JPH0143018B2 - - Google Patents
Info
- Publication number
- JPH0143018B2 JPH0143018B2 JP474384A JP474384A JPH0143018B2 JP H0143018 B2 JPH0143018 B2 JP H0143018B2 JP 474384 A JP474384 A JP 474384A JP 474384 A JP474384 A JP 474384A JP H0143018 B2 JPH0143018 B2 JP H0143018B2
- Authority
- JP
- Japan
- Prior art keywords
- strength
- steel
- less
- present
- austenitic stainless
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Prevention Of Electric Corrosion (AREA)
- Heat Treatment Of Steel (AREA)
- Hydraulic Turbines (AREA)
Description
本発明は、海水ならびに酸性河川等の厳しい腐
食性環境下で使用される鋳鋼品、例えばランナ
ー、プロペラ、バルブ等の材料として用いられる
高強度、高疲労強度を有するオーステナイトステ
ンレス鋳鋼に関する。
近年、省資源、省エネルギーの要求により、発
電プラントの使用条件が苛酷化しており、また従
来用いられなかつたような腐食条件の厳しい環境
における使用も余儀無くされている。
従来、上記腐食性を有する環境下ではSCS14等
のオーステナイトステンレス鋳鋼が適用されてい
たが、これらは強度水準が低く、また腐食疲労強
度も満足できるものではなかつた。
本発明の目的は、従来のオーステナイトステン
レス鋳鋼、すなわちSCS14の基本的化学成分にお
いて、Ni含有量を減少させNを添加することに
より、高強度と高腐食疲労度を有する、海水なら
びに酸性河川など厳しい腐食環境下で使用するラ
ンナー、プロペラ、バルブなどに使用できるオー
ステナイトステンレス鋳鋼を提供するにある。
本発明のオーステナイトステンレス鋳鋼は、重
量%で、C0.12%以下、Si1.0〜1.5%、Mn1.5%以
下、Cr17〜20%、Ni8〜11%、Mo1〜5%、
N0.05〜0.15%、残部Feおよび不可避的不純物よ
りなる。
つぎに本発明の各成分の限定理由について説明
する。Cは強度水準を高めるのに不可欠の元素で
あるが炭化物を形成し、耐食性を著しく害するの
で強度と耐食性を勘案して0.12%以下に限定し
た。
Siは有効な脱酸剤であり、通常の製鋼過程にお
いて必然的に含有され、また強度確保の点から1
%以上必要であるが、1.5%以上含有するとシグ
マ相を析出させ脆化する傾向にあるので1.5%以
下とする。
MnはSi同様脱酸剤として、また耐酸化性を向
上させるために有効である。しかしながらその含
有量を増すと逆に強度が低下するので1.5%以下
に限定した。
Crは腐食環境下で不働態化作用を有し、ステ
ンレス鋼としての機能を発揮させるのに不可欠な
元素であり、また17%よりも少ない場合は適正な
強度が得られない、しかしながら20%を超えると
脆化が顕著となるから17〜20%に限定した。
Niは耐食性を維持するためと基地に固溶して
固溶強化すると共に靭性を増す。またオーステナ
イト相の安定化には8%以上必要であるが、強度
には逆効果を与えるから11%を上限とした。
MoはCrとの共存によつて局部腐食に対する耐
食性を著しく向上させる元素であるが1%以下で
は不十分であり、また5%以上では効果が飽和す
るとともに脆化するので1〜5%に限定した。
Nは基地を強化するのみならず靭延性を損わず
に強度を確保するのに有効な元素であり、その効
果は0.05%以上で現われる。しかし0.15%を超え
ると延靭性を阻害するから0.05〜0.15%に限定し
た。
つぎに本発明の実施例を従来鋼と比較して説明
する。
第1表は本発明の実施例の化学成分を従来鋼の
それと比較して示す。第2表は第1表の各鋼の機
械的性質を示す。第2表より明らかなように、従
来鋼の引張強さは42.2Kg/mm2、45.5Kg/mm2である
のに対し本発明鋼のそれは55Kg/mm2以上であり大
巾に優れており、延性および靭性(シヤルピー衝
撃値)は両者共略同等であり、海水腐食疲労強度
は本発明鋼は大巾に優れている。
The present invention relates to an austenitic stainless steel cast steel having high strength and high fatigue strength and used as a material for cast steel products such as runners, propellers, valves, etc., which are used in severe corrosive environments such as seawater and acidic rivers. In recent years, due to demands for resource and energy conservation, the conditions under which power plants are used have become more severe, and they are also forced to be used in environments with severe corrosive conditions that have not been used in the past. Conventionally, austenitic stainless cast steels such as SCS14 have been used in the above-mentioned corrosive environments, but these have low strength levels and do not have satisfactory corrosion fatigue strength. The purpose of the present invention is to reduce the Ni content and add N to the basic chemical composition of conventional austenitic stainless steel cast steel, namely SCS14, to achieve high strength and high corrosion fatigue. Our goal is to provide austenitic stainless cast steel that can be used in runners, propellers, valves, etc. used in corrosive environments. The austenitic stainless steel cast steel of the present invention includes, in weight percent, C0.12% or less, Si1.0-1.5%, Mn1.5% or less, Cr17-20%, Ni8-11%, Mo1-5%,
Consists of 0.05-0.15% N, the balance Fe and unavoidable impurities. Next, the reasons for limiting each component of the present invention will be explained. C is an essential element for increasing the strength level, but it forms carbides and significantly impairs corrosion resistance, so the content was limited to 0.12% or less in consideration of strength and corrosion resistance. Si is an effective deoxidizing agent and is inevitably included in the normal steelmaking process.
