JP3961568B2 - エポキシ化触媒の製造法 - Google Patents

エポキシ化触媒の製造法 Download PDF

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JP3961568B2
JP3961568B2 JP51468497A JP51468497A JP3961568B2 JP 3961568 B2 JP3961568 B2 JP 3961568B2 JP 51468497 A JP51468497 A JP 51468497A JP 51468497 A JP51468497 A JP 51468497A JP 3961568 B2 JP3961568 B2 JP 3961568B2
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amount
support
catalyst
silver
mixtures
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JP51468497A
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Japanese (ja)
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JPH11513305A (ja
JPH11513305A5 (2
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マツズ，マレク
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シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8946—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
JP51468497A 1995-10-06 1996-10-02 エポキシ化触媒の製造法 Expired - Fee Related JP3961568B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/540,233 US5739075A (en) 1995-10-06 1995-10-06 Process for preparing ethylene oxide catalysts
US08/540,233 1995-10-06
PCT/EP1996/004298 WO1997013579A1 (en) 1995-10-06 1996-10-02 Process for preparing epoxidation catalysts

Publications (3)

Publication Number Publication Date
JPH11513305A JPH11513305A (ja) 1999-11-16
JPH11513305A5 JPH11513305A5 (2) 2004-10-07
JP3961568B2 true JP3961568B2 (ja) 2007-08-22

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP51468497A Expired - Fee Related JP3961568B2 (ja) 1995-10-06 1996-10-02 エポキシ化触媒の製造法

Country Status (8)

Country Link
US (1) US5739075A (2)
EP (1) EP0874688B1 (2)
JP (1) JP3961568B2 (2)
AU (1) AU7284396A (2)
CA (1) CA2232942C (2)
DE (1) DE69618485T2 (2)
ES (1) ES2166468T3 (2)
WO (1) WO1997013579A1 (2)

