JP2002201450A - Adhesive composition, connecting method of circuit terminal using the same, and connected structure of circuit terminal - Google Patents
Adhesive composition, connecting method of circuit terminal using the same, and connected structure of circuit terminalInfo
- Publication number
- JP2002201450A JP2002201450A JP2000401499A JP2000401499A JP2002201450A JP 2002201450 A JP2002201450 A JP 2002201450A JP 2000401499 A JP2000401499 A JP 2000401499A JP 2000401499 A JP2000401499 A JP 2000401499A JP 2002201450 A JP2002201450 A JP 2002201450A
- Authority
- JP
- Japan
- Prior art keywords
- circuit
- connection terminal
- conductive particles
- adhesive composition
- adhesive layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 45
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 45
- 239000000203 mixture Substances 0.000 title claims abstract description 43
- 238000000034 method Methods 0.000 title claims abstract description 24
- 239000002245 particle Substances 0.000 claims abstract description 62
- 239000000463 material Substances 0.000 claims abstract description 38
- 239000012790 adhesive layer Substances 0.000 claims abstract description 31
- 239000003822 epoxy resin Substances 0.000 claims abstract description 21
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 21
- 238000010438 heat treatment Methods 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 239000010410 layer Substances 0.000 claims description 16
- 238000003825 pressing Methods 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 9
- 239000010931 gold Substances 0.000 claims description 9
- 229910052737 gold Inorganic materials 0.000 claims description 8
- -1 platinum group metals Chemical class 0.000 claims description 8
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 6
- 229920000620 organic polymer Polymers 0.000 claims description 5
- 229910052709 silver Inorganic materials 0.000 claims description 5
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 229920001721 polyimide Polymers 0.000 claims description 4
- 239000009719 polyimide resin Substances 0.000 claims description 4
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- 239000011135 tin Substances 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000011521 glass Substances 0.000 description 12
- 239000004593 Epoxy Substances 0.000 description 10
- 229920006287 phenoxy resin Polymers 0.000 description 10
- 239000013034 phenoxy resin Substances 0.000 description 10
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 9
- 230000001588 bifunctional effect Effects 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 229910000510 noble metal Inorganic materials 0.000 description 7
- 239000007787 solid Substances 0.000 description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 239000004973 liquid crystal related substance Substances 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 229930185605 Bisphenol Natural products 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000006087 Silane Coupling Agent Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 229920003986 novolac Polymers 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 229920000800 acrylic rubber Polymers 0.000 description 2
- 239000004840 adhesive resin Substances 0.000 description 2
- 229920006223 adhesive resin Polymers 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 150000004658 ketimines Chemical class 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- 239000003094 microcapsule Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- ZYAASQNKCWTPKI-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propan-1-amine Chemical compound CO[Si](C)(OC)CCCN ZYAASQNKCWTPKI-UHFFFAOYSA-N 0.000 description 1
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- HQQWNBSBUJLMLD-UHFFFAOYSA-N C(C)O[SiH3].NCCC[Si](OC)(OC)OC Chemical compound C(C)O[SiH3].NCCC[Si](OC)(OC)OC HQQWNBSBUJLMLD-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910001361 White metal Inorganic materials 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004841 bisphenol A epoxy resin Substances 0.000 description 1
- 239000004842 bisphenol F epoxy resin Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- 125000000687 hydroquinonyl group Chemical class C1(O)=C(C=C(O)C=C1)* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- KBJFYLLAMSZSOG-UHFFFAOYSA-N n-(3-trimethoxysilylpropyl)aniline Chemical compound CO[Si](OC)(OC)CCCNC1=CC=CC=C1 KBJFYLLAMSZSOG-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- AFEQENGXSMURHA-UHFFFAOYSA-N oxiran-2-ylmethanamine Chemical compound NCC1CO1 AFEQENGXSMURHA-UHFFFAOYSA-N 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000768 polyamine Chemical class 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000010969 white metal Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Structures Or Materials For Encapsulating Or Coating Semiconductor Devices Or Solid State Devices (AREA)
- Electric Connection Of Electric Components To Printed Circuits (AREA)
- Wire Bonding (AREA)
- Adhesive Tapes (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、接着剤組成物、そ
れを用いたCHIP-ON-GLASS実装(以下COG実装と呼
ぶ)またはCHIP-ON-FLEX(以下COF実装と呼ぶ)にお
ける回路端子の接続方法及び回路端子の接続構造に関す
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an adhesive composition, and a circuit terminal in a CHIP-ON-GLASS mounting (hereinafter referred to as COG mounting) or a CHIP-ON-FLEX (hereinafter referred to as COF mounting) using the same. The present invention relates to a connection method and a connection structure of circuit terminals.
【0002】[0002]
【従来の技術】液晶表示用ガラスパネルへの液晶駆動用
ICの実装は、液晶駆動用ICを直接ガラスパネル上に
回路接続部材で接合するCOG実装方法や、液晶駆動用
ICを金属配線を有するフレキシブルテープに接合しガ
ラスパネルと回路接続部材で接合するCOF実装方法が
用いられる。液晶表示の高精細化に伴い、液晶駆動用I
Cの電極である金バンプは狭ピッチ化、狭面積化してい
る。このため、接合材料中の導電粒子が隣接電極間に流
出し、ショートを発生させるといった問題や、バンプ上
に捕捉される接合材料中の導電粒子数が減少し、接続不
良を起こすといった問題がある。そこで、これらの問題
を解決するため、接合材料の少なくとも片面に絶縁性の
接着層を形成することで、COG実装及びCOF実装に
おける接合品質の低下を防ぐ方法が開発されている(例
えば特開平8−279371号公報)。2. Description of the Related Art A liquid crystal driving IC is mounted on a liquid crystal display glass panel by a COG mounting method in which the liquid crystal driving IC is directly joined to the glass panel by a circuit connecting member, or the liquid crystal driving IC has metal wiring. A COF mounting method of bonding to a flexible tape and bonding to a glass panel and a circuit connecting member is used. As the definition of liquid crystal displays has become higher,
The gold bump, which is the electrode of C, has a narrow pitch and a narrow area. For this reason, there is a problem that the conductive particles in the bonding material flow out between the adjacent electrodes, causing a short circuit, and a problem that the number of conductive particles in the bonding material captured on the bumps is reduced, resulting in poor connection. . In order to solve these problems, a method has been developed in which an insulating adhesive layer is formed on at least one surface of a bonding material to prevent a decrease in bonding quality in COG mounting and COF mounting (for example, Japanese Patent Application Laid-Open No. H08-208,1992). -279371).
【0003】[0003]
【発明が解決しようとする課題】しかしながら、上記接
続部材はバンプ面積が3000μm2未満となった場
合、バンプ上に捕捉される接合材料中の導電粒子数が減
少し、安定した接続抵抗値を得るのに十分ではなく、ま
た接続抵抗値を低下させるため、粒子の充填量を増やす
とショート発生率が上昇し、絶縁不良が発生するという
問題があった。本発明は、COG実装やCOF実装に対
して低抵抗の電気接続が得られ、かつショート発生のな
い電気・電子用の接着剤組成物、それを用いた回路端子
の接続方法及び回路端子の接続構造を提供するものであ
る。However, when the bump area of the connection member is less than 3000 μm 2 , the number of conductive particles in the bonding material captured on the bump is reduced, and a stable connection resistance value is obtained. However, there is a problem that when the filling amount of the particles is increased to increase the short-circuiting rate and the insulation failure occurs, the connection resistance value is lowered. The present invention provides an electric / electronic adhesive composition that provides low-resistance electrical connection to COG mounting and COF mounting and does not cause short circuit, a method for connecting circuit terminals using the same, and a method for connecting circuit terminals. Provides structure.
