JPH02107634A - 変性ポリ（２，６―ジメチル―ｐ―オキシフェニレン） - Google Patents

変性ポリ（２，６―ジメチル―ｐ―オキシフェニレン）

Info

Publication number: JPH02107634A
Authority: JP; Japan
Prior art keywords: dimethyl; oxyphenylene; poly; producing; alkali metal
Prior art date: 1988-09-09
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP1231800A

Other languages

English (en)

Japanese (ja)

Inventor

Otello Farias

オテーロ・ファリーアス

Alberto Gandini

アルベルト・ガンディーニ

Raffaella Monga

ラッファエーラ・モンガ

Arnaldo Roggero

アルナルド・ロッジェロ

Raffaello Sisto

ラッファエーロ・シスト

Claudio Valentini

クラウディオ・バレンチーニ

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Eni Tecnologie SpA

Original Assignee

Eniricerche SpA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-09-09

Filing date

1989-09-08

Publication date

1990-04-19

1989-09-08 Application filed by Eniricerche SpA filed Critical Eniricerche SpA

1990-04-19 Publication of JPH02107634A publication Critical patent/JPH02107634A/ja

Status Pending legal-status Critical Current

Links

229920000642 polymer Polymers 0.000 claims abstract description 19
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 9
229910052783 alkali metal Inorganic materials 0.000 claims abstract description 7
239000003795 chemical substances by application Substances 0.000 claims abstract description 7
230000009477 glass transition Effects 0.000 claims abstract description 6
239000003960 organic solvent Substances 0.000 claims abstract description 6
150000001408 amides Chemical class 0.000 claims abstract description 4
150000001340 alkali metals Chemical class 0.000 claims abstract description 3
239000012442 inert solvent Substances 0.000 claims abstract 2
239000012528 membrane Substances 0.000 claims description 39
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
238000004519 manufacturing process Methods 0.000 claims description 11
238000000926 separation method Methods 0.000 claims description 11
239000002904 solvent Substances 0.000 claims description 11
238000006263 metalation reaction Methods 0.000 claims description 8
238000000034 method Methods 0.000 claims description 8
AVQQQNCBBIEMEU-UHFFFAOYSA-N 1,1,3,3-tetramethylurea Chemical compound CN(C)C(=O)N(C)C AVQQQNCBBIEMEU-UHFFFAOYSA-N 0.000 claims description 4
239000012190 activator Substances 0.000 claims description 4
238000005345 coagulation Methods 0.000 claims description 4
230000015271 coagulation Effects 0.000 claims description 4
KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 claims description 3
FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical group CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 3
229910000102 alkali metal hydride Inorganic materials 0.000 claims description 3
150000008046 alkali metal hydrides Chemical class 0.000 claims description 3
239000011541 reaction mixture Substances 0.000 claims description 3
239000000126 substance Substances 0.000 claims description 3
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims description 2
FEWLNYSYJNLUOO-UHFFFAOYSA-N 1-Piperidinecarboxaldehyde Chemical compound O=CN1CCCCC1 FEWLNYSYJNLUOO-UHFFFAOYSA-N 0.000 claims description 2
NFDXQGNDWIPXQL-UHFFFAOYSA-N 1-cyclooctyldiazocane Chemical compound C1CCCCCCC1N1NCCCCCC1 NFDXQGNDWIPXQL-UHFFFAOYSA-N 0.000 claims description 2
SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
239000012973 diazabicyclooctane Substances 0.000 claims description 2
229910052744 lithium Inorganic materials 0.000 claims description 2
LCEDQNDDFOCWGG-UHFFFAOYSA-N morpholine-4-carbaldehyde Chemical compound O=CN1CCOCC1 LCEDQNDDFOCWGG-UHFFFAOYSA-N 0.000 claims description 2
229910052700 potassium Inorganic materials 0.000 claims description 2
239000011591 potassium Substances 0.000 claims description 2
229910052751 metal Inorganic materials 0.000 claims 1
239000002184 metal Substances 0.000 claims 1
230000035699 permeability Effects 0.000 abstract description 12
229940117927 ethylene oxide Drugs 0.000 abstract 2
150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
239000007795 chemical reaction product Substances 0.000 abstract 1
239000004721 Polyphenylene oxide Substances 0.000 description 43
229920006380 polyphenylene oxide Polymers 0.000 description 43
239000007789 gas Substances 0.000 description 14
MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 10
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 8
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 8
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
239000011521 glass Substances 0.000 description 6
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
239000000178 monomer Substances 0.000 description 6
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
238000007306 functionalization reaction Methods 0.000 description 4
239000000203 mixture Substances 0.000 description 4
229910002092 carbon dioxide Inorganic materials 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
238000000614 phase inversion technique Methods 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 description 2
238000005481 NMR spectroscopy Methods 0.000 description 2
KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
238000007796 conventional method Methods 0.000 description 2
238000004090 dissolution Methods 0.000 description 2
239000000463 material Substances 0.000 description 2
238000000691 measurement method Methods 0.000 description 2
238000001465 metallisation Methods 0.000 description 2
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
239000002798 polar solvent Substances 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
239000000725 suspension Substances 0.000 description 2
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
238000002834 transmittance Methods 0.000 description 2
UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
WWSJZGAPAVMETJ-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-3-ethoxypyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C(=NN(C=1)CC(=O)N1CC2=C(CC1)NN=N2)OCC WWSJZGAPAVMETJ-UHFFFAOYSA-N 0.000 description 1
241000283153 Cetacea Species 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
244000043261 Hevea brasiliensis Species 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical group [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
229920000265 Polyparaphenylene Polymers 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000000010 aprotic solvent Substances 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229920005549 butyl rubber Polymers 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229920002301 cellulose acetate Polymers 0.000 description 1
239000000701 coagulant Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
150000004699 copper complex Chemical class 0.000 description 1
238000000151 deposition Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
239000012154 double-distilled water Substances 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
239000000806 elastomer Substances 0.000 description 1
210000002257 embryonic structure Anatomy 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
238000007654 immersion Methods 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229920001684 low density polyethylene Polymers 0.000 description 1
239000004702 low-density polyethylene Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
229920003052 natural elastomer Polymers 0.000 description 1
229920001194 natural rubber Polymers 0.000 description 1
239000012454 non-polar solvent Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000012466 permeate Substances 0.000 description 1
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
229920000515 polycarbonate Polymers 0.000 description 1
239000004417 polycarbonate Substances 0.000 description 1
229920006254 polymer film Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
-1 polyphenylene Polymers 0.000 description 1
229920013637 polyphenylene oxide polymer Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
239000000047 product Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
229920002379 silicone rubber Polymers 0.000 description 1
239000004945 silicone rubber Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/48—Polymers modified by chemical after-treatment
- C08G65/485—Polyphenylene oxides
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/52—Polyethers
- B01D71/522—Aromatic polyethers
- B01D71/5223—Polyphenylene oxide, phenyl ether polymers or polyphenylethers

