JPH01197046A - Production of cr-series stainless steel sheet by using thin thickness casting method - Google Patents
Production of cr-series stainless steel sheet by using thin thickness casting methodInfo
- Publication number
- JPH01197046A JPH01197046A JP2211588A JP2211588A JPH01197046A JP H01197046 A JPH01197046 A JP H01197046A JP 2211588 A JP2211588 A JP 2211588A JP 2211588 A JP2211588 A JP 2211588A JP H01197046 A JPH01197046 A JP H01197046A
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- Japan
- Prior art keywords
- degree
- thin
- superheat
- stainless steel
- thickness
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Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Metal Rolling (AREA)
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
この発明は、薄肉鋳造法を用いるCr系ステンレス鋼薄
板の製造方法に関する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a method for manufacturing a Cr-based stainless steel thin plate using a thin-wall casting method.
(従来の技術)
ステンレス鋼薄板は、たとえば特開昭55−97430
号公報に開示されているように、連続鋳造プロセスによ
って得られた、厚さ200mm前後の鋳片を直接粗圧延
するかあるいは1200℃程度の温度に加熱した後、熱
間圧延して熱延板とし、これをベル型の焼鈍炉により熱
延板焼鈍を施して、冷間圧延、仕上げ焼鈍を施して製品
とされている。(Prior art) Stainless steel thin plates are disclosed in, for example, Japanese Patent Application Laid-Open No. 55-97430.
As disclosed in the publication, a slab with a thickness of around 200 mm obtained by a continuous casting process is directly rough rolled or heated to a temperature of about 1200°C, and then hot rolled to produce a hot rolled sheet. This is then subjected to hot-rolled plate annealing in a bell-shaped annealing furnace, followed by cold rolling and final annealing to produce a product.
しかし、このようにして製造されたCr系ステンレス鋼
冷延鋼板はプレス加工などの成形加工が施されると、圧
延方向と平行にリジングと称される表面凹凸が生じる。However, when the Cr stainless steel cold-rolled steel sheet manufactured in this manner is subjected to forming processing such as press working, surface irregularities called ridging occur in parallel to the rolling direction.
この現象は鋳片の凝固組織、すなわち粗大な柱状晶に起
因すると考えられ、これを防止する方法として、成分組
成、鋳造温度、電磁撹拌などの手段により凝固組織を改
善したり、あるいは熱間圧延条件や熱処理条件を制御す
るなどの方法が用いられてきた。This phenomenon is thought to be caused by the solidification structure of the slab, that is, coarse columnar crystals.To prevent this, it is possible to improve the solidification structure by changing the composition, casting temperature, electromagnetic stirring, etc., or by hot rolling. Methods such as controlling conditions and heat treatment conditions have been used.
たとえば、特開昭58−32568号公報には、鋳造工
程において凝固殻の成長速度を0.8mm/sec以上
に保持しつつ凝固を完了させる方法が提案されている。For example, Japanese Patent Application Laid-Open No. 58-32568 proposes a method of completing solidification while maintaining the growth rate of the solidified shell at 0.8 mm/sec or more in the casting process.
一方、鋳造板厚を薄手化することにより前記リジングの
発生を防止する方法が提案されている。On the other hand, a method has been proposed for preventing the occurrence of ridging by reducing the thickness of the cast plate.
たとえば、特開昭62−54017号公報には、板厚を
30mmもしくは10mm以下に鋳造した後、所定の冷
却あるいは加工、熱処理を施すことにより、Cr系ステ
ンレス鋼のりジング特性を向上させることが提案されて
いる。For example, Japanese Patent Application Laid-Open No. 62-54017 proposes that the gluing properties of Cr-based stainless steel be improved by casting the plate to a thickness of 30 mm or 10 mm or less and then subjecting it to prescribed cooling, processing, or heat treatment. has been done.
また、特開昭62−176649号公報には、単ロール
、双ロール法を用いて板厚を5mm以下に鋳造した後、
焼鈍、冷延及び焼鈍を施すことにより、ロービングのな
いフェライト系ステンレス鋼を製造する方法が提案され
ている。In addition, Japanese Patent Application Laid-open No. 176649/1983 discloses that after casting to a thickness of 5 mm or less using a single roll or twin roll method,
A method has been proposed for producing roving-free ferritic stainless steel by performing annealing, cold rolling, and annealing.
(発明が解決しようとする課題)
従来の技術では、連続鋳造によって鋳片を作る際に冷却
速度が遅いために、柱状晶ならびに等軸晶の粗大化を十
分に抑制することができず、かかる板厚200mm程度
の鋳片を用いた場合リジングの発生を抑制することは困
難であった。(Problems to be Solved by the Invention) In the conventional technology, when making slabs by continuous casting, the cooling rate is slow, so it is not possible to sufficiently suppress the coarsening of columnar crystals and equiaxed crystals. When using slabs with a plate thickness of about 200 mm, it was difficult to suppress the occurrence of ridging.
一方、鋳片を薄手化してリジングを抑制する方法は、単
に板厚を薄くするだけでは、圧減比が低下するために凝
固組織の破壊が困難になり、かえってリジング特性は劣
化する。On the other hand, in the method of suppressing ridging by making the slab thinner, simply reducing the thickness of the slab lowers the reduction ratio, making it difficult to destroy the solidified structure, and on the contrary, the ridging properties deteriorate.
(課題を解決するための手段)
本発明は、薄肉鋳造法を用いたCr系ステンレス鋼薄板
の製造に際し、従来の方法の問題点を解決し、加工性の
優れたCr系ステンレス鋼薄板の製造方法を提供するこ
とを目的とするものであり、特許請求の範囲記載の方法
を提供することによって前記目的を達成できる。すなわ
ち、本発明は薄肉鋳片鋳造に際し、所定の関係式を満足
するように板厚ならびに過熱度を制御し、一方では特定
の元素を添加することにより、凝固組織を制御した帯に
、圧延、焼鈍、あるいは捲き取り処理を行った後に冷間
圧延、仕上げ焼鈍を施すことを特徴とする薄肉鋳造法を
用いたCr系ステンレス鋼薄板の製造方法である。(Means for Solving the Problems) The present invention solves the problems of the conventional method when manufacturing Cr-based stainless steel thin plates using a thin-wall casting method, and manufactures Cr-based stainless steel thin plates with excellent workability. The object is to provide a method, and the object can be achieved by providing the method as described in the claims. That is, the present invention controls the plate thickness and degree of superheating so as to satisfy a predetermined relational expression when casting thin slabs, and also adds specific elements to control the solidification structure by rolling, This is a method for manufacturing a Cr-based stainless steel thin plate using a thin-wall casting method characterized by performing annealing or rolling treatment followed by cold rolling and final annealing.