【0004】[0004]
【課題を解決するための手段】本発明は、〔1〕相対向
する回路電極間に介在され、相対向する回路電極を加圧
し、加圧方向の電極間を電気的に接続する接合材料にお
いて、少なくとも絶縁性の接着層と導電粒子を含有する
接着層からなる接合材料で各接着層は、(1)エポキシ
樹脂、(2)潜在性硬化剤、(3)フィルム形成材、
(4)導電粒子のいずれか3以上を必須成分として含有
する接着剤組成物であり、各接着層から構成される接合
材料の加熱加圧前の面積(A)と加熱加圧後の面積
(B)を用いて表される流動性(B)/(A)の値が
1.3〜2.0である接着剤組成物である。接合材料の
加熱加圧前の面積(A)と加熱加圧後の面積(B)を用
いて表される流動性(B)/(A)の値が1.3〜2.
0であり、流動性が1.3未満では流動性が悪く、良好
な接続が得られない場合があり、2.0を超えると、接
続端子、例えばバンプ上に捕捉される導電粒子の数が少
ないため、接続部分の電気抵抗値が上昇してしまう。 〔2〕接合材料が、(1)エポキシ樹脂、(2)潜在性
硬化剤、(3)フィルム形成材を必須成分として含有す
る絶縁性の接着層と、(1)エポキシ樹脂、(2)潜在
性硬化剤、(3)フィルム形成材、(4)導電粒子を必
須成分として含有する導電粒子を含有する接着層の2層
からなる上記〔1〕に記載の接着剤組成物である。 〔3〕導電粒子の表面が、有機高分子化合物で覆われて
いる上記〔1〕または上記〔2〕に記載の接着剤組成物
である。 〔4〕導電粒子を含有する接着層の厚みが、導電粒子の
粒径の3倍未満である上記〔1〕ないし上記〔3〕のい
ずれかに記載の接着剤組成物である。本発明の接着剤組
成物は、導電粒子を含有する層とその他の層とに分解し
た多層構成とすることができ、この時、導電粒子を含有
する接着層の厚みは、導電粒子の粒径の3倍未満である
のが好ましく、2倍未満がより好ましい。導電粒子を含
有する接着層の厚みが3倍以上の場合、導電粒子が隣接
電極間に流出する量が多くなり、絶縁性が低下するので
好ましくない。また、本発明は、〔5〕第一の接続端子
を有する第一の回路部材と、第二の接続端子を有する第
二の回路部材とを、第一の接続端子と第二の接続端子を
対向して配置し、前記対向配置した第一の接続端子と第
二の接続端子の間に前記〔1〕ないし前記〔4〕のいず
れかに記載の接着剤組成物を介在させ、加熱加圧して前
記対向配置した第一の接続端子と第二の接続端子を電気
的に接続させる回路端子の接続方法である。 〔6〕少なくとも一方の接続端子を有する回路部材がI
Cチップである上記〔5〕に記載の回路端子の接続方法
である。 〔7〕少なくとも一方の接続端子の表面が金、銀、錫、
白金族の金属、インジュウム−錫酸化物(ITO)から
選ばれる少なくとも一種で構成される上記〔5〕または
上記〔6〕に記載の回路端子の接続方法である。 〔8〕少なくとも一方の回路部材表面が窒化シリコン、
シリコーン化合物、ポリイミド樹脂から選ばれる少なく
とも一種でコーティングもしくは付着している上記
〔5〕ないし上記〔7〕のいずれかに記載の回路端子の
接続方法である。さらに、本発明は、According to the present invention, there is provided a bonding material which is interposed between opposing circuit electrodes, presses the opposing circuit electrodes, and electrically connects the electrodes in the pressing direction. A bonding material comprising at least an insulating adhesive layer and an adhesive layer containing conductive particles, each adhesive layer comprising: (1) an epoxy resin, (2) a latent curing agent, (3) a film forming material,
(4) An adhesive composition containing any three or more of the conductive particles as an essential component, and the area (A) of the bonding material composed of each adhesive layer before heating and pressing and the area after heating and pressing ( An adhesive composition having a fluidity (B) / (A) value of 1.3 to 2.0 expressed using B). The value of the fluidity (B) / (A) expressed using the area (A) of the joining material before the heating and pressing and the area (B) after the heating and pressing is 1.3 to 2.
If the fluidity is less than 1.3, the fluidity is poor and good connection may not be obtained in some cases. Since the number is small, the electric resistance value of the connection portion increases. [2] The bonding material is (1) an epoxy resin, (2) a latent curing agent, (3) an insulating adhesive layer containing a film-forming material as essential components, (1) an epoxy resin, and (2) a latent resin. The adhesive composition according to the above [1], which comprises two layers of a hardening agent, (3) a film forming material, and (4) an adhesive layer containing conductive particles containing conductive particles as an essential component. [3] The adhesive composition according to the above [1] or [2], wherein the surface of the conductive particles is covered with an organic polymer compound. [4] The adhesive composition according to any one of [1] to [3], wherein the thickness of the adhesive layer containing the conductive particles is less than three times the particle size of the conductive particles. The adhesive composition of the present invention can be formed into a multilayer structure decomposed into a layer containing conductive particles and other layers, and at this time, the thickness of the adhesive layer containing the conductive particles depends on the particle size of the conductive particles. It is preferably less than 3 times, more preferably less than 2 times. When the thickness of the adhesive layer containing the conductive particles is three times or more, the amount of the conductive particles flowing out between the adjacent electrodes increases, and the insulating property decreases, which is not preferable. In addition, the present invention relates to [5] a first circuit member having a first connection terminal, and a second circuit member having a second connection terminal, the first connection member and the second connection terminal. The adhesive composition according to any one of the above [1] to [4] is disposed between the first connection terminal and the second connection terminal which are disposed to face each other, and heated and pressed. And a circuit terminal for electrically connecting the first connection terminal and the second connection terminal arranged opposite to each other. [6] The circuit member having at least one connection terminal is I
The method for connecting circuit terminals according to the above [5], which is a C chip. [7] The surface of at least one of the connection terminals is gold, silver, tin,
The circuit terminal connection method according to the above [5] or [6], comprising at least one selected from a platinum group metal and indium-tin oxide (ITO). [8] at least one circuit member surface is silicon nitride,
The method of connecting a circuit terminal according to any one of the above [5] to [7], wherein the circuit terminal is coated or adhered with at least one selected from a silicone compound and a polyimide resin. Further, the present invention provides
〔9〕上記〔5〕
ないし上記〔8〕のいずれかに記載の回路端子の接続方
法で得られる回路端子の接続構造である。[9] The above [5]
To a circuit terminal connection structure obtained by the circuit terminal connection method according to any one of the above [8].
