JPH01236243A - 表面変性され、ｕ．ｖ．安定化されたポリ塩化ビニル物品 - Google Patents

表面変性され、ｕ．ｖ．安定化されたポリ塩化ビニル物品

Info

Publication number: JPH01236243A
Authority: JP; Japan
Prior art keywords: article; sheet; solvent; stabilizer; polyvinyl chloride
Prior art date: 1987-10-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP26129688A

Other languages

English (en)

Japanese (ja)

Inventor

Joseph Silbermann

ジョセフ　シルバーマン

Michael Burchill

マイケル　バーチル

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

M&T Chemicals Inc

Original Assignee

M&T Chemicals Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-10-16

Filing date

1988-10-17

Publication date

1989-09-21

1988-10-17 Application filed by M&T Chemicals Inc filed Critical M&T Chemicals Inc

1989-09-21 Publication of JPH01236243A publication Critical patent/JPH01236243A/ja

Status Pending legal-status Critical Current

Links

229920000915 polyvinyl chloride Polymers 0.000 title claims description 30
239000004800 polyvinyl chloride Substances 0.000 title claims description 30
229920005989 resin Polymers 0.000 claims abstract description 44
239000011347 resin Substances 0.000 claims abstract description 44
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 43
239000002904 solvent Substances 0.000 claims abstract description 31
239000012963 UV stabilizer Substances 0.000 claims abstract description 7
239000012298 atmosphere Substances 0.000 claims abstract description 7
230000004048 modification Effects 0.000 claims abstract description 7
238000012986 modification Methods 0.000 claims abstract description 7
PNKUSGQVOMIXLU-UHFFFAOYSA-N Formamidine Chemical compound NC=N PNKUSGQVOMIXLU-UHFFFAOYSA-N 0.000 claims abstract description 3
150000001412 amines Chemical class 0.000 claims abstract description 3
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract description 3
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims abstract description 3
239000012965 benzophenone Substances 0.000 claims abstract description 3
239000012964 benzotriazole Substances 0.000 claims abstract description 3
YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 claims abstract description 3
229960001860 salicylate Drugs 0.000 claims abstract description 3
239000003381 stabilizer Substances 0.000 claims description 60
238000000034 method Methods 0.000 claims description 38
239000003960 organic solvent Substances 0.000 claims description 22
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical group ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 21
239000007788 liquid Substances 0.000 claims description 20
239000004408 titanium dioxide Substances 0.000 claims description 19
239000000049 pigment Substances 0.000 claims description 14
230000000087 stabilizing effect Effects 0.000 claims description 11
230000006641 stabilisation Effects 0.000 claims description 9
238000011105 stabilization Methods 0.000 claims description 9
239000000463 material Substances 0.000 claims description 7
-1 oxanilide organic compound Chemical class 0.000 claims description 6
238000004519 manufacturing process Methods 0.000 claims description 4
239000000126 substance Substances 0.000 claims description 4
230000005855 radiation Effects 0.000 claims description 3
238000011437 continuous method Methods 0.000 claims description 2
239000004611 light stabiliser Substances 0.000 claims description 2
238000002156 mixing Methods 0.000 claims description 2
239000002994 raw material Substances 0.000 claims description 2
239000012736 aqueous medium Substances 0.000 claims 5
229920000642 polymer Polymers 0.000 claims 2
125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims 1
UYTPUPDQBNUYGX-UHFFFAOYSA-N guanine Chemical compound O=C1NC(N)=NC2=C1N=CN2 UYTPUPDQBNUYGX-UHFFFAOYSA-N 0.000 claims 1
239000007864 aqueous solution Substances 0.000 abstract description 3
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 abstract description 2
FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical compound C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 abstract description 2
239000012860 organic pigment Substances 0.000 abstract 2
150000001875 compounds Chemical class 0.000 abstract 1
239000000243 solution Substances 0.000 description 28
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
238000011065 in-situ storage Methods 0.000 description 7
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 6
FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 6
229920003023 plastic Polymers 0.000 description 5
239000004033 plastic Substances 0.000 description 5
230000008569 process Effects 0.000 description 5
XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 4
238000000576 coating method Methods 0.000 description 4
239000000203 mixture Substances 0.000 description 4
