JP2017220011A - 積層膜、表示装置及び入力装置 - Google Patents
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Abstract
Description
[1]第1層、第2層及び第3層がこの順に積層された積層膜であって、
第1層が電気抵抗率が15μΩ・cm以下である金属薄膜であり、
第2層が40原子%以上61原子%以下の窒素を含むアルミニウム窒化膜又はアルミニウム合金窒化膜であり、
第3層が50原子%以上60原子%以下の酸素を含むアルミニウム酸化膜若しくはアルミニウム合金酸化膜、50原子%以上60原子%以下の酸素及び1原子%以上10原子%以下の窒素を含むアルミニウム酸窒化膜若しくはアルミニウム合金酸窒化膜、又は50原子%以上60原子%以下の窒素を含むアルミニウム窒化膜若しくはアルミニウム合金窒化膜である積層膜。
[2][1]に記載の積層膜を備えた表示装置。
[3][1]に記載の積層膜を備えた入力装置。
図1〜図4に本発明の積層膜の一構造例の概略断面図を示す。図1の積層膜は、基板1上に導電層となる金属薄膜である第1層2を備え、その上にアルミニウム窒化膜又はアルミニウム合金窒化膜である第2層3を備え、その上にアルミニウム又はアルミニウム合金の酸化膜、窒化膜又は酸窒化膜である第3層4を備える。第1層と第3層との間に第2層が配置されていればよく、図2で示すように基板1上に第3層4を備え、その上に第2層3を備え、その上にさらに第1層2を備えてもよい。
基板の材料としては、PETフィルム若しくはプラスチック等の樹脂基板、ガラス基板、シリコン基板又はカラーフィルター基板等、従来公知の材料から適宜選択することができる。基板の厚みは用途によっても異なるが、一般的には0.1〜3mmが好ましい。
導電層となる金属電極薄膜(以下、金属膜ともいう。)である第1層2は、単膜としての電気抵抗率が15μΩ・cm以下であり、10μΩ・cm以下が好ましく、8μΩ・cm以下がより好ましい。電気抵抗率の下限は特に限定されないが、通常1.5μΩ・cm以上である。金属膜の電気抵抗率が15μΩ・cmを超えると、積層膜とした時の目安であるシート抵抗が1.5Ω/cm2以下となるように厚膜を積層する必要がある。電気抵抗率及びシート抵抗は四端子法で測定する。
アルミニウム窒化膜又はアルミニウム合金窒化膜である第2層3は光吸収膜として機能する。そのため、第2層は光の入射側又は視認する側に設けることが好ましい。第2層は、金属膜である第1層とアルミニウム又はアルミニウム合金の酸化膜、窒化膜又は酸窒化膜である第3層との間に設ける。
アルミニウム又はアルミニウム合金の酸化膜、窒化膜又は酸窒化膜である第3層4は積層膜の低反射化を実現するために機能するための光学調整層として機能する。そのため、第3層は、アルミニウム又はアルミニウム合金の窒化膜である第2層の直上又は直下に設けることが好ましい。金属膜の低反射化を目的とするため、例えば、図1に示すように第3層を表面側に設けてもよいし、図2に示すように基板側に設けてもよく、その位置は光の入射側又は視認する側に依存する。
(1)50原子%以上60原子%以下の酸素を含む、アルミニウム酸化膜又はアルミニウム合金酸化膜
(2)50原子%以上60原子%以下の酸素及び1原子%以上10原子%以下の窒素を含む、アルミニウム酸窒化膜又はアルミニウム合金酸窒化膜
(3)50原子%以上60原子%以下の窒素を含む、アルミニウム窒化膜又はアルミニウム合金窒化膜
密着層又は保護層5は、金属電極薄膜の種類によって、密着性の改善又は耐食性の改善を目的として適宜設ける。具体的には、例えば、金属電極薄膜が純アルミニウム薄膜又はアルミニウム合金薄膜である場合には、加熱によるヒロック発生を抑制するため、保護層としてTi、Mo、TiN又はMoNを積層することが好ましい。
(1)窒化薄膜中の窒素量
純アルミニウム窒化薄膜及びアルミニウム合金窒化薄膜における膜中窒素量(膜中N濃度)(原子%)はPerkinElmer社製のPHI650走査型オージェ電子分光装置を用いて、エネルギー 3keV、電流 約50nAの電子線を75°の角度で膜表面に照射し、オージェ(Auger)スペクトルを測定した。膜の深さ方向については、Ar+のイオンスパッタでエッチングしながら、上記と同様の条件で測定を行った。
純アルミニウム窒化薄膜及びアルミニウム合金窒化薄膜における反射率及び透過率は、日本分光社製V−570分光光度計を用い、波長400nm〜800nmの反射率スペクトルと透過率スペクトルを測定した。表1には波長450nm、550nm及び650nmにおける反射率と透過率を記載した。また各波長における吸収率は下記式より求めた。
吸収率(%)=100−反射率(%)−透過率(%)
窒化薄膜、金属電極薄膜及びアルミニウム合金窒化積層薄膜のシート抵抗はそれぞれ四端子法で測定した。なお窒化薄膜及び金属電極薄膜の単膜の電気抵抗率は、上記で得られたシート抵抗の値に膜厚を掛けることにより算出した。
積層薄膜の反射率は、日本分光社製V−570分光光度計を用い、波長400nm〜800nmの反射率スペクトルを測定した。
金属電極薄膜の評価を行うため、表1に示す組成となるように、下記条件でスパッタリング法により金属電極薄膜を成膜した。基板には厚みが0.7mmのCorning社製EAGLE XGガラスを用いた。
・成膜装置:ULVAC社製 型式CS−200
・ガス圧:2mTorr
・成膜ガス:Arガス
・成膜パワー:DC500W
・基板温度:室温