【0005】[0005]
【発明の実施の形態】本発明は、相対向する回路電極間
に介在され、相対向する回路電極を加熱加圧し、加圧方
向の電極間を電気的に接続する接合材料において、少な
くとも絶縁性の接着層と導電粒子を含有する接着層から
なる接合材料である。各接着層は、(1)エポキシ樹
脂、(2)潜在性硬化剤、(3)フィルム形成材、
(4)導電粒子のいずれか3以上を必須成分として含有
する接着剤組成物である。接合材料は、絶縁性の接着層
(Z)と導電粒子を含有する接着層(D)から構成さ
れ、その構成は、2層では、Z−Dが、3層では、Z−D
−Z、D−Z−Dが挙げられ、同様に4層以上の構成と
することもできる。そして、各接着層から構成される接
合材料の加熱加圧前の面積(A)と加熱加圧後の面積
(B)を用いて表される流動性(B)/(A)の値が
1.3〜2.0である必要がある。流動性が1.3未満
では流動性が悪く、良好な接続が得られない場合があ
り、2.0を超えると、接続端子、例えばバンプ上に捕
捉される導電粒子の数が少ないため、接続部分の電気抵
抗値が上昇してしまう。流動性の測定は、厚み0.7m
m、15mm×15mmのガラスを用いて、厚み35μ
m、5mm×5mmの接着剤組成物をこの2枚のガラス
間に挟み、200℃、2MPa、10秒で加熱加圧を行
い、初期の面積(A)と加熱加圧後の面積(B)から
(B)/(A)の値を求めた。この面積は、画像処理装
置などを用いても測定することができる。各接着層の厚
みが異なる場合、その厚みに比例させ接合材料の厚みが
35μmとなるようにした。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a bonding material interposed between opposed circuit electrodes for heating and pressing the opposed circuit electrodes and electrically connecting the electrodes in the pressing direction. And a bonding material containing conductive particles. Each adhesive layer is composed of (1) an epoxy resin, (2) a latent curing agent, (3) a film forming material,
(4) An adhesive composition containing any three or more of the conductive particles as an essential component. The bonding material is composed of an insulating adhesive layer (Z) and an adhesive layer (D) containing conductive particles. The structure is as follows: ZD for two layers, ZD for three layers.
-Z, DZD, and similarly, a configuration having four or more layers can be employed. Then, the value of the fluidity (B) / (A) expressed by using the area (A) before the heating and pressurizing and the area (B) after the heating and pressurizing of the bonding material composed of each adhesive layer is 1 .3 to 2.0. If the fluidity is less than 1.3, the fluidity is poor and good connection may not be obtained. If the fluidity is more than 2.0, the connection terminals, for example, the number of conductive particles trapped on the bumps is small, so The electric resistance value of the part increases. The flowability was measured at a thickness of 0.7 m.
m, using glass of 15 mm × 15 mm, thickness 35 μm
m, 5 mm × 5 mm adhesive composition is sandwiched between these two glasses, and heated and pressed at 200 ° C., 2 MPa, and 10 seconds, and the initial area (A) and the area after heated and pressed (B) From (B) / (A). This area can also be measured using an image processing device or the like. When the thickness of each adhesive layer was different, the thickness of the bonding material was 35 μm in proportion to the thickness.
【0006】接合材料を構成する絶縁性の接着層は、
(1)エポキシ樹脂、(2)潜在性硬化剤、(3)フィ
ルム形成材を必須成分として含有することが好ましく、
また、導電粒子を含有する接着層は、(1)エポキシ樹
脂、(2)潜在性硬化剤、(3)フィルム形成材、
(4)導電粒子を必須成分として含有することが好まし
い。導電粒子は、その導電粒子の表面が、有機高分子化
合物で覆われていることが好ましく、有機高分子化合物
の被覆はマイクロカプセルの手法に通常用いられている
方法を採用することができる。例えば、導電粒子に高分
子化合物のスプレー、浸漬乾燥などである。被覆厚み
は、絶縁性を有すればよく、極めて薄い厚みでもよい。
導電粒子を含有する接着層は、その厚みが、導電粒子の
粒径の3倍未満であると好ましい。導電粒子を含有する
接着層の厚みが3倍以上の場合、導電粒子が隣接電極間
に流出する量が多くなり、絶縁性が低下する傾向にあ
り、また、接続端子に保持される導電粒子の数が少なく
なるので、接続抵抗が高くなったり、接続信頼性に劣る
ようになる。[0006] The insulating adhesive layer constituting the bonding material is
It is preferable to contain (1) an epoxy resin, (2) a latent curing agent, and (3) a film-forming material as essential components,
Further, the adhesive layer containing the conductive particles includes (1) an epoxy resin, (2) a latent curing agent, (3) a film forming material,
(4) It is preferable to contain conductive particles as an essential component. The conductive particles preferably have the surface of the conductive particles covered with an organic polymer compound, and the coating of the organic polymer compound may be performed by a method usually used in a microcapsule technique. For example, spraying, immersion drying, and the like of a polymer compound on conductive particles are used. The coating thickness may be an insulating property, and may be an extremely thin thickness.
The thickness of the adhesive layer containing conductive particles is preferably less than three times the particle size of the conductive particles. When the thickness of the adhesive layer containing the conductive particles is three times or more, the amount of the conductive particles flowing out between the adjacent electrodes increases, and the insulating property tends to decrease. Since the number is reduced, connection resistance is increased and connection reliability is deteriorated.
【0007】本発明で使用する(1)エポキシ樹脂とし
ては、エピクロルヒドリンとビスフェノールAやF、A
D等から誘導されるビスフェノール型エポキシ樹脂、エ
ピクロルヒドリンとフェノールノボラックやクレゾール
ノボラックから誘導されるエポキシノボラック樹脂やナ
フタレン環を含んだ骨格を有するナフタレン系エポキシ
樹脂、グリシジルアミン、グリシジルエーテル、ビフェ
ニル、脂環式等の1分子内に2個以上のグリシジル基を
有する各種のエポキシ化合物等を単独にあるいは2種以
上を混合して用いることが可能である。これらのエポキ
シ樹脂は、不純物イオン(Na+、Cl-等)や、加水分
解性塩素等を300ppm以下に低減した高純度品を用
いることがエレクトロンマイグレーション防止のために
好ましい。[0007] The epoxy resin (1) used in the present invention includes epichlorohydrin and bisphenol A, F, A
Bisphenol-type epoxy resin derived from D or the like, epoxychlorohydrin and epoxy novolak resin derived from phenol novolak or cresol novolak, naphthalene-based epoxy resin having a skeleton containing a naphthalene ring, glycidylamine, glycidyl ether, biphenyl, alicyclic It is possible to use various epoxy compounds having two or more glycidyl groups in one molecule, etc. alone or as a mixture of two or more. It is preferable to use a high-purity epoxy resin in which impurity ions (Na + , Cl −, etc.), hydrolyzable chlorine and the like are reduced to 300 ppm or less for preventing electron migration.