以下に本発明の詳細な説明する。The present invention will be explained in detail below.
本発明の第一の目的は、薄肉鋳造法を用いたCr系ステ
ンレス鋼薄板の製造方法を提供することにある。A first object of the present invention is to provide a method for manufacturing a Cr-based stainless steel thin plate using a thin-wall casting method.
従来の連続鋳造法によるCr系ステンレス鋼″iyJ板
の製造においては、連続鋳造によって鋳片を作る際に冷
却速度が遅いために、柱状晶ならびに等軸晶の粗大化を
十分に抑制することができず、かかる板厚200胴程度
の鋳片を用いた場合リジングの発生を抑制することは困
難であった。In the production of Cr-based stainless steel "iyJ plate" using the conventional continuous casting method, the cooling rate is slow when making slabs by continuous casting, so it is not possible to sufficiently suppress the coarsening of columnar crystals and equiaxed crystals. Therefore, it was difficult to suppress the occurrence of ridging when such a slab having a plate thickness of about 200 mm was used.
一方、鋳片を薄手化してリジングを抑制する方法は、単
に板厚を薄くするだけでは、圧減比が低下するために凝
固組織の破壊が困難になり、かえってリジング特性は劣
化する。On the other hand, in the method of suppressing ridging by making the slab thinner, simply reducing the thickness of the slab lowers the reduction ratio, making it difficult to destroy the solidified structure, and on the contrary, the ridging properties deteriorate.
本発明者等は、薄肉鋳造法を用いたCr系ステンレスw
4薄板の製造方法について研究を重ねた結果、Cr系ス
テンレスft4薄板のりジング特性の改善のためには、
成品板のコロニー(近似した方位を有する結晶粒の集団
)のサイズを小さくかつランダムに分散させ、結晶粒径
も比較的小さくすることが必要であり、そのためには凝
固組織を、等軸晶化かつ細粒化する必要があることを見
いだした。The present inventors have developed a Cr-based stainless steel w using a thin-wall casting method.
As a result of repeated research on the manufacturing method of 4 thin plates, we found that in order to improve the gluing characteristics of Cr-based stainless steel FT4 thin plates,
It is necessary to make the size of the colonies (a group of crystal grains with similar orientations) of the finished plate small and randomly dispersed, and to make the crystal grain size relatively small. It was also found that it was necessary to make the grains finer.
すなわち、薄肉鋳造プロセスにおいては、急冷により組
織を細粒化するだけではなく、等軸晶率を高めることが
重要な技術となり、そのためには鋳造板厚、過熱度及び
成分を制御することが必要となる。In other words, in the thin-wall casting process, it is important to not only refine the structure through rapid cooling but also to increase the equiaxed crystallinity, and for this purpose it is necessary to control the thickness of the cast plate, the degree of superheating, and the composition. becomes.
凝固速度は板厚が薄くなるほど大きくなり、結果として
凝固組織は細粒化する一方、過熱度が低下するほど等軸
晶化は容易となるため、等軸線粒化の条件は板厚と過熱
度の関数となる。この際、凝固速度は鋳型材質の影響を
受けるため、熱伝導度の大きい銅や鉄などが好ましいが
、同程度の熱伝導度を有するものであれば他のものでも
特に問題にはならない。The solidification rate increases as the plate thickness decreases, and as a result, the solidified structure becomes finer grained. On the other hand, as the degree of superheating decreases, equiaxed crystallization becomes easier. Therefore, the conditions for equiaxed grain formation depend on the plate thickness and degree of superheating. becomes a function of At this time, since the solidification rate is affected by the mold material, copper, iron, etc. with high thermal conductivity are preferable, but other materials with similar thermal conductivity may be used without any problem.
この傾向は通常のCr系ステンレス鋼において共通であ
り、Cr:8〜30%、C: 0.001〜0.5%、
N:0.001〜0.5%を主成分とし、残部は実質的
にFeからなるCr系ステンレス鋼薄肉鋳片を製造する
にあたり、過熱度を当該溶鋼温度と溶鋼成分の液相線温
度との差と定義すれば、板厚と過熱度の関係が、
O≦ΔT≦−45t+200
ΔT:過熱度(℃)
t:鋳片厚さ(mm)
を満足する条件で鋳造することにより、目的とする等軸
細粒の組織を得ることができる。This tendency is common in ordinary Cr-based stainless steels, with Cr: 8 to 30%, C: 0.001 to 0.5%,
When producing thin slabs of Cr-based stainless steel whose main component is N: 0.001 to 0.5% and the remainder is substantially Fe, the degree of superheating is determined between the molten steel temperature and the liquidus temperature of the molten steel components. Defined as the difference between plate thickness and degree of superheating, the relationship between plate thickness and degree of superheating is O≦∆T≦-45t+200 ∆T: degree of superheating (°C) t: slab thickness (mm) An equiaxed fine-grained structure can be obtained.
ところで凝固組繊を等軸晶化するためには、凝固直前の
溶鋼中に等軸晶の核が生成される必要がある。溶鋼温度
を低下することにより凝固核の生成は促進されるが、一
方で異質核を生成させ得れば、より高い過熱度でも等軸
晶率を高めることができるものと考えられる。発明者等
は種々の元素について検討を行った結果、jV、 Ti
、 Nb、 Zr、 B等について効果を見いだした。By the way, in order to equiaxed the solidified composite fibers, it is necessary to generate equiaxed nuclei in the molten steel immediately before solidification. Although the generation of solidification nuclei is promoted by lowering the molten steel temperature, it is considered that if heterogeneous nuclei can be generated, the equiaxed crystallinity can be increased even at a higher degree of superheating. The inventors investigated various elements and found that jV, Ti
, Nb, Zr, B, etc. were found to be effective.
すなわち、Cr:8〜30%、C:0.001〜0.5
%、N : 0.001〜0.5%を主成分とし、AN
? 0.01〜0.5%、Ti二0.01〜1:o%
、Nb:0.01〜1.0%、Zr:0.01〜1.0
%、B : 0.0003〜0.01%のうち一種もし
くは数種の元素を添加し、残部は実質的にFeからなる
Cr系ステンレス鋼薄肉鋳片を製造するにあたり、板厚
と過熱度の関係が、
0≦ΔT≦−at+b
ΔT:過熱度(℃)
L:鋳片厚さ(mill)
Al:a=40、b=180
Ti:a=35、b=24 O
Nb:a=25、b=200
Zr:a=20、b=140
B :a=35、b=200
を満足する条件で鋳造することにより、目的とする等軸
細粒の組織を得ることができる。この際、数種の元素を
添加した場合は、その添加量に応じた重みずけをして係
数を決めることが望ましい。That is, Cr: 8-30%, C: 0.001-0.5
%, N: 0.001 to 0.5% as the main component, AN
? 0.01-0.5%, Ti2 0.01-1:o%
, Nb: 0.01-1.0%, Zr: 0.01-1.0
%, B: 0.0003 to 0.01%, one or more elements are added, and the balance is essentially Fe. The relationship is: 0≦ΔT≦−at+b ΔT: degree of superheat (°C) L: slab thickness (mill) Al: a=40, b=180 Ti: a=35, b=24 O Nb: a=25, b=200 Zr: a=20, b=140 B: a=35, b=200 By casting under conditions that satisfy the following, the desired equiaxed fine grain structure can be obtained. At this time, when several types of elements are added, it is desirable to determine the coefficients by weighting them according to the amounts added.
