JP6236399B2 - 少なくとも１種のゼオライトｎｕ−８６、少なくとも１種のゼオライトｕｓｙ、及び多孔質鉱物マトリクスを含む触媒、並びに該触媒を用いる、炭化水素供給原料の水素化転化法 - Google Patents
少なくとも１種のゼオライトｎｕ−８６、少なくとも１種のゼオライトｕｓｙ、及び多孔質鉱物マトリクスを含む触媒、並びに該触媒を用いる、炭化水素供給原料の水素化転化法 Download PDFInfo
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- JP6236399B2 JP6236399B2 JP2014548126A JP2014548126A JP6236399B2 JP 6236399 B2 JP6236399 B2 JP 6236399B2 JP 2014548126 A JP2014548126 A JP 2014548126A JP 2014548126 A JP2014548126 A JP 2014548126A JP 6236399 B2 JP6236399 B2 JP 6236399B2
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- Prior art keywords
- catalyst
- zeolite
- weight
- hydrocracking
- alumina
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- 239000003054 catalyst Substances 0.000 title claims description 250
- 239000010457 zeolite Substances 0.000 title claims description 140
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims description 139
- 229910021536 Zeolite Inorganic materials 0.000 title claims description 134
- 238000000034 method Methods 0.000 title claims description 91
- 230000008569 process Effects 0.000 title claims description 57
- 239000011159 matrix material Substances 0.000 title claims description 50
- 229910052500 inorganic mineral Inorganic materials 0.000 title claims description 26
- 239000011707 mineral Substances 0.000 title claims description 26
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 17
- 229930195733 hydrocarbon Natural products 0.000 title claims description 17
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 17
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 85
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 50
- 229910052751 metal Inorganic materials 0.000 claims description 47
- 239000002184 metal Substances 0.000 claims description 47
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- 239000000203 mixture Substances 0.000 claims description 35
- 239000010703 silicon Substances 0.000 claims description 35
- 239000001257 hydrogen Substances 0.000 claims description 18
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- 238000000926 separation method Methods 0.000 claims description 16
- 239000003921 oil Substances 0.000 claims description 15
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- 239000010953 base metal Substances 0.000 claims description 12
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 3
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- 238000009835 boiling Methods 0.000 description 18
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- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
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- CWBIFDGMOSWLRQ-UHFFFAOYSA-N trimagnesium;hydroxy(trioxido)silane;hydrate Chemical compound O.[Mg+2].[Mg+2].[Mg+2].O[Si]([O-])([O-])[O-].O[Si]([O-])([O-])[O-] CWBIFDGMOSWLRQ-UHFFFAOYSA-N 0.000 description 1
- XDZILQXNIZCEDV-UHFFFAOYSA-N trimethyl-[8-(trimethylazaniumyl)octyl]azanium Chemical group C[N+](C)(C)CCCCCCCC[N+](C)(C)C XDZILQXNIZCEDV-UHFFFAOYSA-N 0.000 description 1
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
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- 239000011240 wet gel Substances 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/80—Mixtures of different zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
- B01J29/14—Iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
- B01J29/14—Iron group metals or copper
- B01J29/146—Y-type faujasite
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
