JP4619405B2 - 基板上に硬化面を形成する方法 - Google Patents

基板上に硬化面を形成する方法 Download PDF

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Publication number: JP4619405B2
Authority: JP; Japan
Prior art keywords: metallic glass; substrate; alloy; steel; hardness
Prior art date: 2004-05-06
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

JP2007511510A

Other languages

English (en)

Japanese (ja)

Other versions

JP2007536430A (ja

Inventor

ブラナガン，ダニエル，ジェイ．

Original Assignee

バテルエナジーアライアンス，エルエルシー

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2004-05-06

Filing date

2005-05-02

Publication date

2011-01-26

2004-05-06 Priority claimed from US10/841,873 external-priority patent/US7323071B1/en

2005-05-02 Application filed by バテルエナジーアライアンス，エルエルシー filed Critical バテルエナジーアライアンス，エルエルシー

2007-12-13 Publication of JP2007536430A publication Critical patent/JP2007536430A/ja

2011-01-26 Application granted granted Critical

2011-01-26 Publication of JP4619405B2 publication Critical patent/JP4619405B2/ja

2025-05-02 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000758 substrate Substances 0.000 title claims description 51
238000000034 method Methods 0.000 title claims description 50
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 173
239000011651 chromium Substances 0.000 claims description 154
239000000956 alloy Substances 0.000 claims description 89
229910045601 alloy Inorganic materials 0.000 claims description 88
239000005300 metallic glass Substances 0.000 claims description 67
239000000463 material Substances 0.000 claims description 50
238000000576 coating method Methods 0.000 claims description 44
239000011248 coating agent Substances 0.000 claims description 36
239000000843 powder Substances 0.000 claims description 32
238000010438 heat treatment Methods 0.000 claims description 26
239000007921 spray Substances 0.000 claims description 24
238000001816 cooling Methods 0.000 claims description 21
238000005507 spraying Methods 0.000 claims description 19
229910052804 chromium Inorganic materials 0.000 claims description 12
229910052742 iron Inorganic materials 0.000 claims description 12
230000008018 melting Effects 0.000 claims description 11
238000002844 melting Methods 0.000 claims description 11
238000002425 crystallisation Methods 0.000 claims description 9
230000008025 crystallization Effects 0.000 claims description 9
239000007769 metal material Substances 0.000 claims description 9
229910052698 phosphorus Inorganic materials 0.000 claims description 9
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 8
229910052750 molybdenum Inorganic materials 0.000 claims description 8
229910052721 tungsten Inorganic materials 0.000 claims description 8
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 7
239000002159 nanocrystal Substances 0.000 claims description 7
239000011574 phosphorus Substances 0.000 claims description 7
229910052796 boron Inorganic materials 0.000 claims description 5
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 4
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
239000011733 molybdenum Substances 0.000 claims description 4
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 4
239000010937 tungsten Substances 0.000 claims description 4
229910052720 vanadium Inorganic materials 0.000 claims description 4
239000002178 crystalline material Substances 0.000 claims description 3
229910052735 hafnium Inorganic materials 0.000 claims description 3
229910052758 niobium Inorganic materials 0.000 claims description 3
229910052715 tantalum Inorganic materials 0.000 claims description 3
229910052719 titanium Inorganic materials 0.000 claims description 3
229910052726 zirconium Inorganic materials 0.000 claims description 3
229910052748 manganese Inorganic materials 0.000 claims description 2
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239000002105 nanoparticle Substances 0.000 claims 1
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239000010959 steel Substances 0.000 description 80
239000000203 mixture Substances 0.000 description 36
239000010410 layer Substances 0.000 description 23
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238000012360 testing method Methods 0.000 description 17
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239000002184 metal Substances 0.000 description 11
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238000004455 differential thermal analysis Methods 0.000 description 9
239000000314 lubricant Substances 0.000 description 9
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230000015572 biosynthetic process Effects 0.000 description 4
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238000000113 differential scanning calorimetry Methods 0.000 description 4
239000001307 helium Substances 0.000 description 4
229910052734 helium Inorganic materials 0.000 description 4
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 4
239000007788 liquid Substances 0.000 description 4
239000000155 melt Substances 0.000 description 4
229910052759 nickel Inorganic materials 0.000 description 4
230000036961 partial effect Effects 0.000 description 4
239000002243 precursor Substances 0.000 description 4
230000002829 reductive effect Effects 0.000 description 4
229910052710 silicon Inorganic materials 0.000 description 4
229910052717 sulfur Inorganic materials 0.000 description 4
229910052723 transition metal Inorganic materials 0.000 description 4
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
238000007545 Vickers hardness test Methods 0.000 description 3
238000002441 X-ray diffraction Methods 0.000 description 3
230000009471 action Effects 0.000 description 3
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238000004519 manufacturing process Methods 0.000 description 3
229910000734 martensite Inorganic materials 0.000 description 3
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239000010935 stainless steel Substances 0.000 description 3
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230000003068 static effect Effects 0.000 description 3
239000011593 sulfur Substances 0.000 description 3
238000004381 surface treatment Methods 0.000 description 3
UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
