IE45018L - Co-catalyst - Google Patents
Co-catalystInfo
- Publication number
- IE45018L IE45018L IE770189A IE18977A IE45018L IE 45018 L IE45018 L IE 45018L IE 770189 A IE770189 A IE 770189A IE 18977 A IE18977 A IE 18977A IE 45018 L IE45018 L IE 45018L
- Authority
- IE
- Ireland
- Prior art keywords
- metal
- mcl4
- trichlorides
- vaporised
- takes place
- Prior art date
Links
- 239000003426 co-catalyst Substances 0.000 title 1
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- 229910052719 titanium Inorganic materials 0.000 abstract 3
- 239000010936 titanium Substances 0.000 abstract 3
- 229910052720 vanadium Inorganic materials 0.000 abstract 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 150000008282 halocarbons Chemical class 0.000 abstract 1
- 239000003701 inert diluent Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- -1 organometallic aluminium compound Chemical class 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
- 238000009834 vaporization Methods 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/002—Compounds containing titanium, with or without oxygen or hydrogen, and containing two or more other elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/02—Halides of titanium
- C01G23/026—Titanium trichloride
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G31/00—Compounds of vanadium
- C01G31/006—Compounds containing vanadium, with or without oxygen or hydrogen, and containing two or more other elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G37/00—Compounds of chromium
- C01G37/006—Compounds containing chromium, with or without oxygen or hydrogen, and containing two or more other elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/009—Compounds containing iron, with or without oxygen or hydrogen, and containing two or more other elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/04—Compounds with a limited amount of crystallinty, e.g. as indicated by a crystallinity index
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/10—Solid density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
For the preparation of the trichlorides of titanium and vanadium, a metal is vaporised in vacuo and the vapour thus obtained is reacted at low temperature with MCl4, M being Ti or V. The vaporisation of the metal takes place in a vacuum of between 10<-1> and 10<-6> mm Hg, and the reaction of the metallic vapours and MCl4 takes place at temperatures of between -80 and +20 DEG C in the presence of an inert diluent selected from saturated or unsaturated aliphatic hydrocarbons or from halogenated hydrocarbons. The metal to be vaporised is preferably selected from the group comprising Al, Mg, Cr, Mn, Fe, V and Ti. The trichlorides thus obtained and an organometallic aluminium compound are used in catalytic compositions for the polymerisation of alpha-olefins in high yield.
[GB1576431A]
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1974876A IT1054583B (en) | 1976-01-30 | 1976-01-30 | Titanium or vanadium trichloride prepn. - by reacting the tetrachloride with metal vapour, partic. magnesium, for obtaining olefin polymerisation catalyst |
| IT2525776A IT1065073B (en) | 1976-07-13 | 1976-07-13 | Titanium or vanadium trichloride prepn. - by reacting the tetrachloride with metal vapour, partic. magnesium, for obtaining olefin polymerisation catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE45018L true IE45018L (en) | 1977-07-30 |
