JP2003174145A5 - - Google Patents

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JP2003174145A5
JP2003174145A5 JP2002224451A JP2002224451A JP2003174145A5 JP 2003174145 A5 JP2003174145 A5 JP 2003174145A5 JP 2002224451 A JP2002224451 A JP 2002224451A JP 2002224451 A JP2002224451 A JP 2002224451A JP 2003174145 A5 JP2003174145 A5 JP 2003174145A5
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film
memory device
hydrogen barrier
ferroelectric
line direction
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半導体基板上の層間絶縁膜の上に順次形成された下部電極、強誘電体膜よりなる容量絶縁膜及び上部電極を有し、ワード線方向及びビット線方向に配置された複数の強誘電体キャパシタを備えた強誘電体メモリ装置であって、
複数の前記上部電極を覆うように設けられた絶縁性又は導電性の第1の水素バリア膜を備え、
前記第1の水素バリア膜は、ワード線方向及びビット線方向のうちの一方向に並ぶ前記複数の強誘電体キャパシタよりなるキャパシタ列毎に分離して形成されていることを特徴とする強誘電体メモリ装置。
A plurality of ferroelectric capacitors having a lower electrode, a capacitor insulating film made of a ferroelectric film, and an upper electrode sequentially formed on an interlayer insulating film on a semiconductor substrate, and arranged in a word line direction and a bit line direction A ferroelectric memory device comprising:
An insulating or conductive first hydrogen barrier film provided to cover the plurality of upper electrodes;
The first hydrogen barrier film is formed separately for each capacitor row composed of the plurality of ferroelectric capacitors arranged in one of a word line direction and a bit line direction. Body memory device.
半導体基板上の層間絶縁膜の上に順次形成された下部電極、強誘電体膜よりなる容量絶縁膜及び上部電極を有し、ワード線方向及びビット線方向に配置された複数の強誘電体キャパシタを備えた強誘電体メモリ装置であって、A plurality of ferroelectric capacitors having a lower electrode, a capacitor insulating film made of a ferroelectric film, and an upper electrode sequentially formed on an interlayer insulating film on a semiconductor substrate, and arranged in a word line direction and a bit line direction A ferroelectric memory device comprising:
複数の前記上部電極を覆うように設けられた絶縁性又は導電性の第1の水素バリア膜を備え、An insulating or conductive first hydrogen barrier film provided to cover the plurality of upper electrodes;
前記第1の水素バリア膜は、ワード線方向及びビット線方向のうちの一方向に並ぶ前記複数の強誘電体キャパシタよりなるキャパシタ列のうち、ワード線方向及びビット線方向のうちの他方向に隣り合う一対のキャパシタ列を覆うように形成されていることを特徴とする強誘電体メモリ装置。The first hydrogen barrier film is formed in the other direction of the word line direction and the bit line direction in the capacitor row composed of the plurality of ferroelectric capacitors arranged in one direction of the word line direction and the bit line direction. A ferroelectric memory device formed so as to cover a pair of adjacent capacitor rows.
