JP2020522882A - 炭化ホウ素ハードマスクのドライストリッピング - Google Patents
炭化ホウ素ハードマスクのドライストリッピング Download PDFInfo
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Abstract
Description
[0002] メモリデバイス、論理デバイス、マイクロプロセッサなどの半導体デバイスの形成は、ハードマスクの形成を含む。ハードマスクは、エッチングされる下位の基板上にブランケット層として形成される。フォトレジストのパターニングされた層は、パターンとしてフォトレジスト層を用いてハードマスクがエッチングされる前に、ハードマスクの上に形成される。ハードマスクが下位の基板をエッチングするためのソロパターンとして残るように、ハードマスクのパターニング後、フォトレジスト層は除去される。ハードマスクは下位の基板上に形成され、エッチングされ、次に基板から除去される別個の層であるが、エッチング処理に対する耐性が改善されていることに加えて、コストが安いため、ハードマスクを望ましいものにしている。ホウ素がドープされた炭素及び炭化ホウ素の膜は一般的に、パターニング性能が優れているため、高品質のハードマスクを生成することが知られている。
2BC + 5H2O → B2O3 + 2CO + 5H2 ………(i)
2BC + 7H2O → B2O3 + 2CO2 + 7H2 ……(ii)
三酸化ホウ素(B2O3)は次に過剰な蒸気と反応して、化学反応式(iii)及び(iv)に示したように、ホウ酸(H3BO3)及びメタホウ酸(HBO2)を産生する。
B2O3 + H2O → 2HBO2 …………………………… (iii)
B2O3 + 3H2O → 2H3BO3 ………………………… (iv)
ホウ酸及びメタホウ酸は揮発性の生成物である。ホウ酸及びメタホウ酸は水素ガス、一酸化炭素及び二酸化炭素と混合して、炭化ホウ素と水蒸気との間の反応生成物の気体混合物を形成する。
Claims (15)
- 基板の上に堆積した炭化ホウ素層をストリッピングする方法であって、
炭化ホウ素層が上部に堆積している基板を圧力容器に装填することと、
約500Torrから60barの圧力で、酸化剤を含む処理ガスに前記基板を曝露することと、
前記処理ガスの凝結点を超える温度まで前記圧力容器を加熱することと、
前記処理ガスと前記炭化ホウ素層との間の一又は複数の反応生成物を前記圧力容器から除去することと、
を含む方法。 - 前記基板を処理ガスに曝露することは、
前記基板を約10barを超える圧力で蒸気に曝露することを含む、請求項1に記載の方法。 - 前記基板は、前記基板上に堆積した炭化ホウ素の量の少なくとも10倍の量の蒸気に曝露される、請求項2に記載の方法。
- 前記酸化剤は、オゾン、酸素、水蒸気、重水、アンモニア、過酸化物、水酸化物含有化合物、酸素同位体及び水素同位体からなる群から選択される、請求項1に記載の方法。
- 前記基板は、前記基板上に堆積した炭化ホウ素の量と完全に反応するのに必要な量の酸化剤を超える量の酸化剤に曝露される、請求項1に記載の方法。
- 前記圧力容器は、約300°Cから700°Cの温度まで加熱される、請求項1に記載の方法。
- 前記処理ガスは、約5%の乾燥蒸気から100%の乾燥蒸気を含む、請求項1に記載の方法。
- 複数の基板の上に堆積した炭化ホウ素層をストリッピングする方法であって、
炭化ホウ素層が上部に堆積している少なくとも第1の基板を含む複数の基板を、圧力容器に装填することと、
約500Torrから60barの圧力で、酸化剤を含む処理ガスに前記第1の基板を曝露することと、
前記処理ガスの凝結点を超える温度まで前記圧力容器を加熱することと、
前記処理ガスと前記炭化ホウ素層との間の一又は複数の反応生成物を前記圧力容器から除去することと、
を含む方法。 - 前記第1の基板を処理ガスに曝露することは、
前記第1の基板を約10barを超える圧力で蒸気に曝露することを含む、請求項8に記載の方法。 - 前記酸化剤は、オゾン、酸素、水蒸気、重水、アンモニア、過酸化物、水酸化物含有化合物、酸素同位体及び水素同位体からなる群から選択される、請求項8に記載の方法。
- 前記第1の基板は、前記第1の基板上に堆積した炭化ホウ素の量と完全に反応するのに必要な量の酸化剤を超える量の酸化剤に曝露される、請求項8に記載の方法。
- 前記圧力容器は、約300°Cから700°Cの温度まで加熱される、請求項8に記載の方法。
- 前記処理ガスは、約5%の乾燥蒸気から100%の乾燥蒸気を含む、請求項8に記載の方法。
- 複数の基板の上に堆積した炭化ホウ素層をストリッピングする方法であって、
炭化ホウ素層が上部に堆積している少なくとも第1の基板を含む一又は複数の基板を、圧力容器に装填することと、
約500Torrから60barの圧力で、蒸気を含む処理ガスに前記第1の基板を曝露することと、
