IE57629B1 - Stabilized oil-in-water cleaning microemulsions - Google Patents

Stabilized oil-in-water cleaning microemulsions

Info

Publication number: IE57629B1
Authority: IE; Ireland
Prior art keywords: amine; composition according; alkyl; solvent; compositions
Prior art date: 1984-04-07

Application number

IE2067/84A

Other languages

English (en)

Other versions

IE842067L (en

Original Assignee

Procter & Gamble

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-04-07

Filing date

1984-08-10

Publication date

1993-02-10

1984-08-10 Application filed by Procter & Gamble filed Critical Procter & Gamble

1985-10-07 Publication of IE842067L publication Critical patent/IE842067L/en

1993-02-10 Publication of IE57629B1 publication Critical patent/IE57629B1/en

Links

XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 35
239000004530 micro-emulsion Substances 0.000 title claims description 23
238000004140 cleaning Methods 0.000 title description 17
239000000203 mixture Substances 0.000 claims abstract description 113
239000002904 solvent Substances 0.000 claims abstract description 48
235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 29
239000000194 fatty acid Substances 0.000 claims abstract description 29
229930195729 fatty acid Natural products 0.000 claims abstract description 29
239000003599 detergent Substances 0.000 claims abstract description 28
150000004665 fatty acids Chemical class 0.000 claims abstract description 28
239000007788 liquid Substances 0.000 claims abstract description 26
239000000344 soap Substances 0.000 claims abstract description 22
150000001412 amines Chemical class 0.000 claims abstract description 21
235000007586 terpenes Nutrition 0.000 claims abstract description 20
150000003505 terpenes Chemical class 0.000 claims abstract description 17
CDKDZKXSXLNROY-UHFFFAOYSA-N octylbenzene Chemical compound CCCCCCCCC1=CC=CC=C1 CDKDZKXSXLNROY-UHFFFAOYSA-N 0.000 claims abstract description 12
150000001336 alkenes Chemical class 0.000 claims abstract description 7
150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 6
239000004615 ingredient Substances 0.000 claims description 22
-1 alkyl dimethyl amine Chemical compound 0.000 claims description 20
239000004094 surface-active agent Substances 0.000 claims description 20
239000004744 fabric Substances 0.000 claims description 19
FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 claims description 14
125000000217 alkyl group Chemical group 0.000 claims description 13
150000004996 alkyl benzenes Chemical group 0.000 claims description 12
PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims description 10
102000004190 Enzymes Human genes 0.000 claims description 9
108090000790 Enzymes Proteins 0.000 claims description 9
ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 9
229930195733 hydrocarbon Natural products 0.000 claims description 8
238000004900 laundering Methods 0.000 claims description 8
OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 7
JMHWNJGXUIJPKG-UHFFFAOYSA-N CC(=O)O[SiH](CC=C)OC(C)=O Chemical compound CC(=O)O[SiH](CC=C)OC(C)=O JMHWNJGXUIJPKG-UHFFFAOYSA-N 0.000 claims description 7
244000060011 Cocos nucifera Species 0.000 claims description 6
235000013162 Cocos nucifera Nutrition 0.000 claims description 6
239000004519 grease Substances 0.000 claims description 6
238000000034 method Methods 0.000 claims description 5
239000012188 paraffin wax Substances 0.000 claims description 5
239000011877 solvent mixture Substances 0.000 claims description 5
BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims description 4
238000009835 boiling Methods 0.000 claims description 4
125000004432 carbon atom Chemical group C* 0.000 claims description 4
125000000753 cycloalkyl group Chemical group 0.000 claims description 4
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 4
150000001298 alcohols Chemical class 0.000 claims description 3
150000008051 alkyl sulfates Chemical class 0.000 claims description 3
JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 claims description 3
XTAZYLNFDRKIHJ-UHFFFAOYSA-N n,n-dioctyloctan-1-amine Chemical compound CCCCCCCCN(CCCCCCCC)CCCCCCCC XTAZYLNFDRKIHJ-UHFFFAOYSA-N 0.000 claims description 3
WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 claims description 3
150000003871 sulfonates Chemical class 0.000 claims description 3
MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 claims description 2
ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
229940043237 diethanolamine Drugs 0.000 claims description 2
VMCSSRWYFKRLGP-UHFFFAOYSA-M dihexyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCC[N+](C)(C)CCCCCC VMCSSRWYFKRLGP-UHFFFAOYSA-M 0.000 claims description 2
ONLRKTIYOMZEJM-UHFFFAOYSA-N n-methylmethanamine oxide Chemical compound C[NH+](C)[O-] ONLRKTIYOMZEJM-UHFFFAOYSA-N 0.000 claims description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
YJLYANLCNIKXMG-UHFFFAOYSA-N N-Methyldioctylamine Chemical compound CCCCCCCCN(C)CCCCCCCC YJLYANLCNIKXMG-UHFFFAOYSA-N 0.000 claims 1
229960002380 dibutyl phthalate Drugs 0.000 claims 1
238000005238 degreasing Methods 0.000 abstract description 2
229920000768 polyamine Polymers 0.000 description 19
AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 18
WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 18
238000009472 formulation Methods 0.000 description 13
239000000047 product Substances 0.000 description 12