すなわち、jV、Ti、Nb、Zrは添加量の重量%、
Bは添加量の重量%を100倍したものを重みとし、A
l、Ti等の全添加元素に対する各元素の割合を求め、
その割合に応じて係数a、bを計算すればよい。That is, jV, Ti, Nb, and Zr are added in weight %,
The weight of B is 100 times the weight% of the added amount, and A
Find the ratio of each element to all added elements such as l, Ti, etc.
The coefficients a and b may be calculated according to the ratio.
ここで7VはAl z 03を生成し、これが異質核と
なると考えられる。この添加量は0.01%未満では効
果が少なく、0.5%を越えるとその効果が飽和し・経
済的にメリットが小さくなるので0.01〜0゜5%と
した。Here, 7V generates Al z 03, which is considered to become a foreign nucleus. If the amount added is less than 0.01%, the effect will be small, and if it exceeds 0.5%, the effect will be saturated and the economic benefit will be reduced, so it was set to 0.01 to 0.5%.
TiはTiNを生成し、これが異質核となると考えられ
る。この添加量は、0.01%未満では効果が少なく、
1.0%を越えるとその効果が飽和し経済的にメリット
が小さくなり、また渦流れが悪くなり鋳造性が低下する
ので0.01〜1.0%とした。It is thought that Ti generates TiN, which becomes a foreign nucleus. If the amount added is less than 0.01%, the effect will be small;
If it exceeds 1.0%, the effect will be saturated and the economical benefits will be reduced, and the vortex flow will deteriorate and castability will deteriorate, so the content was set at 0.01 to 1.0%.
NbはNbN、 NbO,NbOx等を生成し、これが
異質核となると考えられる。この添加量は、0.01%
未満では効果が少なく、1.0%を越えるとその効果が
飽和し経済的にメリットが小さくなり、また渦流れが悪
くなり鋳造性が低下するので0.01〜1.0%とした
。Nb generates NbN, NbO, NbOx, etc., which are considered to be foreign nuclei. This addition amount is 0.01%
If it is less than 1.0%, the effect will be small, and if it exceeds 1.0%, the effect will be saturated and the economical benefits will be small, and the eddy flow will deteriorate and the castability will deteriorate, so the content was set at 0.01 to 1.0%.
ZrはZrzO,ZrNを生成し、これが異質核となる
と考えられる。この添加量は、0.01%未満では効果
が少なく、1.0%を越えるとその溶鋼中に酸化物が多
くなり、鋳造性及び成品板の特性を低下させるので0.
01〜1.0%とした。It is thought that Zr produces ZrzO and ZrN, which become heterogeneous nuclei. If the amount added is less than 0.01%, there will be little effect, and if it exceeds 1.0%, oxides will increase in the molten steel, deteriorating the castability and properties of the finished plate.
01 to 1.0%.
BはBN、 8203を生成し、これが異質核となると
考えられる。この添加量は、0.0003%未満では効
果が少なく、0.01%を越えると鋼中に硼化物が多量
に生成し、熱間加工性を著しく損ねるので、0.000
3〜0.01%とした。B produces BN, 8203, which is considered to be a foreign nucleus. If the amount added is less than 0.0003%, the effect will be small, and if it exceeds 0.01%, a large amount of boride will be generated in the steel, which will significantly impair hot workability.
It was set at 3 to 0.01%.
これらの成分範囲及び条件式を満足する条件で鋳造した
鋳片の凝固組織は、結晶粒径200μm以下の等軸晶を
50%以上占めており、これを出発素材としたCr系ス
テンレス鋼薄板は、優れたりジング特性を示す。The solidified structure of slabs cast under conditions that satisfy these component ranges and conditional expressions has equiaxed crystals with a grain size of 200 μm or less accounting for 50% or more, and Cr stainless steel thin sheets using this as a starting material are , exhibits excellent quenching properties.
また凝固組織を等軸晶化かつ細粒化することにより、深
絞り性も向上する。これは細粒化によって再結晶核の生
成サイトとなる粒界面積が増加することと、等軸晶化に
より凝固粒方位がランダム化し、そのため成品板の(1
00)方位が減少しく111)方位が主方位となるため
である。Furthermore, by equiaxed crystallizing and fine-graining the solidified structure, deep drawability is also improved. This is because grain refinement increases the grain boundary area that becomes the site of recrystallization nuclei, and equiaxed crystallization randomizes the solidified grain orientation, resulting in (1)
This is because the 00) direction decreases and the 111) direction becomes the main direction.
本発明の第二の目的は、薄肉鋳造法を用いてCr系ステ
ンレス鋼薄板を製造するにあたり、割れを防止しかつ深
絞り性を向上させることにある。通常Cr系ステンレス
鋼は高温域においてα相及びγ相の二相になっており、
そのまま冷却されるとγ相は硬い相としてα相中に残存
する。この硬い相は冷延性を阻害し冷延割れを引き起こ
すほか、成品板の深絞り性を低下させる原因となる。A second object of the present invention is to prevent cracking and improve deep drawability when manufacturing Cr-based stainless steel thin plates using the thin-wall casting method. Normally, Cr stainless steel has two phases, α phase and γ phase, in the high temperature range.
When cooled as is, the γ phase remains in the α phase as a hard phase. This hard phase inhibits cold rolling properties, causing cold rolling cracks, and also causes a reduction in the deep drawability of the finished sheet.
本発明によれば、薄肉鋳造法により得られた帯を、焼鈍
を行うかあるいは700℃以上1000℃以下で捲き取
って、冷間圧延以降の工程に供する。According to the present invention, the strip obtained by the thin-wall casting method is annealed or rolled up at a temperature of 700° C. or more and 1000° C. or less, and then subjected to the steps after cold rolling.
この場合焼鈍は700℃未満では硬い相の分解に長時間
を必要とするために経済的にメリットがなく、1000
℃超ではγ相が析出する温度域になるために、700℃
以上1000℃以下で行う。また捲き取りも同様の理由
により700℃以上1ooo℃以下で行う。In this case, annealing is not economically advantageous at temperatures below 700°C because it takes a long time to decompose the hard phase;
At temperatures above 700°C, the γ phase precipitates.
