JPH01156583A - Resist style processing of polyester fiber structure - Google Patents
Resist style processing of polyester fiber structureInfo
- Publication number
- JPH01156583A JPH01156583A JP31674987A JP31674987A JPH01156583A JP H01156583 A JPH01156583 A JP H01156583A JP 31674987 A JP31674987 A JP 31674987A JP 31674987 A JP31674987 A JP 31674987A JP H01156583 A JPH01156583 A JP H01156583A
- Authority
- JP
- Japan
- Prior art keywords
- alkali
- polyester
- modified polyester
- polyester fiber
- strength
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000728 polyester Polymers 0.000 title claims abstract description 50
- 239000000835 fiber Substances 0.000 title claims abstract description 25
- 238000012545 processing Methods 0.000 title description 2
- 239000003513 alkali Substances 0.000 claims abstract description 24
- 239000000080 wetting agent Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 7
- 238000005260 corrosion Methods 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 claims description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 12
- -1 polyethylene terephthalate Polymers 0.000 abstract description 8
- 229920000139 polyethylene terephthalate Polymers 0.000 abstract description 8
- 239000005020 polyethylene terephthalate Substances 0.000 abstract description 8
- 238000001035 drying Methods 0.000 abstract description 5
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 abstract description 4
- 235000011121 sodium hydroxide Nutrition 0.000 abstract description 4
- 150000003839 salts Chemical class 0.000 abstract description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract 3
- 239000003906 humectant Substances 0.000 abstract 2
- 230000001939 inductive effect Effects 0.000 abstract 2
- 238000010018 discharge printing Methods 0.000 abstract 1
- 238000004513 sizing Methods 0.000 abstract 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 230000009172 bursting Effects 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000000986 disperse dye Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 229910000027 potassium carbonate Inorganic materials 0.000 description 4
- 238000005904 alkaline hydrolysis reaction Methods 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000003672 processing method Methods 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- CYDRXTMLKJDRQH-UHFFFAOYSA-N benzododecinium Chemical compound CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 CYDRXTMLKJDRQH-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Decoration Of Textiles (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明はポリエステル繊維構造品の接触加工方法に関す
る。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a contact processing method for polyester fiber structures.
〈従来の技術〉
従来、ポリエステル繊維構造品の接触方法としては特公
昭３７−７３９３号公報に示されるアミン、無機酸、酸
化剤で処理したポリエステル繊維がアルカリ加水分解し
易いという技術を変性ポリエステルと未変性ポリエステ
ルからなるポリエステル繊維構造品に応用して変性ポリ
エステル成分のみを接触する方法が知られている。しか
しこれらは倒れも残存した未変性ポリエステル繊維部分
の強度が小さい、変色し易いあるいは経時的に強度が低
下するという実用上の問題があった。<Prior art> Conventionally, as a method for contacting polyester fiber structures, a technique disclosed in Japanese Patent Publication No. 37-7393, in which polyester fibers treated with amines, inorganic acids, and oxidizing agents are easily hydrolyzed by alkaline, was used for contacting modified polyesters. A method is known in which a polyester fiber structure made of unmodified polyester is contacted with only a modified polyester component. However, these have practical problems in that the strength of the unmodified polyester fiber portion that remains even after falling down is low, it is easily discolored, or the strength decreases over time.
〈発明が解決しようとする問題点〉
本発明の目的は残存した未変性ポリエステル繊維部分の
強度低下及び変色を生じない実用上使用に適した工業的
価値のあるポリエステル繊維構造品の接触加工方法を提
供するもので、又耐アルカリ性の分散染料を併用すると
きには残存した未変性ポリエステル繊維部分を着色する
着色接触加工方法をも提供するものである。<Problems to be Solved by the Invention> The purpose of the present invention is to provide a contact processing method for polyester fiber structures that is suitable for practical use and has industrial value without causing a decrease in strength or discoloration of the remaining unmodified polyester fiber portion. The present invention also provides a colored contact processing method for coloring the remaining unmodified polyester fiber portion when an alkali-resistant disperse dye is used in combination.