Families Citing this family (102)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2744038B1 (fr) * 1996-01-26 1998-03-06 Pechiney Recherche Supports de catalyseur en mousse de sic revetue de cerine et systemes catalytiques correspondants
US5861519A (en) * 1997-05-23 1999-01-19 Arco Chemical Technology, L.P. Propylene oxide process using alkaline earth metal compound-supported silver catalysts containing tungsten and potassium promoters
US6383974B1 (en) * 1997-08-26 2002-05-07 Japan Energy Corporation Hydrorefining catalyst and method for manufacturing hydrorefining catalyst
US6812180B2 (en) * 1997-12-10 2004-11-02 Idemitsu Kosan Co., Ltd. Method for preparing catalyst
US7504525B2 (en) * 1998-09-14 2009-03-17 Shell Oil Company Catalyst composition
JP4698835B2 (ja) * 1998-09-14 2011-06-08 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒特性改良のため触媒表面からイオン化可能種を除去する方法
US7232786B2 (en) * 1998-09-14 2007-06-19 Shell Oil Company Catalyst composition
US7232918B2 (en) * 2001-11-06 2007-06-19 Shell Oil Company Catalyst composition
WO2000015334A1 (en) * 1998-09-14 2000-03-23 Shell Internationale Research Maatschappij B.V. Process for preparing catalysts with improved catalytic properties
TR200100749T2 (tr) * 1998-09-14 2001-10-22 Shell Internationale Research Maatschappij B.V. Epoksitleme katalizörü taşıyıcı, bunun hazırlanması ve kullanılması
US20070066480A1 (en) * 1999-10-25 2007-03-22 Moser William R Method of preparing compounds using cavitation and compounds formed therefrom
CA2397367A1 (en) * 2000-01-14 2001-07-19 Worcester Polytechnic Institute Method of preparing compounds using cavitation and compounds formed therefrom
US6403523B1 (en) * 2000-09-18 2002-06-11 Union Carbide Chemicals & Plastics Technology Corporation Catalysts for the oxidative dehydrogenation of hydrocarbons
DE10048844A1 (de) * 2000-10-02 2002-04-11 Basf Ag Verfahren zur Herstellung von Platinmetall-Katalysatoren
US7193094B2 (en) 2001-11-20 2007-03-20 Shell Oil Company Process and systems for the epoxidation of an olefin
US6831037B2 (en) * 2002-02-25 2004-12-14 Saint-Gobain Norpro Corporation Catalyst carriers
AU2003243757A1 (en) * 2002-06-28 2004-01-19 Shell Oil Company A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
DE60333292D1 (de) * 2002-06-28 2010-08-19 Shell Int Research Verfahren für den start eines epoxierungsprozesses und epoxidierungsverfahren für olefine
WO2004039790A1 (en) * 2002-10-28 2004-05-13 Shell Internationale Research Maatschappij B.V. Olefin oxide catalysts
TWI346574B (en) 2003-03-31 2011-08-11 Shell Int Research A catalyst composition, a process for preparing the catalyst composition and a use of the catalyst composition
IN2005DN04374A (2) * 2003-04-01 2010-01-15 Shell Int Research
US7348444B2 (en) * 2003-04-07 2008-03-25 Shell Oil Company Process for the production of an olefin oxide
US6858560B2 (en) 2003-04-23 2005-02-22 Scientific Design Co., Inc. Ethylene oxide catalyst
US20040224841A1 (en) * 2003-05-07 2004-11-11 Marek Matusz Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof
EP1624964B1 (en) 2003-05-07 2019-07-31 Shell International Research Maatschappij B.V. Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof
US20040225138A1 (en) * 2003-05-07 2004-11-11 Mcallister Paul Michael Reactor system and process for the manufacture of ethylene oxide
US8148555B2 (en) * 2003-06-26 2012-04-03 Shell Oil Company Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