前記処理ガスの凝結点を超える温度まで前記圧力容器を加熱することと、
前記処理ガスと前記炭化ホウ素層との間の一又は複数の反応生成物を前記圧力容器から除去することと、
を含む方法。 - 前記処理ガスは、約5%の過熱蒸気から100%の過熱蒸気を含む、請求項14に記載の方法。
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762514554P | 2017-06-02 | 2017-06-02 | |
| US62/514,554 | 2017-06-02 | ||
| US201862648073P | 2018-03-26 | 2018-03-26 | |
| US62/648,073 | 2018-03-26 | ||
| PCT/US2018/035210 WO2018222771A1 (en) | 2017-06-02 | 2018-05-30 | Dry stripping of boron carbide hardmask |
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| JP2020522882A true JP2020522882A (ja) | 2020-07-30 |
| JP2020522882A5 JP2020522882A5 (ja) | 2021-07-26 |
| JP7190450B2 JP7190450B2 (ja) | 2022-12-15 |
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| JP6947914B2 (ja) | 2017-08-18 | 2021-10-13 | アプライド マテリアルズ インコーポレイテッドApplied Materials,Incorporated | 高圧高温下のアニールチャンバ |
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| JP2021503714A (ja) | 2017-11-17 | 2021-02-12 | アプライド マテリアルズ インコーポレイテッドApplied Materials,Incorporated | 高圧処理システムのためのコンデンサシステム |
| CN111902929B (zh) | 2018-03-09 | 2025-09-19 | 应用材料公司 | 用于含金属材料的高压退火处理 |
| US10950429B2 (en) | 2018-05-08 | 2021-03-16 | Applied Materials, Inc. | Methods of forming amorphous carbon hard mask layers and hard mask layers formed therefrom |
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| US11901222B2 (en) | 2020-02-17 | 2024-02-13 | Applied Materials, Inc. | Multi-step process for flowable gap-fill film |
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| US20220230887A1 (en) * | 2021-01-15 | 2022-07-21 | Applied Materials, Inc. | Methods and apparatus for processing a substrate |
| KR20240053429A (ko) * | 2022-10-17 | 2024-04-24 | 피에스케이 주식회사 | 기판 처리 장치 및 기판 처리 방법 |
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| US10529585B2 (en) | 2020-01-07 |
| US20180350621A1 (en) | 2018-12-06 |
| TWI763858B (zh) | 2022-05-11 |
| CN110678973B (zh) | 2023-09-19 |
| CN110678973A (zh) | 2020-01-10 |
| JP7190450B2 (ja) | 2022-12-15 |
| TW201903837A (zh) | 2019-01-16 |
| KR20200004399A (ko) | 2020-01-13 |
| KR102574914B1 (ko) | 2023-09-04 |
| WO2018222771A1 (en) | 2018-12-06 |
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