IT1146738B - PROCEDURE FOR THE PREPARATION OF AN ALDEHYDIDE PHENOL RESIN AND RESIN COMPOSITION FOR THE TREATMENT OF GLASS FIBERS USED FOR TIRES REINFORCEMENT - Google Patents
PROCEDURE FOR THE PREPARATION OF AN ALDEHYDIDE PHENOL RESIN AND RESIN COMPOSITION FOR THE TREATMENT OF GLASS FIBERS USED FOR TIRES REINFORCEMENTInfo
- Publication number
- IT1146738B IT1146738B IT67145/81A IT6714581A IT1146738B IT 1146738 B IT1146738 B IT 1146738B IT 67145/81 A IT67145/81 A IT 67145/81A IT 6714581 A IT6714581 A IT 6714581A IT 1146738 B IT1146738 B IT 1146738B
- Authority
- IT
- Italy
- Prior art keywords
- aldehyde
- phenolic compound
- adhesive
- mixture
- resin
- Prior art date
Links
- 239000003365 glass fiber Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 230000002787 reinforcement Effects 0.000 title abstract 2
- 239000005011 phenolic resin Substances 0.000 title 1
- 239000011342 resin composition Substances 0.000 title 1
- 150000002989 phenols Chemical class 0.000 abstract 5
- 239000000853 adhesive Substances 0.000 abstract 4
- 230000001070 adhesive effect Effects 0.000 abstract 4
- 150000001299 aldehydes Chemical class 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 abstract 4
- 239000000463 material Substances 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- 239000004816 latex Substances 0.000 abstract 2
- 229920000126 latex Polymers 0.000 abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000000654 additive Substances 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 239000000539 dimer Substances 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 abstract 1
- RCHKEJKUUXXBSM-UHFFFAOYSA-N n-benzyl-2-(3-formylindol-1-yl)acetamide Chemical compound C12=CC=CC=C2C(C=O)=CN1CC(=O)NCC1=CC=CC=C1 RCHKEJKUUXXBSM-UHFFFAOYSA-N 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 229920001169 thermoplastic Polymers 0.000 abstract 1
- 239000004416 thermosoftening plastic Substances 0.000 abstract 1
- 239000013638 trimer Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
- C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D30/00—Producing pneumatic or solid tyres or parts thereof
- B29D30/06—Pneumatic tyres or parts thereof (e.g. produced by casting, moulding, compression moulding, injection moulding, centrifugal casting)
- B29D30/38—Textile inserts, e.g. cord or canvas layers, for tyres; Treatment of inserts prior to building the tyre
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
- C08G8/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J121/00—Adhesives based on unspecified rubbers
- C09J121/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D30/00—Producing pneumatic or solid tyres or parts thereof
- B29D30/06—Pneumatic tyres or parts thereof (e.g. produced by casting, moulding, compression moulding, injection moulding, centrifugal casting)
- B29D30/38—Textile inserts, e.g. cord or canvas layers, for tyres; Treatment of inserts prior to building the tyre
- B29D2030/383—Chemical treatment of the reinforcing elements, e.g. cords, wires and filamentary materials, to increase the adhesion to the rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2030/00—Pneumatic or solid tyres or parts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
- C08L2666/16—Addition or condensation polymers of aldehydes or ketones according to C08L59/00 - C08L61/00; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Reinforced Plastic Materials (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Laminated Bodies (AREA)
- Moulding By Coating Moulds (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A method of preparing a thermoplastic, water-soluble, phenolic aldehyde resin involves two steps. Firstly, the phenolic compound and aldehyde are reacted to less than 100 percent completion at an aldehyde to phenolic compound mole ratio of 0.6 to 1.5 and at a pH of 3.5 to 5.5 for 3 to 10 hours at a temperature of 13 to 32 DEG C. Secondly the pH of the reaction is adjusted to above 7.0 to 7.5 and the reaction is continued between the unreacted phenolic compound and aldehyde and resinous mixture to produce a resinous mixture that has a predominant amount of trimer polymer with slight cross-linking and a minor amount of dimer and higher oligomers. The phenolic compound is preferably resorcinol or a mixture of resorcinol and phenol. The resin mixture is processed into an adhesive by combining it with one or more elastomeric latex and various latex additives. The adhesive is aged and has added to it an amine or ammonia to tie up any unreacted aldehyde. Also additional phenolic compound may be added. The adhesive is used to coat filamentary materials in particular glass fibres and the coated filamentary materials are dried to produce reinforcement material for rubber. Uses:- Tyre cords adhesives
