JPH01500108A - アルカリ土類金属アルミニウム含有スピネル組成物の製造方法 - Google Patents

アルカリ土類金属アルミニウム含有スピネル組成物の製造方法

Info

Publication number: JPH01500108A
Authority: JP; Japan
Prior art keywords: composition; gas; spinel; sulfur; reducing
Prior art date: 1986-04-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP62502348A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0566889B2 (de

Inventor

バッタチャリヤ，アラカナンダ

コーミア，ウィリアム　エドワード，ジュニア

ウォルターマン，ジェラルド　マーティン

Original Assignee

カタリスティクス　インタナショナル，インコーポレイテッド

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-04-07

Filing date

1987-04-07

Publication date

1989-01-19

1987-04-07 Application filed by カタリスティクス　インタナショナル，インコーポレイテッド filed Critical カタリスティクス　インタナショナル，インコーポレイテッド

1989-01-19 Publication of JPH01500108A publication Critical patent/JPH01500108A/ja

1993-09-22 Publication of JPH0566889B2 publication Critical patent/JPH0566889B2/ja

Status Granted legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims description 273
229910052596 spinel Inorganic materials 0.000 title claims description 131
239000011029 spinel Substances 0.000 title claims description 131
229910052782 aluminium Inorganic materials 0.000 title claims description 50
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims description 49
229910052784 alkaline earth metal Inorganic materials 0.000 title claims description 42
150000001342 alkaline earth metals Chemical class 0.000 title claims description 38
238000004519 manufacturing process Methods 0.000 title claims description 7
MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 133
238000000034 method Methods 0.000 claims description 133
239000007789 gas Substances 0.000 claims description 93
229910052751 metal Inorganic materials 0.000 claims description 71
239000002184 metal Substances 0.000 claims description 71
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 59
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 claims description 45
239000000126 substance Substances 0.000 claims description 44
229910052720 vanadium Inorganic materials 0.000 claims description 42
230000002378 acidificating effect Effects 0.000 claims description 40
230000003647 oxidation Effects 0.000 claims description 40
238000007254 oxidation reaction Methods 0.000 claims description 40
TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 claims description 38
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 38
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 36
239000008139 complexing agent Substances 0.000 claims description 35
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 34
229910052717 sulfur Inorganic materials 0.000 claims description 34
239000011593 sulfur Substances 0.000 claims description 34
239000000395 magnesium oxide Substances 0.000 claims description 32
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 30
150000003682 vanadium compounds Chemical class 0.000 claims description 24
MUBZPKHOEPUJKR-UHFFFAOYSA-N oxalic acid group Chemical group C(C(=O)O)(=O)O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 21
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 20
239000011777 magnesium Substances 0.000 claims description 19
150000002736 metal compounds Chemical class 0.000 claims description 19
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims description 18
239000002253 acid Substances 0.000 claims description 17
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 17
229910052749 magnesium Inorganic materials 0.000 claims description 17
230000009467 reduction Effects 0.000 claims description 17
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 16
229910052684 Cerium Inorganic materials 0.000 claims description 15
GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical group [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 15
229910052757 nitrogen Inorganic materials 0.000 claims description 15
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 10
125000004432 carbon atom Chemical group C* 0.000 claims description 10
235000019253 formic acid Nutrition 0.000 claims description 10
239000002243 precursor Substances 0.000 claims description 10
POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 claims description 9
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 9
238000002156 mixing Methods 0.000 claims description 9
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 8
229910052737 gold Inorganic materials 0.000 claims description 8
239000010931 gold Substances 0.000 claims description 8
230000001590 oxidative effect Effects 0.000 claims description 8
150000001875 compounds Chemical class 0.000 claims description 7
235000006408 oxalic acid Nutrition 0.000 claims description 7
150000003839 salts Chemical class 0.000 claims description 7
150000007513 acids Chemical class 0.000 claims description 5
-1 alkaline earth metal sulfate Chemical class 0.000 claims description 5
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 5
229910052761 rare earth metal Inorganic materials 0.000 claims description 5
150000002910 rare earth metals Chemical group 0.000 claims description 5
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