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Separation Using Semi-Permeable Membranes (AREA)
Polyethers (AREA)

JP1231800A 1988-09-09 1989-09-08 変性ポリ（２，６―ジメチル―ｐ―オキシフェニレン） Pending JPH02107634A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
IT21875A/88		1988-09-09
IT8821875A IT1227052B (it)	1988-09-09	1988-09-09	Poli(2,6 dimetil p ossifenilene)modificato, procedimento per la sua preparazione e utilizzazione in membrane per la separazione dei gas .

Publications (1)

Publication Number	Publication Date
JPH02107634A true JPH02107634A (ja)	1990-04-19

Family

ID=11188087

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP1231800A Pending JPH02107634A (ja)	1988-09-09	1989-09-08	変性ポリ（２，６―ジメチル―ｐ―オキシフェニレン）

Country Status (4)

Country	Link
US (1)	US5019631A (fr)
EP (1)	EP0360318A1 (fr)
JP (1)	JPH02107634A (fr)
IT (1)	IT1227052B (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1230748B (it) *	1989-07-11	1991-10-29	Eniricerche Spa	Poli(2,6 dimetil-p-ossifenilene modificato), procedimento per la sua preparazione e suo impiego in membrane per la separazione di miscele gassose.
IT1238693B (it) *	1990-02-16	1993-09-01	Montedipe Srl	Mescole a base di polimeri vinilaromatici ad elevate caratteristiche meccaniche
US5120800A (en) *	1990-04-10	1992-06-09	Mitsubishi Petrochemical Co., Ltd.	Process for preparing modified-polyphenylene ether
EP0517017A3 (fr) *	1991-06-07	1993-01-07	Mitsubishi Chemical Corporation	Composition de résine thermoplastique
IT1248093B (it) *	1991-06-20	1995-01-05	Eniricerche Spa	Fibre cave in poli(2,6-dimetil-p-ossifenilene) modificato

