JPH0121835B2 - - Google Patents
Info
- Publication number
- JPH0121835B2 JPH0121835B2 JP58106001A JP10600183A JPH0121835B2 JP H0121835 B2 JPH0121835 B2 JP H0121835B2 JP 58106001 A JP58106001 A JP 58106001A JP 10600183 A JP10600183 A JP 10600183A JP H0121835 B2 JPH0121835 B2 JP H0121835B2
- Authority
- JP
- Japan
- Prior art keywords
- bis
- hydrogen
- carbon dioxide
- group
- tris
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 claims abstract description 24
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 125000004663 dialkyl amino group Chemical group 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 53
- 239000001257 hydrogen Substances 0.000 abstract description 29
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 29
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract description 26
- 239000001569 carbon dioxide Substances 0.000 abstract description 26
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 20
- DRNXZGJGRSUXHW-UHFFFAOYSA-N silyl carbamate Chemical compound NC(=O)O[SiH3] DRNXZGJGRSUXHW-UHFFFAOYSA-N 0.000 abstract description 13
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract description 10
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 abstract description 10
- 239000000203 mixture Substances 0.000 abstract description 8
- -1 bis-benzylaminomethylsilane bis-diphenylaminoethylsilane Chemical compound 0.000 description 16
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 11
- 239000011541 reaction mixture Substances 0.000 description 11
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- 238000005481 NMR spectroscopy Methods 0.000 description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 6
- DWLVWMUCHSLGSU-UHFFFAOYSA-M n,n-dimethylcarbamate Chemical compound CN(C)C([O-])=O DWLVWMUCHSLGSU-UHFFFAOYSA-M 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 238000010992 reflux Methods 0.000 description 6
- 229910000077 silane Inorganic materials 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- 229910052786 argon Inorganic materials 0.000 description 4
- KZFNONVXCZVHRD-UHFFFAOYSA-N dimethylamino(dimethyl)silicon Chemical compound CN(C)[Si](C)C KZFNONVXCZVHRD-UHFFFAOYSA-N 0.000 description 4
- 150000002430 hydrocarbons Chemical group 0.000 description 4
- UIUXUFNYAYAMOE-UHFFFAOYSA-N methylsilane Chemical compound [SiH3]C UIUXUFNYAYAMOE-UHFFFAOYSA-N 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000007983 Tris buffer Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- AWFPGKLDLMAPMK-UHFFFAOYSA-N dimethylaminosilicon Chemical compound CN(C)[Si] AWFPGKLDLMAPMK-UHFFFAOYSA-N 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- GIRKRMUMWJFNRI-UHFFFAOYSA-N tris(dimethylamino)silicon Chemical compound CN(C)[Si](N(C)C)N(C)C GIRKRMUMWJFNRI-UHFFFAOYSA-N 0.000 description 3
- GVBCJFHGXGHMFD-UHFFFAOYSA-N 1-cyclohexyl-N-dimethylsilylmethanamine Chemical compound C[SiH](C)NCC1CCCCC1 GVBCJFHGXGHMFD-UHFFFAOYSA-N 0.000 description 2
- SNYNNFDVNITLRQ-UHFFFAOYSA-N 2,2,4,4,6,6,8-heptamethyl-1,3,5,7,2,4,6,8$l^{3}-tetraoxatetrasilocane Chemical compound C[Si]1O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 SNYNNFDVNITLRQ-UHFFFAOYSA-N 0.000 description 2