229910052744 lithium Inorganic materials 0.000 claims description 2
235000010755 mineral Nutrition 0.000 claims description 2
239000011707 mineral Substances 0.000 claims description 2
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims 24
229910052943 magnesium sulfate Inorganic materials 0.000 claims 12
235000019341 magnesium sulphate Nutrition 0.000 claims 12
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 4
125000001142 dicarboxylic acid group Chemical group 0.000 claims 4
150000002429 hydrazines Chemical class 0.000 claims 4
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 4
GGWBHVILAJZWKJ-KJEVSKRMSA-N ranitidine hydrochloride Chemical compound [H+].[Cl-].[O-][N+](=O)\C=C(/NC)NCCSCC1=CC=C(CN(C)C)O1 GGWBHVILAJZWKJ-KJEVSKRMSA-N 0.000 claims 4
150000002909 rare earth metal compounds Chemical class 0.000 claims 4
150000003681 vanadium Chemical class 0.000 claims 4
150000001768 cations Chemical class 0.000 claims 2
150000001785 cerium compounds Chemical class 0.000 claims 2
235000010210 aluminium Nutrition 0.000 description 43
239000002245 particle Substances 0.000 description 43
239000000047 product Substances 0.000 description 35
239000003054 catalyst Substances 0.000 description 33
229930195733 hydrocarbon Natural products 0.000 description 33
150000002430 hydrocarbons Chemical class 0.000 description 33
239000004215 Carbon black (E152) Substances 0.000 description 32
239000007787 solid Substances 0.000 description 30
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 25
239000000463 material Substances 0.000 description 20
238000006243 chemical reaction Methods 0.000 description 19
239000007864 aqueous solution Substances 0.000 description 14
239000002002 slurry Substances 0.000 description 14
229910052566 spinel group Inorganic materials 0.000 description 13
238000005336 cracking Methods 0.000 description 12
GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 12
238000011069 regeneration method Methods 0.000 description 12
239000003570 air Substances 0.000 description 11
238000002485 combustion reaction Methods 0.000 description 11
230000008929 regeneration Effects 0.000 description 11
239000000243 solution Substances 0.000 description 11
238000001035 drying Methods 0.000 description 10
238000002441 X-ray diffraction Methods 0.000 description 9
239000003921 oil Substances 0.000 description 9
GEVPUGOOGXGPIO-UHFFFAOYSA-N oxalic acid;dihydrate Chemical compound O.O.OC(=O)C(O)=O GEVPUGOOGXGPIO-UHFFFAOYSA-N 0.000 description 9
238000002360 preparation method Methods 0.000 description 9
239000007921 spray Substances 0.000 description 9
238000004523 catalytic cracking Methods 0.000 description 8
239000008187 granular material Substances 0.000 description 8
230000000704 physical effect Effects 0.000 description 8
239000000843 powder Substances 0.000 description 8
229910052815 sulfur oxide Inorganic materials 0.000 description 8
239000003795 chemical substances by application Substances 0.000 description 7
239000008186 active pharmaceutical agent Substances 0.000 description 6
VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 6
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
239000001301 oxygen Substances 0.000 description 6
229910052760 oxygen Inorganic materials 0.000 description 6
230000008569 process Effects 0.000 description 6
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
230000015572 biosynthetic process Effects 0.000 description 5
235000013339 cereals Nutrition 0.000 description 5
230000000694 effects Effects 0.000 description 5
230000006872 improvement Effects 0.000 description 5
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
239000003513 alkali Substances 0.000 description 4
239000002585 base Substances 0.000 description 4
238000010304 firing Methods 0.000 description 4
238000004231 fluid catalytic cracking Methods 0.000 description 4
239000001257 hydrogen Substances 0.000 description 4
229910052739 hydrogen Inorganic materials 0.000 description 4
238000005470 impregnation Methods 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
238000010521 absorption reaction Methods 0.000 description 3
238000009835 boiling Methods 0.000 description 3
238000001354 calcination Methods 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
239000003575 carbonaceous material Substances 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
239000003245 coal Substances 0.000 description 3
238000007796 conventional method Methods 0.000 description 3
238000000354 decomposition reaction Methods 0.000 description 3
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
239000004615 ingredient Substances 0.000 description 3
239000002609 medium Substances 0.000 description 3
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VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
239000003208 petroleum Substances 0.000 description 3
239000002994 raw material Substances 0.000 description 3
238000000926 separation method Methods 0.000 description 3
238000001694 spray drying Methods 0.000 description 3
150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
229910052718 tin Inorganic materials 0.000 description 3
