IL93916A - תגובת תרכובות סובסטראט עם פלואור בתוך אדקטור - Google Patents

תגובת תרכובות סובסטראט עם פלואור בתוך אדקטור

Info

Publication number: IL93916A
Authority: IL; Israel
Prior art keywords: fluorine; substrate; reaction; stream; mixture
Prior art date: 1989-05-01

Application number

IL9391690A

Other languages

English (en)

Original Assignee

Pcr

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-05-01

Filing date

1990-03-28

Publication date

1994-11-28

1990-03-28 Application filed by Pcr filed Critical Pcr

1994-11-28 Publication of IL93916A publication Critical patent/IL93916A/he

Links

239000011737 fluorine Substances 0.000 title claims description 57
229910052731 fluorine Inorganic materials 0.000 title claims description 57
150000001875 compounds Chemical class 0.000 title claims description 33
239000000758 substrate Substances 0.000 title claims description 30
238000006243 chemical reaction Methods 0.000 title claims description 18
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 title description 3
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 54
238000000034 method Methods 0.000 claims description 26
239000000203 mixture Substances 0.000 claims description 12
239000011541 reaction mixture Substances 0.000 claims description 11
239000007788 liquid Substances 0.000 claims description 10
238000001816 cooling Methods 0.000 claims description 9
239000012530 fluid Substances 0.000 claims description 9
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 6
239000011261 inert gas Substances 0.000 claims description 6
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 3
229910000040 hydrogen fluoride Inorganic materials 0.000 claims description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
238000009835 boiling Methods 0.000 claims description 2
238000007710 freezing Methods 0.000 claims description 2
230000008014 freezing Effects 0.000 claims description 2
229910052736 halogen Inorganic materials 0.000 claims description 2
150000002367 halogens Chemical class 0.000 claims description 2
150000005826 halohydrocarbons Chemical class 0.000 claims description 2
239000001257 hydrogen Substances 0.000 claims description 2
229910052739 hydrogen Inorganic materials 0.000 claims description 2
230000001939 inductive effect Effects 0.000 claims 2
238000011144 upstream manufacturing Methods 0.000 claims 2
239000004215 Carbon black (E152) Substances 0.000 claims 1
229930195733 hydrocarbon Natural products 0.000 claims 1
150000002430 hydrocarbons Chemical class 0.000 claims 1
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
238000003682 fluorination reaction Methods 0.000 description 7
229910052757 nitrogen Inorganic materials 0.000 description 6
239000000047 product Substances 0.000 description 6
238000004817 gas chromatography Methods 0.000 description 4
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
-1 and the like Substances 0.000 description 3
239000006227 byproduct Substances 0.000 description 3
239000007789 gas Substances 0.000 description 3
239000007858 starting material Substances 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
238000010276 construction Methods 0.000 description 2
238000011031 large-scale manufacturing process Methods 0.000 description 2
239000000463 material Substances 0.000 description 2
238000007086 side reaction Methods 0.000 description 2
238000011925 1,2-addition Methods 0.000 description 1
229910001369 Brass Inorganic materials 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
229910000975 Carbon steel Inorganic materials 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
229910000792 Monel Inorganic materials 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
239000004809 Teflon Substances 0.000 description 1
229920006362 Teflon® Polymers 0.000 description 1
WFWLQNSHRPWKFK-UHFFFAOYSA-N Tegafur Chemical compound O=C1NC(=O)C(F)=CN1C1OCCC1 WFWLQNSHRPWKFK-UHFFFAOYSA-N 0.000 description 1
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
238000007792 addition Methods 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
150000001345 alkine derivatives Chemical class 0.000 description 1
150000001361 allenes Chemical class 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000010951 brass Substances 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
239000010962 carbon steel Substances 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
150000001925 cycloalkenes Chemical class 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000001514 detection method Methods 0.000 description 1
238000010586 diagram Methods 0.000 description 1
239000000539 dimer Substances 0.000 description 1
239000012467 final product Substances 0.000 description 1
229910000856 hastalloy Inorganic materials 0.000 description 1
238000009776 industrial production Methods 0.000 description 1
239000003701 inert diluent Substances 0.000 description 1
239000012442 inert solvent Substances 0.000 description 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
238000010667 large scale reaction Methods 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
235000020030 perry Nutrition 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
238000005086 pumping Methods 0.000 description 1
238000007348 radical reaction Methods 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
238000013341 scale-up Methods 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
229940029284 trichlorofluoromethane Drugs 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
- C07C17/272—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions
- C07C17/278—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions of only halogenated hydrocarbons
- C07C17/281—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions of only halogenated hydrocarbons of only one compound
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B39/00—Halogenation
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/013—Preparation of halogenated hydrocarbons by addition of halogens
- C07C17/04—Preparation of halogenated hydrocarbons by addition of halogens to unsaturated halogenated hydrocarbons
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/21—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms with simultaneous increase of the number of halogen atoms

