JP2003187802A - リチウム二次電池のカソード活物質として高電圧で使用可能なリチウム挿入化合物 - Google Patents

リチウム二次電池のカソード活物質として高電圧で使用可能なリチウム挿入化合物

Info

Publication number
JP2003187802A
JP2003187802A JP2002324164A JP2002324164A JP2003187802A JP 2003187802 A JP2003187802 A JP 2003187802A JP 2002324164 A JP2002324164 A JP 2002324164A JP 2002324164 A JP2002324164 A JP 2002324164A JP 2003187802 A JP2003187802 A JP 2003187802A
Authority
JP
Japan
Prior art keywords
compound
lithium
active material
formula
limn
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2002324164A
Other languages
English (en)
Japanese (ja)
Inventor
Jean-Paul Peres
ジヤン−ポール・ペレス
Lecerf Andre
アンドレ・ルセール
Clemence Siret
クレマンス・シレ
Jean-Pierre Boeuve
ジヤン−ピエール・ブーブ
Claudette Audry
クローデツト・オードリー
Philippe Biensan
フイリツプ・ビヤンサン
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Alcatel Lucent SAS
Nokia Inc
Original Assignee
Alcatel SA
Nokia Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alcatel SA, Nokia Inc filed Critical Alcatel SA
Publication of JP2003187802A publication Critical patent/JP2003187802A/ja
Pending legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/003—Titanates
    • C01G23/005—Alkali titanates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Complex oxides containing manganese and at least one other metal element
    • C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1242—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (Mn2O4)-, e.g. LiMn2O4 or Li(MxMn2-x)O4
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/40—Complex oxides containing cobalt and at least one other metal element
    • C01G51/42—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • C01G51/44—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese
    • C01G51/54—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese of the type (Mn2O4)-, e.g. Li(CoxMn2-x)O4 or Li(MyCoxMn2-x-y)O4
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/54—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (Mn2O4)-, e.g. Li(NixMn2-x)O4 or Li(MyNixMn2-x-y)O4
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H01M4/623—Binders being polymers fluorinated polymers
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/30—Three-dimensional structures
    • C01P2002/32—Three-dimensional structures spinel-type (AB2O4)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C01P2002/54—Solid solutions containing elements as dopants one element only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/88—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by thermal analysis data, e.g. TGA, DTA, DSC
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
    • H01M50/109—Primary casings; Jackets or wrappings characterised by their shape or physical structure of button or coin shape
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
JP2002324164A 2001-11-08 2002-11-07 リチウム二次電池のカソード活物質として高電圧で使用可能なリチウム挿入化合物 Pending JP2003187802A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0114459A FR2831993A1 (fr) 2001-11-08 2001-11-08 Compose d'insertion du lithium a haute tension utilisable comme matiere active cathodique de generateur electrochimique rechargeable au lithium
FR0114459 2001-11-08

Publications (1)

Publication Number Publication Date
JP2003187802A true JP2003187802A (ja) 2003-07-04

Family

ID=8869189

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2002324164A Pending JP2003187802A (ja) 2001-11-08 2002-11-07 リチウム二次電池のカソード活物質として高電圧で使用可能なリチウム挿入化合物

Country Status (4)

Country Link
US (1) US20030138696A1 (fr)
EP (1) EP1311013A3 (fr)
JP (1) JP2003187802A (fr)
FR (1) FR2831993A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006344391A (ja) * 2005-06-07 2006-12-21 Hitachi Maxell Ltd 非水電解液二次電池
KR101347671B1 (ko) * 2005-06-07 2014-01-03 히다치 막셀 가부시키가이샤 비수전해액 이차 전지
WO2015068735A1 (fr) * 2013-11-08 2015-05-14 東ソー株式会社 Oxyde composite nickel-manganèse, son procédé de production et son utilisation