239000011135 tin Substances 0.000 description 3
241000972773 Aulopiformes Species 0.000 description 2
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
229910021550 Vanadium Chloride Inorganic materials 0.000 description 2
229910021536 Zeolite Inorganic materials 0.000 description 2
150000001242 acetic acid derivatives Chemical class 0.000 description 2
230000002411 adverse Effects 0.000 description 2
229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 2
229910052787 antimony Inorganic materials 0.000 description 2
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
239000002956 ash Substances 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
230000008901 benefit Effects 0.000 description 2
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
239000001569 carbon dioxide Substances 0.000 description 2
229910002092 carbon dioxide Inorganic materials 0.000 description 2
HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 2
229910017052 cobalt Inorganic materials 0.000 description 2
239000010941 cobalt Substances 0.000 description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
150000001991 dicarboxylic acids Chemical class 0.000 description 2
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
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150000004820 halides Chemical class 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
239000007788 liquid Substances 0.000 description 2
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
239000004005 microsphere Substances 0.000 description 2
238000000465 moulding Methods 0.000 description 2
DUWWHGPELOTTOE-UHFFFAOYSA-N n-(5-chloro-2,4-dimethoxyphenyl)-3-oxobutanamide Chemical compound COC1=CC(OC)=C(NC(=O)CC(C)=O)C=C1Cl DUWWHGPELOTTOE-UHFFFAOYSA-N 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
150000002823 nitrates Chemical class 0.000 description 2
RPESBQCJGHJMTK-UHFFFAOYSA-I pentachlorovanadium Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[V+5] RPESBQCJGHJMTK-UHFFFAOYSA-I 0.000 description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
238000012545 processing Methods 0.000 description 2
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241000894007 species Species 0.000 description 2
210000002784 stomach Anatomy 0.000 description 2
239000010457 zeolite Substances 0.000 description 2
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
OSFNTBWKQRIPCR-UHFFFAOYSA-N 7,9-dihydro-3h-purine-2,6,8-trione;dihydrate Chemical compound O.O.N1C(=O)NC(=O)C2=C1NC(=O)N2 OSFNTBWKQRIPCR-UHFFFAOYSA-N 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
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229910052732 germanium Inorganic materials 0.000 description 1
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
230000036571 hydration Effects 0.000 description 1
238000006703 hydration reaction Methods 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
150000002680 magnesium Chemical class 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
239000011259 mixed solution Substances 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
229910052758 niobium Inorganic materials 0.000 description 1
239000010955 niobium Substances 0.000 description 1
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
150000003891 oxalate salts Chemical class 0.000 description 1
BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
125000004430 oxygen atom Chemical group O* 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
239000006069 physical mixture Substances 0.000 description 1
231100000719 pollutant Toxicity 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
239000001294 propane Substances 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
230000004044 response Effects 0.000 description 1
239000004576 sand Substances 0.000 description 1
230000001568 sexual effect Effects 0.000 description 1
230000035939 shock Effects 0.000 description 1
238000007873 sieving Methods 0.000 description 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
229910001388 sodium aluminate Inorganic materials 0.000 description 1
239000012798 spherical particle Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
150000004763 sulfides Chemical class 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
150000003463 sulfur Chemical class 0.000 description 1
229910052715 tantalum Inorganic materials 0.000 description 1
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
239000011269 tar Substances 0.000 description 1
238000012360 testing method Methods 0.000 description 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
230000009466 transformation Effects 0.000 description 1
230000032258 transport Effects 0.000 description 1
239000002699 waste material Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/16—Preparation of alkaline-earth metal aluminates or magnesium aluminates; Aluminium oxide or hydroxide therefrom
- C01F7/162—Magnesium aluminates
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/005—Spinels
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/21—Attrition-index or crushing strength of granulates
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
- Y10S502/524—Spinel

