IT1269984B - Procedimento per la preparazione della cumarina e dei suoi derivati - Google Patents
Procedimento per la preparazione della cumarina e dei suoi derivatiInfo
- Publication number
- IT1269984B IT1269984B ITMI941908A ITMI941908A IT1269984B IT 1269984 B IT1269984 B IT 1269984B IT MI941908 A ITMI941908 A IT MI941908A IT MI941908 A ITMI941908 A IT MI941908A IT 1269984 B IT1269984 B IT 1269984B
- Authority
- IT
- Italy
- Prior art keywords
- substituted
- cumarina
- derivatives
- procedure
- preparation
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 abstract 3
- NBQYFMKBZLSPIY-UHFFFAOYSA-N 3,4,4a,5,6,7-hexahydrochromen-2-one Chemical class C1CCC=C2OC(=O)CCC21 NBQYFMKBZLSPIY-UHFFFAOYSA-N 0.000 abstract 2
- 235000001671 coumarin Nutrition 0.000 abstract 2
- VMUXSMXIQBNMGZ-UHFFFAOYSA-N 3,4-dihydrocoumarin Chemical compound C1=CC=C2OC(=O)CCC2=C1 VMUXSMXIQBNMGZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229960000956 coumarin Drugs 0.000 abstract 1
- 150000004775 coumarins Chemical class 0.000 abstract 1
- 238000006356 dehydrogenation reaction Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
- C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D311/04—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
- C07D311/06—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring with oxygen or sulfur atoms directly attached in position 2
- C07D311/08—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring with oxygen or sulfur atoms directly attached in position 2 not hydrogenated in the hetero ring
- C07D311/10—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring with oxygen or sulfur atoms directly attached in position 2 not hydrogenated in the hetero ring unsubstituted
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pyrane Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
La presente invenzione riguarda un nuovo procedimento per la produzione di cumarina e cumarine sostituite a partire da esaidrocumarine sostituite o da diidrocumarine sostituite.Il procedimento comprende una deidrogenazione in presenza di catalizzatori a base di metalli dell'VIII Gruppo della tabella periodica degli elementi e in presenza di almeno un composto organico facilmente riducibile.L'invenzione consente di ottenere rese eccezionalmente elevate, tali da non richiedere il riciclo dell'esaidrocumarina o della diidrocumarina presenti a fine reazione, e di ottenere inoltre un'elevata selettività e una facile purificazione.
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI941908A IT1269984B (it) | 1994-09-20 | 1994-09-20 | Procedimento per la preparazione della cumarina e dei suoi derivati |
| PCT/EP1995/002687 WO1996009298A1 (en) | 1994-09-20 | 1995-07-11 | Method for preparing coumarin and derivatives thereof |
| KR1019970701752A KR970706269A (ko) | 1994-09-20 | 1995-07-11 | 쿠마린 및 이의 유도체를 제조하는 방법(method for preparing coumarin and derivatives thereof) |
| EP95944756A EP0782572A2 (en) | 1994-09-20 | 1995-07-11 | Method for preparing coumarin and derivatives thereof |
| US08/809,189 US5872265A (en) | 1994-09-20 | 1995-07-11 | Method for preparing coumarin and derivatives thereof |
| JP8510546A JPH10502668A (ja) | 1994-09-20 | 1995-07-11 | クマリン、および、その誘導体の調製法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI941908A IT1269984B (it) | 1994-09-20 | 1994-09-20 | Procedimento per la preparazione della cumarina e dei suoi derivati |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| ITMI941908A0 ITMI941908A0 (it) | 1994-09-20 |
| ITMI941908A1 ITMI941908A1 (it) | 1996-03-20 |
| IT1269984B true IT1269984B (it) | 1997-04-16 |
Family
ID=11369572
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ITMI941908A IT1269984B (it) | 1994-09-20 | 1994-09-20 | Procedimento per la preparazione della cumarina e dei suoi derivati |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5872265A (it) |
| EP (1) | EP0782572A2 (it) |
| JP (1) | JPH10502668A (it) |
| KR (1) | KR970706269A (it) |
| IT (1) | IT1269984B (it) |
| WO (1) | WO1996009298A1 (it) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6752862B2 (en) * | 2001-03-16 | 2004-06-22 | Takasago International Corporation | Color fading/discoloration preventive agent |
| WO2018001963A1 (en) * | 2016-06-27 | 2018-01-04 | Firmenich Sa | Dehydrogenation reaction |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3523125A (en) * | 1968-04-16 | 1970-08-04 | Mobil Oil Corp | Liquid phase oxidative dehydrogenation of aldehydes and ketones |
| NL173403C (nl) * | 1972-06-22 | 1984-01-16 | Stamicarbon | Werkwijze voor de bereiding van cumarine of een methylcumarine. |
| NL180215C (nl) * | 1972-08-31 | 1987-01-16 | Stamicarbon | Werkwijze ter bereiding van desgewenst gealkyleerd cumarine te zamen met het overeenkomstige dihydrocumarine. |
| JPS5540637A (en) * | 1978-09-19 | 1980-03-22 | Mitsui Petrochem Ind Ltd | Preparation of chromene |
| JPS5714759A (en) * | 1980-06-30 | 1982-01-26 | Mitsubishi Electric Corp | Resonance magnetometer of helium optical magnet |
| JPS57146759A (en) * | 1981-03-06 | 1982-09-10 | Otsuka Pharmaceut Co Ltd | Preparation of 5-hydroxycarbostyril |
| DE69013868T2 (de) * | 1989-12-21 | 1995-05-24 | Sumitomo Chemical Co | Katalytische Herstellung von Cumarin-Verbindungen. |
| KR930002338A (ko) * | 1991-07-31 | 1993-02-23 | 모리 히데오 | 쿠마린 및 이의 유도체의 제조방법 |
| JP3079695B2 (ja) * | 1991-10-24 | 2000-08-21 | 住友化学工業株式会社 | クマリン類の製造方法 |
-
1994
- 1994-09-20 IT ITMI941908A patent/IT1269984B/it active IP Right Grant
-
1995
- 1995-07-11 US US08/809,189 patent/US5872265A/en not_active Expired - Fee Related
- 1995-07-11 EP EP95944756A patent/EP0782572A2/en not_active Withdrawn
- 1995-07-11 KR KR1019970701752A patent/KR970706269A/ko not_active Withdrawn
- 1995-07-11 WO PCT/EP1995/002687 patent/WO1996009298A1/en not_active Ceased
- 1995-07-11 JP JP8510546A patent/JPH10502668A/ja not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| KR970706269A (ko) | 1997-11-03 |
| ITMI941908A0 (it) | 1994-09-20 |
| EP0782572A2 (en) | 1997-07-09 |
| JPH10502668A (ja) | 1998-03-10 |
| US5872265A (en) | 1999-02-16 |
| WO1996009298A1 (en) | 1996-03-28 |
| ITMI941908A1 (it) | 1996-03-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 0001 | Granted | ||
| TA | Fee payment date (situation as of event date), data collected since 19931001 |
Effective date: 19970926 |