JP5947792B2 - Ｃｏ気相カップリングによるシュウ酸ジアルキルの合成に用いるモノリス構造体触媒の調製方法、及びシュウ酸ジアルキルの製造方法 - Google Patents

Ｃｏ気相カップリングによるシュウ酸ジアルキルの合成に用いるモノリス構造体触媒の調製方法、及びシュウ酸ジアルキルの製造方法 Download PDF

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JP5947792B2
JP5947792B2 JP2013512744A JP2013512744A JP5947792B2 JP 5947792 B2 JP5947792 B2 JP 5947792B2 JP 2013512744 A JP2013512744 A JP 2013512744A JP 2013512744 A JP2013512744 A JP 2013512744A JP 5947792 B2 JP5947792 B2 JP 5947792B2
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dialkyl oxalate
structure catalyst
active ingredient
monolith structure
catalyst
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Japanese (ja)
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JP2013533105A (ja
Inventor
新賓 馬
新賓 馬
玉軍 趙
玉軍 趙
保偉 王
保偉 王
勝平 王
勝平 王
静 呂
静 呂
振花 李
振花 李
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Tianjin University
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Tianjin University
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Priority claimed from CN201010191579.6A external-priority patent/CN101851160B/zh
Priority claimed from CN2010101915809A external-priority patent/CN101850273B/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8906—Iron and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
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    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/894—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8946—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
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    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8986—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0242—Coating followed by impregnation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2013512744A 2010-06-04 2011-05-31 Ｃｏ気相カップリングによるシュウ酸ジアルキルの合成に用いるモノリス構造体触媒の調製方法、及びシュウ酸ジアルキルの製造方法 Expired - Fee Related JP5947792B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CN201010191579.6 2010-06-04
CN201010191579.6A CN101851160B (zh) 2010-06-04 2010-06-04 使用规整催化剂由co气相偶联合成草酸酯的生产方法
CN201010191580.9 2010-06-04
CN2010101915809A CN101850273B (zh) 2010-06-04 2010-06-04 由co气相偶联合成草酸酯的规整催化剂及其制备方法
PCT/CN2011/075018 WO2011150834A1 (zh) 2010-06-04 2011-05-31 用于co气相偶联合成草酸酯的规整催化剂及其制备方法与应用

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JP2013533105A JP2013533105A (ja) 2013-08-22
JP5947792B2 true JP5947792B2 (ja) 2016-07-06

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US (1) US20130150617A1 (2)
JP (1) JP5947792B2 (2)
IN (1) IN2013CN00099A (2)
WO (1) WO2011150834A1 (2)

Families Citing this family (6)

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Publication number Priority date Publication date Assignee Title
CN105435783B (zh) * 2014-08-27 2018-02-13 中国石油化工股份有限公司 Co气相偶联合成草酸酯的催化剂
CN107335447B (zh) * 2017-06-15 2020-10-27 华南理工大学 一种用于净化挥发性有机物的催化剂及其制备方法
CN111185192A (zh) * 2018-11-15 2020-05-22 河南城建学院 一种用于草酸二甲酯合成的催化剂载体和催化剂
CN111604059A (zh) * 2019-02-22 2020-09-01 上海诺哈尔化工技术有限公司 一种用于草酸酯合成的催化剂及其制备方法和应用
CN110479287A (zh) * 2019-09-12 2019-11-22 西南石油大学 一种用于合成碳酸二甲酯的整体式催化剂及其制备方法、应用方法
EP4171810A1 (en) * 2020-06-30 2023-05-03 Dow Technology Investments LLC Processes for reducing the rate of pressure drop increase in a vessel

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JPS5980630A (ja) * 1982-11-01 1984-05-10 Ube Ind Ltd シユウ酸ジエステルの製法
IT1097268B (it) * 1978-06-23 1985-08-31 Montedison Spa Processo per la preparazione di esteri dell'acido ossalico
DE2946685C2 (de) * 1979-11-20 1985-06-20 Degussa Ag, 6000 Frankfurt Verfahren zur Herstellung eines mit katalyseförderndem Metaloxid beschichteten, in einem Metallmantel angeordneten Verbundkörpers
US4487958A (en) * 1982-09-30 1984-12-11 Union Carbide Corporation Process for preparing a diester of oxalic acid
JPH06145113A (ja) * 1992-11-10 1994-05-24 Daicel Chem Ind Ltd 炭酸ジエステルの製造法
JP2812418B2 (ja) * 1993-05-21 1998-10-22 宇部興産株式会社 エステル化合物の製造法
JP3804813B2 (ja) * 1996-04-16 2006-08-02 宇部興産株式会社 シュウ酸ジエステルの製造法
JP2002273175A (ja) * 2001-03-14 2002-09-24 Toyota Motor Corp 排気ガス浄化装置の製造方法
CN101138722A (zh) * 2007-10-10 2008-03-12 天津大学 Co低压气相合成草酸酯的催化剂及其制备方法
JP2009165904A (ja) * 2008-01-10 2009-07-30 Honda Motor Co Ltd 排ガス浄化装置
CN101850273B (zh) * 2010-06-04 2012-07-18 天津大学 由co气相偶联合成草酸酯的规整催化剂及其制备方法
CN101851160B (zh) * 2010-06-04 2013-03-06 天津大学 使用规整催化剂由co气相偶联合成草酸酯的生产方法

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WO2011150834A1 (zh) 2011-12-08
IN2013CN00099A (2) 2015-07-03
US20130150617A1 (en) 2013-06-13
JP2013533105A (ja) 2013-08-22

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