US20060258532A1 (en) * 2003-08-22 2006-11-16 Thorsteinson Erlind M Improved alumina carriers and silver-based catalysts for the production of alkylene oxides
RU2340607C2 (ru) * 2003-08-22 2008-12-10 Дау Текнолоджи Инвестментс Ллс Модифицированные носители из оксида алюминия и катализаторы на основе серебра для получения алкиленоксидов
RU2394023C2 (ru) * 2003-10-10 2010-07-10 Эвоник Дегусса Гмбх Способ получения метилмеркаптана
EP2277622B1 (en) 2003-10-16 2013-01-09 Dow Technology Investments LLC Method for the preparation of catalysts having enhanced stability, efficiency and/or activity for alkylene oxide production
US6939979B2 (en) * 2003-11-10 2005-09-06 Scientific Design Co., Inc. Oxidation process and catalyst
TW200602123A (en) * 2004-04-01 2006-01-16 Shell Int Research Process for preparing a catalyst, the catalyst, and a use of the catalyst
TW200613056A (en) * 2004-04-01 2006-05-01 Shell Int Research A process for preparing a silver catalyst, the catalyst, and a use of the catalyst for olefin oxidation
TW200600190A (en) * 2004-04-01 2006-01-01 Shell Int Research Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation
US7479565B2 (en) * 2004-06-18 2009-01-20 Shell Oil Company Process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
RU2007101737A (ru) * 2004-06-18 2008-07-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Способ получения оксида олефина, 1,2-диола, 1,2-диолового простого эфира или алканоламина
US7521393B2 (en) * 2004-07-27 2009-04-21 Süd-Chemie Inc Selective hydrogenation catalyst designed for raw gas feed streams
US8536083B2 (en) 2004-09-01 2013-09-17 Shell Oil Company Olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier
WO2006028940A2 (en) 2004-09-01 2006-03-16 Shell Internationale Research Maatschappij B.V. An olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier
BRPI0515905A (pt) * 2004-09-24 2008-08-12 Shell Int Research processo para selecionar partìculas moldadas, um processo para instalar um sistema, um processo para reagir uma carga de alimentação gasosa em um tal sistema, um produto de programa de computação e um sistema de computação
CA2598523C (en) * 2005-02-21 2015-11-24 Shell Internationale Research Maatschappij B.V. An olefin epoxidation process, a catalyst for use in the process, a carrier for use in making the catalyst, and a process for making the carrier
CA2602163C (en) * 2005-03-22 2014-02-18 Shell Internationale Research Maatschappij B.V. A reactor system and process for the manufacture of ethylene oxide
TWI334363B (en) 2005-06-07 2010-12-11 Saint Gobain Ceramics A catalyst carrier
RU2007149318A (ru) 2005-06-07 2009-07-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Кктализатор, способ приготовления катализатора и способ получения оксида олефина, 1, 2-диола, эфира 1, 2-диола или алканоламина
US8791280B2 (en) * 2005-08-10 2014-07-29 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Process for preparation of catalyst carrier and its use in catalyst preparation
US20070213545A1 (en) * 2005-12-22 2007-09-13 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070154377A1 (en) * 2005-12-22 2007-07-05 Rekers Dominicus M Process for the removal of combustible volatile contaminant materials from a process stream