- C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/076—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J29/166—Y-type faujasite
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1104022A FR2984759B1 (fr) | 2011-12-22 | 2011-12-22 | Catalyseur comprenant au moins une zeolithe nu-86, au moins une zeolithe usy et une matrice minerale poreuse et procede d'hydroconversion de charges hydrocarbonees utilisant ce catalyseur |
| FR1104022 | 2011-12-22 | ||
| PCT/FR2012/000481 WO2013093225A1 (fr) | 2011-12-22 | 2012-11-23 | Catalyseur comprenant au moins une zeolithe nu-86, au moins une zeolithe usy et une matrice minerale poreuse et procede d'hydroconversion de charges hydrocarbonees utilisant ce catalyseur |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2015502853A JP2015502853A (ja) | 2015-01-29 |
| JP6236399B2 true JP6236399B2 (ja) | 2017-11-22 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| JP2014548126A Expired - Fee Related JP6236399B2 (ja) | 2011-12-22 | 2012-11-23 | 少なくとも１種のゼオライトｎｕ−８６、少なくとも１種のゼオライトｕｓｙ、及び多孔質鉱物マトリクスを含む触媒、並びに該触媒を用いる、炭化水素供給原料の水素化転化法 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US9718050B2 (fr) |
| EP (1) | EP2794100A1 (fr) |
| JP (1) | JP6236399B2 (fr) |
| KR (1) | KR102024961B1 (fr) |
| CN (1) | CN103998130B (fr) |
| BR (1) | BR112014014787A2 (fr) |
| CA (1) | CA2858049C (fr) |
| FR (1) | FR2984759B1 (fr) |
| MX (1) | MX2014007368A (fr) |
| RU (1) | RU2640585C2 (fr) |
| WO (1) | WO2013093225A1 (fr) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US10384197B2 (en) * | 2016-07-26 | 2019-08-20 | Saudi Arabian Oil Company | Additives for gas phase oxidative desulfurization catalysts |
| KR102283633B1 (ko) * | 2017-01-04 | 2021-08-03 | 사우디 아라비안 오일 컴퍼니 | 탄화수소 공급 원료로부터 복소환형 화합물 및 다핵 방향족 탄화수소의 분리 및 추출을 위한 시스템 및 방법 |
| US10661260B2 (en) | 2017-06-15 | 2020-05-26 | King Fahd University Of Petroleum And Minerals | Zeolite composite catalysts for conversion of heavy reformate to xylenes |
| US11130119B2 (en) | 2019-07-03 | 2021-09-28 | Saudi Arabian Oil Company | Methods for producing multifunctional catalysts for upgrading pyrolysis oil |
| US10953396B2 (en) * | 2019-07-03 | 2021-03-23 | Saudi Arabian Oil Company | Methods for producing mesoporous zeolite multifunctional catalysts for upgrading pyrolysis oil |
| KR20210012523A (ko) | 2019-07-25 | 2021-02-03 | 전남대학교산학협력단 | 메틸클로라이드 생성용 제올라이트 기반 불균일계 촉매 및 상기 촉매를 이용한 메틸클로라이드 제조방법 |
| US10941354B1 (en) * | 2019-10-01 | 2021-03-09 | Saudi Arabian Oil Company | Hydrocracking catalyst comprising a beta zeolite (*BEA) framework substituted with Ti and Zr and methods for its preparation and use |
| CN112717982B (zh) * | 2019-10-28 | 2022-07-08 | 中国石油化工股份有限公司 | 一种加氢裂化催化剂及其制备方法和应用 |
| US11185850B2 (en) | 2019-12-02 | 2021-11-30 | Saudi Arabian Oil Company | Dual functional composite catalyst for olefin metathesis and cracking |
| US10981160B1 (en) | 2019-12-19 | 2021-04-20 | Saudi Arabian Oil Company | Composite hierarchical zeolite catalyst for heavy reformate conversion to xylenes |
| WO2021218982A1 (fr) | 2020-04-28 | 2021-11-04 | 中国石油化工股份有限公司 | Catalyseur d'hydrogénation et son procédé de préparation et son utilisation |
| US11384297B1 (en) | 2021-02-04 | 2022-07-12 | Saudi Arabian Oil Company | Systems and methods for upgrading pyrolysis oil to light aromatics over mixed metal oxide catalysts |
| US11746299B1 (en) | 2022-07-11 | 2023-09-05 | Saudi Arabian Oil Company | Methods and systems for upgrading mixed pyrolysis oil to light aromatics over mixed metal oxide catalysts |