く問題点を解決するための手段〉
′本発明は変性ポリエステル及び未変性ポリエステルか
らなるポリエステル繊維構造品に予めアルカリと湿潤剤
を付着せしめて熱処理を行ない、次いでアルカリで抜蝕
処理することを特徴とするポリエステル繊維構造品の抜
蝕加工方法にある。Means for Solving the Problems>'The present invention is characterized in that alkali and a wetting agent are applied in advance to a polyester fiber structure made of modified polyester and unmodified polyester, heat treatment is performed, and then an alkali removal treatment is performed. There is a method for removing corrosion of polyester fiber structural products.
本発明の特徴はアルカリと湿潤剤の付着熱処理により未
変性ポリエステル成分に影響を与えずに変性ポリエステ
ル成分のみをアルカリ加水分解し易くするものであり、
湿潤剤によりてアルカリによる加水分解効果を変性ポリ
エステル成分に集中させたことにある。The feature of the present invention is that only the modified polyester component can be easily hydrolyzed with alkali without affecting the unmodified polyester component by adhesion heat treatment of alkali and wetting agent.
The reason is that the wetting agent concentrates the hydrolysis effect of the alkali on the modified polyester component.
本発明のポリエステル繊維とは変性ポリエステル及び未
変性ポリエステルを同一の繊維内又は繊維構造品内に含
有し、変性ポリエステルは未変性ポリエステルと同様の
アルカリ浴中処理をしたときに３倍以上アルカリ加水分
解されることが望ましく、ポリエチレンテレフタレート
にイソフタル酸及び／又は金属塩含有スルホネート基含
有ジカルボン酸を共１合して変性したポリエステルが好
ましく用いられるが、更に他のジカルボン酸又はネオペ
ンチルグリコール、ブチレンクリコール等エチレンクリ
コール以外のジオールを一部又は全部共重合してなる変
性ポリエステルも用いられる。The polyester fiber of the present invention contains modified polyester and unmodified polyester in the same fiber or fiber structure, and the modified polyester undergoes alkaline hydrolysis three times or more when treated in the same alkaline bath as the unmodified polyester. It is preferable to use a polyester modified by combining polyethylene terephthalate with isophthalic acid and/or a metal salt-containing sulfonate group-containing dicarboxylic acid. A modified polyester formed by copolymerizing a part or all of a diol other than ethylene glycol may also be used.
変性のための共重合成分の量としては酸及び／又はグリ
コール成分に対して１−１５モル％共重合したものが用
いられる。未変性ポリエステルとしては側鎖に酸基又は
その塩を導入しないもので共重合成分が０．５モル％以
下含むものをいい、ポリエチレンテレフタレートが好ま
しく用いられる。The amount of the copolymerized component for modification is 1 to 15 mol % based on the acid and/or glycol component. The unmodified polyester is one in which no acid group or its salt is introduced into the side chain and contains 0.5 mol% or less of a copolymer component, and polyethylene terephthalate is preferably used.
又、本発明の繊維構造品とは糸条、編物、織物、不織布
等任意の製品形態であり特に限定されるものでない。Furthermore, the fibrous structure of the present invention is not particularly limited and may be in any product form such as yarn, knitted fabric, woven fabric, or nonwoven fabric.
本発明で予め付着させるアルカリとしては苛性ソーダ、
苛性カリウム、炭酸ソーダ、炭酸カリウム等水に溶解し
た時、アルカリ性を示す無機のアルカリ剤が用いられ、
繊維構造品に対して３〜２０重量％付着させることが望
ましい。In the present invention, the alkali to be applied in advance includes caustic soda,
Inorganic alkaline agents that exhibit alkalinity when dissolved in water, such as caustic potassium, soda carbonate, and potassium carbonate, are used.
It is desirable that the amount is 3 to 20% by weight of the fiber structure.
