JPH0158945B2 - - Google Patents
Info
- Publication number
- JPH0158945B2 JPH0158945B2 JP56168735A JP16873581A JPH0158945B2 JP H0158945 B2 JPH0158945 B2 JP H0158945B2 JP 56168735 A JP56168735 A JP 56168735A JP 16873581 A JP16873581 A JP 16873581A JP H0158945 B2 JPH0158945 B2 JP H0158945B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- xylose
- maltose
- coloring
- color
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 claims description 34
- 235000013305 food Nutrition 0.000 claims description 19
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 claims description 17
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 claims description 17
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 13
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 13
- 238000004040 coloring Methods 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 8
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 description 5
- 235000000346 sugar Nutrition 0.000 description 5
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 4
- 239000008103 glucose Substances 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 3
- 235000013312 flour Nutrition 0.000 description 3
- 235000011194 food seasoning agent Nutrition 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 150000008163 sugars Chemical class 0.000 description 3
- AOFUBOWZWQFQJU-SNOJBQEQSA-N (2r,3s,4s,5r)-2,5-bis(hydroxymethyl)oxolane-2,3,4-triol;(2s,3r,4s,5s,6r)-6-(hydroxymethyl)oxane-2,3,4,5-tetrol Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O.OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@@H]1O AOFUBOWZWQFQJU-SNOJBQEQSA-N 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- 239000005696 Diammonium phosphate Substances 0.000 description 2
- 239000004278 EU approved seasoning Substances 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 241001098054 Pollachius pollachius Species 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 235000008429 bread Nutrition 0.000 description 2
- 235000014121 butter Nutrition 0.000 description 2
- 235000009508 confectionery Nutrition 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 2
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 2
- 235000019838 diammonium phosphate Nutrition 0.000 description 2
- 235000013601 eggs Nutrition 0.000 description 2
- 229960004903 invert sugar Drugs 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 239000002075 main ingredient Substances 0.000 description 2
- 235000020124 milk-based beverage Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 235000013379 molasses Nutrition 0.000 description 2
- 235000012149 noodles Nutrition 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 235000014102 seafood Nutrition 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- 241001417494 Sciaenidae Species 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical compound [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 235000014103 egg white Nutrition 0.000 description 1
- 210000000969 egg white Anatomy 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 235000012041 food component Nutrition 0.000 description 1
- 239000005417 food ingredient Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 235000008446 instant noodles Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 description 1
- 235000013923 monosodium glutamate Nutrition 0.000 description 1
- 239000004223 monosodium glutamate Substances 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 235000019640 taste Nutrition 0.000 description 1
- 229910000404 tripotassium phosphate Inorganic materials 0.000 description 1
- 235000019798 tripotassium phosphate Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Coloring Foods And Improving Nutritive Qualities (AREA)
Description
本発明は食品の着色方法に関する。
食品とくに水産ねり製品、パン・菓子類、めん
類、乳飲料、乳酸菌飲料などを、加熱工程中にお
いて糖類と食品に含まれるアミノ酸類とのいわゆ
るメイラード反応と称せられる褐変反応を利用し
て、褐色に着色して商品価値を高めることは公知
である。しかし近年、嗜好の変化や多様化などに
より、単に褐色に仕上げるだけでなく、黄色系統
に仕上げることも要望されるようになつてきた。
そのため新しい黄色系統の着色方法の出現が要望
されている。
本発明者らはこの実情に鑑み、黄色系統の中で
も最も好ましいと思われるつやのある黄金色に食
品を着色する方法について種々研究した結果、キ
シロースとマルトースを併用することにより、そ
の目的が達成されことを見出して本発明を完成す
るに至つた。
本発明は、食品の製造に際し、食品原料にキシ
ロースとマルトースを添加することを特徴とす
る、食品を黄色系統の色に着色する方法である。
従来食品に焼色をつける目的で、キシロース、
ぶどう糖、砂糖、転化糖、デキストリン、廃糖蜜
などの糖類が使用され、褐色化を促進していた。
しかしこれらの糖類の使用では褐色に仕上げるこ
とは容易であつても、黄色系統に仕上げることは
困難であつた。また黄色系統に仕上げ得た場合で
も、高価なキシロースを多量に要するなどのた
め、その費用が著しく増大し、経済性に乏しいな