The above temperature is 1000°C or less. Also, for the same reason, winding is performed at a temperature of 700° C. or higher and 100° C. or lower.
また本発明では、150℃以上1300℃以下の温度範
囲で少なくとも1パスの圧延加工がなされ、次いで上記
条件で焼鈍あるいは捲き取りを行った後、冷間圧延以降
の工程に供する方法が示されている。この目的は、加工
歪の導入によりγ相の分解を促進し、一方では鋳造欠陥
を圧着することにより冷延性並びに成品板の延性を向上
させることにある。Further, the present invention discloses a method in which at least one pass of rolling is performed in a temperature range of 150° C. or higher and 1300° C. or lower, and then annealing or rolling is performed under the above conditions, and then the process is subjected to cold rolling and subsequent steps. There is. The purpose of this is to promote the decomposition of the γ phase by introducing working strain, and at the same time to improve the cold rollability and ductility of the finished sheet by compressing casting defects.
次に本発明の実施例について説明する。Next, examples of the present invention will be described.
実施例1゜
第1表に示す成分のCr系ステンレス鋼を銅製及び鉄製
鋳型を用い、鋳造温度1510〜1600℃1板厚2〜
4 n++++の範囲の薄肉鋳片に鋳造し、光学顕微鏡
を用いて組織観察を行った。当該成分の液相線温度はお
よそ1480〜1500℃である。Example 1 Cr-based stainless steel with the components shown in Table 1 was cast using copper and iron molds at a casting temperature of 1510 to 1600°C and a plate thickness of 2 to
A thin slab with a thickness of 4 n++++ was cast, and its structure was observed using an optical microscope. The liquidus temperature of the component is approximately 1480-1500°C.
この結果を第1図(a)〜ら)に示す。このようにして
鋳造した鋳片の組織は、板厚が薄いほどまた鋳造温度が
低いほど細粒化し、また等軸晶率も高くなる。また、A
!、 Ti、 Nb、 Zr、 Bを添加することに
より、等軸組粒化の範囲は厚手側・高温側に移行する。The results are shown in FIGS. 1(a) to 1(a). The structure of the slab cast in this manner becomes finer as the plate thickness becomes thinner and as the casting temperature becomes lower, and the equiaxed crystallinity also becomes higher. Also, A
! By adding , Ti, Nb, Zr, and B, the range of equiaxed grains shifts to the thick side and high temperature side.
実施例2゜
第2表に示す成分のCr系ステンレス鋼を銅製及び鉄製
鋳型を用い、鋳造温度1510〜1600℃1板厚2〜
4mmの範囲の薄肉鋳片に鋳造した後、840℃で4時
間の焼鈍、80%の冷間圧延、875℃で1分間の焼鈍
を施して、供試材とし、その後、リジング試験を行った
。当該成分の液相線温度はおよそ1480〜1500℃
である。Example 2 Cr-based stainless steel with the components shown in Table 2 was cast using copper and iron molds at a casting temperature of 1510 to 1600°C and a plate thickness of 2 to 300°C.
After casting into a thin slab in the range of 4 mm, it was annealed at 840°C for 4 hours, cold rolled to 80%, and annealed at 875°C for 1 minute to prepare a test material, and then a ridging test was conducted. . The liquidus temperature of the component is approximately 1480-1500℃
It is.
この結果を第3表に示す。等軸晶かつ細粒材はりジング
特性は良好で、同じ粒径でも柱状晶組織を有するものは
りジング特性は悪い。鋳造条件でみれば、板厚が薄いほ
どまた過熱度が低いほどリジング特性は良好である。The results are shown in Table 3. Materials with equiaxed crystals and fine grains have good gluing characteristics, while those with the same grain size but with a columnar crystal structure have poor gluing characteristics. In terms of casting conditions, the thinner the plate thickness and the lower the degree of superheating, the better the ridging properties.
この結果は、鋳造後750℃で1時間保定した場合も、
また鋳造後30%の熱間圧延を行った場合も同様であっ
た。This result shows that even when held at 750℃ for 1 hour after casting,
The same result was obtained when 30% hot rolling was performed after casting.
(発明の効果)
以上詳述した通り、本発明によれば、冷延性、リジング
特性、深絞り性の良好なCr系ステンレス鋼薄板を、薄
肉鋳造法を用いて極めて容易に低コストで製造すること
ができ、工業的な効果は大きい。(Effects of the Invention) As detailed above, according to the present invention, a thin Cr-based stainless steel sheet with good cold rollability, ridging properties, and deep drawability can be produced extremely easily and at low cost using a thin-wall casting method. The industrial effect is great.
第1図(a)〜(h)は、Cr系ステンレス鋼鋳造材の
、結晶粒径に及ぼす板厚と鋳造温度の関係を示したもの
である。図中、数字は結晶粒径をμm単位で示してあり
、また記号は、円が等軸晶率50%以上、三角が等軸晶
率50%未満を示している。
第1図
服 屡 Cmyyt> J!L 肩
(mm)(,2) (4
’)鑞厚 (mm) 板層 (mm
)(C) (改)第1図
$4(mn) 板s<ynm>
(e) (f)
(?) (幻
手続補正書(自発)
昭和63年3月9日
1、事件の表示
昭和63年特許願第22115号
2、発明の名称
薄肉鋳造法を用いるCr系ステンレス鋼薄板の製造方法
3、補正をする者
事件との関係 特許出願人
東京都千代田区大手町二丁目6番3号
(665)新日本製鐵株式會社
代表者 齋 藤 裕
4、代理人〒100
東京都千代田区丸の内通丁目4番1号
6、補正の対象
BA細書の特許請求の範囲の欄及び発明の詳細な説明(
1)!許請求の範囲を別紙の通り補正する。
(2)明細書8頁下から5行「30 mmもしくは」を
削除する。
(3)同15頁下から5行「等軸晶を」を「等軸晶が」
に補正する。
(4)同16頁3〜4行r(1oo)方位が減少しく1
11)方位がJ をr(100)<OVW>方位が減少
しく 111 ) <UVW>方位が」に補正する。
(5)同17頁6行「導入により」のあとに「再結晶及
び」を特徴する
特許請求の範囲
(1) Cr: 8〜30%、C: 0.001〜0
.5%、N : O,OO1〜0.5%を主成分とし、
残部は実質的にFeからなる鋼を、板厚と過熱度(過熱
度を当該溶鋼温度と溶鋼成分の液相線温度との差と定義
する。以下同じ)の関係が、
0≦ΔT≦−45t+200
ΔT:過熱度(”C)
t:鋳片厚さ(mm)
を満足する条件で鋳造した薄帯に、焼鈍、冷間圧延を施
し、次いで仕上げ焼鈍を施すことを特徴とする薄肉鋳造
法を用いるCr系ステンレス鋼薄板の製造方法