又、本発明でアルカリと同時に用いられる湿潤剤として
は捺染の際の過熱蒸気固着における発色性改良に用いら
れるポリエチレングリコール、ポリエチレングリコール
誘導体、グリセリン、尿素、ジシアンアミド等の湿潤性
のある耐熱性助剤があげられ、アルカリと併用すること
によりアルカリを変性ポリエステル成分のみに作用させ
る効果を有する。In addition, wetting agents that can be used together with alkali in the present invention include heat-resistant auxiliaries with wettability such as polyethylene glycol, polyethylene glycol derivatives, glycerin, urea, and dicyanamide, which are used to improve color development in superheated steam fixation during textile printing. When used together with an alkali, it has the effect of causing the alkali to act only on the modified polyester component.
湿潤剤の使用量は併用するブルカＩＪ Ｋ対して３０〜
１５０重景％用いるのが望ましい。アルカリ及び湿潤剤
の付着方法は水に溶かし水溶性の糊剤を加え捺染糊とし
て所定模様に付着する方法が一般的であるが、水溶液の
状態で浸漬、スプレー等により付着させる方法を用いて
もよい。又、耐アルカリ性の分散染料を併用して付着す
ると残存する未変性ポリエステル成分を着色することも
可能である。The amount of wetting agent used is 30~ for Burqa IJK used together.
It is desirable to use 150% focus. The general method for applying alkali and wetting agents is to dissolve them in water, add a water-soluble adhesive, and apply them to a predetermined pattern as a printing paste, but it is also possible to apply them by dipping, spraying, etc. good. It is also possible to color the remaining unmodified polyester component by applying an alkali-resistant disperse dye in combination.
本発明の熱処理は、アルカリと湿潤剤を付着せしめた後
行われ、単に乾燥する目的ではなく変性ポリエステル成
分をアルカリ加水分解し易くするための処理であり、１
１０〜１９０℃の乾熱又は過熱蒸気で１〜３０分間行わ
れる。併用した分散染料の着色も同時に行う際は１４０
〜１９０℃の過熱蒸気による処理が望ましい。The heat treatment of the present invention is performed after adhering the alkali and wetting agent, and is not simply for the purpose of drying, but is a treatment to facilitate alkaline hydrolysis of the modified polyester component.
It is carried out for 1 to 30 minutes using dry heat or superheated steam at 10 to 190°C. 140 when coloring with disperse dye used at the same time
Treatment with superheated steam at ~190°C is preferred.
１９０℃を超える温度では未変性ポリエステル成分が強
度低下、変色を起こすので望ましくないＯ
本発明のアルカリでの抜蝕処理とは苛性ソーダ水溶液で
行われ、２〜３０ Ｐ／ｌの苛性ソーダ濃度で５〜９０
分間行われる。又、ジメチルラウリルベンジルアンモニ
ウムクロライドのようなアルカリ加水分解促進剤を添加
した場合は苛性ソーダ濃度を低く、時間を短く、温度を
低くして行うこともできる。このアルカリ処理により予
めアルカリと湿潤剤の付着し熱処理された変性ポリエス
テル成分を除去する。本発明方法による接触加工品は風
合改良の目的で更に通常のアルカリ減量を行うことも又
アルカリ接触と同時に行うことも可能である。Temperatures exceeding 190°C are undesirable because the strength of the unmodified polyester component decreases and the color changes. 90
It takes place for a minute. Furthermore, when an alkaline hydrolysis accelerator such as dimethyllauryl benzyl ammonium chloride is added, the caustic soda concentration can be lowered, the time can be shortened, and the temperature can be lowered. This alkali treatment removes the heat-treated modified polyester component to which the alkali and wetting agent have adhered in advance. For the purpose of improving the hand of the contact-processed product according to the method of the present invention, it is possible to further carry out conventional alkali weight reduction, or to carry out the alkali contact simultaneously.
〈実施例〉
以下本発明を実施例により説明する。なお実施例中の浄
はｗｔ％を意味する。<Examples> The present invention will be explained below using examples. Note that in the Examples, purity means wt%.