239000000463 material Substances 0.000 description 11
239000002689 soil Substances 0.000 description 8
XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 6
CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 6
125000003545 alkoxy group Chemical group 0.000 description 6
235000019445 benzyl alcohol Nutrition 0.000 description 6
239000000839 emulsion Substances 0.000 description 6
235000019645 odor Nutrition 0.000 description 6
239000004215 Carbon black (E152) Substances 0.000 description 5
150000001875 compounds Chemical class 0.000 description 5
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 5
239000002798 polar solvent Substances 0.000 description 5
239000003381 stabilizer Substances 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
239000002253 acid Substances 0.000 description 4
125000000129 anionic group Chemical group 0.000 description 4
239000003795 chemical substances by application Substances 0.000 description 4
238000005520 cutting process Methods 0.000 description 4
ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
150000002430 hydrocarbons Chemical class 0.000 description 4
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
239000010705 motor oil Substances 0.000 description 4
239000003921 oil Substances 0.000 description 4
150000003839 salts Chemical class 0.000 description 4
239000004382 Amylase Substances 0.000 description 3
108010065511 Amylases Proteins 0.000 description 3
102000013142 Amylases Human genes 0.000 description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
108091005804 Peptidases Proteins 0.000 description 3
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
235000019418 amylase Nutrition 0.000 description 3
239000003945 anionic surfactant Substances 0.000 description 3
150000001450 anions Chemical class 0.000 description 3
125000003118 aryl group Chemical group 0.000 description 3
239000002537 cosmetic Substances 0.000 description 3
229940069096 dodecene Drugs 0.000 description 3
239000002736 nonionic surfactant Substances 0.000 description 3
235000019198 oils Nutrition 0.000 description 3
230000003287 optical effect Effects 0.000 description 3
238000002203 pretreatment Methods 0.000 description 3
239000003352 sequestering agent Substances 0.000 description 3
WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 2
NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
229910019142 PO4 Inorganic materials 0.000 description 2
239000004365 Protease Substances 0.000 description 2
102000005158 Subtilisins Human genes 0.000 description 2
108010056079 Subtilisins Proteins 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
235000020971 citrus fruits Nutrition 0.000 description 2
239000004927 clay Substances 0.000 description 2
LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
239000000975 dye Substances 0.000 description 2
230000000694 effects Effects 0.000 description 2
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
235000019253 formic acid Nutrition 0.000 description 2
239000003350 kerosene Substances 0.000 description 2
XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
229910021645 metal ion Inorganic materials 0.000 description 2
HCGUSKQMLFEMKM-UHFFFAOYSA-N n-methyl-n-octyloctan-1-amine oxide Chemical compound CCCCCCCC[N+](C)([O-])CCCCCCCC HCGUSKQMLFEMKM-UHFFFAOYSA-N 0.000 description 2
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
235000021313 oleic acid Nutrition 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
239000002304 perfume Substances 0.000 description 2
239000012071 phase Substances 0.000 description 2
235000021317 phosphate Nutrition 0.000 description 2
150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
239000010665 pine oil Substances 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
239000011734 sodium Substances 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
238000011105 stabilization Methods 0.000 description 2
239000000375 suspending agent Substances 0.000 description 2
108010075550 termamyl Proteins 0.000 description 2
239000004711 α-olefin Substances 0.000 description 2
GRWFGVWFFZKLTI-UHFFFAOYSA-N α-pinene Chemical compound CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 2
WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 description 1
WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 description 1
ADOQBZAVKYCFOI-HWKANZROSA-N (E)-2-dodecene Chemical compound CCCCCCCCC\C=C\C ADOQBZAVKYCFOI-HWKANZROSA-N 0.000 description 1
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
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NJBCRXCAPCODGX-UHFFFAOYSA-N 2-methyl-n-(2-methylpropyl)propan-1-amine Chemical compound CC(C)CNCC(C)C NJBCRXCAPCODGX-UHFFFAOYSA-N 0.000 description 1
LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 1
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
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108091005658 Basic proteases Proteins 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
241000207199 Citrus Species 0.000 description 1
235000005979 Citrus limon Nutrition 0.000 description 1
244000131522 Citrus pyriformis Species 0.000 description 1
240000000560 Citrus x paradisi Species 0.000 description 1
229920000742 Cotton Polymers 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
235000021360 Myristic acid Nutrition 0.000 description 1
OPKOKAMJFNKNAS-UHFFFAOYSA-N N-methylethanolamine Chemical compound CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 description 1