(2)Cr:8〜30%、C: 0.001〜0.5%
、N : 0.001〜0.5%を主成分とし、Al
: 0.01〜0.5%、Ti:0.01〜1.0%、
Nb:0.01〜1.0%、Zr: 0.01〜1.0
%、B : 0.0003〜0.01%のうち一種もし
くは数種の元素を添加し、残部は実質的にFeからなる
鋼を、板厚と過熱度の関係が、0≦ΔT≦−at+b
ΔT:過熱度(℃)
t:鋳片厚さ(an)
Al:a=40、b=180
Ti:a=35、b=24 O
Nb:a=25、b=200
Zr:a−20、b=140
B :a=35、b=200
を満足する条件で鋳造した薄帯に、焼鈍、冷間圧延を施
し、次いで仕上げ焼鈍を施すことを特徴とする薄肉鋳造
法を用いるCr系ステンレス鋼薄板の製造方法
(3) Cr: 8〜30%、C: 0.001・〜
0.5%、N : 0.0 O1〜0.5%を主成分と
し、残部は実質的にFeからなる鋼を、板厚と過熱度の
関係が、0≦ΔT≦−45t+200
ΔT:過熱度℃)
L:鋳片厚さ(M)
を満足する条件で鋳造した薄帯を、700〜1000℃
の温度域で捲き取り、焼鈍を行うことなく冷間圧延し、
次いで仕上げ焼鈍することを特徴とする薄肉鋳造法を用
いるCr系ステンレス鋼薄板の製造方法
(4) Cr: 8〜30%、C: 0.001〜O
,’5%、N : 0.001〜0.5%を主成分とし
、A7 : 0.01〜0、5%、Ti:0.01〜1
.0%、Nb:0.01〜1.0%、Zr: 0.01
〜1.0%、B : 0.0003〜0.01%のうち
一種もしくは数種の元素を添加し、残部は実質的にFe
からなる鋼を、板厚と過熱度の関係が、0≦ΔT≦−a
t+b
ΔT:過熱度(℃)
t:鋳片厚さ(薗)
iV:a=40、b=180
Ti:a=35、b=24 O
Nb:a−25、b=200
Zr:a=20、b=140
B :a=35、b=200
を満足する条件で鋳造した薄帯を、700〜1000℃
の温度域で捲き取り、焼鈍を行うことなく冷間圧延し、
次いで仕上げ焼鈍することを特徴とする薄肉鋳造法を用
いるCr系ステンレス鋼薄板の製造方法
(5) Cr: 8〜30%、C: 0.001〜0
.5%、N : 0.001〜0.5%を主成分とし、
残部は実質的にFeからなる鋼を、板厚と過熱度の関係
が、O≦ΔT≦−45t+200
ΔT:過熱度(”C)
t:鋳片厚さ(IIIIll)
を満足する条件で鋳造した薄帯を、150−1300℃
の温度域で少なくとも1パスの圧延加工を施して捲き取
った後、焼鈍、冷間圧延し、次いで仕上げ焼鈍すること
を特徴とする薄肉鋳造法を用いるCr系ステンレス鋼薄
板の製造方法
(6) Cr: 8〜30%、C: 0.001〜0
.5%、N : O,OO1〜0.5%を主成分とし、
A!: 0.01〜0.5%、Ti:0.01〜1.0
%、Nb:0.01〜1.0%、Zr: 0.01〜1
.0%、B : 0.0003〜0.01%のうち一種
もしくは数種の元素を添加し、残部は実質的にFeから
なる鋼を、板厚と過熱度の関係が、0≦ΔT≦−at+
b
ΔT:過熱度(℃)
t:鋳片厚さ(M)
jlJ:a=40、b=180
Ti:a=35、b=24 O
Nb:a=25、b=200
Zr :a=20Sb=140
B:a−35、b=200
を満足する条件で鋳造した薄帯を、150〜1300℃
の温度域で少なくとも1パスの圧延加工を施して捲き取
った後、焼鈍、冷間圧延し、次いで仕上げ焼鈍すること
を特徴とする薄肉鋳造法を用いるCr系ステンレス鋼薄
板の製造方法
(7) Cr: 8〜30%、C:O,OO1〜0.
5%、N : O,OO1〜0.5%を主成分とし、残
部は実質的にFeからなる鋼を、板厚と過熱度の関係が
、0≦ΔT≦−45t+200
ΔT:過熱度(C)
t:鋳片厚さ(舗)
を満足する条件で鋳造した薄帯を、700〜1300℃
の温度域で少なくとも1パスの圧延加工を施して700
〜1000℃の温度域で捲き取り、焼鈍を行うことなく
冷間圧延し、次いで仕上げ焼鈍することを特徴とする薄
肉鋳造法を用いるCr系ステンレスw4薄板の製造方法
(8)Cr:8〜30%、C: 0.001〜0.5%
、N : 0.001〜0.5%を主成分とし、N :
0.01〜0.5%、Ti:0.01〜1.0%、N
b:0.01〜1.0%、Zr: 0.01〜1.0%
、B : 0.0003〜0.01%のうち一種もしく
は数種の元素を添加し、残部は実質的にFeからなる鋼
を、板厚と過熱度の関係が、0≦ΔT≦−a t+b
ΔT:過熱度じC)
t:鋳片厚さ(mm)
Al:a=40、b=180
Ti:a−35、b=24 O
Nb:a=25、b=200
Zr:a=20、b=140
B :a=35、b=200
を満足する条件で鋳造した薄帯を、700〜1300℃
の温度域で少なくとも1パスの圧延加工を施して700
〜1000℃の温度域で捲き取り、焼鈍を行うことなく
冷間圧延し、次いで仕上げ焼鈍することを特徴とする薄
肉鋳造法を用いるCr系ステンレスtf4薄板の製造方
法FIGS. 1(a) to 1(h) show the relationship between plate thickness and casting temperature on crystal grain size of Cr-based stainless steel casting material. In the figure, the numbers indicate the crystal grain size in μm, and the symbols indicate that a circle indicates an equiaxed crystal ratio of 50% or more, and a triangle indicates an equiaxed crystal ratio of less than 50%. Figure 1 Clothes 屡 Cmyyt> J! L Shoulder (mm) (,2) (4
') Solder thickness (mm) Plate layer (mm
) (C) (Revised) Figure 1 $4 (mn) Board s<ynm> (e) (f) (?) (Phantom procedural amendment (voluntary) March 9, 1986 1, case display Showa 1963 Patent Application No. 22115 2, Name of the invention: Method for manufacturing Cr-based stainless steel thin plate using thin-wall casting method 3, Relationship with the person making the amendment case Patent applicant: 2-6-3 Otemachi, Chiyoda-ku, Tokyo (665) Nippon Steel Corporation Representative Yutaka Saito 4, Agent 4-1-6, Marunouchi-dori-chome, Chiyoda-ku, Tokyo 100, Subject of amendment explanation(
1)! The scope of claims is amended as shown in the attached sheet. (2) Delete 5 lines "30 mm or more" from the bottom of page 8 of the specification. (3) 5 lines from the bottom of page 15, “Equiaxed crystal” is changed to “Equiaxed crystal ga”
Correct to. (4) Page 16, lines 3-4 r (1oo) The direction is decreasing and 1
11) Correct the direction J to r(100)<OVW>direction decreases.111) <UVW>direction decreases. (5) Claims characterized by "recrystallization and" after "by introduction" on page 17, line 6 (1) Cr: 8-30%, C: 0.001-0
.. 5%, N:O,OO1-0.5% as main components,
The relationship between the plate thickness and the degree of superheating (the degree of superheating is defined as the difference between the temperature of the molten steel and the liquidus temperature of the molten steel components; the same applies hereinafter) for the steel in which the remainder is substantially Fe is 0≦ΔT≦−. 45t+200 ΔT: degree of superheating ("C) t: slab thickness (mm) A thin-walled casting method characterized by subjecting a thin strip cast under conditions satisfying the following conditions to annealing, cold rolling, and then final annealing. Manufacturing method of Cr-based stainless steel thin plate using (2) Cr: 8-30%, C: 0.001-0.5%