アルミニウム合金窒化薄膜の光吸収特性についての評価を行うため、純アルミニウム窒化薄膜(試験例2−1〜2−4)及びアルミニウム合金窒化薄膜(試験例試験例2−5〜2−29)を表2に記載の組成となるように下記条件でスパッタリング法により成膜した。基板には厚みが0.7mmのCorning社製EAGLE XGガラスを用いた。
・成膜装置:ULVAC社製 型式CS−200
・ガス圧:2mTorr
・成膜ガス:Arガス及びN2ガスからなる混合ガス
・成膜パワー:DC500W
・基板温度:室温
アルミニウム合金酸化膜、窒化膜又は酸窒化膜の分光特性を評価するため、純アルミニウム窒化薄膜(試験例3−1〜3−3)及びアルミニウム合金窒化薄膜(試験例3−4〜3−11)を表3に示す組成となるように下記条件でスパッタリング法により成膜した。基板には厚みが0.7mmのCorning社製EAGLE XGガラスを用いた。
・成膜装置:ULVAC社製 型式CS−200
・ガス圧:2mTorr
・成膜ガス:Arガス、N2ガス及びO2ガスからなる混合ガス
・成膜パワー:DC500W
・基板温度:室温
2 第1層(導電層)
3 第2層(アルミニウム窒化膜又はアルミニウム合金窒化膜)
4 第3層(アルミニウム又はアルミニウム合金の酸化膜、窒化膜又は酸窒化膜)
5 密着層又は保護層
[1]第1層、第2層及び第3層がこの順に積層された積層膜であって、
第1層が、電気抵抗率が15μΩ・cm以下である金属薄膜であり、
第2層が40原子%以上61原子%以下の窒素を含むアルミニウム窒化膜又は40原子%以上61原子%以下の窒素と、酸素(O)、銅(Cu)、イットリウム(Y)、ケイ素(Si)、チタン(Ti)、ネオジム(Nd)うち少なくとも1つを含むアルミニウム合金窒化膜であり、
第3層が50原子%以上60原子%以下の酸素と、銅(Cu)、ネオジム(Nd)、鉄(Fe)、炭素(C)の少なくとも1つを含むアルミニウム合金酸化膜、50原子%以上60原子%以下の酸素及び1原子%以上10原子%以下の窒素を含むアルミニウム酸窒化膜、又は50原子%以上60原子%以下の酸素及び1原子%以上10原子%以下の窒素と、銅(Cu)、ネオジム(Nd)、鉄(Fe)、炭素(C)の少なくとも1つを含むアルミニウム合金酸窒化膜であり、
前記第2層の膜厚が20nm〜200nm、かつ、前記第3層の膜厚が15nm〜200nmである積層膜。
[2][1]に記載の積層膜を備えた表示装置。
[3][1]に記載の積層膜を備えた入力装置。
アルミニウム合金の酸化膜、アルミニウム若しくはアルミニウム合金の窒化膜又は酸窒化膜である第3層4は積層膜の低反射化を実現するために機能するための光学調整層として機能する。そのため、第3層は、アルミニウム又はアルミニウム合金の窒化膜である第2層の直上又は直下に設けることが好ましい。金属膜の低反射化を目的とするため、例えば、図1に示すように第3層を表面側に設けてもよいし、図2に示すように基板側に設けてもよく、その位置は光の入射側又は視認する側に依存する。
(1)50原子%以上60原子%以下の酸素を含む、アルミニウム合金酸化膜
(2)50原子%以上60原子%以下の酸素及び1原子%以上10原子%以下の窒素を含む、アルミニウム酸窒化膜又はアルミニウム合金酸窒化膜
(3)50原子%以上60原子%以下の窒素を含む、アルミニウム窒化膜又はアルミニウム合金窒化膜
2 第1層(導電層)
3 第2層(アルミニウム窒化膜又はアルミニウム合金窒化膜)
4 第3層(アルミニウム合金の酸化膜、又はアルミニウム若しくはアルミニウム合金の窒化膜又は酸窒化膜)
5 密着層又は保護層
Claims (3)
- 第1層、第2層及び第3層がこの順に積層された積層膜であって、
第1層が電気抵抗率が15μΩ・cm以下である金属薄膜であり、
第2層が40原子%以上61原子%以下の窒素を含むアルミニウム窒化膜又はアルミニウム合金窒化膜であり、
第3層が50原子%以上60原子%以下の酸素を含むアルミニウム酸化膜若しくはアルミニウム合金酸化膜、50原子%以上60原子%以下の酸素及び1原子%以上10原子%以下の窒素を含むアルミニウム酸窒化膜若しくはアルミニウム合金酸窒化膜、又は50原子%以上60原子%以下の窒素を含むアルミニウム窒化膜若しくはアルミニウム合金窒化膜である積層膜。 - 請求項1に記載の積層膜を備えた表示装置。
- 請求項1に記載の積層膜を備えた入力装置。
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| JP2016113599A JP2017220011A (ja) | 2016-06-07 | 2016-06-07 | 積層膜、表示装置及び入力装置 |
| PCT/JP2017/019882 WO2017212970A1 (ja) | 2016-06-07 | 2017-05-29 | 積層膜、表示装置及び入力装置 |
| TW107119673A TW201833749A (zh) | 2016-06-07 | 2017-06-06 | 積層膜、顯示裝置及輸入裝置 |
| TW106118598A TW201743178A (zh) | 2016-06-07 | 2017-06-06 | 積層膜、顯示裝置及輸入裝置 |
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Also Published As
| Publication number | Publication date |
|---|---|
| WO2017212970A1 (ja) | 2017-12-14 |
| TW201743178A (zh) | 2017-12-16 |
| TW201833749A (zh) | 2018-09-16 |
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