JPH01135733A - クロロトリフルオロエチレン及び１，１−ジブロモ−１−クロロトリフルオロエタンからテロマーを調整する方法 - Google Patents

クロロトリフルオロエチレン及び１，１−ジブロモ−１−クロロトリフルオロエタンからテロマーを調整する方法

Info

Publication number: JPH01135733A
Authority: JP; Japan
Prior art keywords: chlorotrifluoroethylene; catalyst; telomer; reaction; telomers
Prior art date: 1987-11-05
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP63145548A

Other languages

English (en)

Japanese (ja)

Inventor

Bobby F Dannels

ボビー　エフ　ダンネルズ

David Y Tang

ディヴィッド　ワイ　タング

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Occidental Chemical Corp

Original Assignee

Occidental Chemical Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-11-05

Filing date

1988-06-13

Publication date

1989-05-29

1988-06-13 Application filed by Occidental Chemical Corp filed Critical Occidental Chemical Corp

1989-05-29 Publication of JPH01135733A publication Critical patent/JPH01135733A/ja

Status Pending legal-status Critical Current

Links

UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 title claims abstract description 36
WGIRTDAEWOUFQR-UHFFFAOYSA-N 1,1-dibromo-1-chloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Br)Br WGIRTDAEWOUFQR-UHFFFAOYSA-N 0.000 title abstract description 4
238000002360 preparation method Methods 0.000 title description 2
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims abstract description 36
239000003054 catalyst Substances 0.000 claims abstract description 19
229910001507 metal halide Inorganic materials 0.000 claims abstract description 15
150000005309 metal halides Chemical class 0.000 claims abstract description 15
239000003638 chemical reducing agent Substances 0.000 claims abstract description 14
239000002904 solvent Substances 0.000 claims abstract description 11
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 10
239000000203 mixture Substances 0.000 claims abstract description 7
229910052759 nickel Inorganic materials 0.000 claims abstract description 7
239000000376 reactant Substances 0.000 claims abstract description 6
229910052720 vanadium Inorganic materials 0.000 claims abstract description 6
229910052742 iron Inorganic materials 0.000 claims abstract description 4
229910052719 titanium Inorganic materials 0.000 claims abstract description 4
238000006243 chemical reaction Methods 0.000 claims description 28
238000000034 method Methods 0.000 claims description 28
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 claims description 12
239000011541 reaction mixture Substances 0.000 claims description 10
244000028419 Styrax benzoin Species 0.000 claims description 6
235000000126 Styrax benzoin Nutrition 0.000 claims description 6
235000008411 Sumatra benzointree Nutrition 0.000 claims description 6
229960002130 benzoin Drugs 0.000 claims description 6
235000019382 gum benzoic Nutrition 0.000 claims description 6
229910021589 Copper(I) bromide Inorganic materials 0.000 claims description 3
229910052802 copper Inorganic materials 0.000 claims description 3
239000010949 copper Substances 0.000 claims description 3
239000010936 titanium Substances 0.000 claims description 3
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
239000007795 chemical reaction product Substances 0.000 claims description 2
229910021591 Copper(I) chloride Inorganic materials 0.000 claims 1
OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims 1
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
229920000642 polymer Polymers 0.000 abstract description 6
229910021578 Iron(III) chloride Inorganic materials 0.000 abstract description 4
239000003063 flame retardant Substances 0.000 abstract description 4
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 abstract description 4
229910021576 Iron(III) bromide Inorganic materials 0.000 abstract description 3
FEONEKOZSGPOFN-UHFFFAOYSA-K tribromoiron Chemical compound Br[Fe](Br)Br FEONEKOZSGPOFN-UHFFFAOYSA-K 0.000 abstract description 3
229910021592 Copper(II) chloride Inorganic materials 0.000 abstract description 2
ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 abstract description 2
239000007788 liquid Substances 0.000 abstract description 2
238000004519 manufacturing process Methods 0.000 abstract description 2
QTMDXZNDVAMKGV-UHFFFAOYSA-L copper(ii) bromide Chemical compound [Cu+2].[Br-].[Br-] QTMDXZNDVAMKGV-UHFFFAOYSA-L 0.000 abstract 2
229910021590 Copper(II) bromide Inorganic materials 0.000 abstract 1
229910010068 TiCl2 Inorganic materials 0.000 abstract 1
229910021549 Vanadium(II) chloride Inorganic materials 0.000 abstract 1
125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 abstract 1
ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 abstract 1
ITAKKORXEUJTBC-UHFFFAOYSA-L vanadium(ii) chloride Chemical compound Cl[V]Cl ITAKKORXEUJTBC-UHFFFAOYSA-L 0.000 abstract 1
239000000047 product Substances 0.000 description 22
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 7
229910052794 bromium Inorganic materials 0.000 description 7
229910052799 carbon Inorganic materials 0.000 description 7
150000001875 compounds Chemical class 0.000 description 7
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 5
230000003797 telogen phase Effects 0.000 description 5
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
239000000460 chlorine Substances 0.000 description 4
239000012530 fluid Substances 0.000 description 4
238000004817 gas chromatography Methods 0.000 description 4
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 3
125000001246 bromo group Chemical group Br* 0.000 description 3
229910052801 chlorine Inorganic materials 0.000 description 3
238000009826 distribution Methods 0.000 description 3
229910000856 hastalloy Inorganic materials 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
239000000843 powder Substances 0.000 description 3
229920006395 saturated elastomer Polymers 0.000 description 3
OVZATIUQXBLIQT-UHFFFAOYSA-N 1,2-dibromo-1-chloro-1,2,2-trifluoroethane Chemical compound FC(F)(Br)C(F)(Cl)Br OVZATIUQXBLIQT-UHFFFAOYSA-N 0.000 description 2
150000001721 carbon Chemical group 0.000 description 2
238000004821 distillation Methods 0.000 description 2
239000011521 glass Substances 0.000 description 2
239000013627 low molecular weight specie Substances 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 2
241000023308 Acca Species 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
229910015400 FeC13 Inorganic materials 0.000 description 1
229910000990 Ni alloy Inorganic materials 0.000 description 1
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
239000000956 alloy Substances 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
-1 carbon halide Chemical class 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
238000005660 chlorination reaction Methods 0.000 description 1
238000005253 cladding Methods 0.000 description 1
239000012043 crude product Substances 0.000 description 1
239000012467 final product Substances 0.000 description 1
239000004519 grease Substances 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
229920006158 high molecular weight polymer Polymers 0.000 description 1
239000012535 impurity Substances 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
239000000463 material Substances 0.000 description 1
238000010907 mechanical stirring Methods 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000000178 monomer Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 1
230000005855 radiation Effects 0.000 description 1
230000002285 radioactive effect Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
150000003384 small molecules Chemical class 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
229950011008 tetrachloroethylene Drugs 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
238000004457 water analysis Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
- C07C17/272—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions
- C07C17/278—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions of only halogenated hydrocarbons