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16335580A | 1980-06-26 | 1980-06-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IT8167145A0 IT8167145A0 (en) | 1981-02-03 |
| IT1146738B true IT1146738B (en) | 1986-11-19 |
Family
ID=22589667
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IT67145/81A IT1146738B (en) | 1980-06-26 | 1981-02-03 | PROCEDURE FOR THE PREPARATION OF AN ALDEHYDIDE PHENOL RESIN AND RESIN COMPOSITION FOR THE TREATMENT OF GLASS FIBERS USED FOR TIRES REINFORCEMENT |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5714614A (en) |
| BE (1) | BE887384A (en) |
| CA (1) | CA1173580A (en) |
| DE (1) | DE3121382A1 (en) |
| FR (1) | FR2485435A1 (en) |
| GB (1) | GB2082607A (en) |
| IT (1) | IT1146738B (en) |
| NL (1) | NL8100369A (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2125451B (en) * | 1982-08-13 | 1986-01-02 | Borg Warner | Extrusion coated continuous tape |
| BRPI0512817B1 (en) * | 2004-06-28 | 2016-02-10 | Nippon Sheet Glass Co Ltd | fiber to reinforce rubber, method for making fiber, and rubber product using such fiber |
| FR2978769B1 (en) | 2011-08-04 | 2013-09-27 | Michelin Soc Tech | AQUEOUS ADHESIVE COMPOSITION BASED ON POLYALDEHYDE AND POLYPHENOL |
| FR2978770B1 (en) | 2011-08-04 | 2013-09-27 | Michelin Soc Tech | AQUEOUS ADHESIVE COMPOSITION BASED ON POLYALDEHYDE AND PHLOROGLUCINOL |
| FR2978771B1 (en) | 2011-08-04 | 2013-09-27 | Michelin Soc Tech | AQUEOUS ADHESIVE COMPOSITION BASED ON POLYALDEHYDE AND 2,2 ', 4,4'-TETRAHYDROXYDIPHENYL SULFIDE |
| FR3008707B1 (en) * | 2013-07-16 | 2017-11-10 | Michelin & Cie | AQUEOUS ADHESIVE COMPOSITION BASED ON BIOSOURCE ALDEHYDE AND POLYPHENOL |
| FR3017070B1 (en) * | 2014-02-06 | 2017-08-25 | Michelin & Cie | STEEL REINFORCING ELEMENT COATED BY AN ADHESIVE COMPOSITION BASED ON AROMATIC ALDEHYDE AND POLYPHENOL |
| EP3247748B1 (en) | 2015-01-21 | 2024-05-22 | Compagnie Générale des Etablissements Michelin | High-rigidity rubber composition |
| FR3031746A1 (en) | 2015-01-21 | 2016-07-22 | Michelin & Cie | HIGH RIGIDITY RUBBER COMPOSITION |
| FR3031745A1 (en) | 2015-01-21 | 2016-07-22 | Michelin & Cie | HIGH RIGIDITY RUBBER COMPOSITION |
| CN109266283A (en) * | 2018-08-06 | 2019-01-25 | 岳西县明杰电子有限公司 | A kind of ageing-resistant insulation adhesive of transformer |
| CN109456516B (en) * | 2018-11-19 | 2021-03-05 | 北京彤程创展科技有限公司 | Bisphenol compound modified resorcinol resin, rubber composition and preparation method thereof |
| CN111088700A (en) * | 2019-12-03 | 2020-05-01 | 浙江尤夫科技工业有限公司 | Rubber canvas gum dipping formula, preparation method thereof and preparation method of rubber canvas |
| CN115353710A (en) * | 2022-08-19 | 2022-11-18 | 山东北方现代化学工业有限公司 | Nylon-reinforced high-strength glass fiber phenolic composite material and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE365286C (en) * | 1920-06-17 | 1922-12-14 | Hoechst Ag | Process for the preparation of resinous condensation products from phenols and acetaldehyde |
| US2494537A (en) * | 1946-07-26 | 1950-01-17 | Glen E Babcock | Cold-setting resorcinol glue composition and process of preparation |
| GB1034950A (en) * | 1963-11-15 | 1966-07-06 | Pirelli | Improvements in or relating to the preparation of liquid adhesive compositions for the treatment of textile materials and to the treatment of textile materials with suchcompositions |
-
1981
- 1981-01-12 CA CA000368266A patent/CA1173580A/en not_active Expired
- 1981-01-27 NL NL8100369A patent/NL8100369A/en not_active Application Discontinuation
- 1981-02-03 IT IT67145/81A patent/IT1146738B/en active
- 1981-02-04 BE BE0/203697A patent/BE887384A/en not_active IP Right Cessation
- 1981-02-17 FR FR8103100A patent/FR2485435A1/en not_active Withdrawn
- 1981-03-24 JP JP4384881A patent/JPS5714614A/en active Pending
- 1981-05-29 DE DE19813121382 patent/DE3121382A1/en not_active Withdrawn
- 1981-06-04 GB GB8117118A patent/GB2082607A/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| BE887384A (en) | 1981-08-04 |
| GB2082607A (en) | 1982-03-10 |
| DE3121382A1 (en) | 1982-02-25 |
| FR2485435A1 (en) | 1981-12-31 |
| IT8167145A0 (en) | 1981-02-03 |
| CA1173580A (en) | 1984-08-28 |
| NL8100369A (en) | 1982-01-18 |
| JPS5714614A (en) | 1982-01-25 |
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