JP3498947B2 - 再充電可能リチウムマンガン酸化物電池およびリチウムマンガン酸化物電池用材料 - Google Patents

再充電可能リチウムマンガン酸化物電池およびリチウムマンガン酸化物電池用材料

Info

Publication number: JP3498947B2
Authority: JP; Japan
Prior art keywords: lithium manganese; spinel; manganese oxide; compound; lithium
Prior art date: 1999-05-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

JP2000155499A

Other languages

English (en)

Japanese (ja)

Other versions

JP2001006678A (ja

Inventor

ツァンメイジイー

ワンユ

ナエスライマーズジャン

ジーマイケル

Original Assignee

イーワンモリエナジー（カナダ）リミテッド

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-05-26

Filing date

2000-05-25

Publication date

2004-02-23

2000-05-25 Application filed by イーワンモリエナジー（カナダ）リミテッド filed Critical イーワンモリエナジー（カナダ）リミテッド

2001-01-12 Publication of JP2001006678A publication Critical patent/JP2001006678A/ja

2004-02-23 Application granted granted Critical

2004-02-23 Publication of JP3498947B2 publication Critical patent/JP3498947B2/ja

2020-05-25 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical compound [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 title claims description 74
229910002102 lithium manganese oxide Inorganic materials 0.000 title claims description 68
239000000463 material Substances 0.000 title claims description 21
229910052596 spinel Inorganic materials 0.000 claims description 202
239000011029 spinel Substances 0.000 claims description 202
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 90
229910052751 metal Inorganic materials 0.000 claims description 90
239000002184 metal Substances 0.000 claims description 90
150000002736 metal compounds Chemical class 0.000 claims description 69
150000001875 compounds Chemical class 0.000 claims description 58
239000000203 mixture Substances 0.000 claims description 41
239000011572 manganese Substances 0.000 claims description 38
229910052797 bismuth Inorganic materials 0.000 claims description 32
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
238000010438 heat treatment Methods 0.000 claims description 26
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 22
229910052745 lead Inorganic materials 0.000 claims description 22
229910052744 lithium Inorganic materials 0.000 claims description 22
239000002245 particle Substances 0.000 claims description 20
KLARSDUHONHPRF-UHFFFAOYSA-N [Li].[Mn] Chemical compound [Li].[Mn] KLARSDUHONHPRF-UHFFFAOYSA-N 0.000 claims description 17
229910052727 yttrium Inorganic materials 0.000 claims description 17
150000002739 metals Chemical class 0.000 claims description 15
229910052746 lanthanum Inorganic materials 0.000 claims description 13
229910052712 strontium Inorganic materials 0.000 claims description 13
239000003125 aqueous solvent Substances 0.000 claims description 12
229910052788 barium Inorganic materials 0.000 claims description 12
238000000354 decomposition reaction Methods 0.000 claims description 12
229910052749 magnesium Inorganic materials 0.000 claims description 11
229910052748 manganese Inorganic materials 0.000 claims description 10
229910052725 zinc Inorganic materials 0.000 claims description 10
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 9
229910003002 lithium salt Inorganic materials 0.000 claims description 9
159000000002 lithium salts Chemical class 0.000 claims description 9
238000000605 extraction Methods 0.000 claims description 8
150000002642 lithium compounds Chemical class 0.000 claims description 7
ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 5
239000007864 aqueous solution Substances 0.000 claims description 5
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 5
239000011255 nonaqueous electrolyte Substances 0.000 claims description 4
238000000034 method Methods 0.000 description 46
239000000843 powder Substances 0.000 description 42
229910008163 Li1+x Mn2-x O4 Inorganic materials 0.000 description 28
239000000047 product Substances 0.000 description 25
HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 22
229910001416 lithium ion Inorganic materials 0.000 description 22
238000011282 treatment Methods 0.000 description 19
239000011888 foil Substances 0.000 description 15
239000011701 zinc Substances 0.000 description 12
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 11
239000011777 magnesium Substances 0.000 description 11
239000007774 positive electrode material Substances 0.000 description 11
229910052726 zirconium Inorganic materials 0.000 description 11
238000006243 chemical reaction Methods 0.000 description 10
238000007580 dry-mixing Methods 0.000 description 10
230000006872 improvement Effects 0.000 description 10
238000003780 insertion Methods 0.000 description 10
230000037431 insertion Effects 0.000 description 10
150000003839 salts Chemical class 0.000 description 10
239000000523 sample Substances 0.000 description 10
239000008151 electrolyte solution Substances 0.000 description 9
229910044991 metal oxide Inorganic materials 0.000 description 9
150000004706 metal oxides Chemical class 0.000 description 9
239000010406 cathode material Substances 0.000 description 8
238000010586 diagram Methods 0.000 description 8
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 7
KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 7