【0008】本発明で使用する(2)潜在性硬化剤とし
ては、イミダゾール系、ヒドラジド系、三フッ化ホウ素
−アミン錯体、スルホニウム塩、アミンイミド、ポリア
ミンの塩、ジシアンジアミド等が挙げられる。これら
は、単独または混合して使用することができ、分解促進
剤、抑制剤等を混合して用いてもよい。また、これらの
硬化剤をポリウレタン系、ポリエステル系の高分子物質
等で被覆してマイクロカプセル化したものは、可使時間
が延長されるために好ましい。Examples of the latent curing agent (2) used in the present invention include imidazoles, hydrazides, boron trifluoride-amine complexes, sulfonium salts, amine imides, polyamine salts, and dicyandiamide. These may be used alone or as a mixture, and may be used in combination with a decomposition accelerator, an inhibitor and the like. A microcapsule obtained by coating these curing agents with a polyurethane-based or polyester-based polymer substance or the like is preferable because the pot life is extended.
【0009】本発明で使用する(3)フィルム形成材と
しては、フェノキシ樹脂、ポリビニルホルマール樹脂、
ポリスチレン樹脂、ポリビニルブチラール樹脂、ポリエ
ステル樹脂、ポリアミド樹脂、キシレン樹脂、ポリウレ
タン樹脂等が挙げられる。フィルム形成材とは、液状物
を固形化し、構成組成物をフィルム形状とした場合に、
そのフィルムの取扱いが容易で、容易に裂けたり、割れ
たり、べたついたりしない機械特性等を付与するもので
あり、通常の状態でフィルムとしての取扱いができるも
のである。フィルム形成材の中でも接着性、相溶性、耐
熱性、機械強度に優れることからフェノキシ樹脂が好ま
しい。フェノキシ樹脂は2官能フェノール類とエピハロ
ヒドリンを高分子量まで反応させるか、又は2官能エポ
キシ樹脂と2官能フェノール類を重付加させることによ
り得られる樹脂である。具体的には、2官能フェノール
類1モルとエピハロヒドリン0.985〜1.015と
をアルカリ金属水酸化物の存在下において非反応性溶媒
中で40〜120℃の温度で反応させることにより得る
ことができる。また、樹脂の機械的特性や熱的特性の点
からは、特に2官能性エポキシ樹脂と2官能性フェノー
ル類の配合当量比をエポキシ基/フェノール水酸基=1
/0.9〜1/1.1としアルカリ金属化合物、有機リ
ン系化合物、環状アミン系化合物等の触媒の存在下で沸
点が120℃以上のアミド系、エーテル系、ケトン系、
ラクトン系、アルコール系等の有機溶剤中で反応固形分
が50重量部以下で50〜200℃に加熱して重付加反
応させて得たものが好ましい。2官能エポキシ樹脂とし
ては、ビスフェノールA型エポキシ樹脂、ビスフェノー
ルF型エポキシ樹脂、ビスフェノールAD型エポキシ樹
脂、ビスフェノールS型エポキシ樹脂などがある。2官
能フェノール類は2個のフェノール性水酸基を持つもの
で、例えば、ハイドロキノン類、ビスフェノールA、ビ
スフェノールF、ビスフェノールAD、ビスフェノール
S等のビスフェノール類などが挙げられる。フェノキシ
樹脂はラジカル重合性の官能基により変性されていても
よい。フェノキシ樹脂は、単独で用いても、2種類以上
を混合して用いてもよい。The (3) film-forming material used in the present invention includes phenoxy resin, polyvinyl formal resin,
Polystyrene resin, polyvinyl butyral resin, polyester resin, polyamide resin, xylene resin, polyurethane resin and the like can be mentioned. Film forming material, when the liquid material is solidified and the constituent composition is in the form of a film,
The film is easy to handle and imparts mechanical properties and the like that are not easily torn, cracked or sticky, and can be handled as a film in a normal state. Phenoxy resins are preferred among the film-forming materials because of their excellent adhesiveness, compatibility, heat resistance, and mechanical strength. The phenoxy resin is a resin obtained by reacting a bifunctional phenol and epihalohydrin to a high molecular weight or by polyaddition of a bifunctional epoxy resin and a bifunctional phenol. Specifically, it is obtained by reacting 1 mol of bifunctional phenols with epihalohydrin 0.985 to 1.015 in a non-reactive solvent at a temperature of 40 to 120 ° C. in the presence of an alkali metal hydroxide. Can be. In addition, from the viewpoint of the mechanical and thermal properties of the resin, in particular, the blending equivalent ratio of the bifunctional epoxy resin and the bifunctional phenol is set such that epoxy group / phenol hydroxyl group = 1.
/0.9 to 1 / 1.1, amides, ethers, ketones having a boiling point of 120 ° C. or more in the presence of a catalyst such as an alkali metal compound, an organic phosphorus compound, or a cyclic amine compound;
Those obtained by heating at 50 to 200 ° C. in a lactone-based or alcohol-based organic solvent at a reaction solid content of 50 parts by weight or less and performing a polyaddition reaction are preferred. Examples of the bifunctional epoxy resin include a bisphenol A epoxy resin, a bisphenol F epoxy resin, a bisphenol AD epoxy resin, and a bisphenol S epoxy resin. Bifunctional phenols have two phenolic hydroxyl groups and include, for example, hydroquinones, bisphenols such as bisphenol A, bisphenol F, bisphenol AD, and bisphenol S. The phenoxy resin may be modified with a radically polymerizable functional group. The phenoxy resins may be used alone or as a mixture of two or more.
【0010】本発明の接着剤組成物には、アクリル酸、
アクリル酸エステル、メタクリル酸エステルまたはアク
リロニトリルのうち少なくとも一つをモノマー成分とし
た重合体又は共重合体を使用することができ、グリシジ
ルエーテル基を含有するグリシジルアクリレートやグリ
シジルメタクリレートを含む共重合体系アクリルゴムを
併用した場合、応力緩和に優れるので好ましい。これら
アクリルゴムの分子量(重量平均)は接着剤の凝集力を
高める点から20万以上が好ましい。本発明の接着剤組
成物には、さらに、充填剤、軟化剤、促進剤、老化防止
剤、難燃化剤、色素、チキソトロピック剤、カップリン
グ剤及びフェノール樹脂やメラミン樹脂、イソシアネー
ト類等を含有することもできる。充填剤を含有した場
合、接続信頼性等の向上が得られるので好ましい。充填
剤の最大径が導電粒子の粒径未満であれば使用でき、5
〜60体積部(接着剤樹脂成分100体積部に対して)
の範囲が好ましい。60体積部を超えると信頼性向上の
効果が飽和することがあり、5体積部未満では添加の効
果が少ない。[0010] The adhesive composition of the present invention comprises acrylic acid,
A copolymer or a copolymer containing at least one of acrylic acid ester, methacrylic acid ester and acrylonitrile as a monomer component can be used, and a copolymer acrylic rubber containing glycidyl acrylate or glycidyl methacrylate containing a glycidyl ether group can be used. The use of a combination of these is preferred because of excellent stress relaxation. The molecular weight (weight average) of these acrylic rubbers is preferably 200,000 or more from the viewpoint of increasing the cohesive strength of the adhesive. The adhesive composition of the present invention further includes a filler, a softener, an accelerator, an antioxidant, a flame retardant, a dye, a thixotropic agent, a coupling agent, a phenol resin, a melamine resin, and isocyanates. It can also be contained. When a filler is contained, it is preferable because an improvement in connection reliability and the like can be obtained. It can be used if the maximum diameter of the filler is smaller than the particle diameter of the conductive particles.
