JPH01278511A - Unsaturated polyester resin composition for water-permeable coating - Google Patents
Unsaturated polyester resin composition for water-permeable coatingInfo
- Publication number
- JPH01278511A JPH01278511A JP10789688A JP10789688A JPH01278511A JP H01278511 A JPH01278511 A JP H01278511A JP 10789688 A JP10789688 A JP 10789688A JP 10789688 A JP10789688 A JP 10789688A JP H01278511 A JPH01278511 A JP H01278511A
- Authority
- JP
- Japan
- Prior art keywords
- unsaturated polyester
- polyester resin
- meth
- water
- resin composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920006337 unsaturated polyester resin Polymers 0.000 title claims abstract description 11
- 239000000203 mixture Substances 0.000 title claims abstract description 8
- 238000000576 coating method Methods 0.000 title claims description 9
- 239000011248 coating agent Substances 0.000 title claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 8
- 239000000178 monomer Substances 0.000 claims abstract description 8
- 229920006305 unsaturated polyester Polymers 0.000 claims abstract description 7
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims abstract 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 238000009833 condensation Methods 0.000 abstract description 7
- 230000005494 condensation Effects 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 5
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003054 catalyst Substances 0.000 abstract description 2
- -1 cyclohexane peroxide Chemical class 0.000 abstract 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
- 230000035699 permeability Effects 0.000 description 8
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000011342 resin composition Substances 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000001723 curing Methods 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 239000002023 wood Substances 0.000 description 4
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- UICXTANXZJJIBC-UHFFFAOYSA-N 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(OO)CCCCC1 UICXTANXZJJIBC-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000013022 formulation composition Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- ULYZAYCEDJDHCC-UHFFFAOYSA-N isopropyl chloride Chemical compound CC(C)Cl ULYZAYCEDJDHCC-UHFFFAOYSA-N 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004992 toluidines Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は透水性コーティング用不飽和ポリエステル樹脂
組成物に関し、さらに詳しくは各種化粧板等の木質基材
に特に好適なコーティング用樹脂組成物に関づ゛る。Detailed Description of the Invention (Industrial Application Field) The present invention relates to an unsaturated polyester resin composition for water-permeable coating, and more specifically to a coating resin composition particularly suitable for wood substrates such as various decorative laminates. It's related.
（従来の技術）
従来のコーティング用不飽和ポリエステル樹脂組成物と
しては、無水マレイン酸、フマル酸等の不飽和二塩基酸
（一般には無水フタル酸、アジピン酸などの飽和二塩基
酸を混合）とエチレングリ］−ル、ジエヂレングリコー
ル、プロピレングリコール等のグリコール類を反応縮合
させた物をスチレン等の重合性モノマーに溶解したもの
が代表的なものである。(Prior art) Conventional unsaturated polyester resin compositions for coating include unsaturated dibasic acids such as maleic anhydride and fumaric acid (generally mixed with saturated dibasic acids such as phthalic anhydride and adipic acid). A typical example is a product obtained by reaction condensation of glycols such as ethylene glycol, diethyl glycol, propylene glycol, etc., and dissolved in a polymerizable monomer such as styrene.
（発明が解決しようとする問題点）
前記した従来の樹脂組成物では、耐水着を重要視し、透
水性についてはほとんど考慮されていない。(Problems to be Solved by the Invention) In the conventional resin compositions described above, importance is placed on water resistance, and little consideration is given to water permeability.
そのため、結露しやすく、調湿能力についてもほとんど
望めない問題がある。Therefore, there is a problem that dew condensation easily occurs and the humidity control ability is hardly expected.
本発明はこのような事情に鑑みてなされたもので、その
目的どＪ−るところは、従来の塗膜機能を有しながら優
れた透水能力を有し且つ透明性（深み）が改善されてい
て、塗装ののり（付着）もほとんどの塗１１に対して良
好である透水性コーティング用樹脂組成物を提供しよう
とするものである。The present invention was made in view of these circumstances, and its purpose is to provide a film that has the conventional coating function, has excellent water permeability, and has improved transparency (depth). Therefore, the present invention aims to provide a water-permeable coating resin composition that has good adhesion (adhesion) to most coatings.
