IE42284B1 - Process for the preparation of hydrazodicarboxylic acid amide - Google Patents

Process for the preparation of hydrazodicarboxylic acid amide

Info

Publication number: IE42284B1
Authority: IE; Ireland
Prior art keywords: water; hydrazine; reaction; acid amide; process according
Prior art date: 1974-11-02

Application number

IE2372/75A

Other languages

English (en)

Other versions

IE42284L (en

Original Assignee

Bayer Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-11-02

Filing date

1975-10-31

Publication date

1980-07-16

1974-11-02 Priority claimed from DE19742452016 external-priority patent/DE2452016C3/de

1975-10-31 Application filed by Bayer Ag filed Critical Bayer Ag

1976-05-02 Publication of IE42284L publication Critical patent/IE42284L/xx

1980-07-16 Publication of IE42284B1 publication Critical patent/IE42284B1/en

Links

238000000034 method Methods 0.000 title claims description 39
150000001408 amides Chemical class 0.000 title claims description 35
238000002360 preparation method Methods 0.000 title claims description 8
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 57
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims abstract description 46
NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims abstract description 41
IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims abstract description 41
238000006243 chemical reaction Methods 0.000 claims abstract description 38
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 32
239000004202 carbamide Substances 0.000 claims abstract description 32
239000012736 aqueous medium Substances 0.000 claims abstract description 8
239000011541 reaction mixture Substances 0.000 claims description 18
239000012431 aqueous reaction media Substances 0.000 claims description 5
238000009833 condensation Methods 0.000 claims description 2
230000005494 condensation Effects 0.000 claims description 2
ULUZGMIUTMRARO-UHFFFAOYSA-N (carbamoylamino)urea Chemical compound NC(=O)NNC(N)=O ULUZGMIUTMRARO-UHFFFAOYSA-N 0.000 abstract description 4
239000000203 mixture Substances 0.000 abstract description 4
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 3
239000000460 chlorine Substances 0.000 abstract description 3
229910052801 chlorine Inorganic materials 0.000 abstract description 3
238000000746 purification Methods 0.000 abstract description 2
239000004156 Azodicarbonamide Substances 0.000 abstract 1
XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 abstract 1
235000019399 azodicarbonamide Nutrition 0.000 abstract 1
239000003795 chemical substances by application Substances 0.000 abstract 1
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 32
229910021529 ammonia Inorganic materials 0.000 description 16
230000035484 reaction time Effects 0.000 description 16
239000012452 mother liquor Substances 0.000 description 7
239000006227 byproduct Substances 0.000 description 5
239000013505 freshwater Substances 0.000 description 5
239000007858 starting material Substances 0.000 description 5
150000002429 hydrazines Chemical class 0.000 description 4
230000003647 oxidation Effects 0.000 description 4
238000007254 oxidation reaction Methods 0.000 description 4
230000001105 regulatory effect Effects 0.000 description 4
USVVENVKYJZFMW-ONEGZZNKSA-N (e)-carboxyiminocarbamic acid Chemical compound OC(=O)\N=N\C(O)=O USVVENVKYJZFMW-ONEGZZNKSA-N 0.000 description 3
238000011109 contamination Methods 0.000 description 3
239000007789 gas Substances 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
239000002253 acid Substances 0.000 description 2
150000003863 ammonium salts Chemical class 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
238000001914 filtration Methods 0.000 description 2
238000002955 isolation Methods 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
239000000047 product Substances 0.000 description 2
239000007787 solid Substances 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical class [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
239000004604 Blowing Agent Substances 0.000 description 1
101100114416 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) con-10 gene Proteins 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000001099 ammonium carbonate Substances 0.000 description 1
235000012501 ammonium carbonate Nutrition 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
238000007664 blowing Methods 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
238000004821 distillation Methods 0.000 description 1
239000006260 foam Substances 0.000 description 1
229920001821 foam rubber Polymers 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
239000013067 intermediate product Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000011707 mineral Substances 0.000 description 1
QEHKBHWEUPXBCW-UHFFFAOYSA-N nitrogen trichloride Chemical compound ClN(Cl)Cl QEHKBHWEUPXBCW-UHFFFAOYSA-N 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
230000000630 rising effect Effects 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
239000000243 solution Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000725 suspension Substances 0.000 description 1
238000004448 titration Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C281/00—Derivatives of carbonic acid containing functional groups covered by groups C07C269/00 - C07C279/00 in which at least one nitrogen atom of these functional groups is further bound to another nitrogen atom not being part of a nitro or nitroso group
- C07C281/06—Compounds containing any of the groups, e.g. semicarbazides

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

IE2372/75A 1974-11-02 1975-10-31 Process for the preparation of hydrazodicarboxylic acid amide IE42284B1 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE19742452016 DE2452016C3 (de)		1974-11-02	Verfahren zur Herstellung von Hydrazodica rbonamid
DE19752532380 DE2532380C3 (de)		1975-07-19	Verfahren zur Herstellung von Hydrazodicarbonamid