239000012300 argon atmosphere Substances 0.000 description 2
238000005452 bending Methods 0.000 description 2
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238000010586 diagram Methods 0.000 description 2
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238000009718 spray deposition Methods 0.000 description 2
238000002207 thermal evaporation Methods 0.000 description 2
-1 transition metal carbides Chemical class 0.000 description 2
150000003624 transition metals Chemical class 0.000 description 2
101100330726 Arabidopsis thaliana DAR5 gene Proteins 0.000 description 1
229910000967 As alloy Inorganic materials 0.000 description 1
229910001150 Cartridge brass Inorganic materials 0.000 description 1
229910001018 Cast iron Inorganic materials 0.000 description 1
229910052684 Cerium Inorganic materials 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
229910052692 Dysprosium Inorganic materials 0.000 description 1
229910052691 Erbium Inorganic materials 0.000 description 1
229910052693 Europium Inorganic materials 0.000 description 1
229910000640 Fe alloy Inorganic materials 0.000 description 1
229910052688 Gadolinium Inorganic materials 0.000 description 1
229910052689 Holmium Inorganic materials 0.000 description 1
229910052765 Lutetium Inorganic materials 0.000 description 1
229910052779 Neodymium Inorganic materials 0.000 description 1
229910052777 Praseodymium Inorganic materials 0.000 description 1
229910052772 Samarium Inorganic materials 0.000 description 1
229910052581 Si3N4 Inorganic materials 0.000 description 1
238000003917 TEM image Methods 0.000 description 1
229910052771 Terbium Inorganic materials 0.000 description 1
229910052775 Thulium Inorganic materials 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
229910000797 Ultra-high-strength steel Inorganic materials 0.000 description 1
229910052769 Ytterbium Inorganic materials 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
239000010953 base metal Substances 0.000 description 1
238000005422 blasting Methods 0.000 description 1
230000008859 change Effects 0.000 description 1
230000002860 competitive effect Effects 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
238000005520 cutting process Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000004880 explosion Methods 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
238000005242 forging Methods 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
229910052732 germanium Inorganic materials 0.000 description 1
230000009477 glass transition Effects 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
230000020169 heat generation Effects 0.000 description 1
238000001192 hot extrusion Methods 0.000 description 1
238000001513 hot isostatic pressing Methods 0.000 description 1
238000007731 hot pressing Methods 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
238000007373 indentation Methods 0.000 description 1
229910052746 lanthanum Inorganic materials 0.000 description 1
229910001004 magnetic alloy Inorganic materials 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
239000011572 manganese Substances 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
238000005259 measurement Methods 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
238000000465 moulding Methods 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
238000007750 plasma spraying Methods 0.000 description 1
238000007747 plating Methods 0.000 description 1
238000009702 powder compression Methods 0.000 description 1
238000009703 powder rolling Methods 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000003672 processing method Methods 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
238000010791 quenching Methods 0.000 description 1
230000008439 repair process Effects 0.000 description 1
230000027756 respiratory electron transport chain Effects 0.000 description 1
238000005096 rolling process Methods 0.000 description 1
238000001878 scanning electron micrograph Methods 0.000 description 1
238000005480 shot peening Methods 0.000 description 1
229910021332 silicide Inorganic materials 0.000 description 1
HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
238000009751 slip forming Methods 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
238000007711 solidification Methods 0.000 description 1
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239000002915 spent fuel radioactive waste Substances 0.000 description 1
238000007783 splat quenching Methods 0.000 description 1
239000000161 steel melt Substances 0.000 description 1
239000013526 supercooled liquid Substances 0.000 description 1
239000002344 surface layer Substances 0.000 description 1
239000011135 tin Substances 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1

Images

Classifications

- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C45/00—Amorphous alloys
- C22C45/02—Amorphous alloys with iron as the major constituent
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/003—Making ferrous alloys making amorphous alloys
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/02—Coating starting from inorganic powder by application of pressure only
- C23C24/04—Impact or kinetic deposition of particles
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
- C23C4/067—Metallic material containing free particles of non-metal elements, e.g. carbon, silicon, boron, phosphorus or arsenic
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites

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Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Mechanical Engineering (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Plasma & Fusion (AREA)
Physics & Mathematics (AREA)
Coating By Spraying Or Casting (AREA)
Other Surface Treatments For Metallic Materials (AREA)
Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Physical Vapour Deposition (AREA)

JP2007511510A 2004-05-06 2005-05-02 基板上に硬化面を形成する方法 Expired - Fee Related JP4619405B2 (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US10/841,873 US7323071B1 (en)	2000-11-09	2004-05-06	Method for forming a hardened surface on a substrate
PCT/US2005/015365 WO2005116286A2 (en)	2004-05-06	2005-05-02	Method for forming a hardened surface on a substrate