6060 parts by volume (per 100 parts by volume of adhesive resin component)
Is preferable. If it exceeds 60 parts by volume, the effect of improving reliability may be saturated, and if it is less than 5 parts by volume, the effect of addition is small.
【0011】カップリング剤としてはケチミン、ビニル
基、アクリル基、アミノ基、エポキシ基及びイソシアネ
ート基含有物が、接着性の向上の点から好ましい。具体
的には、アミノ基を有するシランカップリング剤とし
て、N−β(アミノエチル)γ−アミノプロピルトリメ
トキシシラン、N−β(アミノエチル)γ−アミノプロ
ピルメチルジメトキシシラン、γ−アミノプロピルトリ
エトキシシラン、N−フェニル−γ−アミノプロピルト
リメトキシシラン等が挙げられる。ケチミンを有するシ
ランカップリング剤として、上記のアミノ基を有するシ
ランカップリング剤に、アセトン、メチルエチルケト
ン、メチルイソブチルケトン等のケトン化合物を反応さ
せて得られたものが挙げられる。As the coupling agent, ketimine, a vinyl group, an acryl group, an amino group, an epoxy group and an isocyanate group-containing material are preferred from the viewpoint of improving the adhesiveness. Specifically, as a silane coupling agent having an amino group, N-β (aminoethyl) γ-aminopropyltrimethoxysilane, N-β (aminoethyl) γ-aminopropylmethyldimethoxysilane, γ-aminopropyltrimethoxysilane Ethoxysilane, N-phenyl-γ-aminopropyltrimethoxysilane and the like can be mentioned. Examples of the silane coupling agent having a ketimine include those obtained by reacting a silane coupling agent having an amino group with a ketone compound such as acetone, methyl ethyl ketone, and methyl isobutyl ketone.
【0012】本発明の接着剤組成物は導電粒子が無くて
も、接続時に相対向する回路電極の直接接触により接続
が得られるが、導電粒子を含有した場合、より安定した
接続が得られる。導電粒子としては、Au、Ag、N
i、Cu、はんだ等の金属粒子やカーボン等があり、十
分なポットライフを得るためには、表層はNi、Cu等
の遷移金属類ではなくAu、Ag、白金属の貴金属類が
好ましくAuがより好ましい。また、Ni等の遷移金属
類の表面をAu等の貴金属類で被覆したものでもよい。
また、非導電性のガラス、セラミック、プラスチック等
に前記した導通層を被覆等により形成し最外層を貴金属
類としたものでもよい。プラスチックに導通層を被覆等
により形成した場合や熱溶融金属粒子の揚合、加熱加圧
により変形性を有するので接続時に電極との接触面積が
増加し、回路部材の回路端子の厚みばらつきを吸収し信
頼性が向上するので好ましい。貴金属類の被覆層の厚み
は良好な抵抗を得るためには、100オングストローム
以上が好ましい。しかし、Ni等の遷移金属の上に貴金
属類の層をもうける揚合では、貴金属類層の欠損や導電
粒子の混合分散時に生じる貴金属類層の欠損等により生
じる酸化還元作用で遊離ラジカルが発生し保存性低下を
引き起こすため、300オングストローム以上が好まし
い。そして、厚くなるとそれらの効果が飽和してくるの
で最大1μmにするのが望ましいが制限するものではな
い。導電粒子は、接着剤樹脂成分100体積部に対して
0.1〜30体積部の範囲で用途により使い分ける。過
剰な導電粒子による隣接回路の短絡等を防止するために
は0.1〜10体積部とするのがより好ましい。The adhesive composition of the present invention can be connected by direct contact of opposing circuit electrodes at the time of connection even without conductive particles, but more stable connection can be obtained when the adhesive composition contains conductive particles. Au, Ag, N as conductive particles
There are metal particles such as i, Cu, solder, and carbon, and the like. In order to obtain a sufficient pot life, the surface layer is preferably made of noble metals such as Au, Ag, and white metal instead of transition metals such as Ni and Cu. More preferred. Further, the surface of a transition metal such as Ni may be coated with a noble metal such as Au.
Further, the conductive layer described above may be formed on a nonconductive glass, ceramic, plastic, or the like by coating or the like, and the outermost layer may be made of a noble metal. When a conductive layer is formed on a plastic by coating, etc., or when it is deformed by fusing and heating and pressing of hot-melt metal particles, the contact area with the electrode increases during connection, and the thickness variation of the circuit terminal of the circuit member is absorbed. This is preferable because the reliability is improved. The thickness of the noble metal coating layer is preferably 100 Å or more in order to obtain good resistance. However, when a layer of a noble metal is formed on a transition metal such as Ni, free radicals are generated due to oxidation-reduction caused by a defect of the noble metal layer or a defect of the noble metal layer caused by mixing and dispersing conductive particles. In order to cause deterioration in storage stability, the thickness is preferably 300 Å or more. When the thickness increases, their effects become saturated. Therefore, it is preferable to set the thickness to 1 μm at the maximum, but there is no limitation. The conductive particles are properly used in a range of 0.1 to 30 parts by volume based on 100 parts by volume of the adhesive resin component. In order to prevent a short circuit or the like in an adjacent circuit due to excessive conductive particles, the content is more preferably 0.1 to 10 parts by volume.
【0013】本発明の接着剤組成物は、COG実装やC
OF実装における、フレキシブルテープやガラス基板と
ICチップとの接着用のフィルム状接着剤として使用す
ることもできる。すなわち、第一の接続端子を有する第
一の回路部材と、第二の接続端子を有する第二の回路部
材とを第一の接続端子と第二の接続端子を対向して配置
し、前記対向配置した第一の接続端子と第二の接続端子
の間に本発明の接着剤組成物(フィルム状接着剤)を介
在させ、加熱加圧して前記対向配置した第一の接続端子
と第二の接続端子を電気的に接続させることができる。
これらの回路部材には接続端子が通常は多数(場合によ
っては単数でもよい)設けられており、前記回路部材の
少なくとも1組をそれらの回路部材に設けられた接続端
子の少なくとも一部を対向配置し、対向配置した接続端
子間に本発明の接着剤を介在させ、加熱加圧することで
対向配置した接続端子同士を電気的に接続して回路板と
する。回路部材の少なくとも1組を加熱加圧することに
より、対向配置した接続端子同士は、直接接触により又
は接着剤組成物中の導電粒子を介して電気的に接続する
ことができる。The adhesive composition of the present invention can be used for COG mounting or C
It can also be used as a film adhesive for bonding a flexible tape or a glass substrate to an IC chip in OF mounting. That is, a first circuit member having a first connection terminal and a second circuit member having a second connection terminal are arranged such that the first connection terminal and the second connection terminal are opposed to each other. The adhesive composition (film-like adhesive) of the present invention is interposed between the arranged first connection terminal and the second connection terminal, and heated and pressurized, and the first connection terminal and the second connection terminal arranged opposite to each other are heated and pressed. The connection terminals can be electrically connected.