- QDCSSSQBJAVUTE-UHFFFAOYSA-N 2-dimethylsilyl-N-ethylethanamine Chemical compound CCNCC[SiH](C)C QDCSSSQBJAVUTE-UHFFFAOYSA-N 0.000 description 2
- LTIUDPOSFOYSKA-UHFFFAOYSA-N 2-ethenyl-2,4,4,6,6,8,8-heptamethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C=C)O[Si](C)(C)O1 LTIUDPOSFOYSKA-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- VSRNFKFFJHDLPE-UHFFFAOYSA-N N,N,N',N'-tetracyclopentyl-1-silylmethanediamine Chemical compound C1CCCC1N(C1CCCC1)C([SiH3])N(C1CCCC1)C1CCCC1 VSRNFKFFJHDLPE-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000012043 crude product Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- UBHZUDXTHNMNLD-UHFFFAOYSA-N dimethylsilane Chemical compound C[SiH2]C UBHZUDXTHNMNLD-UHFFFAOYSA-N 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 238000006459 hydrosilylation reaction Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- APRJFNLVTJWEPP-UHFFFAOYSA-M n,n-diethylcarbamate Chemical compound CCN(CC)C([O-])=O APRJFNLVTJWEPP-UHFFFAOYSA-M 0.000 description 2
- KXPPDWYTBLMTPL-UHFFFAOYSA-N n-trimethylsilylethanamine Chemical compound CCN[Si](C)(C)C KXPPDWYTBLMTPL-UHFFFAOYSA-N 0.000 description 2
- 150000003961 organosilicon compounds Chemical class 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000005292 vacuum distillation Methods 0.000 description 2
- YMSFRGSTTNUPSM-UHFFFAOYSA-N 1-N,1-N,1-N',1-N'-tetrabenzyl-2-silylethane-1,1-diamine Chemical compound C=1C=CC=CC=1CN(CC=1C=CC=CC=1)C(C[SiH3])N(CC=1C=CC=CC=1)CC1=CC=CC=C1 YMSFRGSTTNUPSM-UHFFFAOYSA-N 0.000 description 1
- ITUDOJUJGMTIIH-UHFFFAOYSA-N 1-N,1-N,1-N',1-N'-tetrabenzyl-3-silylpropane-1,1-diamine Chemical compound C=1C=CC=CC=1CN(CC=1C=CC=CC=1)C(CC[SiH3])N(CC=1C=CC=CC=1)CC1=CC=CC=C1 ITUDOJUJGMTIIH-UHFFFAOYSA-N 0.000 description 1
- HVAPMPHCWNZDFY-UHFFFAOYSA-N 1-N,1-N,1-N',1-N'-tetraphenyl-4-silylbutane-1,1-diamine Chemical compound C=1C=CC=CC=1N(C=1C=CC=CC=1)C(CCC[SiH3])N(C=1C=CC=CC=1)C1=CC=CC=C1 HVAPMPHCWNZDFY-UHFFFAOYSA-N 0.000 description 1
- LTZGIGZNGIZXCA-UHFFFAOYSA-N 1-[4-(2-dimethylsilylethyl)-2,4,6,6,8,8-hexamethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocan-2-yl]-N,N-dimethylmethanamine Chemical compound CN(C)C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(CC[SiH](C)C)O1 LTZGIGZNGIZXCA-UHFFFAOYSA-N 0.000 description 1
- YUDUUSWKVFQVKF-UHFFFAOYSA-N 1-cyclopentyl-N-dimethylsilylmethanamine Chemical compound C[SiH](C)NCC1CCCC1 YUDUUSWKVFQVKF-UHFFFAOYSA-N 0.000 description 1
- KWAQABZFJUOKRB-UHFFFAOYSA-N C1(CCCCC1)NC(NC1CCCCC1)[SiH3] Chemical compound C1(CCCCC1)NC(NC1CCCCC1)[SiH3] KWAQABZFJUOKRB-UHFFFAOYSA-N 0.000 description 1
- GOGMPDCZXDYJKC-UHFFFAOYSA-N C=1C=CC=CC=1CN(CC=1C=CC=CC=1)[SiH](C(C)C)N(CC=1C=CC=CC=1)CC1=CC=CC=C1 Chemical compound C=1C=CC=CC=1CN(CC=1C=CC=CC=1)[SiH](C(C)C)N(CC=1C=CC=CC=1)CC1=CC=CC=C1 GOGMPDCZXDYJKC-UHFFFAOYSA-N 0.000 description 1
- MBKFZUWFDYUXEW-UHFFFAOYSA-N C=1C=CC=CC=1CN([SiH](C)C)CC1=CC=CC=C1 Chemical compound C=1C=CC=CC=1CN([SiH](C)C)CC1=CC=CC=C1 MBKFZUWFDYUXEW-UHFFFAOYSA-N 0.000 description 1