238000012545 processing Methods 0.000 description 4
JLZIIHMTTRXXIN-UHFFFAOYSA-N 2-(2-hydroxy-4-methoxybenzoyl)benzoic acid Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1C(O)=O JLZIIHMTTRXXIN-UHFFFAOYSA-N 0.000 description 3
230000008859 change Effects 0.000 description 3
238000004381 surface treatment Methods 0.000 description 3
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 2
QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
230000002745 absorbent Effects 0.000 description 2
239000002250 absorbent Substances 0.000 description 2
YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
239000011449 brick Substances 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
238000010924 continuous production Methods 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
150000008282 halocarbons Chemical class 0.000 description 2
238000002347 injection Methods 0.000 description 2
239000007924 injection Substances 0.000 description 2
150000002576 ketones Chemical class 0.000 description 2
QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 2
238000001782 photodegradation Methods 0.000 description 2
239000007787 solid Substances 0.000 description 2
238000012360 testing method Methods 0.000 description 2
GXJIHRIICFQTSB-UHFFFAOYSA-N (2-hydroxy-4-methoxyphenyl)-(2-hydroxy-4-propoxyphenyl)methanone Chemical compound OC1=CC(OCCC)=CC=C1C(=O)C1=CC=C(OC)C=C1O GXJIHRIICFQTSB-UHFFFAOYSA-N 0.000 description 1
IASKXZZHVHIYTR-UHFFFAOYSA-N (4-ethoxy-2-hydroxyphenyl)-(4-methoxyphenyl)methanone Chemical compound OC1=CC(OCC)=CC=C1C(=O)C1=CC=C(OC)C=C1 IASKXZZHVHIYTR-UHFFFAOYSA-N 0.000 description 1
MXWFQZCOALURKY-UHFFFAOYSA-N (6-butyl-4-ethoxy-6-hydroxycyclohexa-2,4-dien-1-yl)-(4-butylphenyl)methanone Chemical compound C1=CC(CCCC)=CC=C1C(=O)C1C(CCCC)(O)C=C(OCC)C=C1 MXWFQZCOALURKY-UHFFFAOYSA-N 0.000 description 1
ZWVHTXAYIKBMEE-UHFFFAOYSA-N 2-hydroxyacetophenone Chemical compound OCC(=O)C1=CC=CC=C1 ZWVHTXAYIKBMEE-UHFFFAOYSA-N 0.000 description 1
235000017788 Cydonia oblonga Nutrition 0.000 description 1
XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
229920006385 Geon Polymers 0.000 description 1
239000004609 Impact Modifier Substances 0.000 description 1
239000006057 Non-nutritive feed additive Substances 0.000 description 1
SIZSOMFCKPTWDT-UHFFFAOYSA-N OC1=C(C(=O)C2=CC=CC(=C2)OC)C=CC(C1)(OC)OC Chemical compound OC1=C(C(=O)C2=CC=CC(=C2)OC)C=CC(C1)(OC)OC SIZSOMFCKPTWDT-UHFFFAOYSA-N 0.000 description 1
DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 1
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
FLPKSBDJMLUTEX-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) 2-butyl-2-[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]propanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)C(C(=O)OC1CC(C)(C)N(C)C(C)(C)C1)(CCCC)CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 FLPKSBDJMLUTEX-UHFFFAOYSA-N 0.000 description 1
XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 1
230000001680 brushing effect Effects 0.000 description 1
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
239000008116 calcium stearate Substances 0.000 description 1
235000013539 calcium stearate Nutrition 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
239000003086 colorant Substances 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007906 compression Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
238000010586 diagram Methods 0.000 description 1
238000007598 dipping method Methods 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
239000000975 dye Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
230000007717 exclusion Effects 0.000 description 1
239000010946 fine silver Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
230000009931 harmful effect Effects 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
MJVGBKJNTFCUJM-UHFFFAOYSA-N mexenone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=C(C)C=C1 MJVGBKJNTFCUJM-UHFFFAOYSA-N 0.000 description 1
229910000480 nickel oxide Inorganic materials 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
239000002985 plastic film Substances 0.000 description 1
239000002952 polymeric resin Substances 0.000 description 1
238000010020 roller printing Methods 0.000 description 1
239000012748 slip agent Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
239000000725 suspension Substances 0.000 description 1
229920003002 synthetic resin Polymers 0.000 description 1
NBRKLOOSMBRFMH-UHFFFAOYSA-N tert-butyl chloride Chemical compound CC(C)(C)Cl NBRKLOOSMBRFMH-UHFFFAOYSA-N 0.000 description 1
150000003557 thiazoles Chemical class 0.000 description 1
238000001721 transfer moulding Methods 0.000 description 1
238000007666 vacuum forming Methods 0.000 description 1
239000012463 white pigment Substances 0.000 description 1