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3442858A (en) *	1967-10-05	1969-05-06	Gen Electric	Products obtained by cleaving polyphenylene ethers
US3402144A (en) *	1967-10-05	1968-09-17	Gen Electric	Alkali metal-containing polyphenylene ethers
US3522326A (en) *	1967-10-05	1970-07-28	Gen Electric	Graft copolymers of polyphenylene ethers
US4647297A (en) *	1983-06-30	1987-03-03	Monsanto Company	Benzyl substituted phenylene oxide membrane
EP0256530B1 (fr) *	1986-08-14	1991-04-10	Toray Industries, Inc.	Membrane de séparation de gaz

1988
- 1988-09-09 IT IT8821875A patent/IT1227052B/it active
1989
- 1989-08-21 US US07/396,944 patent/US5019631A/en not_active Expired - Fee Related
- 1989-08-31 EP EP89202195A patent/EP0360318A1/fr not_active Withdrawn
- 1989-09-08 JP JP1231800A patent/JPH02107634A/ja active Pending

Also Published As

Publication number	Publication date
IT8821875A0 (it)	1988-09-09
US5019631A (en)	1991-05-28
IT1227052B (it)	1991-03-14
EP0360318A1 (fr)	1990-03-28

Publication	Publication Date	Title
EP0265899B1 (fr)	1991-04-24	Membranes pour la séparation de gaz de polyimide réticulé
Du et al.	2012	Polymers of intrinsic microporosity (PIMs) substituted with methyl tetrazole
US4657564A (en)	1987-04-14	Fluorinated polymeric membranes for gas separation processes
US5725633A (en)	1998-03-10	Sulfonated polyimide gas separation membranes
US8814982B2 (en)	2014-08-26	Tetrazole functionalized polymer membranes
Zhu et al.	2021	One-step synthesis of hydroxyl-functionalized fully carbon main chain PIMs via a Friedel-Crafts reaction for efficient gas separation
US9238202B2 (en)	2016-01-19	Gas separation membranes from chemically and UV treated polymers of intrinsic microporosity
JPH04277024A (ja)	1992-10-02	所定のスルホン化された置換ポリスルホンポリマーをベースにした半透膜
WO2019090140A1 (fr)	2019-05-09	Poly(éthers-couronnes) liés à la base de tröger
EP0426118A2 (fr)	1991-05-08	Membranes en polysulfone sulfoné à abase de hexafluorobisphénol-A et procédé de séparation de fluides
JPH0910567A (ja)	1997-01-14	新規なスルホン化ポリイミド気体分離膜
SU1741609A3 (ru)	1992-06-15	Способ получени полимерной мембраны дл разделени газовых смесей
JP2015073980A (ja)	2015-04-20	ガス分離膜およびガス分離膜モジュール
Percec	1987	Chemical modification of poly (2, 6‐dimethyl‐1, 4‐phenylene oxide) by friedel–crafts reactions
Huertas et al.	2012	Preparation and gas separation properties of partially pyrolyzed membranes (PPMs) derived from copolyimides containing polyethylene oxide side chains
JPH02107634A (ja)	1990-04-19	変性ポリ（２，６―ジメチル―ｐ―オキシフェニレン）
JPH0768143A (ja)	1995-03-14	新規なポリイミドおよびそれから製造した気体分離膜
Houde et al.	1994	Sorption, transport, and history effects in phenolphthalein-based polysulfone
WO2006001907A1 (fr)	2006-01-05	Membranes de phosphazene pour des separations gazeuses
Ekinci et al.	2006	Preparation and Characterization of an Aromatic Polyimide and Its Use as a Selective Membrane for H_2O_2
US20180339275A1 (en)	2018-11-29	Gas separation membrane, gas separation module, gas separator, and gas separation method
US5171794A (en)	1992-12-15	Modified poly(2,6-dimethyl-p-oxyphenylene), a process for its preparation and its use in gas mixture separation membranes
US5169416A (en)	1992-12-08	Process for preparing modified poly-(2,6-dimethyl-p-oxyphenylene)
JP5833986B2 (ja)	2015-12-16	ガス分離複合膜、その製造方法、それを用いたガス分離モジュール、及びガス分離装置、並びにガス分離方法
JPH04108828A (ja)	1992-04-09	無定形の変性ポリ−（２，６−ジメチル−ｐ−オキシフェニレン）