, N: 0.001 to 0.5% as the main component, Al
: 0.01-0.5%, Ti: 0.01-1.0%,
Nb: 0.01-1.0%, Zr: 0.01-1.0
%, B: Steel to which one or more elements from 0.0003 to 0.01% are added, and the remainder substantially consists of Fe, where the relationship between plate thickness and degree of superheat is 0≦ΔT≦−at+b ΔT: degree of superheat (℃) t: slab thickness (an) Al: a=40, b=180 Ti: a=35, b=24 O Nb: a=25, b=200 Zr: a-20, b=140 B: Cr-based stainless steel using a thin-wall casting method characterized by annealing and cold rolling a thin strip cast under conditions satisfying the following conditions: a=35, b=200, and then subjecting it to finish annealing. Manufacturing method of thin plate (3) Cr: 8-30%, C: 0.001.~
0.5%, N: 0.0 The main component is O1~0.5%, and the remainder is substantially Fe. The relationship between plate thickness and degree of superheating is 0≦ΔT≦−45t+200 ΔT: Overheating L: Thickness of slab (M)
It is rolled up and cold rolled without annealing in the temperature range of
Method for manufacturing a Cr-based stainless steel thin plate using a thin-walled casting method characterized by subsequent finish annealing (4) Cr: 8 to 30%, C: 0.001 to O
, '5%, N: 0.001-0.5% as main component, A7: 0.01-0.5%, Ti: 0.01-1
.. 0%, Nb: 0.01-1.0%, Zr: 0.01
~1.0%, B: One or more elements from 0.0003 to 0.01% are added, and the remainder is substantially Fe.
The relationship between plate thickness and degree of superheat is 0≦ΔT≦−a
t+b ΔT: Degree of superheat (℃) t: Slab thickness (Sono) iV: a=40, b=180 Ti: a=35, b=24 O Nb: a-25, b=200 Zr: a=20 , b = 140 B : A = 35, b = 200
It is rolled up and cold rolled without annealing in the temperature range of
Method for manufacturing a Cr-based stainless steel thin plate using a thin-wall casting method characterized by subsequent finish annealing (5) Cr: 8-30%, C: 0.001-0
.. 5%, N: 0.001 to 0.5% as the main component,
The remainder of the steel was essentially made of Fe, and was cast under conditions such that the relationship between plate thickness and degree of superheat satisfied the following: O≦∆T≦-45t+200 ∆T: degree of superheat ("C) t: slab thickness (IIIll) Thin ribbon, 150-1300℃
A method for manufacturing a Cr-based stainless steel thin plate using a thin-wall casting method (6), which is characterized by performing at least one pass of rolling in a temperature range of 100 to 1000 ml, rolling it up, annealing, cold rolling, and then final annealing. Cr: 8-30%, C: 0.001-0
.. 5%, N:O,OO1-0.5% as main components,
A! : 0.01-0.5%, Ti: 0.01-1.0
%, Nb: 0.01-1.0%, Zr: 0.01-1
.. 0%, B: Steel to which one or more elements from 0.0003 to 0.01% are added, and the remainder substantially consists of Fe, where the relationship between plate thickness and degree of superheating is 0≦ΔT≦- at+
b ΔT: Degree of superheat (℃) t: Slab thickness (M) jlJ: a=40, b=180 Ti: a=35, b=24 O Nb: a=25, b=200 Zr: a=20Sb = 140 B: A ribbon cast under the conditions satisfying a-35, b = 200 was heated at 150 to 1300°C.
A method for manufacturing a Cr-based stainless steel thin plate using a thin-wall casting method (7), which is characterized by performing at least one pass of rolling in a temperature range of 100 to 1000 ml, rolling it up, annealing, cold rolling, and then final annealing. Cr: 8-30%, C:O, OO1-0.
5%, N: O, OO 1 to 0.5% as the main components, and the remainder substantially Fe. ) t: Thickness of slab
At least one pass of rolling in a temperature range of 700
Manufacturing method of Cr-based stainless steel W4 thin plate using a thin-wall casting method characterized by rolling in a temperature range of ~1000°C, cold rolling without annealing, and then finish annealing (8) Cr: 8-30 %, C: 0.001-0.5%
, N: 0.001 to 0.5% as the main component, N:
0.01-0.5%, Ti: 0.01-1.0%, N
b: 0.01-1.0%, Zr: 0.01-1.0%
, B: Steel to which one or more elements from 0.0003 to 0.01% are added, and the remainder substantially consists of Fe, where the relationship between plate thickness and degree of superheat is 0≦ΔT≦−a t+b ΔT: degree of superheating C) t: slab thickness (mm) Al: a=40, b=180 Ti: a-35, b=24 O Nb: a=25, b=200 Zr: a=20, b = 140 B: A ribbon cast under conditions satisfying a = 35, b = 200 is heated at 700 to 1300°C.
At least one pass of rolling in a temperature range of 700
A method for manufacturing Cr-based stainless steel TF4 thin plate using a thin-wall casting method characterized by rolling in a temperature range of ~1000°C, cold rolling without annealing, and then final annealing.