| US12460140B2 (en) | 2023-07-20 | 2025-11-04 | Saudi Arabian Oil Company | Two stage fixed-bed catalytic process for upgrading pyrolysis oil to BTX |
| US12540285B2 (en) | 2024-01-09 | 2026-02-03 | Saudi Arabian Oil Company | Two stage fixed-bed catalytic process for upgrading pyrolysis oil to BTX |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2755958B1 (fr) * | 1996-11-19 | 1999-01-08 | Inst Francais Du Petrole | Zeolithe nu-86 desaluminee et son utilisation en conversion des hydrocarbures |
| RU2178451C2 (ru) * | 1996-11-27 | 2002-01-20 | Энститю Франсэ Дю Петроль | Способ улучшения температуры потери текучести парафинового сырья с использованием катализатора на основе цеолита nu-86 |
| FR2758567B1 (fr) * | 1997-01-20 | 1999-02-19 | Inst Francais Du Petrole | Procede de craquage de charges hydrocarbonees a l'aide d'un catalyseur comprenant une zeolithe nu-86 desaluminee |
| EP0938926B1 (fr) * | 1998-02-26 | 2003-08-13 | Institut Francais Du Petrole | Catalyseur comprenant une zéolithe choise dans le groupe formé par les zéolithes NU-85, NU-86 et NU-87 et son utilisation en hydroconversion de charges pétrolières hydrocarbonées |
| FR2836150B1 (fr) * | 2002-02-15 | 2004-04-09 | Inst Francais Du Petrole | Procede d'amelioration de coupes gazoles aromatiques et naphteno-aromatiques |
| RU2328445C2 (ru) * | 2002-05-23 | 2008-07-10 | Консехо Супериор Де Инвестигасьонес Сьентификас | Микропористый кристаллический цеолитный материал (цеолит itq-22), способ его получения и применение в качестве катализатора |
| FR2909012B1 (fr) * | 2006-11-23 | 2009-05-08 | Inst Francais Du Petrole | Catalyseur a base d'un materiau a porosite hierarchisee comprenant du silicium et procede d'hydrocraquage/ hydroconversion et d'hydrotraitement de charges hydrocarbonees. |
| FR2935139B1 (fr) * | 2008-08-19 | 2011-06-10 | Inst Francais Du Petrole | Heteropolyanion de type keggin lacunaire a base de tungstene pour l'hydrocraquage |
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2011
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- 2012-11-23 US US14/367,260 patent/US9718050B2/en not_active Expired - Fee Related
- 2012-11-23 EP EP12813400.4A patent/EP2794100A1/fr not_active Withdrawn
- 2012-11-23 WO PCT/FR2012/000481 patent/WO2013093225A1/fr not_active Ceased
- 2012-11-23 JP JP2014548126A patent/JP6236399B2/ja not_active Expired - Fee Related
- 2012-11-23 KR KR1020147020602A patent/KR102024961B1/ko not_active Expired - Fee Related
- 2012-11-23 BR BR112014014787A patent/BR112014014787A2/pt active Search and Examination
- 2012-11-23 MX MX2014007368A patent/MX2014007368A/es unknown
- 2012-11-23 CN CN201280062425.4A patent/CN103998130B/zh not_active Expired - Fee Related
- 2012-11-23 CA CA2858049A patent/CA2858049C/fr not_active Expired - Fee Related
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Also Published As
| Publication number | Publication date |
|---|---|
| CN103998130B (zh) | 2018-11-13 |
| JP2015502853A (ja) | 2015-01-29 |
| US9718050B2 (en) | 2017-08-01 |
| US20150231615A1 (en) | 2015-08-20 |
| KR102024961B1 (ko) | 2019-09-24 |
| FR2984759A1 (fr) | 2013-06-28 |
| MX2014007368A (es) | 2015-03-09 |
| FR2984759B1 (fr) | 2013-12-20 |
| BR112014014787A2 (pt) | 2017-06-13 |
| RU2640585C2 (ru) | 2018-01-10 |
| EP2794100A1 (fr) | 2014-10-29 |
| RU2014130040A (ru) | 2016-02-10 |
| CN103998130A (zh) | 2014-08-20 |
| KR20140113983A (ko) | 2014-09-25 |
| CA2858049A1 (fr) | 2013-06-27 |
| CA2858049C (fr) | 2020-01-14 |
| WO2013093225A1 (fr) | 2013-06-27 |
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