These circuit members are usually provided with a large number of connection terminals (in some cases, a single terminal may be provided), and at least one set of the circuit members may be provided with at least a part of the connection terminals provided on the circuit members facing each other. Then, the adhesive of the present invention is interposed between the opposed connection terminals, and the connection terminals opposed to each other are electrically connected to each other by heating and pressing to form a circuit board. By heating and pressurizing at least one set of circuit members, the connection terminals arranged opposite to each other can be electrically connected to each other by direct contact or via conductive particles in the adhesive composition.
【0014】本発明の回路端子の接続方法は、本発明の
接着剤組成物を、接続端子の表面が、金、銀、錫、白金
族の金属、インジュウム−錫酸化物(ITO)から選ば
れる少なくとも一種から構成される接続端子(電極回
路)に形成した後、もう一方の接続端子(回路電極)を
位置合わせし加熱加圧して接続することができる。この
とき、一方の回路部材側から光を照射してもよい。本発
明においては、フレキシブルテープがポリイミド樹脂等
の有機絶縁物質、ガラス基板の表面が窒化シリコン、シ
リコーン化合物、ポリイミド樹脂、シリコーン樹脂から
選ばれる少なくとも一種でコーティングもしくは付着し
た回路部材に対して特に良好な接着強度が得られる電気
・電子用の接着剤組成物、それを用いた回路端子の接続
方法及び回路端子の接続構造の提供が可能となる。In the method for connecting circuit terminals of the present invention, the adhesive composition of the present invention is used, and the surface of the connection terminal is selected from gold, silver, tin, platinum group metals, and indium-tin oxide (ITO). After forming at least one type of connection terminal (electrode circuit), the other connection terminal (circuit electrode) can be positioned, heated and pressed, and connected. At this time, light may be emitted from one of the circuit members. In the present invention, the flexible tape is an organic insulating material such as a polyimide resin, the surface of a glass substrate is particularly good for a circuit member coated or adhered with at least one selected from silicon nitride, a silicone compound, a polyimide resin, and a silicone resin. It is possible to provide an electric / electronic adhesive composition capable of obtaining an adhesive strength, a circuit terminal connection method using the same, and a circuit terminal connection structure.
【0015】(実施例1)ビスフェノールA型エポキシ
樹脂とビスフェノールAからガラス転移温度が80℃の
フェノキシ樹脂を合成した。この樹脂50gを、重量比
でトルエン(沸点110.6℃)/酢酸エチル(沸点7
7.1℃)=50/50の混合溶剤に溶解して、固形分
40重量%の溶液とした。固形重量比でフェノキシ樹脂
40g、マイクロカプセル型潜在性硬化剤を含有する
液状エポキシ(HX3941HP;旭化成工業株式会社
製商品名、エポキシ当量185)60gとなるように配
合し、導電粒子(ポリスチレンを核とする粒子の表面に
厚み0.2μmのニッケル層、その外側に厚み0.04
μmの金層を設けた平均粒径5μm粒子にPVA溶液に
より数〜数百Åの厚さに被覆)を5体積%配合分散さ
せ、厚み80μmの片面を表面処理したPET(ポリエ
チレンテレフタレート)フィルムに塗工装置を用いて塗
布し、70℃、10分の熱風乾燥により、接着剤層の厚
みが10μmのフィルム状接着剤組成物を得た。また、
固形重量比でフェノキシ樹脂 40g、マイクロカプセ
ル型潜在性硬化剤を含有する液状エポキシ(エポキシ当
量185)60gとなるように配合し、厚み80μmの
片面を表面処理したPET(ポリエチレンテレフタレー
ト)フィルムに塗工装置を用いて塗布し、70℃、10
分の熱風乾燥により、接着剤層の厚みが10μmのフィ
ルム状接着剤組成物を得た。これらの接着剤組成物をラ
ミネーターを用い貼り合わせ、二層構成のフィルム状接
着剤組成物を得た。Example 1 A phenoxy resin having a glass transition temperature of 80 ° C. was synthesized from bisphenol A type epoxy resin and bisphenol A. 50 g of this resin was mixed with toluene (boiling point 110.6 ° C.) / Ethyl acetate (boiling point 7
(7.1 ° C.) = 50/50 mixed solvent to obtain a solution having a solid content of 40% by weight. The phenolic resin was mixed in a solid weight ratio of 40 g, and a liquid epoxy containing a microcapsule-type latent curing agent (HX3941HP; trade name of Asahi Kasei Kogyo Co., Ltd., epoxy equivalent: 185) was blended so as to be 60 g. A 0.2 μm thick nickel layer on the surface of
5% by volume of PVA solution is dispersed and dispersed in PVA solution to 5 μm average particle diameter provided with a μm gold layer, and a 80 μm thick PET (polyethylene terephthalate) film having one surface treated. It was applied using a coating apparatus and dried at 70 ° C. for 10 minutes with hot air to obtain a film-shaped adhesive composition having an adhesive layer thickness of 10 μm. Also,
40 g of a phenoxy resin and 60 g of a liquid epoxy (epoxy equivalent: 185) containing a microcapsule-type latent curing agent in a solid weight ratio are applied to a PET (polyethylene terephthalate) film having a thickness of 80 μm and a surface treated on one side. Coating using a device, 70 ° C, 10
By drying with hot air for one minute, a film adhesive composition having an adhesive layer thickness of 10 μm was obtained. These adhesive compositions were bonded together using a laminator to obtain a two-layered film adhesive composition.
【0016】(実施例2)固形重量比でフェノキシ樹脂
35g、マイクロカプセル型潜在性硬化剤を含有する
液状エポキシ(エポキシ当量185)65gとなるよう
に配合したほかは実施例1と同様にして二層構成のフィ
ルム状接着剤組成物を得た。Example 2 The same procedure as in Example 1 was repeated except that 35 g of a phenoxy resin and 65 g of a liquid epoxy containing a microcapsule-type latent curing agent (epoxy equivalent: 185) were added in a solid weight ratio of 35 g. A layered film adhesive composition was obtained.
【0017】(比較例1)固形重量比でフェノキシ樹脂
30g、マイクロカプセル型潜在性硬化剤を含有する
液状エポキシ(エポキシ当量185)70gとしたほか
は実施例1と同様にして二層構成のフィルム状接着剤組
成物を得た。Comparative Example 1 A two-layer film was prepared in the same manner as in Example 1 except that the solid weight ratio was changed to 30 g of phenoxy resin and 70 g of liquid epoxy (epoxy equivalent: 185) containing a microcapsule-type latent curing agent. An adhesive composition was obtained.