Claims (8)
N:0.001〜0.5%を主成分とし、残部は実質的
にFeからなる鋼を、板厚と過熱度(過熱度を当該溶鋼
温度と溶鋼成分の液相線温度との差と定義する。以下同
じ)の関係が、 0≦ΔT≦−45t+200 ΔT:過熱度(℃) t:鋳片厚さ(mm) を満足する条件で鋳造した薄帯に、焼鈍、冷間圧延を施
し、次いで仕上げ焼鈍を施すことを特徴とする薄肉鋳造
法を用いるCr系ステンレス鋼薄板の製造方法(1) Cr: 8-30%, C: 0.001-0.5%,
A steel whose main component is N: 0.001 to 0.5%, and the remainder is substantially Fe, is prepared by measuring the plate thickness and degree of superheating (the degree of superheating is defined as the difference between the temperature of the molten steel and the liquidus temperature of the molten steel components). The following relationship is established: 0≦∆T≦-45t+200 ∆T: degree of superheat (°C) t: slab thickness (mm) A method for manufacturing a Cr-based stainless steel thin plate using a thin-wall casting method, which is characterized by performing finish annealing.
N:0.001〜0.5%を主成分とし、Al:0.0
1〜0.5%、Ti:0.01〜1.0%、Nb:0.
01〜1.0%、Zr:0.01〜1.0%、B:0.
0003〜0.01%のうち一種もしくは数種の元素を
添加し、残部は実質的にFeからなる鋼を、板厚と過熱
度の関係が、 0≦ΔT≦−at+b ΔT:過熱度(℃) t:鋳片厚さ(mm) Al:a=40、b=180 Ti:a=35、b=240 Nb:a=25、b=200 Zr:a=20、b=140 B:a=35、b=200 を満足する条件で鋳造した薄帯に、焼鈍、冷間圧延を施
し、次いで仕上げ焼鈍を施すことを特徴とする薄肉鋳造
法を用いるCr系ステンレス鋼薄板の製造方法(2) Cr: 8-30%, C: 0.001-0.5%,
Main component is N: 0.001 to 0.5%, Al: 0.0
1-0.5%, Ti: 0.01-1.0%, Nb: 0.
01-1.0%, Zr: 0.01-1.0%, B: 0.
The relationship between plate thickness and degree of superheat is 0≦∆T≦-at+b ∆T: degree of superheat (°C). ) t: Slab thickness (mm) Al: a=40, b=180 Ti: a=35, b=240 Nb: a=25, b=200 Zr: a=20, b=140 B: a= 35, a method for manufacturing a Cr-based stainless steel thin plate using a thin-wall casting method, characterized in that a thin strip cast under conditions satisfying b=200 is subjected to annealing, cold rolling, and then final annealing.
N:0.001〜0.5%を主成分とし、残部は実質的
にFeからなる鋼を、板厚と過熱度の関係が、 0≦ΔT≦−45t+200 ΔT:過熱度(℃) t:鋳片厚さ(mm) を満足する条件で鋳造した薄帯を、700〜1000℃
の温度域で捲き取り、焼鈍を行うことなく冷間圧延し、
次いで仕上げ焼鈍することを特徴とする薄肉鋳造法を用
いるCr系ステンレス鋼薄板の製造方法(3) Cr: 8-30%, C: 0.001-0.5%,
The relationship between plate thickness and degree of superheat is as follows: 0≦∆T≦-45t+200 ∆T: degree of superheat (°C) t: Thin strips cast under conditions that satisfy the slab thickness (mm) are heated at 700 to 1000℃.
It is rolled up and cold rolled without annealing in the temperature range of
A method for manufacturing a Cr-based stainless steel thin plate using a thin-wall casting method, which is then subjected to finish annealing.
N:0.001〜0.5%を主成分とし、Al:0.0
1〜0.5%、Ti:0.01〜1.0%、Nb:0.
01〜1.0%、Zr:0.01〜1.0%、B:0.
0003〜0.01%のうち一種もしくは数種の元素を
添加し、残部は実質的にFeからなる鋼を、板厚と過熱
度の関係が、 0≦ΔT≦−at+b ΔT:過熱度(℃) t:鋳片厚さ(mm) Al:a=40、b=180 Ti:a=35、b=240 Nb:a=25、b=200 Zr:a=20、b=140 B:a=35、b=200 を満足する条件で鋳造した薄帯を、700〜1000℃
の温度域で捲き取り、焼鈍を行うことなく冷間圧延し、
次いで仕上げ焼鈍することを特徴とする薄肉鋳造法を用
いるCr系ステンレス鋼薄板の製造方法(4) Cr: 8-30%, C: 0.001-0.5%,
Main component is N: 0.001 to 0.5%, Al: 0.0
1-0.5%, Ti: 0.01-1.0%, Nb: 0.
01-1.0%, Zr: 0.01-1.0%, B: 0.
The relationship between plate thickness and degree of superheat is 0≦∆T≦-at+b ∆T: degree of superheat (°C). ) t: Slab thickness (mm) Al: a=40, b=180 Ti: a=35, b=240 Nb: a=25, b=200 Zr: a=20, b=140 B: a= 35, the ribbon cast under conditions satisfying b=200 was heated at 700 to 1000°C.
It is rolled up and cold rolled without annealing in the temperature range of
A method for manufacturing a Cr-based stainless steel thin plate using a thin-wall casting method, which is then subjected to finish annealing.
N:0.001〜0.5%を主成分とし、残部は実質的
にFeからなる鋼を、板厚と過熱度の関係が、 0≦ΔT≦−45t+200 ΔT:過熱度(℃) t:鋳片厚さ(mm) を満足する条件で鋳造した薄帯を、150〜1300℃
の温度域で少なくとも1パスの圧延加工を施して捲き取
った後、焼鈍、冷間圧延し、次いで仕上げ焼鈍すること
を特徴とする薄肉鋳造法を用いるCr系ステンレス鋼薄
板の製造方法(5) Cr: 8-30%, C: 0.001-0.5%,
The relationship between plate thickness and degree of superheat is as follows: 0≦∆T≦-45t+200 ∆T: degree of superheat (°C) t: Thickness of the slab (mm) The ribbon was cast under the conditions of 150 to 1300℃.
A method for manufacturing a Cr-based stainless steel thin plate using a thin-wall casting method, which is characterized by performing at least one rolling pass in a temperature range of
N:0.001〜0.5%を主成分とし、Al:0.0
1〜0.5%、Ti:0.01〜1.0%、Nb:0.
01〜1.0%、Zr:0.01〜1.0%、B:0.
