kemény poliuretánhabok elõállítására |
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| EP (1) | EP2697296B1 (hu) |
| JP (1) | JP2014510821A (hu) |
| KR (1) | KR20140026488A (hu) |
| CN (1) | CN103619928B (hu) |
| AU (1) | AU2012241986B2 (hu) |
| BR (1) | BR112013026495B1 (hu) |
| CA (1) | CA2833066A1 (hu) |
| ES (1) | ES2626009T3 (hu) |
| HU (1) | HUE032607T2 (hu) |
| LT (1) | LT2697296T (hu) |
| MA (1) | MA35040B1 (hu) |
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| PL (1) | PL2697296T3 (hu) |
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| TN (1) | TN2013000424A1 (hu) |
| UA (1) | UA110132C2 (hu) |
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| US8895636B2 (en) | 2012-01-02 | 2014-11-25 | Basf Se | Producing rigid polyurethane foams and rigid polyisocyanurate foams |
| US9475220B2 (en) | 2013-02-13 | 2016-10-25 | Basf Se | Process for producing composite elements |
| WO2017144492A1 (de) * | 2016-02-22 | 2017-08-31 | Basf Se | Verfahren zur herstellung eines diblockcopolymers |
| CN109776748A (zh) * | 2019-01-22 | 2019-05-21 | 天津爱德加科技有限公司 | 一种耐高温全水硬质聚氨酯泡沫组合聚醚、硬质聚氨酯泡沫及其制备方法 |
| JP7233400B2 (ja) * | 2020-06-24 | 2023-03-06 | 株式会社日本アクア | ウレタン樹脂組成物用原料および建築物の断熱方法 |
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| GB2030584B (en) * | 1978-10-03 | 1983-03-23 | Lankro Chem Ltd | Photopolymerisable solder resist compositions |
| DE3627236A1 (de) * | 1986-08-12 | 1988-02-18 | Basf Ag | Hydrophile polyurethan-hartschaumstoffe, verfahren zu deren herstellung und deren verwendung |
| JP3242711B2 (ja) * | 1992-09-21 | 2001-12-25 | 三井化学株式会社 | ポリオール組成物 |
| DE19502969A1 (de) | 1995-01-31 | 1996-08-01 | Elastogran Gmbh | Verfahren zur Herstellung von Polyurethan-Hartschaumstoffen |
| JPH0987355A (ja) * | 1995-09-27 | 1997-03-31 | Sanyo Chem Ind Ltd | 硬質ポリウレタンフォームの製造法 |
| EP0895487A4 (en) * | 1996-04-23 | 1999-06-30 | Hehr International Inc | MODIFIED, STABLE, FOAMABLE URETHANE COMPOSITION AND METHOD |
| DE19634700A1 (de) | 1996-08-28 | 1998-03-05 | Bayer Ag | Verfahren zur Herstellung von Polyurethanhartschaumstoffen |
| DE19742013A1 (de) * | 1997-09-24 | 1999-03-25 | Basf Ag | Offenzellige Hartschaumstoffe auf Isocyanatbasis |
| DE19817507A1 (de) * | 1998-04-20 | 1999-10-21 | Basf Ag | Verfahren zur Herstellung von Polyurethan-Hartschaumstoffen mit einer verminderten Wärmeleitfähigkeit und ihre Verwendung |
| JP3670158B2 (ja) * | 1999-03-31 | 2005-07-13 | 日清紡績株式会社 | 難燃性硬質ポリウレタンフォーム用樹脂組成物 |
| DE10009649A1 (de) * | 2000-03-01 | 2001-09-06 | Basf Ag | Offenzellige Polyurethan-Hartschaumstoffe |
| US6423759B1 (en) * | 2000-12-20 | 2002-07-23 | Bayer Corporation | Co-initiated polyols useful for the production of rigid polyurethane foams |
| US6495722B1 (en) | 2001-09-17 | 2002-12-17 | Huntsman Petrochemical Corporation | Mannich polyols for rigid spray foams |
| JP4070003B2 (ja) * | 2002-03-22 | 2008-04-02 | 東洋ゴム工業株式会社 | 硬質ポリウレタンフォームサンドイッチパネル用ポリオール組成物及び硬質ポリウレタンフォームサンドイッチパネルの製造方法 |
| DE10336938A1 (de) * | 2003-08-07 | 2005-03-10 | Basf Ag | Offenzellige Polyurethan-Hartschaumstoffe |
| DE10337787A1 (de) * | 2003-08-14 | 2005-03-24 | Basf Ag | Flammgeschützter Polyurethanhartschaumstoff, enthaltend siliconfreie Schaumstabilisatoren |
