IT1273662B - Procedimento per la preparazione di polimeri amorfi del propiline' - Google Patents

Procedimento per la preparazione di polimeri amorfi del propiline'

Info

Publication number
IT1273662B
IT1273662B ITMI941517A ITMI941517A IT1273662B IT 1273662 B IT1273662 B IT 1273662B IT MI941517 A ITMI941517 A IT MI941517A IT MI941517 A ITMI941517 A IT MI941517A IT 1273662 B IT1273662 B IT 1273662B
Authority
IT
Italy
Prior art keywords
amorphous polymers
propiline
procedure
preparation
tetraidroindenilici
Prior art date
Application number
ITMI941517A
Other languages
English (en)
Inventor
Gabriele Govoni
Mario Sacchetti
Stefano Pasquali
Original Assignee
Spherilene Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Spherilene Srl filed Critical Spherilene Srl
Publication of ITMI941517A0 publication Critical patent/ITMI941517A0/it
Priority to ITMI941517A priority Critical patent/IT1273662B/it
Priority to ES95111234T priority patent/ES2161810T3/es
Priority to DE69522393T priority patent/DE69522393T2/de
Priority to EP95111234A priority patent/EP0693506B1/en
Priority to US08/504,319 priority patent/US6391991B1/en
Priority to RU95113175/04A priority patent/RU95113175A/ru
Priority to JP7184124A priority patent/JPH0859722A/ja
Priority to CA002154300A priority patent/CA2154300A1/en
Priority to KR1019950021367A priority patent/KR960004380A/ko
Priority to CN95115261A priority patent/CN1052736C/zh
Publication of ITMI941517A1 publication Critical patent/ITMI941517A1/it
Application granted granted Critical
Publication of IT1273662B publication Critical patent/IT1273662B/it
Priority to CN99118617A priority patent/CN1267656A/zh

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465Indenes; Completely or partially hydrogenated indenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00Systems containing two condensed rings
    • C07C2602/02Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61925Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

E' POSSIBILE PREPARARE POLIMERI SOSTANZIALMENTE AMORFI DEL PROPILENE DOTATI DI ELEVATO PESO MOLECOLARE, OPERANDO A TEMPERATURE DI INTERESSE INDUSTRIALE, EFFETTUANDO LA REAZIONE DI POLIMERIZZAZIONE DEL PROPILENE IN PRESENZA DI CATALIZZATORI METALLOCENICI COMPRENDENTI PARTICOLARI COMPOSTI BIS-INDENILICI O BIS-4, 5, 6, 7-TETRAIDROINDENILICI SOSTITUITI IN POSIZIONE 2 SUI GRUPPI INDENILICI O TETRAIDROINDENILICI.
ITMI941517A 1994-07-20 1994-07-20 Procedimento per la preparazione di polimeri amorfi del propiline' IT1273662B (it)

Priority Applications (11)

Application Number Priority Date Filing Date Title
ITMI941517A IT1273662B (it) 1994-07-20 1994-07-20 Procedimento per la preparazione di polimeri amorfi del propiline'
ES95111234T ES2161810T3 (es) 1994-07-20 1995-07-18 Procedimiento para la preparacion de polimeros amorfos de propileno.
DE69522393T DE69522393T2 (de) 1994-07-20 1995-07-18 Verfahren zur Herstellung von amorphen Propylenpolymeren
EP95111234A EP0693506B1 (en) 1994-07-20 1995-07-18 Process for the preparation of amorphous polymers of propylene
US08/504,319 US6391991B1 (en) 1994-07-20 1995-07-19 Process for the preparation of amorphous polymers of propylene
RU95113175/04A RU95113175A (ru) 1994-07-20 1995-07-19 Способ получения аморфных полимеров пропилена, способ получения инденового соединения
JP7184124A JPH0859722A (ja) 1994-07-20 1995-07-20 非晶質のプロピレンのポリマーの製造方法
CA002154300A CA2154300A1 (en) 1994-07-20 1995-07-20 Process for the preparation of amorphous polymers of propylene
KR1019950021367A KR960004380A (ko) 1994-07-20 1995-07-20 무정형 프로필렌 중합체의 제조방법
CN95115261A CN1052736C (zh) 1994-07-20 1995-07-20 无定形丙烯聚合物的制备方法
CN99118617A CN1267656A (zh) 1994-07-20 1999-08-31 制备适用作金属茂配位体的茚化合物的方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI941517A IT1273662B (it) 1994-07-20 1994-07-20 Procedimento per la preparazione di polimeri amorfi del propiline'

Publications (3)

Publication Number Publication Date
ITMI941517A0 ITMI941517A0 (it) 1994-07-20
ITMI941517A1 ITMI941517A1 (it) 1996-01-20
IT1273662B true IT1273662B (it) 1997-07-09

Family

ID=11369318

Family Applications (1)

Application Number Title Priority Date Filing Date
ITMI941517A IT1273662B (it) 1994-07-20 1994-07-20 Procedimento per la preparazione di polimeri amorfi del propiline'

Country Status (10)