| IE45018B1 IE45018B1 (en) | 1982-06-02 |
Family
ID=26327289
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE189/77A IE45018B1 (en) | 1976-01-30 | 1977-01-28 | Catalyst, its production and use in polymerization of olefins |
Country Status (26)
| Country | Link |
|---|---|
| JP (1) | JPS6050806B2 (en) |
| AR (1) | AR217821A1 (en) |
| AU (1) | AU512820B2 (en) |
| CA (1) | CA1118748A (en) |
| CH (1) | CH628597A5 (en) |
| DD (2) | DD130130A5 (en) |
| DE (2) | DE2703604C3 (en) |
| DK (1) | DK147620C (en) |
| EG (1) | EG13429A (en) |
| ES (1) | ES455759A1 (en) |
| FR (2) | FR2345467A1 (en) |
| GB (1) | GB1576431A (en) |
| GR (1) | GR60862B (en) |
| IE (1) | IE45018B1 (en) |
| IL (1) | IL51283A (en) |
| IN (1) | IN145866B (en) |
| LU (1) | LU76666A1 (en) |
| MX (1) | MX142961A (en) |
| MY (1) | MY8200212A (en) |
| NL (1) | NL172329C (en) |
| NO (2) | NO150208C (en) |
| PH (1) | PH15890A (en) |
| PT (1) | PT66123B (en) |
| SU (1) | SU1056905A3 (en) |
| TR (1) | TR19781A (en) |
| YU (3) | YU39988B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1080687B (en) * | 1977-06-30 | 1985-05-16 | Snam Progetti | TRIALHYGEN TITANIUM-BASED CHEMICAL COMPOSITIONS, PROCEDURE FOR THEIR PREPARATION AND USE |
| IT1081277B (en) * | 1977-06-30 | 1985-05-16 | Snam Progetti | CHEMICAL COMPOSITIONS BASED ON TRIALHYGEN TITANIUM PROCEDURE FOR THEIR PREPARATION AND USE |
| IT1113421B (en) * | 1979-03-07 | 1986-01-20 | Anic Spa | METHOD FOR THE REDUCTION OF METALLIC ALCOXIDS AND USE OF THE COMPOUNDS SO OBTAINED |
| IT1130243B (en) * | 1980-02-01 | 1986-06-11 | Anic Spa | CHEMICAL COMPOSITION BASED ON TRIALHYGEN TITANIUM, METHOD FOR ITS PREPARATION AND PROCESS OF POLYMERIZATION OR COPOLYMERISATION OF UNSATURATED COMPOUNDS USING THE SAME |
| IT1137631B (en) * | 1981-07-29 | 1986-09-10 | Anic Spa | PROCEDURE FOR HIGH YIELD POLYMERIZATION AND COPOLYMERIZATION OF HYDRAULICALLY UNSATURATED COMPOUNDS AND MEDIA SUITABLE FOR SOCPO |
| IT1210855B (en) * | 1982-02-12 | 1989-09-29 | Assoreni Ora Enichem Polimeri | LINEAR STRUCTURE ETHYLENE POLYMERS AND PROCESSES FOR THEIR PREPARATION. |
| FR3033565B1 (en) * | 2015-03-09 | 2017-03-24 | Centre Nat Rech Scient | IRON PRECATALYST AND USE THEREOF IN THE POLYMERIZATION OF OLEFINS |
| RU2707362C1 (en) * | 2019-04-05 | 2019-11-26 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Российский химико-технологический университет имени Д.И. Менделеева" (РХТУ им. Д.И. Менделеева) | Method of producing titanium trichloride |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3109822A (en) * | 1963-11-05 | catalyst composition | ||
| DE1302122C2 (en) * | 1954-12-03 | 1979-09-13 | Montecatini Edison S.pA, Mailand (Italien); Ziegler, Karl, Dr.Dr.eh, 4330 Mülheim | METHOD FOR MANUFACTURING LINEAR HEAD-TAIL POLYPROPYLENE OR -POL-ALPHA- BUTYLENE |
| NL113684C (en) * | 1956-04-02 | |||
| AT218733B (en) * | 1957-05-28 | 1961-12-27 | Titan Gmbh | Process for the production of a new, homogeneous, anhydrous aluminum-titanium-chlorine compound |
| DE1168876B (en) * | 1962-04-28 | 1964-04-30 | Basf Ag | Process for the preparation of a complex compound of titanium trichloride and aluminum chloride |
| DE1268598B (en) * | 1964-03-04 | 1968-05-22 | Rexall Drug Chemical | Process for the preparation of a catalyst for the polymerization of alpha-olefins |