【0018】(回路の接続)バンプ面積50μm×50
μm、ピッチ100μm、高さ20μmの金バンプを配
置したICチップと厚み1.1mmのガラス上にインジ
ュウム−錫酸化物(ITO)を蒸着により形成したIT
O基板(表面抵抗、<20Ω/□)とを、上記接着剤組
成物を用い、石英ガラスと加圧ヘッドで挟み、200
℃、100MPa(バンプ面積換算)で10秒間加熱加
圧して接続した。このとき、フィルム状接着剤組成物は
あらかじめITO基板上に、接着剤組成物の接着面を7
0℃、0.5MPa(バンプ面積換算)で5秒間加熱加
圧して貼り付け、その後、PETフィルムを剥離してI
Cチップと接続した。 (流動性の測定)厚み0.7mm、15mm×15mm
のガラスを用いて、厚み35μm、5mm×5mmの回
路接続用樹脂組成物からなる回路用接続材料をこのガラ
スに挟み、200℃、2MPa、10秒で加熱加圧を行
い、初期の面積(A)と加熱加圧後の面積(B)から
(B)/(A)の値を求めた。 (バンプ上捕捉粒子数の測定)回路の接続後、ガラス側
からバンプを金属顕微鏡(倍率200倍)で観察し、バ
ンプ上の導電粒子数をカウントし平均値を求めた。 (接続抵抗の測定)回路の接続後接続部の電気抵抗値
を、初期と、−40℃/30分と100℃/30分の温
度サイクル槽中に500サイクル保持した後に2端子測
定法を用いマルチメータで測定した。それらの測定結果
を表1に示した。(Circuit connection) Bump area 50 μm × 50
An IC chip on which gold bumps having a pitch of 100 μm and a height of 20 μm are arranged, and an indium tin oxide (ITO) formed on a 1.1 mm thick glass by vapor deposition.
An O substrate (surface resistance, <20Ω / □) was sandwiched between quartz glass and a pressure head using the above-mentioned adhesive composition.
The connection was made by heating and pressing at 100 ° C. and 100 MPa (bump area conversion) for 10 seconds. At this time, the adhesive surface of the adhesive composition was previously coated on the ITO substrate by 7 minutes.
At 0 ° C, 0.5MPa (converted to bump area), heat and pressure for 5 seconds to adhere, then peel off the PET film and
Connected to C chip. (Measurement of fluidity) Thickness 0.7 mm, 15 mm x 15 mm
A circuit connecting material made of a resin composition for circuit connecting having a thickness of 35 μm and 5 mm × 5 mm was sandwiched between the glasses, and heated and pressed at 200 ° C., 2 MPa, and 10 seconds to obtain an initial area (A ) And the area (B) after heating and pressing, the value of (B) / (A) was determined. (Measurement of Number of Trapped Particles on Bump) After connection of the circuit, the bumps were observed from the glass side with a metallographic microscope (magnification: 200 times), and the number of conductive particles on the bumps was counted to obtain an average value. (Measurement of connection resistance) After the circuit was connected, the electric resistance value of the connection portion was initially kept at 500 cycles in a temperature cycle bath of −40 ° C./30 minutes and 100 ° C./30 minutes, and then a two-terminal measurement method was used. It was measured with a multimeter. Table 1 shows the measurement results.
【0019】[0019]
【表1】 [Table 1]
【0020】フィルム形成材として用いたフェノキシ樹
脂の配合量が少なく、エポキシ樹脂の配合量が多くなる
と流動性が増加してくる。流動性が増加するとバンプ上
の導電粒子数が減少してくる。粒子数が減少すると温度
サイクル試験後の接続信頼性を評価する接続抵抗の大幅
な増加が見られ、20Ω以上にもなる。本発明の接合材
料の流動性が1.3〜2.0の範囲では、初期と信頼性
試験後の接続抵抗が両者で低く良好な結果を示す。一
方、比較例1の流動性が2.5では、初期値の接続抵抗
は低く良好であるが、信頼性試験後の接続抵抗は著しく
大きくなり回路部材の接合材料には適しない。また、種
々実験した結果、導電粒子を含有する接着層の厚みが、
導電粒子の粒径の3倍未満であると、バンプ上に捕捉さ
れる導電粒子の数が多くなり接続抵抗が低い状態を維持
することができた。さらに、流動性が1.3未満では、流
動性が悪く気泡の巻き込みを生じ良好な接続が得られな
かった。導電粒子が有機高分子で覆われている場合、流
動性に大きな影響はないが、隣接接続端子間のショート
の発生がなく絶縁不良が解消される。また、導電粒子の
充填量を増やし、確実な接続を確保することができた。When the amount of the phenoxy resin used as the film forming material is small and the amount of the epoxy resin is large, the fluidity increases. As the fluidity increases, the number of conductive particles on the bump decreases. When the number of particles decreases, the connection resistance for evaluating the connection reliability after the temperature cycle test greatly increases, and reaches as high as 20Ω or more. When the fluidity of the bonding material of the present invention is in the range of 1.3 to 2.0, both the initial and the connection resistance after the reliability test are low, and good results are shown. On the other hand, when the fluidity of Comparative Example 1 is 2.5, the initial value of the connection resistance is low and good, but the connection resistance after the reliability test is remarkably large and is not suitable as a bonding material for circuit members. Also, as a result of various experiments, the thickness of the adhesive layer containing the conductive particles,
When the diameter was less than three times the particle diameter of the conductive particles, the number of the conductive particles captured on the bumps increased, and the state where the connection resistance was low could be maintained. Further, when the fluidity is less than 1.3, the fluidity is poor and bubbles are involved, so that a good connection cannot be obtained. When the conductive particles are covered with the organic polymer, there is no significant effect on the fluidity, but there is no short circuit between adjacent connection terminals and the insulation failure is eliminated. In addition, the filling amount of the conductive particles was increased, and a reliable connection could be secured.