229910015643 LiMn 2 O 4 Inorganic materials 0.000 description 7
238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 7
RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 7
229910015902 Bi 2 O 3 Inorganic materials 0.000 description 6
229910013870 LiPF 6 Inorganic materials 0.000 description 6
IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 description 6
230000000694 effects Effects 0.000 description 6
JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 6
239000006228 supernatant Substances 0.000 description 6
238000012360 testing method Methods 0.000 description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 5
229910002651 NO3 Inorganic materials 0.000 description 5
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 5
230000015572 biosynthetic process Effects 0.000 description 5
239000003792 electrolyte Substances 0.000 description 5
229910002804 graphite Inorganic materials 0.000 description 5
239000010439 graphite Substances 0.000 description 5
239000002243 precursor Substances 0.000 description 5
238000012545 processing Methods 0.000 description 5
239000002904 solvent Substances 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
229910052782 aluminium Inorganic materials 0.000 description 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
239000011230 binding agent Substances 0.000 description 4
238000000576 coating method Methods 0.000 description 4
230000000052 comparative effect Effects 0.000 description 4
239000011874 heated mixture Substances 0.000 description 4
AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 4
235000015110 jellies Nutrition 0.000 description 4
239000008274 jelly Substances 0.000 description 4
YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 4
150000005677 organic carbonates Chemical group 0.000 description 4
230000008569 process Effects 0.000 description 4
239000002002 slurry Substances 0.000 description 4
DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Chemical compound [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 description 4
238000003786 synthesis reaction Methods 0.000 description 4
229910052715 tantalum Inorganic materials 0.000 description 4
229910012851 LiCoO 2 Inorganic materials 0.000 description 3
229910018584 Mn 2-x O 4 Inorganic materials 0.000 description 3
239000002033 PVDF binder Substances 0.000 description 3
ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 3
230000009471 action Effects 0.000 description 3
150000001298 alcohols Chemical class 0.000 description 3
239000011248 coating agent Substances 0.000 description 3
238000010828 elution Methods 0.000 description 3
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 3
238000002156 mixing Methods 0.000 description 3
229910052758 niobium Inorganic materials 0.000 description 3
238000007254 oxidation reaction Methods 0.000 description 3
229920000098 polyolefin Polymers 0.000 description 3
229920002981 polyvinylidene fluoride Polymers 0.000 description 3
239000000243 solution Substances 0.000 description 3
229910052566 spinel group Inorganic materials 0.000 description 3
238000004381 surface treatment Methods 0.000 description 3
239000004246 zinc acetate Substances 0.000 description 3
QYIGOGBGVKONDY-UHFFFAOYSA-N 1-(2-bromo-5-chlorophenyl)-3-methylpyrazole Chemical compound N1=C(C)C=CN1C1=CC(Cl)=CC=C1Br QYIGOGBGVKONDY-UHFFFAOYSA-N 0.000 description 2
229910000014 Bismuth subcarbonate Inorganic materials 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
229910017569 La2(CO3)3 Inorganic materials 0.000 description 2
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
229910000004 White lead Inorganic materials 0.000 description 2
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
230000002378 acidificating effect Effects 0.000 description 2
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
229940049676 bismuth hydroxide Drugs 0.000 description 2
229910000416 bismuth oxide Inorganic materials 0.000 description 2
TZSXPYWRDWEXHG-UHFFFAOYSA-K bismuth;trihydroxide Chemical compound [OH-].[OH-].[OH-].[Bi+3] TZSXPYWRDWEXHG-UHFFFAOYSA-K 0.000 description 2
239000000571 coke Substances 0.000 description 2
UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 description 2
TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 2
FWIZHMQARNODNX-UHFFFAOYSA-L dibismuth;oxygen(2-);carbonate Chemical compound [O-2].[O-2].[Bi+3].[Bi+3].[O-]C([O-])=O FWIZHMQARNODNX-UHFFFAOYSA-L 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
238000001035 drying Methods 0.000 description 2
RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 description 2
238000009830 intercalation Methods 0.000 description 2
230000002687 intercalation Effects 0.000 description 2
NZPIUJUFIFZSPW-UHFFFAOYSA-H lanthanum carbonate Chemical compound [La+3].[La+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O NZPIUJUFIFZSPW-UHFFFAOYSA-H 0.000 description 2
229960001633 lanthanum carbonate Drugs 0.000 description 2
FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 description 2
RLJMLMKIBZAXJO-UHFFFAOYSA-N lead nitrate Chemical compound [O-][N+](=O)O[Pb]O[N+]([O-])=O RLJMLMKIBZAXJO-UHFFFAOYSA-N 0.000 description 2