| DE1229050B (en) * | 1965-01-13 | 1966-11-24 | Basf Ag | Process for the preparation of a catalyst component which is particularly active in the polymerization of propylene using Ziegler catalysts |
| GB1299862A (en) * | 1969-01-23 | 1972-12-13 | Shell Int Research | Improvements in or relating to the catalytic polymerisation of olefins |
| GB1359547A (en) * | 1970-12-04 | 1974-07-10 | Naphtachimie Sa | Based catalysts |
| BE785673A (en) * | 1971-06-30 | 1973-01-02 | Naphtachimie Sa | POLYMERIZATION CATALYZERS OF OLEFINS PREPARED FROM DECOMPOSED ORGANOMAGNESIANS |
| DE2158956A1 (en) * | 1971-11-27 | 1973-05-30 | Basf Ag | Prepn of violet titanium trichloride - by plasma chemical conversion of titanium tetrachloride |
| BE794323A (en) * | 1972-01-20 | 1973-07-19 | Naphtachimie Sa | PROCESS FOR THE MANUFACTURE OF ATACTIC POLYOLEFIN WAXES |
| IT998599B (en) * | 1972-09-18 | 1976-02-20 | Naphtachimie Sa | PROCEDURE OF POLYMERIZATION OF OLEFINS USING PRE ACTIVATED CATALYSTS |
| GB1467051A (en) * | 1974-01-03 | 1977-03-16 | Shell Int Research | Process for the production of polyolefins and catalyst therefor |
| JPS5724361B2 (en) | 1974-03-27 | 1982-05-24 | ||
| IL46858A (en) | 1974-04-17 | 1979-01-31 | Snam Progetti | Process for the polymerization of alpha-olefins,catalyst employed in said process and method for the preparation thereof |
-
1977
- 1977-01-18 IL IL51283A patent/IL51283A/en unknown
- 1977-01-18 GR GR52596A patent/GR60862B/en unknown
- 1977-01-20 CA CA000270122A patent/CA1118748A/en not_active Expired
- 1977-01-20 AU AU21472/77A patent/AU512820B2/en not_active Expired
- 1977-01-23 YU YU230/77A patent/YU39988B/en unknown
- 1977-01-25 DK DK30877A patent/DK147620C/en not_active IP Right Cessation
- 1977-01-25 TR TR19781A patent/TR19781A/en unknown
- 1977-01-26 EG EG51/77A patent/EG13429A/en active
- 1977-01-27 GB GB3437/77A patent/GB1576431A/en not_active Expired
- 1977-01-27 FR FR7702334A patent/FR2345467A1/en active Granted
- 1977-01-27 AR AR266342A patent/AR217821A1/en active
- 1977-01-27 NO NO770274A patent/NO150208C/en unknown
- 1977-01-28 PH PH19393A patent/PH15890A/en unknown
- 1977-01-28 ES ES455759A patent/ES455759A1/en not_active Expired
- 1977-01-28 MX MX167866A patent/MX142961A/en unknown
- 1977-01-28 PT PT66123A patent/PT66123B/en unknown
- 1977-01-28 DE DE2703604A patent/DE2703604C3/en not_active Expired
- 1977-01-28 DD DD7700197143A patent/DD130130A5/en unknown
- 1977-01-28 SU SU772446350A patent/SU1056905A3/en active
- 1977-01-28 IE IE189/77A patent/IE45018B1/en not_active IP Right Cessation
- 1977-01-28 LU LU76666A patent/LU76666A1/xx unknown
- 1977-01-28 DD DD77205331A patent/DD138218A5/en unknown
- 1977-01-28 JP JP52007909A patent/JPS6050806B2/en not_active Expired
- 1977-01-28 DE DE2759512A patent/DE2759512C2/en not_active Expired
- 1977-01-28 CH CH108477A patent/CH628597A5/en not_active IP Right Cessation
- 1977-01-29 IN IN133/CAL/77A patent/IN145866B/en unknown
- 1977-01-31 NL NLAANVRAGE7701005,A patent/NL172329C/en not_active IP Right Cessation
- 1977-06-14 FR FR7718179A patent/FR2345212A1/en active Granted
-
1981
- 1981-01-27 NO NO810263A patent/NO152562C/en unknown
-
1982
- 1982-07-29 YU YU1657/82A patent/YU44358B/en unknown
- 1982-07-29 YU YU1658/82A patent/YU44359B/en unknown
- 1982-12-30 MY MY212/82A patent/MY8200212A/en unknown
Also Published As
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MK9A | Patent expired |