Country Link
US (1) US6391991B1 (it)
EP (1) EP0693506B1 (it)
JP (1) JPH0859722A (it)
KR (1) KR960004380A (it)
CN (2) CN1052736C (it)
CA (1) CA2154300A1 (it)
DE (1) DE69522393T2 (it)
ES (1) ES2161810T3 (it)
IT (1) IT1273662B (it)
RU (1) RU95113175A (it)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1277696B1 (it) * 1995-12-22 1997-11-11 Enichem Spa Catalizzatori per la polimerizzazione di alfa-olefine
US5705579A (en) * 1996-07-17 1998-01-06 Phillips Petroleum Company Olefin polymerization
DE19644040A1 (de) * 1996-10-31 1998-05-07 Hoechst Ag Verfahren zur Hydrierung von Metallocenen
MXPA00002181A (es) 1998-07-02 2003-04-22 Montell Technology Company Bv Procedimiento para la preparacion de polimeros de alfa-olefinas sustancialmente amorfos composiciones que los contienen, y procedimiento para la preparacion de ligandos puenteados.
EP1854804B1 (en) 1999-12-28 2011-05-04 Basell Polyolefine GmbH Heterocyclic metallocene compounds and use thereof in catalyst systems for producing olefin polymers
JP4771938B2 (ja) 2003-05-12 2011-09-14 バーゼル・ポリオレフィン・ゲーエムベーハー 1−ブテンの重合方法
WO2011087731A1 (en) 2010-01-14 2011-07-21 Exxonmobil Chemical Patents Inc. Processes and apparatus for continuous solution polymerization
WO2011087729A2 (en) 2010-01-14 2011-07-21 Exxonmobil Chemical Patents Inc. Processes and apparatus for polymer finishing and packaging
WO2011087728A2 (en) 2010-01-14 2011-07-21 Exxonmobil Chemical Patents Inc. Processes and apparatus for continuous solution polymerization
EP2536784B2 (en) 2010-02-19 2020-11-25 ExxonMobil Chemical Patents Inc. Elastomeric polymer blends and processes for their production
BR112012022316B1 (pt) * 2010-03-04 2019-12-24 Total Res & Technology Feluy processo para preparar um sistema de catalisador suportado, sistema de catalisador suportado obtido por um processo, processo para preparar uma poliolefina, processo para preparar um polipropileno e poliolefina obtida por um processo
US20120178333A1 (en) * 2011-01-07 2012-07-12 Rextac Llc Bi-modal Poly-alpha-olefin Blend
US8916659B1 (en) 2013-10-31 2014-12-23 Exxonmobil Chemical Patents Inc. Process and apparatus for continuous solution polymerization
EP3218426B1 (en) 2014-11-12 2022-03-30 ExxonMobil Chemical Patents Inc. Purification of plasticizer and use thereof in a polymer production process and plant
JP2018522099A (ja) 2015-06-15 2018-08-09 エクソンモービル・ケミカル・パテンツ・インク 連続溶液重合プロセス
WO2018022263A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
US11198747B2 (en) 2018-06-04 2021-12-14 Exxonmobil Chemical Patents Inc. Catalyst systems including two hafnocene catalyst compounds
US11369949B2 (en) 2018-06-04 2022-06-28 Exxonmobil Chemical Patents Inc. Metallocenes with Si—Si bridges
WO2019236349A1 (en) 2018-06-04 2019-12-12 Exxonmobil Chemical Patents Inc. Catalyst systems including two hafnocene catalyst compounds
SG11202102663QA (en) 2018-09-19 2021-04-29 Exxonmobil Chemical Patents Inc Devolatilization processes
KR102830642B1 (ko) * 2018-09-28 2025-07-08 다우 글로벌 테크놀로지스 엘엘씨 치환된 사이클로펜타디엔 화합물 및 메탈로센의 합성
KR102813863B1 (ko) 2018-09-28 2025-05-29 다우 글로벌 테크놀로지스 엘엘씨 시클로펜테논의 합성
WO2020167399A1 (en) 2019-02-11 2020-08-20 Exxonmobil Chemical Patents Inc. Biphasic polymerization processes and ethylene-based polyolefins therefrom
KR102687447B1 (ko) * 2019-08-22 2024-07-23 한화솔루션 주식회사 전이금속 화합물, 이를 포함하는 촉매 및 이들의 제조방법
US20230002525A1 (en) 2019-12-17 2023-01-05 Exxonmobil Chemical Patents Inc. Solution Polymerization Process for Making High-Density Polyethylene with Long-Chain Branching
KR20240093897A (ko) 2021-11-23 2024-06-24 엑손모빌 케미칼 패턴츠 인코포레이티드 중합체 형성을 위한 플랜트 및 방법

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US4874880A (en) 1987-03-10 1989-10-17 Chisso Corporation Bis(di-, tri- or tetra-substituted-cyclopentadienyl)-zirconium dihalides
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Also Published As

Publication number Publication date
KR960004380A (ko) 1996-02-23
DE69522393T2 (de) 2002-10-17
US6391991B1 (en) 2002-05-21
CN1123796A (zh) 1996-06-05
ES2161810T3 (es) 2001-12-16
EP0693506A3 (en) 1998-04-08
CN1267656A (zh) 2000-09-27
EP0693506B1 (en) 2001-08-29
ITMI941517A0 (it) 1994-07-20
EP0693506A2 (en) 1996-01-24
DE69522393D1 (de) 2001-10-04
CN1052736C (zh) 2000-05-24
JPH0859722A (ja) 1996-03-05
RU95113175A (ru) 1997-06-27
CA2154300A1 (en) 1996-01-21
ITMI941517A1 (it) 1996-01-20

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Effective date: 19970725