239000005642 Oleic acid Substances 0.000 description 1
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
235000019482 Palm oil Nutrition 0.000 description 1
235000021314 Palmitic acid Nutrition 0.000 description 1
229920002873 Polyethylenimine Polymers 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
230000001154 acute effect Effects 0.000 description 1
150000003973 alkyl amines Chemical class 0.000 description 1
150000005215 alkyl ethers Chemical group 0.000 description 1
XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 1
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239000003899 bactericide agent Substances 0.000 description 1
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125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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238000004851 dishwashing Methods 0.000 description 1
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125000001183 hydrocarbyl group Chemical group 0.000 description 1
239000003752 hydrotrope Substances 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
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239000011777 magnesium Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011654 magnesium acetate Substances 0.000 description 1
235000011285 magnesium acetate Nutrition 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
235000011147 magnesium chloride Nutrition 0.000 description 1
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
239000000347 magnesium hydroxide Substances 0.000 description 1
229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
229910001425 magnesium ion Inorganic materials 0.000 description 1
159000000003 magnesium salts Chemical group 0.000 description 1
CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
235000019341 magnesium sulphate Nutrition 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
239000003550 marker Substances 0.000 description 1
238000005555 metalworking Methods 0.000 description 1
JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229930003647 monocyclic monoterpene Natural products 0.000 description 1
150000002767 monocyclic monoterpene derivatives Chemical class 0.000 description 1
LTEQMZWBSYACLV-UHFFFAOYSA-N n-hexyl benzene Natural products CCCCCCC1=CC=CC=C1 LTEQMZWBSYACLV-UHFFFAOYSA-N 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
229910017464 nitrogen compound Inorganic materials 0.000 description 1
150000002830 nitrogen compounds Chemical class 0.000 description 1
239000012454 non-polar solvent Substances 0.000 description 1
LIXVMPBOGDCSRM-UHFFFAOYSA-N nonylbenzene Chemical group CCCCCCCCCC1=CC=CC=C1 LIXVMPBOGDCSRM-UHFFFAOYSA-N 0.000 description 1
150000002889 oleic acids Chemical class 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
239000003002 pH adjusting agent Substances 0.000 description 1
239000002540 palm oil Substances 0.000 description 1
IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
238000005191 phase separation Methods 0.000 description 1
150000003021 phthalic acid derivatives Chemical class 0.000 description 1
229920005646 polycarboxylate Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229920001282 polysaccharide Polymers 0.000 description 1
239000005017 polysaccharide Substances 0.000 description 1
235000020777 polyunsaturated fatty acids Nutrition 0.000 description 1
229960003975 potassium Drugs 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
PJAHUDTUZRZBKM-UHFFFAOYSA-K potassium citrate monohydrate Chemical compound O.[K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O PJAHUDTUZRZBKM-UHFFFAOYSA-K 0.000 description 1
229940050931 potassium citrate monohydrate Drugs 0.000 description 1
YLLIGHVCTUPGEH-UHFFFAOYSA-M potassium;ethanol;hydroxide Chemical compound [OH-].[K+].CCO YLLIGHVCTUPGEH-UHFFFAOYSA-M 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000003755 preservative agent Substances 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
238000005956 quaternization reaction Methods 0.000 description 1
239000002994 raw material Substances 0.000 description 1
230000029219 regulation of pH Effects 0.000 description 1
238000009991 scouring Methods 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
235000019832 sodium triphosphate Nutrition 0.000 description 1
239000011343 solid material Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
229930006978 terpinene Natural products 0.000 description 1
150000003507 terpinene derivatives Chemical class 0.000 description 1
229940116411 terpineol Drugs 0.000 description 1
FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
239000004753 textile Substances 0.000 description 1
230000001988 toxicity Effects 0.000 description 1
231100000419 toxicity Toxicity 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical class OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
239000003981 vehicle Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000003799 water insoluble solvent Substances 0.000 description 1
239000002888 zwitterionic surfactant Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0017—Multi-phase liquid compositions
- C11D17/0021—Aqueous microemulsions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Life Sciences & Earth Sciences (AREA)
Detergent Compositions (AREA)
Colloid Chemistry (AREA)
Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Cosmetics (AREA)
Medicinal Preparation (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