（問題点を解決するだめの手段）
本発明は斯る目的を達成するために、不飽和ポリエステ
ルにヒドロキシエチルメタクリレ−１−やヒトＩ］キシ
エチルアクリレー１〜等の水酸基含有（メタ）アクリレ
ートモノマーを、不飽和ポリエステル１００重量部に対
し水酸基含有（メタ）アクリレートモノマー４０〜１５
０重量部の範囲で配合してなるものである。(Another Means to Solve the Problems) In order to achieve the above object, the present invention provides unsaturated polyesters containing hydroxyl groups (meth) such as hydroxyethyl methacrylate-1-, human I]xyethyl acrylate 1-, etc. The acrylate monomer is 40 to 15 parts by weight of hydroxyl group-containing (meth)acrylate monomer per 100 parts by weight of unsaturated polyester.
The content is in the range of 0 parts by weight.
本発明において、不飽和ポリエステルは、無水マレイン
酸、無水フマル酸等の不飽和二塩基酸く一般にはフタル
酸、アジピン酸などの飽和二塩基酸を混合）とエヂレン
グリ］−ル、ジエヂレングリコール、プロピレングリ」
−ル等のグリ」−ル類を反応縮合さけた物が挙げられる
。In the present invention, the unsaturated polyester is a mixture of unsaturated dibasic acids such as maleic anhydride and fumaric anhydride (generally a mixture of saturated dibasic acids such as phthalic acid and adipic acid), ethylene glycol, and dielene glycol. , Propylene Gri”
Examples include those obtained by reaction condensation of glycols such as -ols.
そして、不飽和ポリニスデルに対する水酸基含有（メタ
）アクリレートモノマーの配合量の調節は、水酸基含有
（メタ）アクリレートモノマーの使用量が不飽和ポリエ
ステルに対して適正割合内で多い程、透水性が高くなる
。しかし、適正割合を超えて多量になると、樹脂組成物
が木質基材に浸透しや（−＜また硬化時の収縮も大きく
なるため、良好な光沢が１ｑられ４１くなる。また、透
水性が過剰に４ｒりすぎて、吸水時にふくれ等の耐水性
の欠如に阜く欠陥が生じやすくなる。The amount of the hydroxyl group-containing (meth)acrylate monomer blended into the unsaturated polynisder is adjusted so that the greater the amount of the hydroxyl group-containing (meth)acrylate monomer used within the appropriate ratio relative to the unsaturated polyester, the higher the water permeability will be. However, if the amount exceeds the appropriate ratio, the resin composition will penetrate into the wood base material (-< Also, shrinkage during curing will increase, resulting in a good gloss of 1q and 41%. Also, the water permeability will decrease. Excessive use of 4R tends to cause defects due to lack of water resistance such as blistering when water is absorbed.
一方、少量し過ぎては、目的と覆る透水性が十分でなく
なり、結露防止効果や調湿能力が発揮されない。また、
樹脂組成物の硬化性が低下覆る。On the other hand, if the amount is too small, the desired water permeability will not be sufficient, and the dew condensation prevention effect and humidity control ability will not be exhibited. Also,
The curability of the resin composition decreases.
又、硬化触媒或いは硬化促進剤としては、加熱硬化では
、シクロへキザノンパーＡキサイド、クメンハイドロパ
ーオキ４ノイド、ラウロイルバーオーキザイド、ｔｅｒ
ｔ−プチルパーベンゾエ−１−。In addition, as a curing catalyst or curing accelerator, in the case of heat curing, cyclohexanone peroxide, cumene hydroperoxynoid, lauroyl veroxide, ter
t-Butylperbenzoe-1-.
ジーｔ： ｅ ｒ ｔ−ブチルバーオーに１ナイト、ペ
ンゾイルバーオキリイド又は同ペース１〜．アゾヒスイ
ソブブＩ」二ｌ〜リル舌があり、これらに適量のフタル
酸ジメチル、フタル酸ジブデル、小スフニー１〜等で希
釈したものが用いられることもある。常温硬化では一般
に過酸化物−促進剤の系が含有され、よく使われるもの
としてはメチルエチルケトンバーオキザイド、ナフテン
酸コバル１〜又はオクヂル酸コバルト、過酸化ペンゾイ
ルージメヂルアニリン又はトルイジンなどがあるが、こ
れらの含有量は樹脂に対して、たとえばメチルエチルク
′トンパーオーキザイドでは１重量％、ナフテン酸コバ
ルトでは０．５重量％が望ましい。促進剤としてはこの
他にも金属石りん類や数種の有機化合物も効果が大きい
。G-t: ert-butyl baro for 1 night, penzoyl bar oxylide or the same pace for 1~. There are several types of azohisisobubu I, and these are sometimes used diluted with an appropriate amount of dimethyl phthalate, dibdel phthalate, small phthalate, etc. Cold curing generally involves peroxide-accelerator systems, commonly used include methyl ethyl ketone peroxide, cobalt naphthenate or cobalt ocdylate, penzoyl dimylaniline peroxide or toluidine. However, the content of these components is desirably 1% by weight for methyl ethyl chloride peroxidide and 0.5% by weight for cobalt naphthenate, based on the resin. In addition to these accelerators, metal phosphorus and several types of organic compounds are also highly effective.
