IL76896A - 2-azolylmethyl-1-cyclo-propyl-ethanol derivatives,their preparation and their use as plant growth regulators and fungicides - Google Patents

2-azolylmethyl-1-cyclo-propyl-ethanol derivatives,their preparation and their use as plant growth regulators and fungicides

Info

Publication number
IL76896A
IL76896A IL76896A IL7689685A IL76896A IL 76896 A IL76896 A IL 76896A IL 76896 A IL76896 A IL 76896A IL 7689685 A IL7689685 A IL 7689685A IL 76896 A IL76896 A IL 76896A
Authority
IL
Israel
Prior art keywords
azolylmethyl
fungicides
cyclo
propyl
preparation
Prior art date
Application number
IL76896A
Other languages
English (en)
Other versions
IL76896A0 (en
Original Assignee
Bayer Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE3440116A external-priority patent/DE3440116A1/de
Priority claimed from DE19853522440 external-priority patent/DE3522440A1/de
Priority claimed from DE19853534310 external-priority patent/DE3534310A1/de
Application filed by Bayer Ag filed Critical Bayer Ag
Publication of IL76896A0 publication Critical patent/IL76896A0/xx
Publication of IL76896A publication Critical patent/IL76896A/xx

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/10—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms
    • C07D295/112—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms with the ring nitrogen atoms and the doubly bound oxygen or sulfur atoms separated by carbocyclic rings or by carbon chains interrupted by carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/63—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of halogen; by substitution of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
    • C07C45/71—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form being hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/80—Ketones containing a keto group bound to a six-membered aromatic ring containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/80—Ketones containing a keto group bound to a six-membered aromatic ring containing halogen
    • C07C49/813—Ketones containing a keto group bound to a six-membered aromatic ring containing halogen polycyclic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/84—Ketones containing a keto group bound to a six-membered aromatic ring containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/08—Compounds containing oxirane rings with hydrocarbon radicals, substituted by halogen atoms, nitro radicals or nitroso radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/34—Compounds containing oxirane rings with hydrocarbon radicals, substituted by sulphur, selenium or tellurium atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/36—Compounds containing oxirane rings with hydrocarbon radicals, substituted by nitrogen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)
IL76896A 1984-11-02 1985-10-31 2-azolylmethyl-1-cyclo-propyl-ethanol derivatives,their preparation and their use as plant growth regulators and fungicides IL76896A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE3440116A DE3440116A1 (de) 1984-11-02 1984-11-02 Substituierte azolylmethyl-cyclopropyl-carbinol-derivate
DE19853522440 DE3522440A1 (de) 1985-06-22 1985-06-22 Substituierte azolylmethyl-cyclopropyl-carbinol-derivate
DE19853534310 DE3534310A1 (de) 1985-09-26 1985-09-26 Substituierte azolylmethyl-cyclopropyl-carbinol-derivate

Publications (2)

Publication Number Publication Date
IL76896A0 IL76896A0 (en) 1986-02-28
IL76896A true IL76896A (en) 1989-09-28

Family

ID=27192476

Family Applications (1)

Application Number Title Priority Date Filing Date
IL76896A IL76896A (en) 1984-11-02 1985-10-31 2-azolylmethyl-1-cyclo-propyl-ethanol derivatives,their preparation and their use as plant growth regulators and fungicides

Country Status (14)

Country Link
US (3) US5089640A (fr)
EP (1) EP0180136B1 (fr)
JP (1) JPH0662582B2 (fr)
KR (1) KR860004034A (fr)
CN (1) CN1008735B (fr)
BR (1) BR8505476A (fr)
CA (2) CA1257869A (fr)
DE (1) DE3581051D1 (fr)
DK (1) DK504485A (fr)
ES (5) ES8701732A1 (fr)
HU (1) HU198118B (fr)
IL (1) IL76896A (fr)
NZ (1) NZ214013A (fr)
PT (1) PT81368B (fr)

