IL129079A - A method for making salts of carboxylic acids - Google Patents

A method for making salts of carboxylic acids

Info

Publication number: IL129079A
Authority: IL; Israel
Prior art keywords: primary alcohol; catalyst; catalytic dehydrogenation; aqueous solution; hydroxide
Prior art date: 1998-03-23

Application number

IL12907999A

Other languages

English (en)

Hebrew (he)

Other versions

IL129079A0 (en

Inventor

Alberto Villanti

Gianna Conti

Original Assignee

Finchimica Srl

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-03-23

Filing date

1999-03-21

Publication date

2004-05-12

1999-03-21 Application filed by Finchimica Srl filed Critical Finchimica Srl

2000-02-17 Publication of IL129079A0 publication Critical patent/IL129079A0/xx

2004-05-12 Publication of IL129079A publication Critical patent/IL129079A/en

Links

238000000034 method Methods 0.000 title claims abstract description 29
150000003839 salts Chemical class 0.000 title claims abstract description 19
150000001735 carboxylic acids Chemical class 0.000 title description 6
238000002360 preparation method Methods 0.000 title description 4
239000003054 catalyst Substances 0.000 claims abstract description 29
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 21
150000003138 primary alcohols Chemical class 0.000 claims abstract description 13
239000007864 aqueous solution Substances 0.000 claims abstract description 9
230000003197 catalytic effect Effects 0.000 claims abstract description 9
238000006356 dehydrogenation reaction Methods 0.000 claims abstract description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims abstract description 8
238000004519 manufacturing process Methods 0.000 claims abstract description 7
230000005587 bubbling Effects 0.000 claims abstract description 6
239000003153 chemical reaction reagent Substances 0.000 claims abstract description 6
239000010949 copper Substances 0.000 claims abstract description 6
229910052802 copper Inorganic materials 0.000 claims abstract description 6
238000006392 deoxygenation reaction Methods 0.000 claims abstract description 6
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims abstract description 5
150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract description 5
229910001882 dioxygen Inorganic materials 0.000 claims abstract description 5
239000011261 inert gas Substances 0.000 claims abstract description 5
239000003638 chemical reducing agent Substances 0.000 claims abstract description 4
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
239000001307 helium Substances 0.000 claims description 5
229910052734 helium Inorganic materials 0.000 claims description 5
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 5
239000001257 hydrogen Substances 0.000 claims description 5
229910052739 hydrogen Inorganic materials 0.000 claims description 5
HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical group [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 claims description 5
229910052757 nitrogen Inorganic materials 0.000 claims description 4
-1 phosphomethyl Chemical group 0.000 claims description 3
125000000217 alkyl group Chemical group 0.000 claims description 2
125000004432 carbon atom Chemical group C* 0.000 claims description 2
150000001875 compounds Chemical class 0.000 claims description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
239000004280 Sodium formate Substances 0.000 claims 1
235000019254 sodium formate Nutrition 0.000 claims 1
238000006243 chemical reaction Methods 0.000 description 24
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
239000001301 oxygen Substances 0.000 description 7
229910052760 oxygen Inorganic materials 0.000 description 7
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
230000000694 effects Effects 0.000 description 6
239000000126 substance Substances 0.000 description 6
KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 5
ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 5
239000000243 solution Substances 0.000 description 5
150000001414 amino alcohols Chemical class 0.000 description 4
238000012360 testing method Methods 0.000 description 4
239000002253 acid Substances 0.000 description 3
230000007423 decrease Effects 0.000 description 3
NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical class OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 3
229910000000 metal hydroxide Inorganic materials 0.000 description 3
150000004692 metal hydroxides Chemical class 0.000 description 3
229910052759 nickel Inorganic materials 0.000 description 3
230000035484 reaction time Effects 0.000 description 3
QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical class NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
238000013019 agitation Methods 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
238000007872 degassing Methods 0.000 description 2
230000008030 elimination Effects 0.000 description 2
238000003379 elimination reaction Methods 0.000 description 2
238000001914 filtration Methods 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
238000004064 recycling Methods 0.000 description 2
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
239000004471 Glycine Substances 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
238000007259 addition reaction Methods 0.000 description 1
239000003905 agrochemical Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
239000004411 aluminium Substances 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
239000013011 aqueous formulation Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
235000019253 formic acid Nutrition 0.000 description 1
239000007789 gas Substances 0.000 description 1
150000002332 glycine derivatives Chemical class 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
238000009776 industrial production Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
238000004172 nitrogen cycle Methods 0.000 description 1
229910000510 noble metal Inorganic materials 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
238000005839 oxidative dehydrogenation reaction Methods 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000000575 pesticide Substances 0.000 description 1
239000000825 pharmaceutical preparation Substances 0.000 description 1
229940127557 pharmaceutical product Drugs 0.000 description 1
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
238000005303 weighing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/295—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with inorganic bases, e.g. by alkali fusion
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C227/02—Formation of carboxyl groups in compounds containing amino groups, e.g. by oxidation of amino alcohols

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Preparation Of Compounds By Using Micro-Organisms (AREA)

IL12907999A 1998-03-23 1999-03-21 A method for making salts of carboxylic acids IL129079A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT98TO000249A ITTO980249A1 (it)	1998-03-23	1998-03-23	Procedimento per la preparazione di sali di acidi carbossilici