IE2067/84A 1984-04-07 1984-08-10 Stabilized oil-in-water cleaning microemulsions IE57629B1 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GB848409054A GB8409054D0 (en)	1984-04-07	1984-04-07	Stabilized oil-in-water cleaning microemulsions

Publications (2)

Publication Number	Publication Date
IE842067L IE842067L (en)	1985-10-07
IE57629B1 true IE57629B1 (en)	1993-02-10

Family

ID=10559352

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IE2067/84A IE57629B1 (en)	1984-04-07	1984-08-10	Stabilized oil-in-water cleaning microemulsions

Country Status (11)

Country	Link
EP (1)	EP0160762B1 (de)
JP (1)	JPH0633425B2 (de)
AT (1)	ATE41172T1 (de)
CA (1)	CA1230534A (de)
DE (1)	DE3477019D1 (de)
EG (1)	EG16585A (de)
ES (1)	ES8605572A1 (de)
FI (1)	FI73732C (de)
GB (1)	GB8409054D0 (de)
GR (1)	GR80087B (de)
IE (1)	IE57629B1 (de)

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US5075026A (en) *	1986-05-21	1991-12-24	Colgate-Palmolive Company	Microemulsion all purpose liquid cleaning composition
US4921627A (en) *	1986-11-14	1990-05-01	Ecolab Inc.	Detersive system and low foaming aqueous surfactant solutions containing a mono(C1-4 alkyl)-di(C6-20) alkylamine oxide compound
US4938893A (en) *	1986-11-14	1990-07-03	Ecolab Inc.	Detersive systems and low foaming aqueous surfactant solutions containing a mono (C1-4 alkyl)-di(C6-20 alkyl)-amine oxide compound
IT1240734B (it) *	1990-04-02	1993-12-17	Syremont Spa	Procedimento per la pulitura di matrici porose idrofile
US5405548A (en) *	1991-01-30	1995-04-11	Elf Atochem North America Inc.	Methylbenzyl formate paint strippers
WO1992020773A1 (en) *	1991-05-10	1992-11-26	Ethyl Corporation	Cleaning composition
US5726140A (en) *	1992-06-02	1998-03-10	Elf Atochem North America, Inc.	Water-in-oil emulsion having aqueous phase evaporation retarded with wax
US5780409A (en) *	1992-06-02	1998-07-14	Elf Atochem North America, Inc.	Water-in-oil emulsion having aqueous phase evaporation retarded with wax IR 3323D
FR2697265B1 (fr) *	1992-10-28	1994-12-09	Atochem Elf Sa	Utilisation d'un ester étheroxyde d'alcoylèneglycol pour le dégraissage de la surface d'un objet et procédé et composition à cet usage.
US5749977A (en) *	1992-10-28	1998-05-12	Elf Atochem S.A.	Process and composition for degreasing the surface of an object
DE69430628T2 (de) *	1993-04-02	2002-10-10	The Dow Chemical Co., Midland	Mikroemulsion- und emulsion-reinigungszusammensetzungen
US5883066A (en) *	1993-06-28	1999-03-16	The Procter & Gamble Company	Liquid detergent compositions containing cellulase and amine
US5763386A (en) *	1993-08-04	1998-06-09	Colgate Palmolive Company	Microemulsion all purpose liquid cleaning compositions comprising ethoxylated polyhydric alcohols with at least partial esters thereof, and optional dralkyl sulfosuccinate
BR9508318A (pt) *	1994-07-21	1997-12-23	Minnesota Mining & Mfg	Composição impadora concentrada
US5741769A (en) *	1994-11-23	1998-04-21	Colgate Palmolive Company	Microemulsion light duty liquid cleaning compositions
EP0773284A1 (de)	1995-11-10	1997-05-14	The Procter & Gamble Company	Mikroemulsion mit hohem Gehalt an anionischen Tensiden unter Verwendung verzweigter Fettsäuren