【0021】[0021]
【発明の効果】本発明によれば、COG実装やCOF実
装において、バンプ面積の小さい駆動用ICであっても
低抵抗の電気接続が得られる、電気・電子用の接着剤組
成物、それを用いた回路端子の接続方法及び回路端子の
接続構造の提供が可能となる。According to the present invention, there is provided an adhesive composition for electric / electronic use which can provide a low-resistance electric connection even in a driving IC having a small bump area in COG mounting or COF mounting. It is possible to provide the connection method of the used circuit terminals and the connection structure of the circuit terminals.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) H01L 23/29 H01R 11/01 501C 23/31 H05K 3/32 B H01R 11/01 501 H01L 23/30 B H05K 3/32 (72)発明者 廣澤 幸寿 茨城県下館市大字五所宮1150番地 日立化 成工業株式会社五所宮事業所内 (72)発明者 藤井 正規 茨城県下館市大字五所宮1150番地 日立化 成工業株式会社五所宮事業所内 Fターム(参考) 4J004 AA10 AA13 BA03 CC02 CE01 DA03 DB02 FA05 4J040 DB021 DB022 DD021 DD022 EB081 EB082 EC041 EC042 EC061 EC062 EC071 EC072 EC081 EC082 EC121 EC122 ED001 ED002 EE061 EE062 EF031 EF032 EG001 EG002 HA026 HA066 HC01 HC15 HC16 HC18 HC23 HD18 JA09 JA12 JB02 JB10 KA14 KA32 KA42 LA09 MA02 MA04 MA10 NA20 4M109 AA02 BA05 BA07 CA22 EA02 EA20 EB02 EB18 EC07 5E319 AA03 AC04 AC11 BB11 GG01 GG20 5F044 KK03 KK06 LL07 LL11 RR17 RR18 RR19 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) H01L 23/29 H01R 11/01 501C 23/31 H05K 3/32 B H01R 11/01 501 H01L 23/30 B H05K 3/32 (72) Inventor Yukihisa Hirosawa 1150 Goshomiya, Shimodate-shi, Ibaraki Pref.Hitachi Kasei Kogyo Co., Ltd. Goshomiya Office Co., Ltd. F-term (reference) 4J004 AA10 AA13 BA03 CC02 CE01 DA03 DB02 FA05 4J040 DB021 DB022 DD021 DD022 EB081 EB082 EC041 EC042 EC061 EC062 EC071 EC072 EC081 EC082 EC121 EC122 ED001 ED002 EE061 EF06 EE061 EF06 EE061 HC18 HC23 HD18 JA09 JA12 JB02 JB10 KA14 KA32 KA42 LA09 MA02 MA04 MA10 NA20 4M109 AA02 BA05 BA07 CA2 2 EA02 EA20 EB02 EB18 EC07 5E319 AA03 AC04 AC11 BB11 GG01 GG20 5F044 KK03 KK06 LL07 LL11 RR17 RR18 RR19
Claims (9)
向する回路電極を加圧し、加圧方向の電極間を電気的に
接続する接合材料において、少なくとも絶縁性の接着層
と導電粒子を含有する接着層からなる接合材料で各接着
層は、(1)エポキシ樹脂、(2)潜在性硬化剤、
(3)フィルム形成材、(4)導電粒子のいずれか3以
上を必須成分として含有する接着剤組成物であり、各接
着層から構成される接合材料の加熱加圧前の面積(A)
と加熱加圧後の面積(B)を用いて表される流動性
(B)/(A)の値が1.3〜2.0である接着剤組成
物。1. A bonding material interposed between opposing circuit electrodes, pressurizing the opposing circuit electrodes, and electrically connecting the electrodes in the pressing direction with at least an insulating adhesive layer and conductive particles. Each bonding layer is composed of (1) an epoxy resin, (2) a latent curing agent,
(3) An adhesive composition containing, as an essential component, at least three of a film-forming material and (4) conductive particles, and the area (A) of a bonding material composed of each adhesive layer before heating and pressing.
And an adhesive composition having a fluidity (B) / (A) value of 1.3 to 2.0 expressed by using an area (B) after heating and pressing.
(2)潜在性硬化剤、(3)フィルム形成材を必須成分
として含有する絶縁性の接着層と、(1)エポキシ樹
脂、(2)潜在性硬化剤、(3)フィルム形成材、
(4)導電粒子を必須成分として含有する導電粒子を含
有する接着層の2層からなる請求項1に記載の接着剤組
成物。2. A bonding material comprising: (1) an epoxy resin;
(2) a latent curing agent, (3) an insulating adhesive layer containing a film forming material as an essential component, (1) an epoxy resin, (2) a latent curing agent, (3) a film forming material,
(4) The adhesive composition according to claim 1, comprising an adhesive layer containing conductive particles containing conductive particles as an essential component.
覆われている請求項1または請求項2に記載の接着剤組
成物。3. The adhesive composition according to claim 1, wherein the surface of the conductive particles is covered with an organic polymer compound.
電粒子の粒径の3倍未満である請求項1ないし請求項3
のいずれかに記載の接着剤組成物。4. The method according to claim 1, wherein the thickness of the adhesive layer containing the conductive particles is less than three times the particle diameter of the conductive particles.
The adhesive composition according to any one of the above.
と、第二の接続端子を有する第二の回路部材とを、第一
の接続端子と第二の接続端子を対向して配置し、前記対
向配置した第一の接続端子と第二の接続端子の間に請求
項1ないし請求項4のいずれかに記載の接着剤組成物を
介在させ、加熱加圧して前記対向配置した第一の接続端
子と第二の接続端子を電気的に接続させる回路端子の接
続方法。5. A first circuit member having a first connection terminal and a second circuit member having a second connection terminal are arranged with the first connection terminal and the second connection terminal facing each other. The adhesive composition according to any one of claims 1 to 4, wherein the adhesive composition according to any one of claims 1 to 4 is interposed between the first connection terminal and the second connection terminal disposed opposite to each other, and heated and pressurized to form the second connection terminal. A connection method of a circuit terminal for electrically connecting one connection terminal and a second connection terminal.
部材がICチップである請求項5に記載の回路端子の接
続方法。6. The method according to claim 5, wherein the circuit member having at least one connection terminal is an IC chip.
銀、錫、白金族の金属、インジュウム−錫酸化物(IT
O)から選ばれる少なくとも一種で構成される請求項5
または請求項6に記載の回路端子の接続方法。7. The surface of at least one connection terminal is gold,
Silver, tin, platinum group metals, indium-tin oxide (IT
6. A structure comprising at least one selected from O).
Alternatively, the method for connecting circuit terminals according to claim 6.
リコン、シリコーン化合物、ポリイミド樹脂から選ばれ
る少なくとも一種でコーティングもしくは付着している
請求項5ないし請求項7のいずれかに記載の回路端子の
接続方法。8. The method according to claim 5, wherein at least one surface of the circuit member is coated or adhered with at least one selected from silicon nitride, a silicone compound, and a polyimide resin. .
載の回路端子の接続方法で得られる回路端子の接続構
造。9. A connection structure for circuit terminals obtained by the method for connecting circuit terminals according to claim 5. Description:
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|---|---|---|---|
| JP2000401499A JP2002201450A (en) | 2000-12-28 | 2000-12-28 | Adhesive composition, connecting method of circuit terminal using the same, and connected structure of circuit terminal |
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|---|---|---|---|
| JP2000401499A JP2002201450A (en) | 2000-12-28 | 2000-12-28 | Adhesive composition, connecting method of circuit terminal using the same, and connected structure of circuit terminal |
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| JP2002201450A true JP2002201450A (en) | 2002-07-19 |
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ID=18865924
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| JP2002203871A (en) * | 2000-12-28 | 2002-07-19 | Hitachi Chem Co Ltd | Adhesive composite, method for connecting circuit terminal using the same and structure of connecting circuit terminal |
| JP2006233203A (en) * | 2005-01-31 | 2006-09-07 | Asahi Kasei Electronics Co Ltd | Anisotropically electroconductive adhesive film |
| JP2006233200A (en) * | 2005-01-31 | 2006-09-07 | Asahi Kasei Electronics Co Ltd | Anisotropically electroconductive adhesive film |
| JP2006233202A (en) * | 2005-01-31 | 2006-09-07 | Asahi Kasei Electronics Co Ltd | Anisotropically electroconductive adhesive film for circuit connection |
| JP2006233201A (en) * | 2005-01-31 | 2006-09-07 | Asahi Kasei Electronics Co Ltd | Anisotropically electroconductive adhesive film |
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| JP2008248099A (en) * | 2007-03-30 | 2008-10-16 | Namics Corp | Liquid semiconductor encapsulant and semiconductor device encapsulated using the same |
| WO2010007817A1 (en) * | 2008-07-16 | 2010-01-21 | ソニーケミカル&インフォメーションデバイス株式会社 | Anisotropic conductive adhesive |
| JP2010016388A (en) * | 2009-07-13 | 2010-01-21 | Hitachi Chem Co Ltd | Circuit connecting method |
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