JP6162425B2 - 金属調化粧板 - Google Patents
金属調化粧板 Download PDFInfo
- Publication number
- JP6162425B2 JP6162425B2 JP2013034106A JP2013034106A JP6162425B2 JP 6162425 B2 JP6162425 B2 JP 6162425B2 JP 2013034106 A JP2013034106 A JP 2013034106A JP 2013034106 A JP2013034106 A JP 2013034106A JP 6162425 B2 JP6162425 B2 JP 6162425B2
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- JP
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- Prior art keywords
- layer
- resin
- adhesive
- metal vapor
- impregnated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910052751 metal Inorganic materials 0.000 title claims description 17
- 239000002184 metal Substances 0.000 title claims description 17
- 239000000853 adhesive Substances 0.000 claims description 34
- 230000001070 adhesive effect Effects 0.000 claims description 34
- 239000011162 core material Substances 0.000 claims description 10
- 229920005989 resin Polymers 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 10
- -1 polyethylene terephthalate Polymers 0.000 claims description 9
- 229920000877 Melamine resin Polymers 0.000 claims description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 6
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 6
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 5
- 229920001568 phenolic resin Polymers 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000010410 layer Substances 0.000 description 12
- 239000000123 paper Substances 0.000 description 11
- 239000012790 adhesive layer Substances 0.000 description 8
- 238000007740 vapor deposition Methods 0.000 description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 7
- 229910052802 copper Inorganic materials 0.000 description 7
- 239000010949 copper Substances 0.000 description 7
- 238000005470 impregnation Methods 0.000 description 5
- 229920002635 polyurethane Polymers 0.000 description 5
- 239000004814 polyurethane Substances 0.000 description 5
- 239000002985 plastic film Substances 0.000 description 4
- 229920002799 BoPET Polymers 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 229920006255 plastic film Polymers 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000007731 hot pressing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000012792 core layer Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- MHCLJIVVJQQNKQ-UHFFFAOYSA-N ethyl carbamate;2-methylprop-2-enoic acid Chemical compound CCOC(N)=O.CC(=C)C(O)=O MHCLJIVVJQQNKQ-UHFFFAOYSA-N 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 125000005641 methacryl group Chemical group 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Landscapes
- Laminated Bodies (AREA)
Description
26g/m2のオーバーレイ原紙にメラミン−ホルムアルデヒド樹脂を主成分とする樹脂液を含浸率が130%となるように含浸、乾燥して接着性シート(9)を得た。
198g/m2のクラフト紙にフェノール−ホルムアルデヒド樹脂を主成分とする樹脂液を含浸率が53%となるように含浸、乾燥してフェノール樹脂含浸コア紙を得た。
下から順に、コア材(10)としてフェノール樹脂含浸コア紙を4枚、接着性シート(9)紙を1枚、銅蒸着フィルム(8)を1枚積層し、132℃、70kg/cm2の熱圧条件で成形して金属調化粧板を得た。
実施例1において、厚みが25μmで透明PETフィルム(6)のない銅蒸着フィルムを用いた以外は同様に実施した。
実施例1において、接着性シート(9)を用いなかった以外は同様に実施した。
実施例1において、銅蒸着フィルムに代えて厚み1mmのステンレス板を用い、接着性シートを用いなかった以外は同様に実施した。
外観:目視による。欠点なしを○、コア層の地合いを拾い凹凸があるものを×とした。
層間密着性:沸騰水の中に2時間浸漬後、80℃の恒温槽に24時間放置し、金属蒸着フィルム層の剥離が無かったものを○、剥離および亀裂があったものを×とした。
カット性:木工用の刃物で切削しても端部の欠けがなく、問題なきを○、木工用の刃物での切削ができなかったものを×とした。
2 印刷層
3 プラスチックフィルム
4 接着剤層
5 金属蒸着層
6 プラスチックフィルム
7 接着剤層
8 金属蒸着フィルム
9 接着性シート
10 フェノール樹脂含浸コア紙
20 金属調化粧板
Claims (2)
- ポリエチレンテレフタレートフィルム間に金属蒸着層が形成された金属蒸着フィルムと、メラミン−ホルムアルデヒド樹脂が含浸された接着性シートと、フェノール−ホルムアルデヒド樹脂が含浸されたコア材とが積層され、熱圧一体化されてなり、最表層が紫外線硬化型樹脂層である金属調化粧板。
- ポリエチレンテレフタレートフィルム間に金属蒸着層が形成された金属蒸着フィルムと、メラミン−ホルムアルデヒド樹脂が含浸された接着性シートと、フェノール−ホルムアルデヒド樹脂が含浸されたコア材とが積層され、温度125〜160℃、圧力40〜70kg/cm2で熱圧一体化されてなり、最表層が紫外線硬化型樹脂層である金属調化粧板の製造方法。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013034106A JP6162425B2 (ja) | 2013-02-25 | 2013-02-25 | 金属調化粧板 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013034106A JP6162425B2 (ja) | 2013-02-25 | 2013-02-25 | 金属調化粧板 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2014162079A JP2014162079A (ja) | 2014-09-08 |
| JP6162425B2 true JP6162425B2 (ja) | 2017-07-12 |
Family
ID=51613166
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013034106A Active JP6162425B2 (ja) | 2013-02-25 | 2013-02-25 | 金属調化粧板 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP6162425B2 (ja) |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0178146U (ja) * | 1987-11-16 | 1989-05-25 | ||
| JP2868565B2 (ja) * | 1990-01-24 | 1999-03-10 | 大日本印刷株式会社 | 化粧材の製造法 |
| JPH08118539A (ja) * | 1994-10-24 | 1996-05-14 | Dainippon Printing Co Ltd | 金属化粧板 |
| JPH08290542A (ja) * | 1995-04-25 | 1996-11-05 | Dainippon Printing Co Ltd | 熱硬化性樹脂化粧板 |
| JP2001138469A (ja) * | 1999-11-17 | 2001-05-22 | Dainippon Printing Co Ltd | 耐摩耗性を有する化粧材 |
| JP4063644B2 (ja) * | 2002-11-27 | 2008-03-19 | 日本プライ株式会社 | 光輝性積層フィルム及び光輝性成形品 |
| JP2008247016A (ja) * | 2007-03-30 | 2008-10-16 | Dainippon Printing Co Ltd | 鏡面化粧シート及びこれを用いた化粧板 |
| JP5346632B2 (ja) * | 2009-03-17 | 2013-11-20 | 信越ポリマー株式会社 | 電波透過性加飾フィルムおよびこれを用いた装飾部材 |
| JP5054736B2 (ja) * | 2009-07-28 | 2012-10-24 | アイカ工業株式会社 | メタル不燃化粧板 |
| JP5527149B2 (ja) * | 2010-09-30 | 2014-06-18 | 大日本印刷株式会社 | 金属板用化粧シート及びこれを用いた化粧金属板 |
| JP2012171329A (ja) * | 2011-02-24 | 2012-09-10 | Teijin Dupont Films Japan Ltd | 二軸配向ポリエステルフィルムロールおよびその製造方法 |
| JP5994281B2 (ja) * | 2011-02-28 | 2016-09-21 | 東レ株式会社 | 表面加飾用積層フィルムおよびその製造方法、ならびに表面加飾シート |
-
2013
- 2013-02-25 JP JP2013034106A patent/JP6162425B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2014162079A (ja) | 2014-09-08 |
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