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

IL9391690A 1989-05-01 1990-03-28 תגובת תרכובות סובסטראט עם פלואור בתוך אדקטור IL93916A (he)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US07/345,588 US5177275A (en)	1989-05-01	1989-05-01	Reaction of substrate compounds with fluorine in an eductor

Publications (1)

Publication Number	Publication Date
IL93916A true IL93916A (he)	1994-11-28

Family

ID=23355633

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL9391690A IL93916A (he)	1989-05-01	1990-03-28	תגובת תרכובות סובסטראט עם פלואור בתוך אדקטור

Country Status (4)

Country	Link
US (2)	US5177275A (he)
EP (1)	EP0396168A1 (he)
JP (1)	JPH0368525A (he)
IL (1)	IL93916A (he)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5488142A (en) *	1993-10-04	1996-01-30	Minnesota Mining And Manufacturing Company	Fluorination in tubular reactor system
SE505324C2 (sv) *	1994-11-14	1997-08-04	Gems Pet Systems Ab	Framställning av 11C-metyljodid
WO1999046223A1 (en) *	1998-03-09	1999-09-16	Scott Specialty Gases, Inc.	Method and apparatus for direct fluorination of carbon or sulfur compounds
US6187986B1 (en)	1998-10-17	2001-02-13	Marathon Ashland Petroleum, Llc	Fresh plant inventory hydrofluoric acid eduction process
KR100658248B1 (ko) *	1999-05-20	2006-12-14	더 싸우쓰 아프리칸 뉴클리어 에너지 코포레이션 리미티드	플루오르화 반응
GB0009156D0 (en) *	2000-04-14	2000-05-31	F2 Chemicals Ltd	Fluorination method
GB0021618D0 (en) *	2000-09-02	2000-10-18	Ici Plc	Production of hydrofluoroalkanes
US7624818B2 (en) *	2004-02-19	2009-12-01	Baker Hughes Incorporated	Earth boring drill bits with casing component drill out capability and methods of use
DE102006053380A1 (de) *	2006-11-13	2008-05-15	Wacker Chemie Ag	Verfahren zur Herstellung von chlorierten Carbonylverbindungen in Jet Loop Reaktoren
US8822741B2 (en) *	2010-07-13	2014-09-02	Solvay Specialty Polymers Italy S.P.A.	Process for the fluorination of haloolefins
CN109277009A (zh)	2011-12-05	2019-01-29	斯蒂芬·M·萨菲奥蒂	用于产生均质油田凝胶的系统和方法
WO2021031431A1 (en) *	2019-08-22	2021-02-25	Fujian Yongjing Technology Co., Ltd	Process for preparing fluorobenzene by direct fluorination
KR20220041173A (ko) *	2019-08-22	2022-03-31	푸젠 융징 테크놀로지 컴퍼니 리미티드	직접 플루오르화에 의해 무기 또는 유기 화합물을 플루오르화하는 공법
WO2021036047A1 (en) *	2019-08-27	2021-03-04	Fujian Yongjing Technology Co., Ltd	Process for preparing fluorobenzene and benzoic acid hypofluorite
JP7216099B2 (ja) *	2019-08-27	2023-01-31	フジアンヨンジンテクノロジーカンパニーリミテッド	フルオロベンゼン誘導体及び安息香酸ハイポフルオライト誘導体の製造プロセス