前記複数の強誘電体キャパシタのうち、前記一方向に並ぶ複数の強誘電体キャパシタの前記下部電極同士の間に埋め込まれた絶縁性の第2の水素バリア膜をさらに備えていることを特徴とする請求項1または請求項2記載の強誘電体メモリ装置。An insulating second hydrogen barrier film embedded between the lower electrodes of the plurality of ferroelectric capacitors arranged in one direction among the plurality of ferroelectric capacitors is further provided. The ferroelectric memory device according to claim 1 or 2. 前記上部電極は、前記一方向に並ぶ前記複数の強誘電体キャパシタに共通に形成されていることを特徴とする請求項1または請求項2記載の強誘電体メモリ装置。3. The ferroelectric memory device according to claim 1, wherein the upper electrode is formed in common for the plurality of ferroelectric capacitors arranged in the one direction. 前記層間絶縁膜に形成されているコンタクトプラグと前記下部電極との間に形成された導電性の第3の水素バリア膜をさらに備えていることを特徴とする請求項1または請求項2に記載の強誘電体メモリ装置。According to claim 1 or 2, characterized in that it further comprises a third hydrogen barrier film formed conductive between the interlayer insulating film is formed the contact plug and the lower electrode Ferroelectric memory device. 前記一方向に並ぶ前記複数の強誘電体キャパシタよりなるキャパシタ列は、前記第1の水素バリア膜、前記第2の水素バリア膜及び前記第3の水素バリア膜によって完全に覆われていることを特徴とする請求項5に記載の強誘電体メモリ装置。A capacitor row composed of the plurality of ferroelectric capacitors arranged in one direction is completely covered by the first hydrogen barrier film, the second hydrogen barrier film, and the third hydrogen barrier film . 6. The ferroelectric memory device according to claim 5 , wherein: 前記共通の上部電極と前記第1の水素バリア膜との間に形成され、前記共通の上部電極の周縁部に形成される段差を緩和する段差緩和膜をさらに備えていることを特徴とする請求項4に記載の強誘電体メモリ装置。 Claims said common upper electrode and formed between the first hydrogen barrier film, characterized in that it comprises further the step reducing film for alleviating the step formed on the peripheral portion of said common upper electrode Item 5. The ferroelectric memory device according to Item 4 . 前記第2の水素バリア膜は、Si34膜、SiON膜、Al23膜、TiO2 膜、又はTiとAlとの合金の酸化物膜若しくは酸窒化物膜よりなることを特徴とする請求項3に記載の強誘電体メモリ装置。 The second hydrogen barrier film is made of a Si 3 N 4 film, a SiON film, an Al 2 O 3 film, a TiO 2 film, or an oxide film or oxynitride film of an alloy of Ti and Al. The ferroelectric memory device according to claim 3 . 前記第1の水素バリア膜は、Si34膜、SiON膜、Al23膜、TiO2 膜、TiN膜若しくはTiとAlとの合金膜、又はTiとAlとの合金の酸化物膜、窒化物膜若しくは酸窒化物膜よりなることを特徴とする請求項1に記載の強誘電体メモリ装置。 The first hydrogen barrier film is a Si 3 N 4 film, a SiON film, an Al 2 O 3 film, a TiO 2 film, a TiN film, an alloy film of Ti and Al, or an oxide film of an alloy of Ti and Al. 2. The ferroelectric memory device according to claim 1 , comprising a nitride film or an oxynitride film. 前記第3の水素バリア膜は、TiとAlとの合金膜、TiとAlとの合金の窒化物膜若しくは酸窒化物膜、又はTiN膜よりなることを特徴とする請求項5に記載の強誘電体メモリ装置。The strong hydrogen film according to claim 5 , wherein the third hydrogen barrier film is made of an alloy film of Ti and Al, a nitride film or an oxynitride film of an alloy of Ti and Al, or a TiN film. Dielectric memory device. 半導体基板上の層間絶縁膜の上に順次形成された下部電極、強誘電体膜よりなる容量絶縁膜及び上部電極を有し、ワード線方向及びビット線方向に配置された複数の強誘電体キャパシタを備えた強誘電体メモリ装置の製造方法であって、
前記層間絶縁膜の上に、前記複数の強誘電体キャパシタの下部電極を形成する工程と、
前記下部電極上に容量絶縁膜を形成する工程と、
前記容量絶縁膜の上に上部電極を形成する工程と、
絶縁性又は導電性の第1の水素バリア膜を、複数の前記上部電極を覆い、かつ、ワード 線方向及びビット線方向のうちの一方向に並ぶ前記複数の強誘電体キャパシタよりなるキャパシタ列毎に分離して形成する工程とを備えていることを特徴とする強誘電体メモリ装置の製造方法。
A plurality of ferroelectric capacitors having a lower electrode, a capacitor insulating film made of a ferroelectric film, and an upper electrode sequentially formed on an interlayer insulating film on a semiconductor substrate, and arranged in a word line direction and a bit line direction A method for manufacturing a ferroelectric memory device comprising:
Forming lower electrodes of the plurality of ferroelectric capacitors on the interlayer insulating film;
Forming a capacitive insulating film on the lower electrode;
Forming an upper electrode on the capacitive insulating film;
An insulating or conductive first hydrogen barrier film covering each of the plurality of upper electrodes, and for each capacitor row comprising the plurality of ferroelectric capacitors arranged in one direction of the word line direction and the bit line direction And a step of forming the ferroelectric memory device separately.