Publications (2)

Publication Number	Publication Date
IE42284L IE42284L (en)	1976-05-02
IE42284B1 true IE42284B1 (en)	1980-07-16

Family

ID=25767918

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IE2372/75A IE42284B1 (en)	1974-11-02	1975-10-31	Process for the preparation of hydrazodicarboxylic acid amide

Country Status (11)

Country	Link
JP (1)	JPS5839152B2 (it)
BR (1)	BR7507176A (it)
CA (1)	CA1063620A (it)
ES (1)	ES442260A1 (it)
FR (1)	FR2289495A1 (it)
GB (1)	GB1465019A (it)
IE (1)	IE42284B1 (it)
IN (1)	IN141781B (it)
IT (1)	IT1048048B (it)
LU (1)	LU73694A1 (it)
NL (1)	NL7512738A (it)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN102775330A (zh) *	2012-07-24	2012-11-14	杭州海虹精细化工有限公司	一种尿素法生产水合肼过程中副产盐碱的回收处理方法

1975
- 1975-10-13 GB GB4181975A patent/GB1465019A/en not_active Expired
- 1975-10-30 NL NL7512738A patent/NL7512738A/xx not_active Application Discontinuation
- 1975-10-31 BR BR7507176*A patent/BR7507176A/pt unknown
- 1975-10-31 IE IE2372/75A patent/IE42284B1/en unknown
- 1975-10-31 JP JP50130562A patent/JPS5839152B2/ja not_active Expired
- 1975-10-31 CA CA238,760A patent/CA1063620A/en not_active Expired
- 1975-10-31 LU LU73694A patent/LU73694A1/xx unknown
- 1975-10-31 ES ES75442260A patent/ES442260A1/es not_active Expired
- 1975-10-31 FR FR7533475A patent/FR2289495A1/fr active Granted
- 1975-10-31 IT IT52021/75A patent/IT1048048B/it active
1976
- 1976-01-22 IN IN132/CAL/76A patent/IN141781B/en unknown

Also Published As

Publication number	Publication date
GB1465019A (en)	1977-02-16
IT1048048B (it)	1980-11-20
IE42284L (en)	1976-05-02
ES442260A1 (es)	1977-07-01
CA1063620A (en)	1979-10-02
FR2289495A1 (fr)	1976-05-28
IN141781B (it)	1977-04-16
LU73694A1 (it)	1976-08-13
FR2289495B1 (it)	1980-08-14
JPS5168526A (en)	1976-06-14
BR7507176A (pt)	1976-08-03
JPS5839152B2 (ja)	1983-08-27
NL7512738A (nl)	1976-05-04

Publication	Publication Date	Title
US7683217B2 (en)	2010-03-23	Process for preparing monomethylhydrazine
IE42020B1 (en)	1980-05-21	Preparation of hydroxypivaldehyde
KR100214231B1 (ko)	1999-08-02	아진 합성용 반응기 중 co2 함량을 감소시키는 방법
Lecher et al.	1948	Compounds of trialkylamine oxides with sulfur dioxide and trioxide
US4052460A (en)	1977-10-04	Production of 3,3-dimethyl-2-oxo-butyric acid salt
US3869541A (en)	1975-03-04	Method for manufacturing hydrazine
US4983764A (en)	1991-01-08	Process for preparing N-phosphonomethyl-glycine
US4855501A (en)	1989-08-08	Process for preparation of monomethylhydrazine
IE42284B1 (en)	1980-07-16	Process for the preparation of hydrazodicarboxylic acid amide
US4912268A (en)	1990-03-27	Process for manufacture of fluoroaromatics
US3993651A (en)	1976-11-23	Triethylenediamine recovery
US2575290A (en)	1951-11-13	Continuous process for manufacture of perchloromethyl mercaptan
US4172092A (en)	1979-10-23	Production of thiocarbohydrazide
US3969421A (en)	1976-07-13	Process for producing ethylphenols
JPS6155902B2 (it)	1986-11-29
US4088684A (en)	1978-05-09	Urea reactor effluent solution recycle in urea synthesis
US4176135A (en)	1979-11-27	Process for preparing hydrazodicarbonamide
US4898974A (en)	1990-02-06	Production of 3,3-dimethyl-2-oxo-butyric acid salt
US4256661A (en)	1981-03-17	Production of thiosemicarbazide
JPS6127980A (ja)	1986-02-07	オキシフラバン化合物の製造法
JPH0335242B2 (it)	1991-05-27
US2708153A (en)	1955-05-10	Manufacture of hydrazine hydrobromide
CA1110657A (en)	1981-10-13	Production of thiosemicarbazide
US4564704A (en)	1986-01-14	Production of 3,3-dimethyl-2-oxo-butyric acid salt
KR790001266B1 (ko)	1979-09-20	하이드라조디카복실산 아마이드의 제조방법