又、使用目的に応じて、たとえば顔料、染料。Also, depending on the purpose of use, for example, pigments and dyes.
粘度調節剤、たれ防止剤、クロス及びレベリング材、沈
降防止剤９色分れ防止剤、顔料分散剤、皮張り防止剤、
充てん剤、補強剤、離型剤等の各種添加物が加えられる
。Viscosity modifier, anti-sag agent, cloth and leveling material, anti-settling agent 9 anti-color separation agent, pigment dispersant, anti-skinning agent,
Various additives such as fillers, reinforcing agents, and mold release agents are added.
（実施例） 以下本発明を実施例で詳細に説明する。(Example) The present invention will be explained in detail below with reference to Examples.
実施例エ
プロピレングリコール０．９５モル、ジエチレングリコ
ール０．２モル、無水フタル酸０．４モルおよび無水マ
レインｌ１ｉ０．６モルを反応縮合させた反応液 １
００重量部に２−ヒドロキシエチルメタクリレ−１〜１
００重量部を加えて不飽和ポリエステル樹脂液を作成し
た。Example Reaction liquid 1 in which 0.95 mol of epropylene glycol, 0.2 mol of diethylene glycol, 0.4 mol of phthalic anhydride and 0.6 mol of maleic anhydride 11 were reacted and condensed.
00 parts by weight of 2-hydroxyethyl methacrylate-1 to 1
00 parts by weight was added to prepare an unsaturated polyester resin liquid.
実施例ＩＩ
プロピレングリ−１−ル０．２王ル、トリメチー１１−
ルブ［ｊパンジアリルエーテル０２モル、ジエチレング
リコール０６モル、エチレングリコール０．２モルおよ
び無水マレイン酸１．０２モルを反応縮合させた反応液
１００重量部に２−ヒドロキシエチルメタクリレ−１・
５０重量部を加えて不飽和ポリエステル樹脂液を作成し
た。Example II Propylene glycol 0.2Kl, trimethyl 11-
2-hydroxyethyl methacrylate-1.
50 parts by weight was added to prepare an unsaturated polyester resin liquid.
実施例■
プロピレングリコール１３モル、ジエチレングリコール
０６モル、ヘラ１〜酸０．７モル、無水フタル酸０．３
モルおよび無水マレイン！ １．４モルを反応縮合さＶ
ｔこ反応液１００重量部に２−ヒドロキシエチルメタク
リレ−１・６６重量部を加えて不飽和ポリエステル樹脂
液を作成した。Example ■ 13 moles of propylene glycol, 06 moles of diethylene glycol, 0.7 moles of spatula 1 to acid, 0.3 moles of phthalic anhydride
Mol and anhydrous malein! 1.4 mol of V
1.66 parts by weight of 2-hydroxyethyl methacrylate was added to 100 parts by weight of the reaction solution to prepare an unsaturated polyester resin liquid.
次に、本発明との比較のために、−殻内な不飽和ポリエ
ステル樹脂を示す。Next, for comparison with the present invention, an in-shell unsaturated polyester resin is shown.
比較例
プロピレングリコール２モル、ジエチレングリコール２
モル、無水フタル酸２モルＪ）よび無水フタル酸２モル
を反応縮合さゼた反応液１００重量部にスチレン５０重
量部を加えて不飽和ポリニスデル樹脂を作成した。Comparative example 2 moles of propylene glycol, 2 moles of diethylene glycol
An unsaturated polynisder resin was prepared by adding 50 parts by weight of styrene to 100 parts by weight of a reaction solution obtained by reaction condensation of 2 moles of phthalic anhydride and 2 moles of phthalic anhydride.
前記実施例１〜■および比較例の配合組成を表１に示す
。Table 1 shows the formulation compositions of Examples 1 to ① and Comparative Example.
表１
次に本発明の透水性の不飽和ポリエステル樹脂と、比較
例の非透水性不飽和ポリエステル樹脂との透水性の差異
を示すため、ベニヤにツキ板を接着り、 ｌ；ものＡど
、ベニヤに化粧紙を接着したちのＢとに、夫々、実施例
■で得られた樹脂液Ｃと比較例の樹脂液りを塗布してＮ
ｆ！、硬化したもので比較した。Table 1 Next, in order to show the difference in water permeability between the water permeable unsaturated polyester resin of the present invention and the non-water permeable unsaturated polyester resin of the comparative example, a plywood board was glued to the veneer. Applying resin liquid C obtained in Example ① and resin liquid obtained in Comparative Example to B and B with decorative paper adhered to the veneer, respectively.
f! , compared with the hardened one.