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

JP63145548A 1987-11-05 1988-06-13 クロロトリフルオロエチレン及び１，１−ジブロモ−１−クロロトリフルオロエタンからテロマーを調整する方法 Pending JPH01135733A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US11699087A	1987-11-05	1987-11-05
US116990		1987-11-05

Publications (1)

Publication Number	Publication Date
JPH01135733A true JPH01135733A (ja)	1989-05-29

Family

ID=22370438

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP63145548A Pending JPH01135733A (ja)	1987-11-05	1988-06-13	クロロトリフルオロエチレン及び１，１−ジブロモ−１−クロロトリフルオロエタンからテロマーを調整する方法

Country Status (5)

Country	Link
JP (1)	JPH01135733A (fr)
CA (1)	CA1321797C (fr)
DE (1)	DE3820934A1 (fr)
FR (1)	FR2622883A1 (fr)
GB (1)	GB2211838B (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB2630367A (en)	2023-05-25	2024-11-27	Tailfin Ltd	External pocket for luggage pack

1988
- 1988-05-25 GB GB8812352A patent/GB2211838B/en not_active Expired - Fee Related
- 1988-05-26 CA CA000567738A patent/CA1321797C/fr not_active Expired - Fee Related
- 1988-06-13 JP JP63145548A patent/JPH01135733A/ja active Pending
- 1988-06-21 DE DE19883820934 patent/DE3820934A1/de not_active Withdrawn
- 1988-06-27 FR FR8808610A patent/FR2622883A1/fr active Pending

Also Published As

Publication number	Publication date
GB2211838B (en)	1991-08-21
CA1321797C (fr)	1993-08-31
GB2211838A (en)	1989-07-12
GB8812352D0 (en)	1988-06-29
FR2622883A1 (fr)	1989-05-12
DE3820934A1 (de)	1989-05-18

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US4577044A (en)	1986-03-18	Preparation of chlorotrifluoroethylene telomers with fluoroxytrifluoromethane
US3795710A (en)	1974-03-05	Process for preparing fluoro-halogenated propane derivatives and use thereof
BE1005095A3 (fr)	1993-04-20	Procede pour la preparation de 1,1-dichloro-1,3,3,3-tetrafluoropropane.
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US4533762A (en)	1985-08-06	Preparation of chlorotrifluoroethylene telomers with bisfluoroxydifluoromethane
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CN101805240B (zh)	2013-11-06	一种全氟烷基碘化物的调聚方法
CA1108651A (fr)	1981-09-08	Methode de fluoration en phase liquide
US4129602A (en)	1978-12-12	Liquid phase fluorination process
JPH04305544A (ja)	1992-10-28	パラジクロロベンゼンの製法
CA1231727A (fr)	1988-01-19	Couplage de telomeres de chlorotrifluoroethylene
JPS6023333A (ja)	1985-02-05	パ−フルオルアルキル沃化物の製造法