US20070203348A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070203352A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070203350A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070197808A1 (en) * 2005-12-22 2007-08-23 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070197801A1 (en) * 2005-12-22 2007-08-23 Bolk Jeroen W Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitables for such a process
US7704908B2 (en) * 2005-12-22 2010-04-27 Shell Oil Company Method for reusing rhenium from a donor spent epoxidation catalyst
US7459589B2 (en) * 2005-12-22 2008-12-02 Shell Oil Company Process for the preparation of an alkylene glycol
GB2433705A (en) * 2005-12-22 2007-07-04 Shell Int Research A method of installing an epoxidation catalyst
US20070203349A1 (en) * 2005-12-22 2007-08-30 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
US20070151451A1 (en) * 2005-12-22 2007-07-05 Rekers Dominicus M Process for the cooling, concentration or purification of ethylene oxide
CA2641225A1 (en) * 2006-02-03 2007-08-16 Shell Internationale Research Maatschappij B.V. A process for treating a catalyst, the catalyst, and use of the catalyst
US8097557B2 (en) 2006-08-08 2012-01-17 Sd Lizenverwertungsgesellschaft Mbh & Co. Kg Two-stage calcination for catalyst production
WO2008064076A2 (en) * 2006-11-20 2008-05-29 Shell Oil Company A process for treating a carrier, a process for preparing a catalyst, the catalyst, and use of the catalyst
US20080154051A1 (en) * 2006-12-20 2008-06-26 Jeroen Willem Bolk Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process
US20080154052A1 (en) * 2006-12-20 2008-06-26 Jeroen Willem Bolk Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process
JP5542659B2 (ja) * 2007-05-09 2014-07-09 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー エポキシ化触媒、触媒を調製する方法、および酸化オレフィン、１，２−ジオール、１，２−ジオールエーテル、１，２−カーボネートまたはアルカノールアミンの製造方法
CN101715444B (zh) * 2007-05-09 2012-11-21 国际壳牌研究有限公司 环氧化催化剂及其制备方法和生产环氧烷、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或烷醇胺的方法
AR066469A1 (es) * 2007-05-09 2009-08-19 Shell Int Research Un proceso de produccion de oxido de olefina , 1,2- diol, 1,2- diol eter, 1,2- carbonato o alcanolamina
RU2452564C2 (ru) 2007-05-11 2012-06-10 Барри Дж. БИЛЛИГ Активация высокоселективных катализаторов в установках синтеза оксидов олефинов
US9144765B2 (en) 2007-05-18 2015-09-29 Shell Oil Company Reactor system, an absorbent and a process for reacting a feed
AR066574A1 (es) * 2007-05-18 2009-08-26 Shell Int Research Un sistema reactor, un proceso de produccion de oxido de olefina 1,2-diol 1,2-diol eter , 1,2-carbonato o alcanolamina
US8569527B2 (en) 2007-05-18 2013-10-29 Shell Oil Company Reactor system, an absorbent and a process for reacting a feed
WO2009029578A2 (en) * 2007-08-27 2009-03-05 Shell Oil Company A carrier, a process for preparing the carrier, an olefin epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
US7763096B2 (en) 2008-05-06 2010-07-27 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Recovery of rhenium
KR101629037B1 (ko) * 2008-05-07 2016-06-09 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 에폭시화 방법의 스타트업 방법, 산화에틸렌, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법
CA2723592C (en) 2008-05-07 2016-08-16 Shell Internationale Research Maatschappij B.V. A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
CA2724084A1 (en) 2008-05-15 2009-11-19 Shell Internationale Research Maatschappij B.V. Process for the preparation of an alkylene carbonate and an alkylene glycol
EP2285795B1 (en) 2008-05-15 2017-03-22 Shell Internationale Research Maatschappij B.V. Process for the preparation of alkylene carbonate and/or alkylene glycol