その結果を表２に示す。The results are shown in Table 2.
表２
（注１） 透湿度（■／ｃｍ２ｈ ）はＪＩｓ、に６５
４９記載の方法に基づいて測定した。Table 2 (Note 1) Moisture permeability (■/cm2h) is JIs, 65
It was measured based on the method described in 49.
（注２） 密着性はレロハンアーブ剥離デス［〜により
評価した。(Note 2) Adhesion was evaluated by Rerohan Arb Peeling Test [~].
（発明の効果） したがって本発明によれば次の利点がある。(Effect of the invention) Therefore, the present invention has the following advantages.
■ 透水性を有しているから、結露を防止でき、特に台
所や風呂場等の湿度が高い場所にお（プる構成材のコー
ティング用に好適である。■ Because it has water permeability, it can prevent condensation and is particularly suitable for coating structural materials in high humidity areas such as kitchens and bathrooms.
■ 調湿能力を有しているので、特に化粧板等の木質基
材の湿度調整に有益である。■ Since it has a humidity control ability, it is particularly useful for controlling the humidity of wood substrates such as decorative boards.
■ 基材に対する含浸性および密着性が良好で木質基材
はもとより鉄板等の金属やガラス等の基材にも有用であ
る。- It has good impregnation and adhesion to substrates and is useful not only for wood substrates but also for metals such as iron plates and glass substrates.
■ 透明性（深み）が良好で、特に艶を求められる化粧
板等に有用である。■ It has good transparency (depth) and is especially useful for decorative boards that require gloss.
特許出願人 九州塗料工業株式会社
特許出願人 日本触媒化学工業株式会社代 理
人 早 川 改 名−９
＝Patent applicant Kyushu Paint Industry Co., Ltd. Patent applicant Nippon Shokubai Chemical Co., Ltd. Agent
Person Hayakawa name changed -9
=
Claims (1)
ートやヒドロキシエチルアクリレート等の水酸基含有（
メタ）アクリレートモノマーを、不飽和ポリエステル１
００重量部に対し水酸基含有（メタ）アクリレートモノ
マー４０〜１５０重量部の範囲で配合してなる透水性コ
ーティング用不飽和ポリエステル樹脂組成物。1. Unsaturated polyester containing hydroxyl groups such as hydroxyethyl methacrylate and hydroxyethyl acrylate (
meth)acrylate monomer, unsaturated polyester 1
1. An unsaturated polyester resin composition for water permeable coating, comprising 40 to 150 parts by weight of a hydroxyl group-containing (meth)acrylate monomer per 00 parts by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63107896A JPH0673949B2 (en) | 1988-04-28 | 1988-04-28 | Veneer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63107896A JPH0673949B2 (en) | 1988-04-28 | 1988-04-28 | Veneer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01278511A true JPH01278511A (en) | 1989-11-08 |
| JPH0673949B2 JPH0673949B2 (en) | 1994-09-21 |
Family
ID=14470817
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63107896A Expired - Lifetime JPH0673949B2 (en) | 1988-04-28 | 1988-04-28 | Veneer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0673949B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003183489A (en) * | 2001-12-21 | 2003-07-03 | Nippon Synthetic Chem Ind Co Ltd:The | Unsaturated polyester resin composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4921428A (en) * | 1972-06-19 | 1974-02-25 | ||
| JPS56120719A (en) * | 1980-02-29 | 1981-09-22 | Dainippon Ink & Chem Inc | Resin composition |
| JPS58154765A (en) * | 1982-02-05 | 1983-09-14 | Daicel Chem Ind Ltd | Photo-curing resin composition |
-
1988
- 1988-04-28 JP JP63107896A patent/JPH0673949B2/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4921428A (en) * | 1972-06-19 | 1974-02-25 | ||
| JPS56120719A (en) * | 1980-02-29 | 1981-09-22 | Dainippon Ink & Chem Inc | Resin composition |
| JPS58154765A (en) * | 1982-02-05 | 1983-09-14 | Daicel Chem Ind Ltd | Photo-curing resin composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003183489A (en) * | 2001-12-21 | 2003-07-03 | Nippon Synthetic Chem Ind Co Ltd:The | Unsaturated polyester resin composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0673949B2 (en) | 1994-09-21 |
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