- AWSPFFNDLAZTBF-UHFFFAOYSA-N C=1C=CC=CC=1CN([SiH](N(CC=1C=CC=CC=1)CC=1C=CC=CC=1)N(CC=1C=CC=CC=1)CC=1C=CC=CC=1)CC1=CC=CC=C1 Chemical compound C=1C=CC=CC=1CN([SiH](N(CC=1C=CC=CC=1)CC=1C=CC=CC=1)N(CC=1C=CC=CC=1)CC=1C=CC=CC=1)CC1=CC=CC=C1 AWSPFFNDLAZTBF-UHFFFAOYSA-N 0.000 description 1
- UPCHQOGVQKXCNM-UHFFFAOYSA-N C=1C=CC=CC=1N([SiH](C)C)C1=CC=CC=C1 Chemical compound C=1C=CC=CC=1N([SiH](C)C)C1=CC=CC=C1 UPCHQOGVQKXCNM-UHFFFAOYSA-N 0.000 description 1
- XXEVQQQTHDJAFN-UHFFFAOYSA-N CCN(CC)C(C[SiH3])N(CC)CC Chemical compound CCN(CC)C(C[SiH3])N(CC)CC XXEVQQQTHDJAFN-UHFFFAOYSA-N 0.000 description 1
- DBTKGGFFVHEJDB-UHFFFAOYSA-N CN(C)C(C[SiH3])N(C)C Chemical compound CN(C)C(C[SiH3])N(C)C DBTKGGFFVHEJDB-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- FWDDVARYKVFPAX-UHFFFAOYSA-N N,N,N',N'-tetraphenyl-1-silylmethanediamine Chemical compound C=1C=CC=CC=1N(C=1C=CC=CC=1)C([SiH3])N(C=1C=CC=CC=1)C1=CC=CC=C1 FWDDVARYKVFPAX-UHFFFAOYSA-N 0.000 description 1
- BNFYBHXESJBEKM-UHFFFAOYSA-N N,N-dibenzyl-2-silylethanamine Chemical compound C1(=CC=CC=C1)CN(CC1=CC=CC=C1)CC[SiH3] BNFYBHXESJBEKM-UHFFFAOYSA-N 0.000 description 1
- IMWNPCWQWFYMAR-UHFFFAOYSA-N N-(cyclopentylamino)silylcyclopentanamine Chemical compound C1(CCCC1)N[SiH2]NC1CCCC1 IMWNPCWQWFYMAR-UHFFFAOYSA-N 0.000 description 1
- VFODVNXPRZYZAL-UHFFFAOYSA-N N-(dicyclohexylsilylmethyl)aniline Chemical compound C1CCCCC1[SiH](C1CCCCC1)CNC1=CC=CC=C1 VFODVNXPRZYZAL-UHFFFAOYSA-N 0.000 description 1
- JCHBPOHOSDKNQJ-UHFFFAOYSA-N N-(diethylsilylmethyl)aniline Chemical compound CC[SiH](CC)CNC1=CC=CC=C1 JCHBPOHOSDKNQJ-UHFFFAOYSA-N 0.000 description 1
- DRJVSLKXUILURR-UHFFFAOYSA-N N-bis(N-phenylanilino)silyl-N-phenylaniline Chemical compound C1=CC=CC=C1N(C=1C=CC=CC=1)[SiH](N(C=1C=CC=CC=1)C=1C=CC=CC=1)N(C=1C=CC=CC=1)C1=CC=CC=C1 DRJVSLKXUILURR-UHFFFAOYSA-N 0.000 description 1
- RHWAEXIZCLEBKK-UHFFFAOYSA-N N-bis(dicyclopentylamino)silyl-N-cyclopentylcyclopentanamine Chemical compound C1CCCC1N([SiH](N(C1CCCC1)C1CCCC1)N(C1CCCC1)C1CCCC1)C1CCCC1 RHWAEXIZCLEBKK-UHFFFAOYSA-N 0.000 description 1
- SEDFDCNKXRSLNS-UHFFFAOYSA-N N-cyclohexyl-N-dimethylsilylcyclohexanamine Chemical compound C1CCCCC1N([SiH](C)C)C1CCCCC1 SEDFDCNKXRSLNS-UHFFFAOYSA-N 0.000 description 1
- LVAWIXVGVCMGHV-UHFFFAOYSA-N N-cyclopentyl-N-dimethylsilylcyclopentanamine Chemical compound C1CCCC1N([SiH](C)C)C1CCCC1 LVAWIXVGVCMGHV-UHFFFAOYSA-N 0.000 description 1
- FOVBYPWELQHADC-UHFFFAOYSA-N N-dimethylsilyl-2-phenylethanamine Chemical compound C[SiH](C)NCCC1=CC=CC=C1 FOVBYPWELQHADC-UHFFFAOYSA-N 0.000 description 1
- RDKXOOCTKMIEGS-UHFFFAOYSA-N [SiH4].NC(O)=O Chemical compound [SiH4].NC(O)=O RDKXOOCTKMIEGS-UHFFFAOYSA-N 0.000 description 1
- 230000009102 absorption Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- ADTGAVILDBXARD-UHFFFAOYSA-N diethylamino(dimethyl)silicon Chemical compound CCN(CC)[Si](C)C ADTGAVILDBXARD-UHFFFAOYSA-N 0.000 description 1
- WZUCGJVWOLJJAN-UHFFFAOYSA-N diethylaminosilicon Chemical compound CCN([Si])CC WZUCGJVWOLJJAN-UHFFFAOYSA-N 0.000 description 1
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- NCAKWMZPHTZJOT-UHFFFAOYSA-N n-[bis(diethylamino)silyl]-n-ethylethanamine Chemical compound CCN(CC)[SiH](N(CC)CC)N(CC)CC NCAKWMZPHTZJOT-UHFFFAOYSA-N 0.000 description 1