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DE3608792A1 (de) * 1986-03-15 1987-09-24 Hoechst Ag 1,1-disubstituierte cyclopropanderivate, verfahren zu ihrer herstellung und ihre verwendung
DE3704262A1 (de) * 1987-02-12 1988-08-25 Bayer Ag Verwendung von azolylmethyl-cyclopropylcarbinol-derivaten zur bekaempfung von pseudocercosporella herpotrichoides
DE3720756A1 (de) * 1987-06-24 1989-01-05 Bayer Ag Azolylmethyl-cyclopropyl-carbinol-derivate
DE3812967A1 (de) * 1987-06-24 1989-01-05 Bayer Ag Azolylmethyl-cyclopropyl-derivate
DE3813129A1 (de) * 1987-07-01 1989-01-12 Bayer Ag Hydroxyethyl-azolyl-derivate
DE3722133A1 (de) * 1987-07-04 1989-01-12 Bayer Ag Azolyl-tetrahydropyran-derivate
DE3813874A1 (de) * 1987-07-10 1989-01-19 Bayer Ag Hydroxyalkyl-azolyl-derivate
AU621076B2 (en) * 1987-12-25 1992-03-05 Sumitomo Pharmaceuticals Company, Limited Process for preparation of sulfone derivatives
DE3811302A1 (de) * 1988-04-02 1989-10-19 Bayer Ag Derivate des triazolylmethyl-cyclopropyl-carbinols als materialschutzmittel
US5216180A (en) * 1989-06-30 1993-06-01 Bayer Aktiengesellschaft Microbicidal hydroxyethyl-cyclopropyl-azolyl derivatives
DE3921481A1 (de) * 1989-06-30 1991-01-03 Bayer Ag Hydroxyethyl-cyclopropyl-azolyl-derivate
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DE3942417A1 (de) * 1989-12-21 1991-06-27 Bayer Ag Triazolylmethyl-cyclopropyl-derivate
US5225015A (en) * 1991-04-15 1993-07-06 Corning Incorporated Method for making stiffened ceramic matrix composite panel
DE4131139A1 (de) * 1991-09-19 1993-03-25 Bayer Ag Verfahren zur herstellung von 1-fluor-cyclopropan-1-carbonsaeure
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ATE206410T1 (de) * 1995-04-06 2001-10-15 Sankyo Co Triazole als fungizide mittel.
GB0131126D0 (en) * 2001-12-05 2002-12-11 Secr Defence Detection method and apparatus
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CA2726714A1 (fr) * 2008-08-26 2010-03-04 Kureha Corporation Derives de 5-benzyl-4-azolylmethyl-4-spiro[2.4]heptanol, leurs procedes de fabrication et agents pour l'agriculture et l'horticulture et agents de protection de materiel industriel correspondants
CN102639508A (zh) 2009-12-08 2012-08-15 株式会社吴羽 唑衍生物及其制造方法、该衍生物的中间体化合物及其制造方法、以及含有该衍生物的农业园艺试剂和工业材料保护剂
RU2013133873A (ru) 2010-12-21 2015-01-27 БАЙЕР КРОПСАЙЕНС ЭлПи ШЕРОХОВАТЫЕ МУТАНТЫ Bacillus И СПОСОБЫ ИХ ПРИМЕНЕНИЯ ДЛЯ УСКОРЕНИЯ РОСТА РАСТЕНИЙ, УЛУЧШЕНИЯ ЗДОРОВЬЯ РАСТЕНИЙ И БОРЬБЫ С БОЛЕЗНЯМИ И ВРЕДИТЕЛЯМИ
US9253983B2 (en) 2011-05-31 2016-02-09 Kureha Corporation Triazole compound and use thereof
WO2012165498A1 (fr) * 2011-06-03 2012-12-06 株式会社クレハ Composé de triazole et son utilisation
CA2836566A1 (fr) 2011-06-07 2012-12-13 Kureha Corporation Agent chimique pour l'agriculture ou l'horticulture, composition pour lutter contre les maladies des plantes, procede pour lutter contre les maladies des plantes et produit pour lutter contre les maladies des plantes
BR112014005654A2 (pt) 2011-09-12 2017-03-28 Bayer Cropscience Lp métodos para melhorar a saúde e promover o crescimento de uma planta e/ou de melhorar o amadurecimento da fruta
CA2856711A1 (fr) * 2011-11-25 2013-05-30 Bayer Intellectual Property Gmbh Nouveaux derives d'alcanol heterocycliques
CN105102443B (zh) 2013-02-04 2017-07-28 先正达参股股份有限公司 新颖的杀微生物剂
WO2015189035A1 (fr) * 2014-06-10 2015-12-17 Basf Se Composés [1,2,4]-triazoles et imidazoles substitués utilisés comme fongicides
DE102014226196A1 (de) * 2014-12-17 2016-06-23 Henkel Ag & Co. Kgaa Photolabile Duftstoffvorläuferverbindung
JP2018516235A (ja) * 2015-04-02 2018-06-21 バイエル・クロップサイエンス・アクチェンゲゼルシャフト 殺有害生物剤および植物成長調節剤としてのトリアゾール誘導体
AU2016239175A1 (en) * 2015-04-02 2017-08-24 Bayer Cropscience Aktiengesellschaft Triazole derivatives as pesticides and plant growth regulators
WO2016156282A1 (fr) 2015-04-02 2016-10-06 Bayer Cropscience Aktiengesellschaft Nouveaux composés de triazole pour contrôler des champignons nocifs phytopathogènes
WO2018050535A1 (fr) 2016-09-13 2018-03-22 Bayer Cropscience Aktiengesellschaft Combinaisons de composés actifs
WO2018060071A1 (fr) 2016-09-29 2018-04-05 Bayer Cropscience Aktiengesellschaft Nouveaux dérivés triazole
AR109695A1 (es) 2016-09-29 2019-01-16 Bayer Cropscience Ag Derivados de triazol como fungicidas y como reguladores del crecimiento de plantas
AR109545A1 (es) 2016-09-29 2018-12-19 Bayer Cropscience Ag Derivados de triazol
CN116640043A (zh) * 2023-04-24 2023-08-25 岳阳市康利医药化工有限公司 一种1-氟环丙烷羧酸的合成方法