% or more, but if it is contained more than 1.5%, the sigma phase tends to precipitate and become brittle, so the content should be 1.5% or less. Like Si, Mn is effective as a deoxidizing agent and for improving oxidation resistance. However, increasing its content would result in a decrease in strength, so it was limited to 1.5% or less. Cr has a passivation effect in a corrosive environment and is an essential element for achieving the functionality of stainless steel.If it is less than 17%, appropriate strength cannot be obtained. If it exceeds, embrittlement becomes noticeable, so it was limited to 17 to 20%. Ni is dissolved in solid solution in the matrix to maintain corrosion resistance, strengthen it as a solid solution, and increase toughness. Further, although 8% or more is necessary to stabilize the austenite phase, it has the opposite effect on strength, so the upper limit was set at 11%. Mo is an element that significantly improves corrosion resistance against local corrosion when coexisting with Cr, but if it is less than 1%, it is insufficient, and if it is more than 5%, the effect will be saturated and it will become brittle, so it is limited to 1 to 5%. did. N is an effective element that not only strengthens the matrix but also secures strength without impairing toughness and ductility, and its effect appears at 0.05% or more. However, if it exceeds 0.15%, the ductility is inhibited, so it is limited to 0.05 to 0.15%. Next, examples of the present invention will be explained in comparison with conventional steel. Table 1 shows the chemical composition of the examples of the present invention in comparison with that of conventional steel. Table 2 shows the mechanical properties of each steel in Table 1. As is clear from Table 2, the tensile strength of the conventional steel is 42.2Kg/mm 2 and 45.5Kg/mm 2 , whereas that of the steel of the present invention is 55Kg/mm 2 or more, which is significantly superior. , ductility and toughness (Sharpey impact value) are approximately the same, and the steel of the present invention is significantly superior in seawater corrosion fatigue strength.
【表】【table】
【表】
以上説明したように、本発明鋼は従来鋼より、
強度および腐食疲労強度において大巾に優れ、海
水ならびに酸性河川等の厳しい腐食性環境下で使
用されるランナー、プロペラ、バルブ等の材料と
して極めて優れた性能を発揮する。[Table] As explained above, the steel of the present invention has a higher
It has excellent strength and corrosion fatigue strength, and exhibits extremely excellent performance as a material for runners, propellers, valves, etc. used in harsh corrosive environments such as seawater and acidic rivers.
Claims (1)
%以下、Cr17〜20%、Ni8〜11%、Mo1〜5%、
N0.05〜0.15%、残部Feおよび不可避的不純物か
ら成ることを特徴とする高強度、高腐食疲労強度
を有するオーステナイトステンレス鋳鋼。1 Weight% C0.12% or less, Si1.0-1.5%, Mn1.5
% or less, Cr17~20%, Ni8~11%, Mo1~5%,
Austenitic stainless steel cast steel with high strength and high corrosion fatigue strength, characterized by consisting of 0.05~0.15% N, the balance Fe and unavoidable impurities.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP474384A JPS60149747A (en) | 1984-01-17 | 1984-01-17 | Austenitic stainless cast steel having high-strength and high-corrosion fatigue strength |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP474384A JPS60149747A (en) | 1984-01-17 | 1984-01-17 | Austenitic stainless cast steel having high-strength and high-corrosion fatigue strength |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60149747A JPS60149747A (en) | 1985-08-07 |
| JPH0143018B2 true JPH0143018B2 (en) | 1989-09-18 |
Family
ID=11592390
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP474384A Granted JPS60149747A (en) | 1984-01-17 | 1984-01-17 | Austenitic stainless cast steel having high-strength and high-corrosion fatigue strength |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60149747A (en) |
-
1984
- 1984-01-17 JP JP474384A patent/JPS60149747A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60149747A (en) | 1985-08-07 |
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