- TWVSWDVJBJKDAA-UHFFFAOYSA-N n-[bis(dimethylamino)silyl]-n-methylmethanamine Chemical compound CN(C)[SiH](N(C)C)N(C)C TWVSWDVJBJKDAA-UHFFFAOYSA-N 0.000 description 1
- VTKCTRBIIUPIQH-UHFFFAOYSA-N n-[dimethyl(phenyl)silyl]-1-phenylmethanamine Chemical compound C=1C=CC=CC=1[Si](C)(C)NCC1=CC=CC=C1 VTKCTRBIIUPIQH-UHFFFAOYSA-N 0.000 description 1
- CBLWNFBMHXOVNU-UHFFFAOYSA-N n-[ethyl(dimethyl)silyl]aniline Chemical compound CC[Si](C)(C)NC1=CC=CC=C1 CBLWNFBMHXOVNU-UHFFFAOYSA-N 0.000 description 1
- SZXMTLJJOIUCEV-UHFFFAOYSA-N n-triethylsilylaniline Chemical compound CC[Si](CC)(CC)NC1=CC=CC=C1 SZXMTLJJOIUCEV-UHFFFAOYSA-N 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000002390 rotary evaporation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- CQDJUAPLVNTUHG-UHFFFAOYSA-N tri(piperidin-1-yl)silane Chemical compound C1CCCCN1[SiH](N1CCCCC1)N1CCCCC1 CQDJUAPLVNTUHG-UHFFFAOYSA-N 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more CâSi linkages
- C07F7/18—Compounds having one or more CâSi linkages as well as one or more CâOâSi linkages
- C07F7/1896—Compounds having one or more Si-O-acyl linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/025—Silicon compounds without C-silicon linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
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Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ äžè¬åŒ HSiRnïŒO2CNRâ²Râ³ïŒ3-o ãäœãåŒäžïŒ²ã¯ççŽ æ°ïŒã12ãæãã眮æåºã
æããªãã飜åã®ã¢ã«ãã«ãŸãã¯ãžã¢ã«ãã«ã¢ã
ãåºã§ãããRâ²åã³Râ³ã¯ççŽ æ°ïŒã12ãæãã
眮æåºãæããªãã飜åã®ã¢ã«ãã«ãŸãã¯ã¢ãªãŒ
ã«çåæ°ŽçŽ åºããæã矀ãã倫ã ç¬ç«ã«éžã°ãã
ãã®ã§ãããïœã¯ïŒãïŒã®å€ã§ãããã ã®ååç©ããæã矀ããéžã°ããååç©ã ïŒ ïŒ²ïŒRâ²åã³Râ³ã倫ã ç¬ç«ã«ïŒãïŒåã®ççŽ
ååãå«ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ååç©ã
ãæã矀ããéžã°ããååç©ã ïŒ ïŒ²ïŒRâ²åã³Râ³ã倫ã ç¬ç«ã«ïŒãïŒåã®ã¢ã«
ãã«åºã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ååç©
ããæã矀ããéžã°ããååç©ã ïŒ ïœïŒïŒã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å
åç©ããæã矀ããéžã°ããååç©ã ïŒ ïœïŒïŒã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å
åç©ããæã矀ããéžã°ããååç©ã ïŒ ïœïŒïŒã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å
åç©ããæã矀ããéžã°ããååç©ã
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US430373 | 1982-09-30 | ||
| US06/430,373 US4400526A (en) | 1982-09-30 | 1982-09-30 | Hydrogen bearing silyl carbamates |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5970691A JPS5970691A (ja) | 1984-04-21 |
| JPH0121835B2 true JPH0121835B2 (ja) | 1989-04-24 |
Family
ID=23707280
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58106001A Granted JPS5970691A (ja) | 1982-09-30 | 1983-06-15 | æ°ŽçŽ å«æã·ãªã«ã«âãã¡âã |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4400526A (ja) |
| EP (1) | EP0112434B1 (ja) |
| JP (1) | JPS5970691A (ja) |
| AT (1) | ATE36535T1 (ja) |
| AU (1) | AU1578583A (ja) |
| BR (1) | BR8303156A (ja) |
| CA (1) | CA1200815A (ja) |
| DE (1) | DE3377716D1 (ja) |
| IN (1) | IN159324B (ja) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4496754A (en) * | 1982-12-28 | 1985-01-29 | Union Carbide Corporation | Silyl carbamates and synthesis thereof |