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4495994B2 (ja) * 2004-03-29 2010-07-07 株式会社東芝 非水電解質二次電池
FR2879822B1 (fr) * 2004-12-21 2009-05-22 Commissariat Energie Atomique Materiau d'electrode positive optimise pour accumulateurs au lithium, procede pour sa realisation, electrode, accumulateur et batterie mettant en oeuvre ce materiau
FR2901640B1 (fr) * 2006-05-24 2008-09-12 Accumulateurs Fixes Compose d'insertion du lithium utilisable comme matiere active cathodique d'un generateur electrochimique rechargeable au lithium
US8076026B2 (en) * 2010-02-05 2011-12-13 International Battery, Inc. Rechargeable battery using an aqueous binder
US7931985B1 (en) 2010-11-08 2011-04-26 International Battery, Inc. Water soluble polymer binder for lithium ion battery
US20110143206A1 (en) * 2010-07-14 2011-06-16 International Battery, Inc. Electrode for rechargeable batteries using aqueous binder solution for li-ion batteries
US8102642B2 (en) * 2010-08-06 2012-01-24 International Battery, Inc. Large format ultracapacitors and method of assembly
JP6035013B2 (ja) * 2011-08-30 2016-11-30 株式会社半導体エネルギー研究所 電極の作製方法
US9478828B2 (en) * 2012-12-04 2016-10-25 Samsung Sdi Co., Ltd. Electrolyte for rechargeable lithium battery and rechargeable lithium battery including the same
CN104961161A (zh) * 2015-05-25 2015-10-07 华南理工大学 一种高度稳定的锰酸锂正极材料及其制备方法
CN110729462B (zh) * 2019-10-22 2021-05-25 湖北大学 金属阳离子插层结构的锰氧化物电极材料及其制备方法和应用

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0644974A (ja) * 1992-07-21 1994-02-18 Hitachi Maxell Ltd リチウム遷移金属酸化物、その製造方法および上記リチウム遷移金属酸化物を用いたリチウム二次電池
JP3502118B2 (ja) * 1993-03-17 2004-03-02 松下電器産業株式会社 リチウム二次電池およびその負極の製造法
US5478675A (en) * 1993-12-27 1995-12-26 Hival Ltd. Secondary battery
CA2158242C (fr) * 1995-09-13 2000-08-15 Qiming Zhong Composes d'insertion haute tension pour piles au lithium
JP2893327B2 (ja) * 1996-04-01 1999-05-17 脇原 将孝 電極、及びリチウム二次電池
WO1998038648A1 (fr) * 1997-02-28 1998-09-03 Fmc Corporation Cathodes dopees a oxydes pour accumulateur electrique au lithium et pour accumulateur aux ions de lithium
US6040089A (en) * 1997-02-28 2000-03-21 Fmc Corporation Multiple-doped oxide cathode material for secondary lithium and lithium-ion batteries
US6749648B1 (en) * 2000-06-19 2004-06-15 Nanagram Corporation Lithium metal oxides
JP3634694B2 (ja) * 1998-12-18 2005-03-30 三洋電機株式会社 リチウム二次電池
KR100326457B1 (ko) * 1999-03-10 2002-02-28 김순택 리튬 이차 전지용 양극 활물질 및 그 제조 방법
JP3615415B2 (ja) * 1999-03-24 2005-02-02 三洋電機株式会社 非水系二次電池
JP3511489B2 (ja) * 1999-10-14 2004-03-29 日本碍子株式会社 リチウム二次電池用捲回型電極体の作製方法
JP2001135302A (ja) * 1999-11-01 2001-05-18 Ngk Insulators Ltd リチウム二次電池及びその作製方法
JP2001148249A (ja) * 1999-11-19 2001-05-29 Chuo Denki Kogyo Co Ltd リチウム二次電池用正極活物質材料とリチウム二次電池
JP4644895B2 (ja) * 2000-01-24 2011-03-09 株式会社豊田中央研究所 リチウム二次電池
JP2002042814A (ja) * 2000-07-28 2002-02-08 Hitachi Maxell Ltd 非水二次電池用正極活物質およびそれを用いた非水二次電池
JP5013386B2 (ja) * 2000-11-17 2012-08-29 日立マクセルエナジー株式会社 非水二次電池用正極活物質およびそれを用いた非水二次電池
US6984470B2 (en) * 2001-03-26 2006-01-10 Kabushiki Kaisha Toshiba Positive electrode active material and nonaqueous electrolyte secondary battery
DE60235944D1 (de) * 2001-10-18 2010-05-27 Nec Corp Positives aktives Elektrodenmaterial, positive Elektrode und nicht-wässrige sekundäre Elektrolytbatterie diese benutzend

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006344391A (ja) * 2005-06-07 2006-12-21 Hitachi Maxell Ltd 非水電解液二次電池
KR101347671B1 (ko) * 2005-06-07 2014-01-03 히다치 막셀 가부시키가이샤 비수전해액 이차 전지
WO2015068735A1 (fr) * 2013-11-08 2015-05-14 東ソー株式会社 Oxyde composite nickel-manganèse, son procédé de production et son utilisation

Also Published As

Publication number Publication date
EP1311013A3 (fr) 2006-12-27
US20030138696A1 (en) 2003-07-24
FR2831993A1 (fr) 2003-05-09
EP1311013A2 (fr) 2003-05-14

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