どの欠点を有していた。
本発明によれば、食品に対してキシロースとマ
ルトースを併用添加することにより、従来のキシ
ロース、ぶどう糖、砂糖、転化糖、デキストリ
ン、廃糖蜜などを単用又は併用する方法では得ら
れなかつたつやのある黄金色に着色することがで
きる。そして本発明の方法は安易に着色できると
いう利点をも有する。本発明の方法による着色
は、おそらくキシロースの有する強く着色しうる
特性と、マルトースの有するうすく黄色に着色し
うる特性及びつやを付与しうる特性との相乗作用
により得られるものであろうと考えられる。
本発明を実施するに際しては、食品原料にキシ
ロースとマルトースを添加する。食品原料として
は、例えば水産ねり製品の主原料である魚肉すり
身及びこれに油脂類、殿粉、調味料、香辛料など
を配合した混合物、パン・菓子類、めん類などの
主原料である小麦粉及びこれにバター、卵、調味
料などを配合した混合物、殺菌、包装前の乳飲
料、乳酸菌飲料などがあげられる。
キシロースとマルトースの配合比率は、キシロ
ース1重量部に対してマルトース0.1〜20重量部、
特に0.2〜10重量部が好適である。そして両成分
を合わせて通常は食品原料に対し0.1〜5重量%、
特に0.2〜3重量%を添加することが好ましい。
なお着色を速めたり又は強くする目的で、前記の
両成分にさらにグルタミン酸又はそのナトリウム
塩、グリシン、リジン、アルギニンなどのアミノ
酸、燐酸二アンモニウム、燐酸三アンモニウム、
燐酸三カリウム、炭酸カリウムなどの塩類を添加
することもできる。これら成分は加熱工程以前の
任意の食品製造工程で食品原料に混合すればよ
い。各成分は液状、粉末、粒状その他任意の形状
で、あらかじめ各成分を予備的に混合するか又は
それぞれ単独で添加することができる。
次いでこの食品原料を必要に応じ成形したの
ち、好ましくは加熱処理することにより、食品を
つやのある黄色に着色することができる。通常は
食品を黄色に着色するための工程を設ける必要は
なく、食品の加工及び殺菌を目的とする加熱工程
によつて着色を促進することもできる。
実施例中の部及び%は、それぞれ重量部及び重
量%を意味する。
実施例 1
スケソウダラ冷凍すり身100部、食塩2.5部、グ
ルタミン酸ナトリウム0.5部、ばれいしよ殿粉7
部及び氷水30部を用い、これにキシロース0.2部
及びマルトース0.5部を添加して、常法により揚
げかまぼこを製造した。
得られた揚げかまぼこの着色状態を20名の審査
員により観察評価した。比較のために従来品であ
るキシロース0.4部、ぶどう糖4部又は市販製剤
(キシロース25%、燐酸二アンモニウム2%、ぶ
どう糖73%含有)0.7部を添加して、同じ方法に
より製造したかまぼこを用いた。評価結果を次表
に示す。つやのある黄金色を呈しているものを
「良い」とし、色調がそれに遠ざかる程度によつ
て「普通」あるいは「悪い」と評価した。
The present invention relates to a method for coloring foods. Foods, especially seafood paste products, breads, confectionery, noodles, milk drinks, lactic acid bacteria drinks, etc., can be browned during the heating process by utilizing the so-called Maillard reaction between sugars and amino acids contained in foods. It is known that coloring can be used to increase commercial value. However, in recent years, due to changes and diversification of tastes, there has been a demand for not only a brown finish but also a yellow finish.
Therefore, there is a demand for a new yellow-based coloring method. In view of this situation, the present inventors conducted various research on methods for coloring foods with a glossy golden color, which is considered to be the most desirable yellow color, and found that the purpose was achieved by using xylose and maltose together. This discovery led to the completion of the present invention. The present invention is a method for coloring foods in a yellowish color, which is characterized by adding xylose and maltose to food raw materials during the production of foods. Conventionally, xylose,
Sugars such as glucose, sugar, invert sugar, dextrin, and blackstrap molasses were used to promote browning.
However, with the use of these sugars, although it was easy to achieve a brown finish, it was difficult to achieve a yellowish finish. Furthermore, even if a yellow color can be achieved, the cost increases significantly due to the large amount of expensive xylose required, resulting in disadvantages such as poor economic efficiency. According to the present invention, by adding xylose and maltose together to foods, a glossy texture that cannot be obtained by conventional methods of using xylose, glucose, sugar, invert sugar, dextrin, blackstrap molasses, etc. alone or in combination can be obtained. It can be colored golden yellow. The method of the present invention also has the advantage of being easy to color. It is thought that the coloring achieved by the method of the present invention is probably achieved by the synergistic effect of the strong coloring property of xylose and the pale yellow coloring property and gloss-imparting property of maltose. When carrying out the present invention, xylose and maltose are added to food raw materials. Food raw materials include, for example, fish paste, which is the main ingredient in seafood paste products, and mixtures of this with oils and fats, starch, seasonings, spices, etc., and wheat flour, which is the main ingredient in breads, confectionery, noodles, etc. Examples include mixtures containing butter, eggs, seasonings, etc., milk drinks that have not been sterilized or packaged, and lactic acid bacteria drinks. The blending ratio of xylose and maltose is 0.1 to 20 parts by weight of maltose to 1 part by weight of xylose.
Particularly suitable is 0.2 to 10 parts by weight. The total amount of both ingredients is usually 0.1 to 5% by weight based on the food ingredients.
It is particularly preferable to add 0.2 to 3% by weight.