Publications (2)

Publication Number	Publication Date
JP2007536430A JP2007536430A (ja)	2007-12-13
JP4619405B2 true JP4619405B2 (ja)	2011-01-26

Family

ID=35451487

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP2007511510A Expired - Fee Related JP4619405B2 (ja)	2004-05-06	2005-05-02	基板上に硬化面を形成する方法

Country Status (7)

Country	Link
EP (1)	EP1749113A4 (de)
JP (1)	JP4619405B2 (de)
KR (1)	KR100908937B1 (de)
CN (1)	CN1997765B (de)
AU (1)	AU2005248324B2 (de)
CA (1)	CA2565090C (de)
WO (1)	WO2005116286A2 (de)

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RU2533982C2 (ru) *	2009-04-30	2014-11-27	Шеврон Ю.Эс.Эй.Инк.	Обработка поверхности аморфных покрытий
JP5638809B2 (ja) *	2010-01-12	2014-12-10	株式会社中山アモルファス	アモルファス皮膜付き金属材およびアモルファス皮膜形成方法
ES2686928T3 (es) *	2012-05-16	2018-10-22	Max-Planck-Institut Für Eisenforschung GmbH	Proceso para la producción de un carburo mesoporoso
US10392685B2 (en) *	2013-10-31	2019-08-27	The Regents Of The University Of Michigan	Composite metal alloy material
CA2939134A1 (en) *	2014-02-14	2015-08-20	The Nanosteel Company, Inc.	Shot material and shot peening method
WO2015176061A1 (en) *	2014-05-16	2015-11-19	The Nanosteel Company, Inc.	Layered construction of metallic materials
TWI532855B (zh)	2015-12-03	2016-05-11	財團法人工業技術研究院	鐵基合金塗層與其形成方法
CN105547051A (zh) *	2015-12-12	2016-05-04	西安交通大学	一种金属玻璃增强密度梯度型装甲防护装置
NL1041641B1 (en) *	2015-12-22	2017-07-03	Bosch Gmbh Robert	Transverse element provided with a nanocrystalline surface layer for a drive belt for a continuously variable transmission and method for producing it.
CN106893963B (zh) *	2017-01-20	2019-02-15	中国人民解放军装甲兵工程学院	一种用于制备Al-Fe-Nb-Cr非晶涂层的粉芯丝材
CN110387542B (zh) *	2019-08-23	2021-04-20	兰州城市学院	一种高耐磨金属陶瓷涂层制备设备
CN113174547B (zh) *	2021-04-30	2022-11-04	郑州大学	铁基非晶合金粉、其制备方法及在激光熔覆中的应用
CN113652625B (zh) *	2021-08-17	2023-05-05	上海浦海求实电力新技术股份有限公司	用于钻石型配电网的电力排管内表面喷涂材料及其制备方法
CN114854959A (zh) *	2022-05-11	2022-08-05	广西玉柴机器配件制造有限公司	一种超高强度高延伸率厚大球墨铸铁件及其热处理方法

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JPH07256363A (ja) *	1994-03-16	1995-10-09	Kawasaki Heavy Ind Ltd	薄板材成形用金型及びこの金型を使用する酸化物分散強化合金薄板材の成形方法
US6258185B1 (en) *	1999-05-25	2001-07-10	Bechtel Bwxt Idaho, Llc	Methods of forming steel
JP4093688B2 (ja) *	1999-10-07	2008-06-04	Ｊｆｅスチール株式会社	連続鋳造用鋳型
JP3805601B2 (ja) *	2000-04-20	2006-08-02	独立行政法人科学技術振興機構	高耐蝕性・高強度Ｆｅ−Ｃｒ基バルクアモルファス合金
US6689234B2 (en) *	2000-11-09	2004-02-10	Bechtel Bwxt Idaho, Llc	Method of producing metallic materials
EP1633558B1 (de) *	2003-05-23	2018-10-24	The Nanosteel Company, Inc.	Aus auf eisen basierenden glaslegierungen geformtes, geschichtetes metallisches material

2005
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WO2005116286A2 (en)	2005-12-08
CA2565090A1 (en)	2005-12-08
AU2005248324A1 (en)	2005-12-08
CN1997765B (zh)	2012-05-30
CN1997765A (zh)	2007-07-11
CA2565090C (en)	2012-01-24
JP2007536430A (ja)	2007-12-13
WO2005116286A3 (en)	2006-09-08
AU2005248324B2 (en)	2008-08-28
EP1749113A2 (de)	2007-02-07
KR20090014422A (ko)	2009-02-10
EP1749113A4 (de)	2009-04-15
KR100908937B1 (ko)	2009-07-22

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