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Materials Engineering (AREA)
Oil, Petroleum & Natural Gas (AREA)
Geology (AREA)
Life Sciences & Earth Sciences (AREA)
General Chemical & Material Sciences (AREA)
Inorganic Chemistry (AREA)
Catalysts (AREA)
Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Treating Waste Gases (AREA)
Exhaust Gas Treatment By Means Of Catalyst (AREA)
Compositions Of Oxide Ceramics (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)
Inorganic Compounds Of Heavy Metals (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)

JP62502348A 1986-04-07 1987-04-07 アルカリ土類金属アルミニウム含有スピネル組成物の製造方法 Granted JPH01500108A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US06/848,955 US4728635A (en)	1986-04-07	1986-04-07	Alkaline earth metal spinels and processes for making
US848,955		1986-04-07

Publications (2)

Publication Number	Publication Date
JPH01500108A true JPH01500108A (ja)	1989-01-19
JPH0566889B2 JPH0566889B2 (de)	1993-09-22

Family

ID=25304714

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP62502348A Granted JPH01500108A (ja)	1986-04-07	1987-04-07	アルカリ土類金属アルミニウム含有スピネル組成物の製造方法

Country Status (9)

Country	Link
US (1)	US4728635A (de)
EP (1)	EP0263872B1 (de)
JP (1)	JPH01500108A (de)
AT (1)	ATE69738T1 (de)
AU (1)	AU592867B2 (de)
BR (1)	BR8707260A (de)
CA (1)	CA1314276C (de)
DE (1)	DE3774828D1 (de)
WO (1)	WO1987006158A1 (de)

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US6129834A (en)	1995-05-05	2000-10-10	W. R. Grace & Co. -Conn.	NOx reduction compositions for use in FCC processes
US6165933A (en)	1995-05-05	2000-12-26	W. R. Grace & Co.-Conn.	Reduced NOx combustion promoter for use in FCC processes
US6800586B2 (en) *	2001-11-23	2004-10-05	Engelhard Corporation	NOx reduction composition for use in FCC processes
US20050205465A1 (en) *	2002-02-22	2005-09-22	Peters Alan W	NOx reduction compositions for use in FCC processes
US20040086442A1 (en) *	2002-08-13	2004-05-06	Intercat, Inc.	Flue gas treatments to reduce NOx and CO emissions
US7045056B2 (en) *	2002-10-10	2006-05-16	Engelhard Corporation	CO oxidation promoters for use in FCC processes
US20040074809A1 (en) *	2002-10-21	2004-04-22	George Yaluris	Reduction of gas phase reduced nitrogen species in partial burn FCC processes
WO2005003034A1 (es) *	2003-07-07	2005-01-13	Instituto Mexicano Del Petróleo	Obtención de óxidos multimetálicos derivados de compuestos del tipo hidrotalcita.
US20050100493A1 (en) *	2003-11-06	2005-05-12	George Yaluris	Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking
US20050100494A1 (en) *	2003-11-06	2005-05-12	George Yaluris	Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking
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US7304011B2 (en) *	2004-04-15	2007-12-04	W.R. Grace & Co. -Conn.	Compositions and processes for reducing NOx emissions during fluid catalytic cracking
US20050232839A1 (en)	2004-04-15	2005-10-20	George Yaluris	Compositions and processes for reducing NOx emissions during fluid catalytic cracking
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CN100425339C (zh) *	2004-07-14	2008-10-15	中国石油化工股份有限公司	一种硫转移催化剂及其制备方法
US20060040823A1 (en) *	2004-08-18	2006-02-23	Stockwell David M	Catalyst for NOx and/or SOx control
CN102497929B (zh) *	2005-03-24	2014-10-08	格雷斯公司	控制FCCU中NOx排放物的方法
BRPI0610326B1 (pt) *	2005-04-27	2015-07-21	W. R. Grace & Co.- Conn	Composições e processos para reduzir emissões de nox durante o craqueamento catalítico de fluído.
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1986
- 1986-04-07 US US06/848,955 patent/US4728635A/en not_active Expired - Lifetime
1987
- 1987-04-07 CA CA000534084A patent/CA1314276C/en not_active Expired - Fee Related
- 1987-04-07 WO PCT/US1987/000751 patent/WO1987006158A1/en not_active Ceased
- 1987-04-07 JP JP62502348A patent/JPH01500108A/ja active Granted
- 1987-04-07 AU AU72837/87A patent/AU592867B2/en not_active Expired
- 1987-04-07 DE DE8787903036T patent/DE3774828D1/de not_active Expired - Lifetime
- 1987-04-07 AT AT87903036T patent/ATE69738T1/de not_active IP Right Cessation
- 1987-04-07 EP EP87903036A patent/EP0263872B1/de not_active Expired
- 1987-04-07 BR BR8707260A patent/BR8707260A/pt not_active IP Right Cessation