| WO2005044889A1 (en) * | 2003-11-03 | 2005-05-19 | Dow Global Technologies Inc. | Rigid polyurethane foam based on toluene diamine-initiated polyols |
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| EP1577332A1 (en) * | 2004-03-15 | 2005-09-21 | Huntsman International Llc | Process for making rigid polyurethane foams |
| DE102004042525A1 (de) | 2004-09-02 | 2006-03-09 | Bayer Materialscience Ag | Auf aliphatischen Polyesterpolyolen basierende PUR-/PIR-Hartschaumstoffe |
| DE102004044915A1 (de) * | 2004-09-14 | 2006-03-16 | Basf Ag | Polyurethanhartschaumstoffe |
| DE102005017363A1 (de) | 2005-04-14 | 2006-10-19 | Basf Ag | Verfahren zur Herstellung von Polyurethan- und Polyisocyanurat-Hartschaumstoffen |
| RU2343165C1 (ru) * | 2007-08-29 | 2009-01-10 | Федеральное казенное предприятие (ФКП) "Пермский пороховой завод" | Композиция для получения жестких пенополиуретанов теплоизоляционного назначения |
| ITMI20081867A1 (it) * | 2008-10-22 | 2010-04-22 | Dow Global Technologies Inc | Processo per lapreparazione di schiume poliuretaniche rigide a celle chiuse |
| MX2011009801A (es) | 2009-03-18 | 2011-11-04 | Basf Se | Metodo para producir espumas de poliuretano rigidas. |
| WO2010111021A1 (en) * | 2009-03-24 | 2010-09-30 | Dow Global Technologies Inc. | Production of rigid polyurethane foams and the use thereof |
| EP2386585B1 (en) * | 2010-04-21 | 2017-03-22 | Dow Global Technologies LLC | Foam insulation unit |
| EP2461022A1 (de) * | 2010-12-01 | 2012-06-06 | Basf Se | Kernschäume aus Polyurethan für die Herstellung von Flügeln, insbesondere für Windkraftanlagen |
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- 2012-04-11 AU AU2012241986A patent/AU2012241986B2/en not_active Ceased
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- 2012-04-11 MX MX2013011974A patent/MX337069B/es active IP Right Grant
- 2012-04-11 BR BR112013026495-0A patent/BR112013026495B1/pt active IP Right Grant
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- 2012-04-11 ES ES12712682.9T patent/ES2626009T3/es active Active
- 2012-04-11 EP EP12712682.9A patent/EP2697296B1/de active Active
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- 2012-04-11 RU RU2013150677/05A patent/RU2601755C2/ru active
- 2012-04-11 CA CA2833066A patent/CA2833066A1/en not_active Abandoned
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Also Published As
| Publication number | Publication date |
|---|---|
| JP2014510821A (ja) | 2014-05-01 |
| ES2626009T3 (es) | 2017-07-21 |
| TN2013000424A1 (en) | 2015-03-30 |
| AU2012241986B2 (en) | 2015-09-17 |
| EP2697296A1 (de) | 2014-02-19 |
| MX2013011974A (es) | 2013-11-04 |
| EP2697296B1 (de) | 2017-02-22 |
| LT2697296T (lt) | 2017-05-10 |
| MX337069B (es) | 2016-02-11 |
| BR112013026495A2 (pt) | 2016-12-27 |
| CA2833066A1 (en) | 2012-10-18 |
| RU2013150677A (ru) | 2015-05-20 |
| AU2012241986A1 (en) | 2013-10-31 |
| PL2697296T3 (pl) | 2017-08-31 |
| ZA201308560B (en) | 2015-12-23 |
| WO2012140025A1 (de) | 2012-10-18 |
| BR112013026495B1 (pt) | 2021-01-12 |
| PT2697296T (pt) | 2017-05-30 |
| CN103619928B (zh) | 2016-01-06 |
| KR20140026488A (ko) | 2014-03-05 |
| MA35040B1 (fr) | 2014-04-03 |
| RU2601755C2 (ru) | 2016-11-10 |
| CN103619928A (zh) | 2014-03-05 |
| UA110132C2 (uk) | 2015-11-25 |
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