半導体基板上の層間絶縁膜の上に順次形成された下部電極、強誘電体膜よりなる容量絶縁膜及び上部電極を有し、ワード線方向及びビット線方向に配置された複数の強誘電体キャパシタを備えた強誘電体メモリ装置の製造方法であって、A plurality of ferroelectric capacitors having a lower electrode, a capacitor insulating film made of a ferroelectric film, and an upper electrode sequentially formed on an interlayer insulating film on a semiconductor substrate, and arranged in a word line direction and a bit line direction A method for manufacturing a ferroelectric memory device comprising:
前記層間絶縁膜の上に、前記複数の強誘電体キャパシタの下部電極を形成する工程と、Forming lower electrodes of the plurality of ferroelectric capacitors on the interlayer insulating film;
前記下部電極上に容量絶縁膜を形成する工程と、Forming a capacitive insulating film on the lower electrode;
前記容量絶縁膜の上に上部電極を形成する工程と、Forming an upper electrode on the capacitive insulating film;
絶縁性又は導電性の第1の水素バリア膜を、複数の前記上部電極を覆い、かつ、ワード線方向及びビット線方向のうちの一方向に並ぶ前記複数の強誘電体キャパシタよりなるキャパシタ列のうち、ワード線方向及びビット線方向のうちの他方向に隣り合う一対のキャパシタ列を覆うように形成する工程とを備えていることを特徴とする強誘電体メモリ装置の製造方法。An insulating or conductive first hydrogen barrier film covers a plurality of the upper electrodes, and includes a plurality of ferroelectric capacitors arranged in one direction of a word line direction and a bit line direction. A method of manufacturing a ferroelectric memory device comprising: forming a pair of capacitor rows adjacent to each other in the other of the word line direction and the bit line direction.
前記下部電極を形成する工程の後で、前記容量絶縁膜を形成する工程よりも前に、前記層間絶縁膜及び前記下部電極の上に絶縁性の第2の水素バリア膜を堆積した後、該第2の水素バリア膜を平坦化して、前記複数の強誘電体キャパシタのうち、前記一方向に並ぶ複数の強誘電体キャパシタの前記下部電極同士の間に第2の水素バリア膜を埋め込む工程をさらに備えていることを特徴とする請求項11または請求項12記載の強誘電体メモリ装置の製造方法。After the step of forming the lower electrode and before the step of forming the capacitive insulating film, after depositing an insulating second hydrogen barrier film on the interlayer insulating film and the lower electrode, Planarizing the second hydrogen barrier film, and embedding the second hydrogen barrier film between the lower electrodes of the plurality of ferroelectric capacitors arranged in one direction among the plurality of ferroelectric capacitors. 13. The method of manufacturing a ferroelectric memory device according to claim 11 or 12, further comprising: 前記下部電極を形成する工程よりも前に、前記層間絶縁膜に形成されているコンタクトプラグと前記下部電極との間に介在する導電性の第3の水素バリア膜を形成する工程をさらに備えていることを特徴とする請求項11または請求項12に記載の強誘電体メモリ装置の製造方法。Prior to the step of forming the lower electrode, the method further includes a step of forming a conductive third hydrogen barrier film interposed between the contact plug formed in the interlayer insulating film and the lower electrode. 13. The method for manufacturing a ferroelectric memory device according to claim 11, wherein the ferroelectric memory device is a semiconductor memory device. 前記一方向に並ぶ前記複数の強誘電体キャパシタよりなるキャパシタ列は、前記第1の水素バリア膜、前記第2の水素バリア膜及び前記第3の水素バリア膜によって完全に覆われていることを特徴とする請求項14に記載の強誘電体メモリ装置の製造方法。A capacitor row composed of the plurality of ferroelectric capacitors arranged in one direction is completely covered by the first hydrogen barrier film, the second hydrogen barrier film, and the third hydrogen barrier film . 15. The method of manufacturing a ferroelectric memory device according to claim 14 , wherein 記上部電極を形成する工程と前記第1の水素バリア膜を形成する工程との間に、前記上部電極と前記第1の水素バリア膜との間に介在し、前記上部電極の周縁部に形成される段差を緩和する段差緩和膜を形成する工程をさらに備えていることを特徴とする請求項11または請求項12に記載の強誘電体メモリ装置の製造方法。