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Also Published As

Publication number	Publication date
DE3774828D1 (de)	1992-01-09
EP0263872A1 (de)	1988-04-20
BR8707260A (pt)	1988-04-19
AU592867B2 (en)	1990-01-25
AU7283787A (en)	1987-11-09
WO1987006158A1 (en)	1987-10-22
CA1314276C (en)	1993-03-09
JPH0566889B2 (de)	1993-09-22
ATE69738T1 (de)	1991-12-15
EP0263872B1 (de)	1991-11-27
US4728635A (en)	1988-03-01

Legal Events

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2004-10-12	R250	Receipt of annual fees	Free format text: JAPANESE INTERMEDIATE CODE: R250
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2007-06-20	FPAY	Renewal fee payment (event date is renewal date of database)	Free format text: PAYMENT UNTIL: 20070922 Year of fee payment: 14

Publication	Publication Date	Title
JPH01500108A (ja)	1989-01-19	アルカリ土類金属アルミニウム含有スピネル組成物の製造方法
US4830840A (en)	1989-05-16	Process for removing sulfur oxide and nitrogen oxide
US4904627A (en)	1990-02-27	Alkaline earth metal spinel/kaolin clays and processes for making
JPH01236297A (ja)	1989-09-21	硫黄酸化物の放出を減ずる方法及びそれに有用な組成物
US4472267A (en)	1984-09-18	Catalyst and process for conversion of hydrocarbons
US4469589A (en)	1984-09-04	Catalyst and process for conversion of hydrocarbons
US4471070A (en)	1984-09-11	Preparative process for alkaline earth metal, aluminum-containing spinels
US4957892A (en)	1990-09-18	Process for combusting solid sulfur containing material
US4758418A (en)	1988-07-19	Process for combusting solid sulfur-containing material
US4495304A (en)	1985-01-22	Catalyst for conversion of hydrocarbons
US4522937A (en)	1985-06-11	Preparative process for alkaline earth metal, aluminum-containing spinels
JPH0729054B2 (ja)	1995-04-05	金属含有スピネル組成物及びその使用方法
US4495305A (en)	1985-01-22	Catalyst for conversion of hydrocarbons
US4476245A (en)	1984-10-09	Preparative process for alkaline earth metal, aluminum-containing spinels
US4642178A (en)	1987-02-10	Process for conversion of hydrocarbons
EP0045170B1 (de)	1988-02-03	Verfahren zum Verbrennen schwefelhaltigen Materials, Verfahren zur Kohlenwasserstoffumwandlung und für diese Verfahren geeignete katalytische Zusammensetzung
US20160082424A1 (en)	2016-03-24	Multimetallic Anionic Clays and Derived Products for SOx Removal in the Fluid Catalytic Cracking Process
EP0110702B1 (de)	1988-08-10	Verfahren zur Herstellung von Erdalkalimetall und aluminiumhaltigen Spinellen
JPS62502968A (ja)	1987-11-26	改良されたアルカリ土類金属、アルミニウム含有スピネル組成物及び該組成物を使用する方法
JPS5847087A (ja)	1983-03-18	炭化水素の転換方法
CA1162522A (en)	1984-02-21	Catalyst and process for conversion of hydrocarbons