DE19615271A1 (de) *	1996-04-18	1997-10-23	Huels Chemische Werke Ag	Tensidhaltige Reinigungsmittel in Form einer Mikroemulsion
US5759290A (en) *	1996-06-13	1998-06-02	Colgate Palmolive Company	Liquid crystal compositions
US5834417A (en) *	1996-06-13	1998-11-10	Colgate Palmolive Co.	Light duty liquid cleaning compositions
HUP9903434A3 (en) *	1996-06-14	2001-02-28	Colgate Palmolive Co New York	Liquid crystal compositions
US5700331A (en) *	1996-06-14	1997-12-23	Colgate-Palmolive Co.	Thickened cleaning composition
US5703028A (en) *	1996-06-14	1997-12-30	Colgate-Palmolive Co	Liquid crystal detergent compositions based on anionic sulfonate-ether sulfate mixtures
US5719114A (en) *	1996-06-28	1998-02-17	Colgate Palmolive Company	Cleaning composition in various liquid forms comprising acaricidal agents
US5756441A (en) *	1996-08-07	1998-05-26	Colgate Palmolive Company	High foaming nonionic surfactant based liquid detergent
US5714454A (en) *	1996-08-07	1998-02-03	Colgate-Palmolive Co.	Light duty liquid cleaning compositions comprising alkyl sulroglycerides
US6010998A (en) *	1997-05-12	2000-01-04	Exxon Chemical Patents, Inc.	Cleaning composition containing pine oil extenders
US5851976A (en) *	1997-12-08	1998-12-22	Colgate Palmolive Company	Microemulsion all purpose liquid cleaning compositions
CO5040174A1 (es) *	1997-12-12	2001-05-29	Colgate Palmolive Co	Composiciones antimicrobianas para multiples propositos en microemulsion que contienen un tensioactivo cationico
US5843880A (en) *	1998-01-09	1998-12-01	Colgate Palmolive Company	Purpose liquid cleaning/micro emulsion compositions comprising triethanol amine and mixture of partially esterified fully esterified and non-esterified polyhydric alcohols
US6194371B1 (en)	1998-05-01	2001-02-27	Ecolab Inc.	Stable alkaline emulsion cleaners
US6159925A (en) *	2000-04-06	2000-12-12	Colgate-Palmolive Co.	Acidic liquid crystal compositions
GB0216173D0 (en) *	2002-07-12	2002-08-21	Fabric Care Res Ass Ltd	A laundry preparation
CN101014691A (zh) *	2004-09-08	2007-08-08	宝洁公司	具有改善的气味的衣物处理组合物
AR072859A1 (es)	2008-05-23	2010-09-29	Colgate Palmolive Co	Metodos y composiciones liquidas de limpieza
BR112014011725A2 (pt)	2011-11-25	2017-05-30	Unilever Nv	composição de detergente líquido
BR112015001328A2 (pt)	2012-07-26	2018-05-22	Unilever Nv	composição de detergente líquido de fase lamelar e método para lavar artigos de tecido
EP2727991A1 (de) *	2012-10-30	2014-05-07	The Procter & Gamble Company	Flüssige Handgeschirrspül-, Reinigungs- und Desinfektionsmittel
DE102014202990A1 (de)	2014-02-19	2015-08-20	Henkel Ag & Co. Kgaa	Konzentrate
DE102014213314A1 (de)	2014-07-09	2016-01-14	Henkel Ag & Co. Kgaa	Neuartiges Waschverfahren
DE102016204268A1 (de)	2016-03-15	2017-09-21	Henkel Ag & Co. Kgaa	Waschmittelzusammensetzung
DE102016204390A1 (de)	2016-03-16	2017-09-21	Henkel Ag & Co. Kgaa	Verfahren zum Reinigen von Wäsche in einer Waschmaschine sowie eine Waschmaschine
FI3540052T3 (fi)	2018-03-14	2026-02-05	Indian Oil Corp Ltd	Stabiili lignosellulolyyttinen entsyymikoostumus
DE102020007520A1 (de)	2020-12-09	2022-06-09	Ovidiu Dicoi	Modifizierte strukturierte, fließfähige Wasch- und Reinigungsmittel