0003〜0.01%のうち一種もしくは数種の元素を
添加し、残部は実質的にFeからなる鋼を、板厚と過熱
度の関係が、 0≦ΔT≦−at+b ΔT:過熱度(℃) t:鋳片厚さ(mm) Al:a=40、b=180 Ti:a=35、b=240 Nb:a=2、b=200 Zr:a=20、b=140 B:a=35、b=200 を満足する条件で鋳造した薄帯を、150〜1300℃
の温度域で少なくとも1パスの圧延加工を施して捲き取
った後、焼鈍、冷間圧延し、次いで仕上げ焼鈍すること
を特徴とする薄肉鋳造法を用いるCr系ステンレス鋼薄
板の製造方法(6) Cr: 8-30%, C: 0.001-0.5%,
Main component is N: 0.001 to 0.5%, Al: 0.0
1-0.5%, Ti: 0.01-1.0%, Nb: 0.
01-1.0%, Zr: 0.01-1.0%, B: 0.
The relationship between plate thickness and degree of superheat is 0≦∆T≦-at+b ∆T: degree of superheat (°C). ) t: Slab thickness (mm) Al: a=40, b=180 Ti: a=35, b=240 Nb: a=2, b=200 Zr: a=20, b=140 B: a= 35, the ribbon cast under conditions satisfying b=200 was heated at 150 to 1300°C.
A method for manufacturing a Cr-based stainless steel thin plate using a thin-wall casting method, which is characterized by performing at least one rolling pass in a temperature range of
N:0.001〜0.5%を主成分とし、残部は実質的
にFeからなる鋼を、板厚と過熱度の関係が、 0≦ΔT≦−45t+200 ΔT:過熱度(℃) t:鋳片厚さ(mm) を満足する条件で鋳造した薄帯を、150〜1300℃
の温度域で少なくとも1パスの圧延加工を施して700
〜1000℃の温度域で捲き取り、焼鈍を行うことなく
冷間圧延し、次いで仕上げ焼鈍することを特徴とする薄
肉鋳造法を用いるCr系ステンレス鋼薄板の製造方法(7) Cr: 8-30%, C: 0.001-0.5%,
The relationship between plate thickness and degree of superheat is as follows: 0≦∆T≦-45t+200 ∆T: degree of superheat (°C) t: Thickness of the slab (mm) The ribbon was cast under the conditions of 150 to 1300℃.
At least one pass of rolling in a temperature range of 700
A method for manufacturing a Cr-based stainless steel thin plate using a thin-wall casting method characterized by rolling in a temperature range of ~1000°C, cold rolling without annealing, and then final annealing.
N:0.001〜0.5%を主成分とし、N:0.01
〜0.5%、Ti:0.01〜1.0%、Nb:0.0
1〜1.0%、Zr:0.01〜1.0%、B:0.0
003〜0.01%のうち一種もしくは数種の元素を添
加し、残部は実質的にFeからなる鋼を、板厚と過熱度
の関係が、 0≦ΔT≦−at+b ΔT:過熱度(℃) t:鋳片厚さ(mm) Al:a=40、b=180 Ti:a=35、b=240 Nb:a=25、b=200 Zr:a=20、b=140 B:a=35、b=200 を満足する条件で鋳造した薄帯を、150〜1300℃
の温度域で少なくとも1パスの圧延加工を施して700
〜1000℃の温度域で捲き取り、焼鈍を行うことなく
冷間圧延し、次いで仕上げ焼鈍することを特徴とする薄
肉鋳造法を用いるCr系ステンレス鋼薄板の製造方法(8) Cr: 8-30%, C: 0.001-0.5%,
Main component is N: 0.001 to 0.5%, N: 0.01
~0.5%, Ti: 0.01~1.0%, Nb: 0.0
1-1.0%, Zr: 0.01-1.0%, B: 0.0
The relationship between plate thickness and degree of superheat is 0≦∆T≦-at+b ∆T: degree of superheat (°C). ) t: Slab thickness (mm) Al: a=40, b=180 Ti: a=35, b=240 Nb: a=25, b=200 Zr: a=20, b=140 B: a= 35, the ribbon cast under conditions satisfying b=200 was heated at 150 to 1300°C.
At least one pass of rolling in a temperature range of 700
A method for manufacturing a Cr-based stainless steel thin plate using a thin-wall casting method characterized by rolling in a temperature range of ~1000°C, cold rolling without annealing, and then final annealing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2211588A JPH0688102B2 (en) | 1988-02-03 | 1988-02-03 | Method for producing Cr-based stainless steel sheet using thin casting method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2211588A JPH0688102B2 (en) | 1988-02-03 | 1988-02-03 | Method for producing Cr-based stainless steel sheet using thin casting method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01197046A true JPH01197046A (en) | 1989-08-08 |
| JPH0688102B2 JPH0688102B2 (en) | 1994-11-09 |
Family
ID=12073885
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2211588A Expired - Fee Related JPH0688102B2 (en) | 1988-02-03 | 1988-02-03 | Method for producing Cr-based stainless steel sheet using thin casting method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0688102B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2667524A1 (en) * | 1990-10-08 | 1992-04-10 | Kawasaki Steel Co | PROCESS FOR MANUFACTURING ROUND INGOTS FOR SOLDERLESS STEEL PIPES. |
| WO2014057875A1 (en) * | 2012-10-10 | 2014-04-17 | 日立金属株式会社 | Ferritic heat-resistant cast steel with excellent machinability and exhaust component consisting of same |
| JP2023544120A (en) * | 2020-10-09 | 2023-10-20 | オウトクンプ オサケイティオ ユルキネン | How to produce stainless steel |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5741729B2 (en) | 2010-12-09 | 2015-07-01 | ソニー株式会社 | Image processing apparatus and image processing method |
-
1988
- 1988-02-03 JP JP2211588A patent/JPH0688102B2/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2667524A1 (en) * | 1990-10-08 | 1992-04-10 | Kawasaki Steel Co | PROCESS FOR MANUFACTURING ROUND INGOTS FOR SOLDERLESS STEEL PIPES. |
| WO2014057875A1 (en) * | 2012-10-10 | 2014-04-17 | 日立金属株式会社 | Ferritic heat-resistant cast steel with excellent machinability and exhaust component consisting of same |
| CN104718304A (en) * | 2012-10-10 | 2015-06-17 | 日立金属株式会社 | Ferritic heat-resistant cast steel with excellent machinability and exhaust component consisting of same |
| JPWO2014057875A1 (en) * | 2012-10-10 | 2016-09-05 | 日立金属株式会社 | Ferritic heat-resistant cast steel with excellent machinability and exhaust system parts composed thereof |
| US9758851B2 (en) | 2012-10-10 | 2017-09-12 | Hitachi Metals, Ltd. | Heat-resistant, cast ferritic steel having excellent machinability and exhaust member made thereof |
| JP2023544120A (en) * | 2020-10-09 | 2023-10-20 | オウトクンプ オサケイティオ ユルキネン | How to produce stainless steel |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0688102B2 (en) | 1994-11-09 |
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