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1563994A (en) *	1975-05-15	1980-04-02	Albright & Wilson	Sulph(on)ation process and mixer
US4230668A (en) *	1976-02-19	1980-10-28	The Badger Company, Inc.	Process and apparatus for producing halogenated unsaturated hydrocarbons
DE2819308A1 (de) *	1978-05-02	1979-11-15	Hoechst Ag	Verfahren zur herstellung von 1,2-dichloraethan
IT1200806B (it) *	1985-10-21	1989-01-27	Ausimont Spa	Procedimento per la preparazione di idroalofluoroalcani

1989
- 1989-05-01 US US07/345,588 patent/US5177275A/en not_active Expired - Fee Related
1990
- 1990-03-28 IL IL9391690A patent/IL93916A/he not_active IP Right Cessation
- 1990-04-18 EP EP90200946A patent/EP0396168A1/en not_active Withdrawn
- 1990-04-24 JP JP2108568A patent/JPH0368525A/ja active Pending
1992
- 1992-05-01 US US07/876,978 patent/US5334788A/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
EP0396168A1 (en)	1990-11-07
US5177275A (en)	1993-01-05
US5334788A (en)	1994-08-02
JPH0368525A (ja)	1991-03-25

Legal Events

Date	Code	Title	Description
1996-12-05	RH	Patent void

Publication	Publication Date	Title
US5334788A (en)	1994-08-02	Reaction of substrate compounds with fluorine in an eductor
CA1248973A (en)	1989-01-17	Process for the preparation of tertiary-butyl hydroperoxide
US5705728A (en)	1998-01-06	Process for the production of ethylene and mixture containing ethylene
US5744657A (en)	1998-04-28	Process for the preparation of perfluorocarbons
US4849555A (en)	1989-07-18	Synthesis of 1-chloro-1, 1-difluoroethane
JP2921611B2 (ja)	1999-07-19	エタン誘導体の製法
WO1989007095A1 (en)	1989-08-10	Nitration of benzene or toluene in a molten nitrate salt
JP2000159505A (ja)	2000-06-13	フッ素化ハロゲン化合物の製造方法
US4227001A (en)	1980-10-07	Preparation of polychlorinated pyridines from 2,4-dichloro-6-(trichloro methyl)pyridine
CN112313197A (zh)	2021-02-02	用于生产1-氯-3,3,3-三氟丙烯的方法
CA2013186A1 (en)	1990-11-01	Reaction of substrate compounds with fluorine in an eductor
JPH08259491A (ja)	1996-10-08	オレフインの接触酸化によつてカルボニル化合物を製造するための方法、及びマイクロエマルシヨン中に存在する触媒
US2439812A (en)	1948-04-20	Method for making phenol
KR100309364B1 (ko)	2002-04-24	테트라플루오로메탄의제조방법
JP3059717B2 (ja)	2000-07-04	モノおよび／またはビス（モノおよび／またはジおよび／またはトリクロロメチル）ベンゼンの連続製造方法
US3697608A (en)	1972-10-10	Dechlorination process
EP0450584B1 (en)	1994-08-24	Bromination method
US4487935A (en)	1984-12-11	Production of mixtures rich in 6-chloro-2-trichloromethyl pyridine
US3338982A (en)	1967-08-29	Chlorination of olefins in the presence of amides
US3872174A (en)	1975-03-18	Production of dichloroethylene using melt chlorination process
US3404180A (en)	1968-10-01	Manufacture of carbonyl fluoride
US3265603A (en)	1966-08-09	Process for the chlorination of 2-chloro-6-nitro-benzonitrile
US5426256A (en)	1995-06-20	Minimizing heavy ends production in the manufacture of perchloroethylene from hydrocarbons or partially chlorinated hydrocarbons
EP0612708B1 (en)	1997-12-03	Manufacture of perchloroethylene from carbon tetrachloride in the presence of hydrogen
US3496244A (en)	1970-02-17	Production of dichloroethane