In addition, for the purpose of accelerating or intensifying coloring, in addition to the above-mentioned two components, glutamic acid or its sodium salt, amino acids such as glycine, lysine, and arginine, diammonium phosphate, triammonium phosphate,
Salts such as tripotassium phosphate and potassium carbonate can also be added. These components may be mixed with food raw materials in any food manufacturing process prior to the heating process. Each component can be in any form such as liquid, powder, or granule, and can be preliminarily mixed or added individually. Next, this food material is molded as necessary, and then preferably heat-treated, thereby making it possible to color the food product a glossy yellow color. Usually, there is no need to provide a process for coloring foods yellow, and coloring can be promoted by a heating process for the purpose of processing and sterilizing foods. Parts and % in the examples mean parts by weight and % by weight, respectively. Example 1 100 parts of frozen ground pollack, 2.5 parts of salt, 0.5 parts of monosodium glutamate, 7 parts of potato starch
0.2 parts of xylose and 0.5 parts of maltose were added to this to produce fried kamaboko in a conventional manner. The coloring state of the obtained fried kamaboko was observed and evaluated by 20 judges. For comparison, we used kamaboko prepared in the same manner with the addition of 0.4 parts of conventional products, 0.4 parts of xylose and 4 parts of glucose, or 0.7 parts of a commercial preparation (containing 25% xylose, 2% diammonium phosphate, and 73% glucose). . The evaluation results are shown in the table below. Those exhibiting a shiny golden color were rated as "good", and depending on the extent to which the color tone deviated from that, they were rated as "average" or "poor".
【表】
この結果から、本発明による製品は従来品を用い
た製品に比べて、きわめてすぐれた色調、すなわ
ちつやのある黄金色を呈することが認められた。
実施例 2
生魚肉(グチ、エソ)60部、スケソウダラ冷凍
すり身40部、殿粉10部、食塩3部、調味料1部、
卵白3部、砂糖4部及び氷水20部を用い、これに
キシロース0.2部及びマルトース1部を添加し、
常法によりちくわを製造した。本品はあざやかな
つやのある黄金色を呈した。
実施例 3
薄力粉100部、無塩バター30部、食塩0.6部、ベ
ーキングパウダー0.5部、全卵25部及び粉糖50部
を用い、これにキシロース0.5部及びマルトース
0.5部を添加し、混合して生地を整えたのち、160
℃で20分間焼成しててクツキーを製造した。本品
は均一でつやのある黄金色を呈した。
実施例 4
小麦粉100部、食塩1.5部、かんすい(固形物換
算)0.14部及び水33部を用い、これにキシロース
0.3部及びマルトース0.3部を添加して常法により
即席めんを製造した。本品はつやのある黄金色を
呈した。[Table] From the results, it was confirmed that the product according to the present invention exhibited an extremely superior color tone, that is, a glossy golden color, compared to products using conventional products. Example 2 60 parts of raw fish meat (croaker, eso), 40 parts of frozen ground pollack, 10 parts of starch, 3 parts of salt, 1 part of seasoning,
Using 3 parts of egg white, 4 parts of sugar, and 20 parts of ice water, add 0.2 part of xylose and 1 part of maltose,
Chikuwa was produced using a conventional method. This product had a bright, shiny golden color. Example 3 Using 100 parts of soft flour, 30 parts of unsalted butter, 0.6 parts of salt, 0.5 parts of baking powder, 25 parts of whole eggs and 50 parts of powdered sugar, to which 0.5 parts of xylose and maltose were added.
After adding 0.5 part and mixing to prepare the dough, 160
The kutsky was produced by baking at ℃ for 20 minutes. This product exhibited a uniform, glossy golden color. Example 4 Using 100 parts of wheat flour, 1.5 parts of salt, 0.14 parts of kansui (solid matter equivalent) and 33 parts of water, xylose was added to this.
Instant noodles were produced by a conventional method by adding 0.3 parts of maltose and 0.3 parts of maltose. This product had a shiny golden color.
Claims (1)
びマルトースを添加することを特徴とする、食品
を黄色系統の色に着色する方法。1. A method for coloring food in a yellowish color, which is characterized by adding xylose and maltose to food raw materials during food production.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56168735A JPS5871869A (en) | 1981-10-23 | 1981-10-23 | Coloring method for food product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56168735A JPS5871869A (en) | 1981-10-23 | 1981-10-23 | Coloring method for food product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5871869A JPS5871869A (en) | 1983-04-28 |
| JPH0158945B2 true JPH0158945B2 (en) | 1989-12-14 |
Family
ID=15873440
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56168735A Granted JPS5871869A (en) | 1981-10-23 | 1981-10-23 | Coloring method for food product |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5871869A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4953712B2 (en) * | 2006-07-13 | 2012-06-13 | サッポロビール株式会社 | Method for producing sparkling alcoholic beverage using Maillard reaction product and sparkling alcoholic beverage produced by the method |
| US8840943B2 (en) | 2007-04-06 | 2014-09-23 | Nestec S.A. | Multi-colored cake cones |
| KR20130064883A (en) * | 2011-12-09 | 2013-06-19 | 씨제이제일제당 (주) | Low calorie and fat contents cracker composition containing the xylose, and the cracker, and method for manufacturing the cracker |
-
1981
- 1981-10-23 JP JP56168735A patent/JPS5871869A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5871869A (en) | 1983-04-28 |
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