実施例
海成分にエチレン５−ソジウムスルホイソフタル酸ヲポ
リエチレンテレフタレー） Ｋ ５．３モル％共重合し
た変性ポリエステル１７％、島成分ニポリエチレンテレ
フタレート７３％を用い、島成分の数を８とした７８ｄ
／１２ｆの海島型複合繊維にて３２Ｇの天竺編地を編成
した。次いでこの編物に下記の捺染糊を柄状に付着し、
１３０℃で２分間の乾燥後過熱蒸気にて１７５℃で１５
分間熱処理した。その後水洗を行い、苛性ソーダ１０
Ｊ’／ｌで沸騰水溶中で３０分間処理した。常法に従い
中和後乾燥し、柄部のみが青く０，４ｄのマルチ化した
ポリエチレンテレフタレート繊維部分が残った接触加工
品を得た。Example 17% of modified polyester copolymerized with 5.3 mol% of ethylene 5-sodium sulfoisophthalate (polyethylene terephthalate) was used as the sea component, and 73% of polyethylene terephthalate was used as the island component, and the number of island components was 8. 78d
A 32G cotton jersey fabric was knitted with /12f sea-island composite fiber. Next, the following printing paste is attached to this knitted fabric in a pattern shape,
After drying at 130℃ for 2 minutes, drying at 175℃ with superheated steam for 15 minutes.
Heat treated for minutes. After that, wash with water and use caustic soda 10
J'/l in boiling water for 30 minutes. After neutralization and drying according to a conventional method, a contact processed product was obtained in which only the handle part remained blue and the 0.4d mulched polyethylene terephthalate fiber part remained.
この編地の柄部の破裂強力は５．８ ｋｌｌ／ａｒｔ”
であり、ポリエステル繊維の経時変化３年に相当する７
０℃、９０〜１００％ＲＨ下で１週間の促進テスト後で
も破裂強力は５．６ ｋｇ７ｃｍ”でほとんど強力低下
がなく実用に耐えるものでありた。The bursting strength of the handle of this knitted fabric is 5.8 kll/art”
7, which corresponds to 3 years of aging of polyester fibers.
Even after one week of accelerated testing at 0° C. and 90 to 100% RH, the bursting strength was 5.6 kg 7 cm”, which was sufficient for practical use with almost no decrease in strength.
比較として本実施例の捺染糊より湿潤剤のみを除いたほ
かは実施例と同様に行って得た接触加工品は柄部が変色
したのみで接触不良でありた。又、湿潤剤を除いて炭酸
カリウムを１．５倍増やして付着したものも接触不良で
あり、２．０倍付着したものは接触は可能であるが柄部
が変色し、ポリエチレンテレフタレートの劣化が大きく
、破裂強力が２．１ ｋｙ／α２と実用に耐えないもの
であった。又、アルカリ、湿潤剤の付着の代りに硫酸２
％を付着し、実施例と同様に行ったものは柄部が炭化し
変色が太き（、ポリエチレンテレフタレートの劣化が大
きく、破裂強力が１．３ ｋｇ／ａｎ”と実用に耐える
ものでなかった。For comparison, a contact-processed product obtained in the same manner as in the example except that only the wetting agent was removed from the printing paste of this example had only a discolored handle and poor contact. In addition, a product with a 1.5 times increase in potassium carbonate without the wetting agent also has poor contact, and a product with a 2.0 times increase in potassium carbonate can be contacted, but the handle becomes discolored and the polyethylene terephthalate deteriorates. It was large and had a bursting strength of 2.1 ky/α2, which was not suitable for practical use. Also, instead of attaching alkali or wetting agent, sulfuric acid 2
% and the same procedure as in the example was carried out, the handle part was carbonized and the discoloration was thick (the polyethylene terephthalate deteriorated significantly, and the bursting strength was 1.3 kg/an", which was not suitable for practical use. .
促進テスト後の破裂強力も０．６ ｋｌｌ／ｃｙｔ”と
低下が更に大きく実用に耐えるものでなかった。The bursting strength after the accelerated test was also significantly lowered to 0.6 kll/cyt'', which was not suitable for practical use.