TWI462912B (zh) * 2009-04-21 2014-12-01 Dow Technology Investments Llc 環氧化反應及其操作條件
CA2759397C (en) * 2009-04-21 2019-01-29 Dow Technology Investments Llc Improved method of achieving and maintaining a specified alkylene oxide production parameter with a high efficiency catalyst
JP2012524785A (ja) * 2009-04-21 2012-10-18 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 高効率触媒を用いたアルキレンオキシド簡易製造方法
US8845975B2 (en) * 2009-12-28 2014-09-30 Dow Technology Investments Llc Method of controlling the production of silver chloride on a silver catalyst in the production of alkylene oxides
EP2542340A4 (en) 2010-03-01 2014-03-19 Shell Oil Co EPOXIDATION CATALYST, PROCESS FOR PREPARING THE CATALYST AND METHOD FOR PRODUCING AN OLEFIN OXIDE
US8648225B2 (en) * 2010-04-12 2014-02-11 Chevron Phillips Chemical Company Lp Process for hydrogenating highly unsaturated hydrocarbons and catalyst therefor
TW201208763A (en) * 2010-05-17 2012-03-01 Scient Design Co Method for making a highly selective ethylene oxide catalyst
JP2013505993A (ja) * 2010-07-10 2013-02-21 住友化学株式会社 酸化オレフィンの製造方法
US9018126B2 (en) * 2010-07-13 2015-04-28 Shell Oil Company Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide
CN102441435B (zh) * 2010-09-30 2014-01-01 中国石油化工股份有限公司 制备银催化剂用氧化铝载体的方法、由此得到的载体及其应用
US8742147B2 (en) 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
US8742146B2 (en) 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
BR112013027585B1 (pt) 2011-04-29 2020-09-29 Shell Internationale Research Maatschappij B.V Método para melhorar a seletividade de um catalisador de alta seletividade suportado usado na epoxidação de etileno e método para preparar um 1,2-diol, um 1,2-diol éter, um 1,2-carbonato ou uma alcanolamina
CN102950029B (zh) * 2011-08-19 2016-03-30 中国石油化工股份有限公司 改性氧化铝载体、其制备方法、由其制成的银催化剂及其在环氧乙烷生产中的应用
CN104884167B (zh) * 2012-12-31 2017-07-07 科学设计公司 用于生产改善的环氧乙烷催化剂的煅烧方法
US10300462B2 (en) 2013-12-19 2019-05-28 Scientific Design Company, Inc. High concentration silver solutions for ethylene oxide catalyst preparation
BR112018011943B1 (pt) 2015-12-15 2021-11-30 Shell Internationale Research Maatschappij B.V. Processo e sistema de reação para produção de óxido de etileno, carbonato de etileno e/ou etilenoglicol a partir de etileno
BR112018011947B1 (pt) 2015-12-15 2021-06-01 Shell Internationale Research Maatschappij B.V. Processo e sistema de reação para produção de óxido de etileno, carbonato de etileno e/ou etilenoglicol a partir de etileno
WO2017102698A1 (en) 2015-12-15 2017-06-22 Shell Internationale Research Maatschappij B.V. Processes and systems for removing an alkyl iodide impurity from a recycle gas stream in the production of ethylene oxide
EP3389843B1 (en) 2015-12-15 2020-09-30 Shell Internationale Research Maatschappij B.V. Guard bed process
TWI772330B (zh) 2016-10-14 2022-08-01 荷蘭商蜆殼國際研究所 用於定量分析氣態製程流之方法及設備
US11801493B2 (en) 2016-12-02 2023-10-31 Shell Usa, Inc. Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide
CN110639518A (zh) * 2019-09-03 2020-01-03 北京氦舶科技有限责任公司 一种乙烯环氧化反应用银催化剂及其制备方法和应用
CA3204704A1 (en) 2020-12-29 2022-07-07 Shell Internationale Research Maatschappij B.V. Process for the production of ethylene oxide
EP4673492A2 (en) 2023-03-02 2026-01-07 Basf Se Environmenal friendly ethylene oxide, propylene oxide and downstream products
WO2024213626A1 (en) 2023-04-12 2024-10-17 Basf Se Vinyl acetate having low deuterium content