VLOJXAQYHIVPFI-UHFFFAOYSA-H lead(2+);diacetate;tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Pb+2].[Pb+2].[Pb+2].CC([O-])=O.CC([O-])=O VLOJXAQYHIVPFI-UHFFFAOYSA-H 0.000 description 2
-1 lithium manganese oxyfluoride lithium Chemical compound 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000007773 negative electrode material Substances 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
230000000149 penetrating effect Effects 0.000 description 2
239000011877 solvent mixture Substances 0.000 description 2
238000003860 storage Methods 0.000 description 2
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 2
239000000126 substance Substances 0.000 description 2
229910052719 titanium Inorganic materials 0.000 description 2
229910052721 tungsten Inorganic materials 0.000 description 2
VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
NGDQQLAVJWUYSF-UHFFFAOYSA-N 4-methyl-2-phenyl-1,3-thiazole-5-sulfonyl chloride Chemical compound S1C(S(Cl)(=O)=O)=C(C)N=C1C1=CC=CC=C1 NGDQQLAVJWUYSF-UHFFFAOYSA-N 0.000 description 1
241000208140 Acer Species 0.000 description 1
241000694440 Colpidium aqueous Species 0.000 description 1
229910000003 Lead carbonate Inorganic materials 0.000 description 1
229910013063 LiBF 4 Inorganic materials 0.000 description 1
229910015645 LiMn Inorganic materials 0.000 description 1
229910013716 LiNi Inorganic materials 0.000 description 1
229910014211 My O Inorganic materials 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000010405 anode material Substances 0.000 description 1
QZPSXPBJTPJTSZ-UHFFFAOYSA-N aqua regia Chemical compound Cl.O[N+]([O-])=O QZPSXPBJTPJTSZ-UHFFFAOYSA-N 0.000 description 1
150000001553 barium compounds Chemical class 0.000 description 1
150000001622 bismuth compounds Chemical class 0.000 description 1
229910052810 boron oxide Inorganic materials 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
230000008859 change Effects 0.000 description 1
238000002144 chemical decomposition reaction Methods 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000008199 coating composition Substances 0.000 description 1
230000003750 conditioning effect Effects 0.000 description 1
239000013068 control sample Substances 0.000 description 1
239000011889 copper foil Substances 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000005520 cutting process Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
238000007599 discharging Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
125000000350 glycoloyl group Chemical group O=C([*])C([H])([H])O[H] 0.000 description 1
XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
238000009413 insulation Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
238000005184 irreversible process Methods 0.000 description 1
150000002604 lanthanum compounds Chemical class 0.000 description 1
150000002611 lead compounds Chemical class 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000006138 lithiation reaction Methods 0.000 description 1
229910021437 lithium-transition metal oxide Inorganic materials 0.000 description 1
150000002681 magnesium compounds Chemical class 0.000 description 1
NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 1
239000012528 membrane Substances 0.000 description 1
239000011812 mixed powder Substances 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012544 monitoring process Methods 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
238000002161 passivation Methods 0.000 description 1
238000007789 sealing Methods 0.000 description 1
238000002791 soaking Methods 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000007784 solid electrolyte Substances 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
150000003438 strontium compounds Chemical class 0.000 description 1
239000000758 substrate Substances 0.000 description 1
230000002194 synthesizing effect Effects 0.000 description 1
JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 1
238000005406 washing Methods 0.000 description 1
238000004804 winding Methods 0.000 description 1
BXJPTTGFESFXJU-UHFFFAOYSA-N yttrium(3+);trinitrate Chemical compound [Y+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O BXJPTTGFESFXJU-UHFFFAOYSA-N 0.000 description 1
150000003752 zinc compounds Chemical class 0.000 description 1
150000003755 zirconium compounds Chemical class 0.000 description 1
229910001928 zirconium oxide Inorganic materials 0.000 description 1
ZUWXYYNYQIKFSJ-UHFFFAOYSA-N zirconium(2+);dinitrate Chemical compound [Zr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZUWXYYNYQIKFSJ-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/12—Complex oxides containing manganese and at least one other metal element
- C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
- C01G45/1242—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (Mn2O4)-, e.g. LiMn2O4 or Li(MxMn2-x)O4
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/30—Three-dimensional structures
- C01P2002/32—Three-dimensional structures spinel-type (AB2O4)
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
- C01P2002/54—Solid solutions containing elements as dopants one element only
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0587—Construction or manufacture of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making