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US4276186A (en) *	1979-06-26	1981-06-30	International Business Machines Corporation	Cleaning composition and use thereof
EP0040882B1 (de) *	1980-05-27	1985-01-30	THE PROCTER & GAMBLE COMPANY	Flüssige Reinigungsmittelzusammensetzungen
CA1178160A (en) *	1981-09-10	1984-11-20	Donald B. Compton	Liquid hard-surface cleaner

1984
- 1984-04-07 GB GB848409054A patent/GB8409054D0/en active Pending
- 1984-08-06 EP EP84305319A patent/EP0160762B1/de not_active Expired
- 1984-08-06 DE DE8484305319T patent/DE3477019D1/de not_active Expired
- 1984-08-06 AT AT84305319T patent/ATE41172T1/de not_active IP Right Cessation
- 1984-08-09 CA CA000460634A patent/CA1230534A/en not_active Expired
- 1984-08-10 ES ES535069A patent/ES8605572A1/es not_active Expired
- 1984-08-10 GR GR80087A patent/GR80087B/el unknown
- 1984-08-10 IE IE2067/84A patent/IE57629B1/en not_active IP Right Cessation
- 1984-08-10 FI FI843160A patent/FI73732C/fi not_active IP Right Cessation
- 1984-08-11 EG EG50984A patent/EG16585A/xx active
- 1984-08-11 JP JP59168722A patent/JPH0633425B2/ja not_active Expired - Lifetime

Also Published As

Publication number	Publication date
GR80087B (en)	1984-10-30
EG16585A (en)	1994-10-30
ATE41172T1 (de)	1989-03-15
JPH0633425B2 (ja)	1994-05-02
FI73732C (fi)	1987-11-09
EP0160762B1 (de)	1989-03-08
ES8605572A1 (es)	1986-03-16
FI73732B (fi)	1987-07-31
FI843160L (fi)	1985-10-08
IE842067L (en)	1985-10-07
JPS60212499A (ja)	1985-10-24
DE3477019D1 (en)	1989-04-13
GB8409054D0 (en)	1984-05-16
CA1230534A (en)	1987-12-22
EP0160762A1 (de)	1985-11-13
ES535069A0 (es)	1986-03-16
FI843160A0 (fi)	1984-08-10

Legal Events

Date	Code	Title	Description
1998-06-17	MM4A	Patent lapsed

Publication	Publication Date	Title
EP0160762B1 (de)	1989-03-08	Stabilisierte Öl-in-Wasser-Reinigungsmittel-Mikroemulsion
EP0137616B1 (de)	1988-01-27	Flüssige Detergentien mit einem Lösungsmittel
US4561991A (en)	1985-12-31	Fabric cleaning compositions for clay-based stains
EP0137615B1 (de)	1988-01-27	Gewebereinigungsmittel-Zusammensetzungen für Schmutzflecke
EP0164467B1 (de)	1988-06-29	Reinigungsmittelzusammensetzungen mit einem Lösungsmittel
US5393468A (en)	1995-02-28	Hard surface cleaner
US5082584A (en)	1992-01-21	Microemulsion all purpose liquid cleaning composition
GB2144763A (en)	1985-03-13	Liquid detergent compositions with magnesium salts
US5462690A (en)	1995-10-31	Liquid cleaning compositions
CA2002267A1 (en)	1990-05-07	Stable microemulsion cleaning composition
EP0080749A1 (de)	1983-06-08	Flüssige Detergenszusammensetzungen
EP0216416A2 (de)	1987-04-01	Flüssige, viskose, phasenstabile, ein Lösungsmittel enthaltendes Reinigungsmittel
AU690553B2 (en)	1998-04-30	Stable microemulsion cleaning composition
EP0748865B1 (de)	1999-05-12	Stabile flüssige Reinigungsmittel, die Pinienöl enthalten
JPH10512619A (ja)	1998-12-02	分枝脂肪酸を使用した多量の陰イオン界面活性剤を有するミクロエマルション
IE862189L (en)	1987-02-15	Built liquid detergents
US6180582B1 (en)	2001-01-30	Liquid cleaning compositions