Publications (2)

Publication Number	Publication Date
IL129079A0 IL129079A0 (en)	2000-02-17
IL129079A true IL129079A (en)	2004-05-12

Family

ID=11416624

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL12907999A IL129079A (en)	1998-03-23	1999-03-21	A method for making salts of carboxylic acids

Country Status (11)

Country	Link
US (1)	US6239312B1 (de)
EP (1)	EP0945428B1 (de)
AT (1)	ATE248803T1 (de)
AU (1)	AU740306B2 (de)
BR (1)	BR9901155A (de)
DE (1)	DE69910871D1 (de)
ES (1)	ES2207049T3 (de)
IL (1)	IL129079A (de)
IN (1)	IN188987B (de)
IT (1)	ITTO980249A1 (de)
PT (1)	PT945428E (de)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
KR20020009601A (ko) *	1999-05-03	2002-02-01	추후보정	일차 알코올로부터 카르복실산 염들의 제조방법
US6376708B1 (en) *	2000-04-11	2002-04-23	Monsanto Technology Llc	Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
US6927304B2 (en)	2000-05-22	2005-08-09	Monsanto Technology Llc	De-oxygenation treatment for noble metal on carbon catalysts used in liquid phase oxidation reactions
AU2003257062A1 (en)	2002-08-02	2004-02-23	Massachusetts Institute Of Technology	Copper-catalyzed formation of carbon-heteroatom and carbon-carbon bonds
US9062278B2 (en) *	2010-02-19	2015-06-23	Basf Se	Preparing ether carboxylates
AU2011217344B2 (en) *	2010-02-19	2016-03-24	Basf Se	Method for the production of ether carboxylates
AU2011217307B2 (en) *	2010-02-19	2016-07-28	Basf Se	Method for the production of ether carboxylates
US8309759B2 (en) *	2010-02-19	2012-11-13	Basf Se	Preparing ether carboxylates

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB2148287B (en)	1983-10-05	1987-04-15	Nippon Catalytic Chem Ind	Preparation of aminocarboxylic acid salts from amino alcohols
ES2022044A6 (es)	1990-09-25	1991-11-16	Ercros Sa	Procedimiento para la obtencion de derivados del acido acetico.
ES2031412A6 (es)	1990-10-04	1992-12-01	Ercros Sa	Perfeccionamientos introducidos en un procedimiento de obtencion de derivados de acido acetico.
WO1992006949A1 (en)	1990-10-23	1992-04-30	Nippon Shokubai Co., Ltd.	Process for producing salt of amino carboxylic acid
KR970009569B1 (ko) *	1990-11-27	1997-06-14	닛뽕 쇼꾸 바이가가꾸 고오교 가부시끼가이샤	아미노카르복실산염의 제조방법
US5292936A (en)	1993-04-12	1994-03-08	Monsanto Company	Process to prepare amino carboxylic acid salts
US5689000A (en) *	1994-07-01	1997-11-18	Monsanto Company	Process for preparing carboxylic acid salts and catalysts useful in such process
US5916840A (en) *	1994-07-01	1999-06-29	Monsanto Company	Process for preparing carboxylic acid salts and catalysts useful in such process
US5986128A (en) *	1996-11-01	1999-11-16	Monsanto Company	Use of monosodium iminodiacetic acid solutions in the preparation of N-phosphonomethyliminodiacetic acid

1998
- 1998-03-23 IT IT98TO000249A patent/ITTO980249A1/it unknown
1999
- 1999-03-17 US US09/271,135 patent/US6239312B1/en not_active Expired - Fee Related
- 1999-03-19 AU AU21278/99A patent/AU740306B2/en not_active Ceased
- 1999-03-21 IL IL12907999A patent/IL129079A/en not_active IP Right Cessation
- 1999-03-22 ES ES99105731T patent/ES2207049T3/es not_active Expired - Lifetime
- 1999-03-22 DE DE69910871T patent/DE69910871D1/de not_active Expired - Lifetime
- 1999-03-22 IN IN332MA1999 patent/IN188987B/en unknown
- 1999-03-22 PT PT99105731T patent/PT945428E/pt unknown
- 1999-03-22 AT AT99105731T patent/ATE248803T1/de not_active IP Right Cessation
- 1999-03-22 EP EP99105731A patent/EP0945428B1/de not_active Expired - Lifetime
- 1999-03-23 BR BR9901155-7A patent/BR9901155A/pt not_active IP Right Cessation

Also Published As

Publication number	Publication date
AU740306B2 (en)	2001-11-01
ATE248803T1 (de)	2003-09-15
IN188987B (de)	2002-11-30
EP0945428A2 (de)	1999-09-29
ES2207049T3 (es)	2004-05-16
EP0945428A3 (de)	2000-01-12
DE69910871D1 (de)	2003-10-09
PT945428E (pt)	2004-01-30
AU2127899A (en)	1999-10-07
BR9901155A (pt)	2000-01-11
IL129079A0 (en)	2000-02-17
EP0945428B1 (de)	2003-09-03
ITTO980249A1 (it)	1999-09-23
US6239312B1 (en)	2001-05-29

Legal Events

Date	Code	Title
2004-09-27	FF	Patent granted
2005-02-20	KB	Patent renewed
2005-05-17	KB	Patent renewed
2010-05-17	MM9K	Patent not in force due to non-payment of renewal fees

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