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ATE49200T1 (de) * 1981-11-27 1990-01-15 Ciba Geigy Ag Mikrobizide triazolyl-ethyl-aether.
DE3365739D1 (en) 1982-01-15 1986-10-09 Ciba Geigy Ag Fungicidal and plant-growth regulating tri-azolcarbinol derivatives
EP0106515B1 (fr) * 1982-09-30 1988-12-28 Pfizer Limited Dérivés du triazole comme agents antifongiques
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DE3245504A1 (de) * 1982-12-09 1984-06-14 Bayer Ag, 5090 Leverkusen Fungizide mittel, deren herstellung und verwendung
CH658654A5 (de) * 1983-03-04 1986-11-28 Sandoz Ag Azolderivate, verfahren zu ihrer herstellung und mittel die diese verbindungen enthalten.

Also Published As

Publication number Publication date
ES555050A0 (es) 1987-03-01
HUT39328A (en) 1986-09-29
ES555047A0 (es) 1987-03-01
PT81368A (en) 1985-11-01
ES8703854A1 (es) 1987-03-01
BR8505476A (pt) 1986-08-05
ES8701732A1 (es) 1986-12-01
ES555049A0 (es) 1987-03-01
NZ214013A (en) 1988-07-28
IL76896A0 (en) 1986-02-28
ES555048A0 (es) 1987-03-01
DK504485A (da) 1986-05-03
CN85108725A (zh) 1986-05-10
JPS61126049A (ja) 1986-06-13
JPH0662582B2 (ja) 1994-08-17
ES548445A0 (es) 1986-12-01
PT81368B (en) 1987-08-05
ES8703852A1 (es) 1987-03-01
CA1257869A (fr) 1989-07-25
US5089640A (en) 1992-02-18
KR860004034A (ko) 1986-06-16
DK504485D0 (da) 1985-11-01
EP0180136B1 (fr) 1991-01-02
US4988382A (en) 1991-01-29
US4921528A (en) 1990-05-01
HU198118B (en) 1989-08-28
EP0180136A3 (en) 1987-08-12
CN1008735B (zh) 1990-07-11
ES8703851A1 (es) 1987-03-01
CA1257263A (fr) 1989-07-11
ES8703853A1 (es) 1987-03-01
DE3581051D1 (de) 1991-02-07
EP0180136A2 (fr) 1986-05-07

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