| US4631346A (en) * | 1985-03-04 | 1986-12-23 | General Electric Company | Silyl carbamates and their use in the preparation of bis (aminoalkyl) disiloxanes |
| US4837349A (en) * | 1985-09-19 | 1989-06-06 | Suntory Limited | Tertiary-butyldimethylsilyl carbamate derivative and process for producing the same |
| US5166243A (en) * | 1986-06-30 | 1992-11-24 | Union Carbide Chemicals & Plastics Technology Corporation | Polyorganosiloxane cross-linkers for RTV sealants |
| IT1229681B (it) * | 1989-04-27 | 1991-09-06 | Consiglio Nazionale Ricerche | N,n-dialchilcarbammati di silicio e di alluminio e loro prodotti di idrolisi. |
| US5198565A (en) * | 1989-04-27 | 1993-03-30 | Consiglio Nazionale Delle Ricerche | Silicon and aluminum N,N-dialkylcarbamates and their hydrolysis products and process for their preparation |
| US6204382B1 (en) * | 1994-08-05 | 2001-03-20 | Cytec Technology Corp. | Carboxylated amino-1,3,5-triazines, derivatives thereof and processes for preparing the same |
| DE102009045849B4 (de) * | 2009-10-20 | 2018-03-08 | Technische UniversitÀt Bergakademie Freiberg | Verfahren zur Herstellung von Oligo- und Polysiloxanen |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA902628A (en) * | 1972-06-13 | Berger Abe | Silylorganocarbamates and preparation | |
| US3284485A (en) * | 1963-12-20 | 1966-11-08 | Gen Electric | Organopolysiloxanes cured with organosilyl tris-carbamates |
| US3364175A (en) * | 1966-10-20 | 1968-01-16 | Gen Electric | Polydiorganosiloxanes cured with alkoxysilyl carbamates |
| US3517001A (en) * | 1967-09-20 | 1970-06-23 | Gen Electric | Nitrogen-containing organosilicon materials |
| US3715371A (en) * | 1971-11-16 | 1973-02-06 | Hercules Inc | Adhesion promoting agents |
| SU540869A1 (ru) * | 1975-04-01 | 1976-12-30 | ÐÑеЎпÑОÑÑОе Ð/Я Ð-4236 | СпПÑПб пПлÑÑеМО ÑОлОлПвÑÑ ÑÑОÑПв каÑбаЌОМПвПй кОÑлПÑÑ |
| US4064151A (en) * | 1976-05-17 | 1977-12-20 | United Carbide Corporation | Halosilyl carbamates |
| US4255348A (en) * | 1979-10-24 | 1981-03-10 | Union Carbide Corporation | Preparation of dimethylaminosilanes |
-
1982
- 1982-09-30 US US06/430,373 patent/US4400526A/en not_active Expired - Lifetime
-
1983
- 1983-04-29 CA CA000427061A patent/CA1200815A/en not_active Expired
- 1983-06-14 BR BR8303156A patent/BR8303156A/pt unknown
- 1983-06-15 JP JP58106001A patent/JPS5970691A/ja active Granted
- 1983-06-15 EP EP83105871A patent/EP0112434B1/en not_active Expired
- 1983-06-15 DE DE8383105871T patent/DE3377716D1/de not_active Expired
- 1983-06-15 AT AT83105871T patent/ATE36535T1/de not_active IP Right Cessation
- 1983-06-15 IN IN754/CAL/83A patent/IN159324B/en unknown
- 1983-06-15 AU AU15785/83A patent/AU1578583A/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| ATE36535T1 (de) | 1988-09-15 |
| EP0112434A2 (en) | 1984-07-04 |
| EP0112434A3 (en) | 1985-11-13 |
| EP0112434B1 (en) | 1988-08-17 |
| DE3377716D1 (en) | 1988-09-22 |
| AU1578583A (en) | 1984-04-05 |
| BR8303156A (pt) | 1984-06-12 |
| US4400526A (en) | 1983-08-23 |
| CA1200815A (en) | 1986-02-18 |
| JPS5970691A (ja) | 1984-04-21 |
| IN159324B (ja) | 1987-05-02 |
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