Family Cites Families (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3316279A (en) * 1964-06-09 1967-04-25 Union Oil Co Preparation of olefin oxides
GB1325715A (en) * 1969-12-23 1973-08-08 Exxon Research Engineering Co Bimetallic catalyst manufacture and use in ethylene oxidation
US3844981A (en) * 1969-12-23 1974-10-29 Exxon Research Engineering Co Method for preparation of olefin oxidation catalyst
US3702259A (en) * 1970-12-02 1972-11-07 Shell Oil Co Chemical production of metallic silver deposits
US4356312A (en) * 1972-01-07 1982-10-26 Shell Oil Company Ethylene oxide process
US4012425A (en) * 1972-01-07 1977-03-15 Shell Oil Company Ethylene oxide process
US4010115A (en) * 1972-01-07 1977-03-01 Shell Oil Company Catalyst for the oxidation of ethylene to ethylene oxide
US3962285A (en) * 1972-06-05 1976-06-08 Exxon Research And Engineering Company Olefin oxidation process
US3972829A (en) * 1974-11-07 1976-08-03 Universal Oil Products Company Method of depositing a catalytically active metallic component on a carrier material
US4005049A (en) * 1975-05-23 1977-01-25 Standard Oil Company (Indiana) Silver catalysts
US4212772A (en) * 1976-05-19 1980-07-15 Basf Aktiengesellschaft Catalyst for the manufacture of ethylene oxide
EP0002045B1 (de) * 1977-11-19 1981-09-02 BASF Aktiengesellschaft Verfahren zur Herstellung eines Äthylenoxydkatalysators
DE2844402A1 (de) * 1978-10-12 1980-04-30 Basf Ag Silber enthaltende traegerkatalysatoren, verfahren zu ihrer herstellung und verfahren zur herstellung von aethylenoxid mittels dieser katalysatoren
DE2904919A1 (de) * 1979-02-09 1980-08-21 Basf Ag Verfahren zur herstellung und regenerierung von traegerkatalysatoren sowie deren verwendung fuer die herstellung von aethylenoxid
JPS56108533A (en) * 1980-01-30 1981-08-28 Nippon Shokubai Kagaku Kogyo Co Ltd Silver catalyst for preparing ethylene oxide
JPS56149320A (en) * 1980-04-21 1981-11-19 Sumitomo Alum Smelt Co Ltd Manufacture of activated alumina molding with low density
NL8201396A (nl) * 1982-04-01 1983-11-01 Dow Chemical Nederland Zilver katalysator en een werkwijze voor de bereiding daarvan.
US4459372A (en) * 1982-08-25 1984-07-10 Uop Inc. Surface-metallated refractory inorganic oxides, method of their preparation and catalyst supported on the oxides
GB8304749D0 (en) * 1983-02-21 1983-03-23 Ici Plc Catalysts
EP0172280B1 (en) * 1983-03-14 1988-03-09 E.I. Du Pont De Nemours And Company Catalyst composition
US4579728A (en) * 1985-04-24 1986-04-01 Shell Oil Company Wide pore alumina supports
EP0211521B1 (en) * 1985-07-31 1990-03-21 Imperial Chemical Industries Plc Process of promoting catalysts for the production of alkylene oxides
DE3675601D1 (de) * 1985-08-16 1990-12-20 Sumitomo Chemical Co Verfahren zur vorbereitung einer festen base.
GB8611121D0 (en) * 1986-05-07 1986-06-11 Shell Int Research Silver catalyst
US4808738A (en) * 1986-10-31 1989-02-28 Shell Oil Company Ethylene oxide process
US4766105A (en) * 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4761394A (en) * 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US5057481A (en) * 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US4908343A (en) * 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
GB8716653D0 (en) * 1987-07-15 1987-08-19 Shell Int Research Silver-containing catalyst
US4897498A (en) * 1988-01-28 1990-01-30 Eastman Kodak Company Selective monoepoxidation of olefins
CN1009437B (zh) * 1988-02-03 1990-09-05 中国石油化工总公司 乙烯氧化制环氧乙烷高效银催化剂
US5072886A (en) * 1988-09-09 1991-12-17 Simon Fraser University Method of preparing a new ultra-fine particle transition alumina
US5081324A (en) * 1989-01-11 1992-01-14 Amoco Corporation Lower alkane conversion
US5028577A (en) * 1989-01-11 1991-07-02 Amoco Corporation Lower alkane conversion catalysts
US4992409A (en) * 1989-01-11 1991-02-12 Amoco Corporation Catalyst and method of preparing the catalyst for lower alkane conversion
US5130286A (en) * 1989-01-11 1992-07-14 Amoco Corporation Catalyst for lower alkane conversion
EP0383636A1 (en) * 1989-02-17 1990-08-22 Nippon Shokubai Co., Ltd. Carrier for catalyst and method for production thereof
DE3905578A1 (de) * 1989-02-23 1990-08-30 Basf Ag Verfahren zur herstellung eines silberkatalysators
US5071815A (en) * 1989-09-01 1991-12-10 British Columbia Research Corporation Method for producing catalysts
US5037794A (en) * 1989-09-12 1991-08-06 The B. F. Goodrich Company Attrition resistant catalyst support
US5081096A (en) * 1990-07-25 1992-01-14 Eastman Kodak Company Epoxidation catalyst
US5102848A (en) * 1990-09-28 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US5100859A (en) * 1991-01-22 1992-03-31 Norton Company Catalyst carrier
DE4106508A1 (de) * 1991-03-01 1992-09-03 Basf Ag Silberkatalysator
US5153165A (en) * 1991-05-09 1992-10-06 Phillips Petroleum Company Preparation of alkaline earth oxide catalysts
JP3312916B2 (ja) * 1991-06-06 2002-08-12 三菱化学株式会社 酸化エチレン製造用銀触媒
US5502020A (en) * 1993-04-14 1996-03-26 Mitsubishi Petrochemical Co., Ltd. Catalyst for production of ethylene oxide and process for producing the catalyst
US5447897A (en) * 1993-05-17 1995-09-05 Shell Oil Company Ethylene oxide catalyst and process
US5380697A (en) * 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
US5364826A (en) * 1993-09-13 1994-11-15 Shell Oil Company Process for preparing ethylene oxide catalysts
EP0716884B2 (en) * 1994-12-15 2009-09-23 Shell Internationale Researchmaatschappij B.V. Process for preparing ethylene oxide catalysts

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WO1997013579A1 (en) 1997-04-17
CA2232942A1 (en) 1997-04-17
EP0874688A1 (en) 1998-11-04
ES2166468T3 (es) 2002-04-16
CA2232942C (en) 2005-01-04
AU7284396A (en) 1997-04-30
DE69618485D1 (de) 2002-02-14
EP0874688B1 (en) 2002-01-09

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