Between the step of forming a step of forming a pre-SL upper portion electrode the first hydrogen barrier film, interposed between the before and SL upper portion electrode first hydrogen barrier film, front Stories upper portion 13. The method of manufacturing a ferroelectric memory device according to claim 11 , further comprising a step of forming a step-reducing film that relieves a step formed on the peripheral portion of the electrode. 前記第2の水素バリア膜は、Si34膜、SiON膜、Al23膜、TiO2 膜、又はTiとAlとの合金の酸化物膜若しくは酸窒化物膜よりなることを特徴とする請求項15に記載の強誘電体メモリ装置の製造方法。 The second hydrogen barrier film is made of a Si 3 N 4 film, a SiON film, an Al 2 O 3 film, a TiO 2 film, or an oxide film or oxynitride film of an alloy of Ti and Al. The method of manufacturing a ferroelectric memory device according to claim 15. 前記第1の水素バリア膜は、Si34膜、SiON膜、Al23膜、TiO2 膜、TiN膜若しくはTiとAlとの合金膜、又はTiとAlとの合金の酸化物膜、窒化物膜若しくは酸窒化物膜よりなることを特徴とする請求項11または請求項12に記載の強誘電体メモリ装置の製造方法。 The first hydrogen barrier film is a Si 3 N 4 film, a SiON film, an Al 2 O 3 film, a TiO 2 film, a TiN film, an alloy film of Ti and Al, or an oxide film of an alloy of Ti and Al. The method of manufacturing a ferroelectric memory device according to claim 11 , comprising a nitride film or an oxynitride film. 前記第3の水素バリア膜は、TiとAlとの合金膜、TiとAlとの合金の窒化物膜若しくは酸窒化物膜、又はTiN膜よりなることを特徴とする請求項14に記載の強誘電体メモリ装置の製造方法。The strong hydrogen film according to claim 14 , wherein the third hydrogen barrier film is made of an alloy film of Ti and Al, a nitride film or an oxynitride film of an alloy of Ti and Al, or a TiN film. A method of manufacturing a dielectric memory device.
JP2002224451A 2001-09-27 2002-08-01 Ferroelectric memory device and manufacturing method thereof Expired - Lifetime JP3962296B2 (en)

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TWI229935B (en) 2002-11-13 2005-03-21 Matsushita Electric Industrial Co Ltd Semiconductor device and method for fabricating the same
JP4549947B2 (en) * 2003-05-27 2010-09-22 パナソニック株式会社 Semiconductor device
JP3935475B2 (en) 2004-03-18 2007-06-20 松下電器産業株式会社 Semiconductor device and manufacturing method thereof
US8552484B2 (en) 2004-07-02 2013-10-08 Fujitsu Semiconductor Limited Semiconductor device and method for fabricating the same
JP4042730B2 (en) 2004-09-02 2008-02-06 セイコーエプソン株式会社 Ferroelectric memory and manufacturing method thereof
JP2006108152A (en) * 2004-09-30 2006-04-20 Oki Electric Ind Co Ltd Semiconductor memory device
JP4422644B2 (en) 2005-03-30 2010-02-24 富士通マイクロエレクトロニクス株式会社 Manufacturing method of semiconductor device
JP2006302987A (en) * 2005-04-18 2006-11-02 Nec Electronics Corp Semiconductor device and manufacturing method thereof
JP4756915B2 (en) * 2005-05-31 2011-08-24 Okiセミコンダクタ株式会社 Ferroelectric memory device and manufacturing method thereof
WO2006134664A1 (en) 2005-06-17 2006-12-21 Fujitsu Limited Semiconductor device and method for manufacturing same
JP4557903B2 (en) * 2006-02-10 2010-10-06 パナソニック株式会社 Semiconductor device and manufacturing method thereof
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