捺染糊；
無水炭酸カリウム（アルカリ） １０％グリセリン
（湿潤剤） ５水
１３カヤロンポリエステルブル
ーＴ−８２
（日本化薬（株）製 分散染料）
メイプロＮＰ （１２％水溶液）７０
〈発明の効果〉
本発明によれば変性ポリエステルと未変性ポリエステル
からなるポリエステル繊維の繊維構造品を強力低下及び
経時強力低下がなく、変色もな（接触加工することが可
能であり、極めて実用性のある接触加工品を得ることが
可能である。Printing paste; Anhydrous potassium carbonate (alkali) 10% glycerin (wetting agent) 5 Water
13 Kayalon Polyester Blue T-82 (Disperse dye manufactured by Nippon Kayaku Co., Ltd.) Maypro NP (12% aqueous solution) 70 <Effects of the invention> According to the present invention, the fiber structure of polyester fibers consisting of modified polyester and unmodified polyester There is no decrease in strength or strength over time, and there is no discoloration (contact processing is possible, and extremely practical contact-processed products can be obtained).
Claims (1)
エステル繊維構造品に予めアルカリと湿潤剤を付着せし
めて熱処理を行ない、次いでアルカリで抜蝕処理するこ
とを特徴とするポリエステル繊維構造品の抜蝕加工方法
。A method for removing corrosion of a polyester fiber structural product, which comprises applying an alkali and a wetting agent to a polyester fiber structure made of modified polyester and unmodified polyester in advance, heat-treating the product, and then subjecting the polyester fiber structure to an alkali removal treatment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP31674987A JPH01156583A (en) | 1987-12-15 | 1987-12-15 | Resist style processing of polyester fiber structure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP31674987A JPH01156583A (en) | 1987-12-15 | 1987-12-15 | Resist style processing of polyester fiber structure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01156583A true JPH01156583A (en) | 1989-06-20 |
Family
ID=18080485
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP31674987A Pending JPH01156583A (en) | 1987-12-15 | 1987-12-15 | Resist style processing of polyester fiber structure |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01156583A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05263375A (en) * | 1992-03-16 | 1993-10-12 | Kanebo Ltd | Opal processed product of polyester fiber cloth |
-
1987
- 1987-12-15 JP JP31674987A patent/JPH01156583A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05263375A (en) * | 1992-03-16 | 1993-10-12 | Kanebo Ltd | Opal processed product of polyester fiber cloth |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH06506731A (en) | Removal of excess dye from new fibers | |
| JPH06506027A (en) | Removal of printing paste thickener and excess dye after textile printing | |
| JPH01156583A (en) | Resist style processing of polyester fiber structure | |
| CN109944092B (en) | Short-process wool dyeing process using reactive dye | |
| JP3805557B2 (en) | Discharge processing method for fiber fabric sheet | |
| JPH0291288A (en) | Method for etching processing of polyester textile product | |
| JP3228919B2 (en) | Disinfectant for natural fiber material, method of processing and method of natural fiber material | |
| JPH09217269A (en) | Antimicrobial fiber and its production | |
| JP3228918B2 (en) | Disinfectant for synthetic fiber material, method of processing and method of synthetic fiber material | |
| JP2699106B2 (en) | Extraction processing method for polyester fiber products | |
| JP2001089972A (en) | Discharge-printing agent for synthetic fiber material, discharge printing method, and discharge synthetic fiber material | |
| JP3545166B2 (en) | Extrusion-processed product and its manufacturing method | |
| JPS583068B2 (en) | How to get the latest information | |
| JPH0457966A (en) | Method for scouring silk | |
| JPH0299662A (en) | Bleaching agent for fiber and method for bleaching | |
| JPS58169580A (en) | Resist style of rayon fiber | |
| JPH1112924A (en) | Blanket manufacturing method | |
| JPH07189125A (en) | Processing of cellulose fiber | |
| JPS6253490A (en) | Resist style of cellulosic fiber | |
| US4121900A (en) | Method for modifying fibers of a fabric by electrolysis and the products so produced | |
| JPS6117951B2 (en) | ||
| JP3035013B2 (en) | Flameproofing of feathers | |
| CN115652643A (en) | Ramie textile finishing agent, finishing method and application | |
| JPS6366948B2 (en) | ||
| JPS6253478A (en) | Removal of oligomer |