Landscapes

Manufacture Of Macromolecular Shaped Articles (AREA)
Compositions Of Macromolecular Compounds (AREA)

JP26129688A 1987-10-16 1988-10-17 表面変性され、ｕ．ｖ．安定化されたポリ塩化ビニル物品 Pending JPH01236243A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US10955687A	1987-10-16	1987-10-16
US109556		1987-10-16

Publications (1)

Publication Number	Publication Date
JPH01236243A true JPH01236243A (ja)	1989-09-21

Family

ID=22328292

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP26129688A Pending JPH01236243A (ja)	1987-10-16	1988-10-17	表面変性され、ｕ．ｖ．安定化されたポリ塩化ビニル物品

Country Status (3)

Country	Link
JP (1)	JPH01236243A (da)
BR (1)	BR8805361A (da)
DK (1)	DK577488A (da)

1988
- 1988-10-17 BR BR8805361A patent/BR8805361A/pt not_active Application Discontinuation
- 1988-10-17 JP JP26129688A patent/JPH01236243A/ja active Pending
- 1988-10-17 DK DK577488A patent/DK577488A/da not_active Application Discontinuation

Also Published As

Publication number	Publication date
DK577488D0 (da)	1988-10-17
DK577488A (da)	1989-04-17
BR8805361A (pt)	1989-06-13

Publication	Publication Date	Title
US4770905A (en)	1988-09-13	Process for surface modification of polymer articles
DE2905449C2 (de)	1982-12-02	Überzugszusammensetzungen für Verpackungserzeugnisse
DE2422378A1 (de)	1975-11-06	Verfahren zur herstellung von kunststoffgiesslingen
US4126660A (en)	1978-11-21	Process for the manufacture of oriented sheets of thermoplastic resin which are protected against the action of ultraviolet rays
DE10022246A1 (de)	2001-11-15	Beschichtungsmittel für die Herstellung schwer benetzbarer Oberflächen
US5091213A (en)	1992-02-25	Process for surface modification of polymer articles
US5110626A (en)	1992-05-05	U.V. stabilized article
DE3400079A1 (de)	1985-07-11	Wasserspreitendes kunststoffmaterial, verfahren zu seiner herstellung u. verwendung als verglasungs- und bedachungsmaterial
EP0148443B1 (de)	1987-04-22	Weichgemachter Polyvinylalkohol
US5110634A (en)	1992-05-05	Process for making a surface modified polymer article
CA2060664A1 (en)	1991-10-17	Surface modified, u.v. stabilized, polyvinyl chloride article
US4865880A (en)	1989-09-12	Surface modified, U.V. stabilized, polyvinyl chloride article
US5185191A (en)	1993-02-09	Surface modified, U.V. stabilized, polyvinyl chloride article
JPH01236243A (ja)	1989-09-21	表面変性され、ｕ．ｖ．安定化されたポリ塩化ビニル物品
US4913082A (en)	1990-04-03	Process for surface modification of polymer articles
US4978576A (en)	1990-12-18	Surface modified, U.V. stabilized, polyvinyl chloride article
AU632990B2 (en)	1993-01-21	U.v. stabilized article and process for making same
US4792465A (en)	1988-12-20	Process for making surface modified U.V. stabilized PVC articles
US4925739A (en)	1990-05-15	Surface modified polymer article and process for making same
AU604369B2 (en)	1990-12-13	Uv stabilizer composition for surface modifying a pvc resinous sheet
US4919972A (en)	1990-04-24	Process for surface modification of polymer articles
US3847651A (en)	1974-11-12	Process for providing an opaque waterproof protective coating film on a substrate
WO1993001228A1 (en)	1993-01-21	U.v. stabilizer composition for surface modifying a pvc resinous sheet
EP0470690A2 (en)	1992-02-12	Modifying the surface of polymer articles
US3534130A (en)	1970-10-13	Method of surface treating shaped articles of thermoplastic synthetic resins