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JP2000155499A 1999-05-26 2000-05-25 再充電可能リチウムマンガン酸化物電池およびリチウムマンガン酸化物電池用材料 Expired - Fee Related JP3498947B2 (ja)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US31885499A	1999-05-26	1999-05-26
US09/318854		2000-01-14
US09/484399		2000-01-14
US09/484,399 US6489060B1 (en)	1999-05-26	2000-01-14	Rechargeable spinel lithium batteries with greatly improved elevated temperature cycle life

Publications (2)

Publication Number	Publication Date
JP2001006678A JP2001006678A (ja)	2001-01-12
JP3498947B2 true JP3498947B2 (ja)	2004-02-23

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JP2000155499A Expired - Fee Related JP3498947B2 (ja)	1999-05-26	2000-05-25	再充電可能リチウムマンガン酸化物電池およびリチウムマンガン酸化物電池用材料

Country Status (5)

Country	Link
US (1)	US6489060B1 (fr)
EP (1)	EP1056143B1 (fr)
JP (1)	JP3498947B2 (fr)
CA (1)	CA2308404C (fr)
DE (1)	DE60036154T2 (fr)

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2000
- 2000-01-14 US US09/484,399 patent/US6489060B1/en not_active Expired - Lifetime
- 2000-05-10 CA CA2308404A patent/CA2308404C/fr not_active Expired - Lifetime
- 2000-05-25 JP JP2000155499A patent/JP3498947B2/ja not_active Expired - Fee Related
- 2000-05-26 EP EP00111435A patent/EP1056143B1/fr not_active Expired - Lifetime
- 2000-05-26 DE DE60036154T patent/DE60036154T2/de not_active Expired - Lifetime

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Publication number	Priority date	Publication date	Assignee	Title
US9246174B2 (en)	2011-08-17	2016-01-26	Nec Corporation	Lithium ion battery

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Publication number	Publication date
EP1056143B1 (fr)	2007-08-29
US6489060B1 (en)	2002-12-03
CA2308404A1 (fr)	2000-11-26
DE60036154T2 (de)	2008-05-21
EP1056143A3 (fr)	2004-07-28
CA2308404C (fr)	2011-03-29
JP2001006678A (ja)	2001-01-12
EP1056143A2 (fr)	2000-11-29
DE60036154D1 (de)	2007-10-11

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Publication	Publication Date	Title
JP3498947B2 (ja)	2004-02-23	再充電可能リチウムマンガン酸化物電池およびリチウムマンガン酸化物電池用材料
US7314682B2 (en)	2008-01-01	Lithium metal oxide electrodes for lithium batteries
US9130226B2 (en)	2015-09-08	Surface stabilized electrodes for lithium batteries
US6680143B2 (en)	2004-01-20	Lithium metal oxide electrodes for lithium cells and batteries
JP5073662B2 (ja)	2012-11-14	スピネル構造を有する、リチウムセル電池のためのニッケルおよびマンガンをベースとする高電圧正電極材料
US7732096B2 (en)	2010-06-08	Lithium metal oxide electrodes for lithium batteries
EP2096692B1 (fr)	2013-10-02	Matériau de cathode actif et cathode et batterie au lithium l'incluant
EP1281207B1 (fr)	2016-03-09	Materiau positif actif pour batterie secondaire au lithium et son procede de preparation
EP4023603A1 (fr)	2022-07-06	Matériau actif d'électrode positive pour batterie secondaire au lithium-ion et batterie secondaire au lithium-ion
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EP4181234A1 (fr)	2023-05-17	Matériau actif de cathode pour batterie entièrement solide à base de sulfure, son procédé de préparation, complexe de cathode le comprenant et procédé de fabrication du complexe de cathode
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KR20170136601A (ko)	2017-12-11	비수계 전해질 이차 전지용 정극 활물질과 그의 제조 방법, 및 상기 정극 활물질을 이용한 비수계 전해질 이차 전지
KR101130318B1 (ko)	2012-03-26	리튬 이차 전지용 양극 활물질, 이의 제조방법 및 이를 포함하는 리튬 이차 전지
EP4170751B1 (fr)	2025-09-03	Matériau actif de cathode pour batterie secondaire au lithium et batterie secondaire au lithium le comprenant
JP3649996B2 (ja)	2005-05-18	非水電解質二次電池用正極活物質
JP5168829B2 (ja)	2013-03-27	正極活物質および非水電解質電池
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JP5076301B2 (ja)	2012-11-21	二次電池
JPH10116614A (ja)	1998-05-06	リチウム二次電池用正極材料
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JP3498947B2 - 再充電可能リチウムマンガン酸化物電池およびリチウムマンガン酸化物電池用材料 - Google Patents

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